CN109180147A - Ink-jet seeps flower Ceramic Tiles ink-jet infiltration flower blank and helps toner and its application method - Google Patents

Ink-jet seeps flower Ceramic Tiles ink-jet infiltration flower blank and helps toner and its application method Download PDF

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Publication number
CN109180147A
CN109180147A CN201811130208.XA CN201811130208A CN109180147A CN 109180147 A CN109180147 A CN 109180147A CN 201811130208 A CN201811130208 A CN 201811130208A CN 109180147 A CN109180147 A CN 109180147A
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ink
flower
jet
ceramic tiles
toner
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王正旺
江洪
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Guangdong Qing Porcelain New Material Technology Co Ltd
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Guangdong Qing Porcelain New Material Technology Co Ltd
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Priority to CN201811130208.XA priority Critical patent/CN109180147A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3232Titanium oxides or titanates, e.g. rutile or anatase
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite

Abstract

The present invention relates to ceramic ink jet printing technical fields, specifically provide a kind of ink-jet and seep flower Ceramic Tiles ink-jet and seep flower blank and help toner and its application method.It is described to help toner at least one of alpha-type aluminum oxide, aluminium hydroxide.After the assistant toner is mixed with Ceramic Tiles fabric, ink is spent using infiltration and ink bleed water is helped to decorate it, and by calcining, polishing treatment, acquisition seeps flower Ceramic Tiles with the consistent ink-jet of color development, color development weight is stablized, therefore is suitble to popularization and application.

Description

Ink-jet seeps flower Ceramic Tiles ink-jet infiltration flower blank and helps toner and its application method
Technical field
Flower Ceramic Tiles ink-jet, which is seeped, the invention belongs to ceramic ink jet printing technical field more particularly to a kind of ink-jet seeps flower blank Help toner and its application method.
Background technique
Polished bricks are the surfaces of all-body tile green body by a kind of brick of light made of polishing, belong to one kind of all-body tile, Due to its relative to all-body tile have surface is more smooth, more high rigidity, more preferable wearability and be widely used.Skill is spent by seeping Art can be formed on its surface imitative stone, imitation wood and other effects, can be used in the decoration of toilet, kitchen, interior space etc..
In recent years, rich and varied decoration technique greatly improves the decorative effect of Ceramic Tiles, is especially known as ceramics The all-round popularization application of the inkjet printing technology of industry third time decoration technique revolution, so that ceramic brick product pattern is more rich It is rich, true to nature, personalized and rich in unlimited creativity.
Wherein, ceramic ink jet printing technology is a kind of ceramic surface decoration technique, is only applicable to wall brick and Antique Imitation Tiles field. Since polished bricks need to carry out rubbing down to surface after firing, existing ceramic ink jet printing technology can not be applied, so that at present Most polished bricks are also to rely on cloth system, lead to that its pattern is relatively easy, texture slightly shows rough.
It is a kind of osmosis type ink that ceramic ink jet, which seeps flower ink, is primarily referred to as organic metal salt (as colorant) and is dissolved in Be prepared in solvent can on ceramic matrix color development a kind of ink, such ink is permeable to base-material by bleeding agent The depth of 0.6~1.0mm, after firing, colorant is converted into the metal oxide that color can be presented at high temperature, forms figure Case.Ceramic Tiles after polishing also can sufficiently show bright in luster, texture naturally, the strong characteristic of three-dimensional sense.Both polishing had been remained The original various aspects excellent properties of brick, the decoration for also greatly enriching polished bricks by the application of inkjet printing technology is horizontal, Further improve the competitiveness and vitality of polished bricks.Therefore, seeping flower ink has following four big advantages: (1) ceramic tile pattern Three-dimensional sense is stronger, and surface texture can be more fine and smooth true to nature, close to the texture of lithotome;(2) solve ordinary ink it is red, The problem of the colors color development such as grey, black;(3) it keeps the pattern textures of polished bricks more abundant, and Mohs' hardness reached 5.5~ 6, it is more wear-resisting than currently popular full throwing glaze;(4) common polished bricks want the original of jettisoning ceramic tile surface 1mm or more in polishing Material, and the use of the polishing thickness for seeping flower the produced polished bricks of ink is about 0.1~0.3mm, it is thick to significantly reduce polishing Degree, reduces the discharge of solid waste, waste residue.Metal oxide meeting and face but in the sintering process of ceramic tile, in ink A series of chemical reaction occurs for layer green body ingredient, so that metal oxide color development is unstable or even is unable to color development, it is especially red Color and yellow.For this problem, the chromophoric mechanism from metal oxide is needed, some additives are increased, it can be to color development Metal oxide is implemented to stablize reaction, to ensure that metal oxide can stablize colour generation at high temperature.Such as Publication No. The Chinese patent of CN105000915A discloses the application that a kind of superfine silicon dioxide seeps flower Ceramic Tiles toner as ink-jet, specifically It is that ultra-fine porous silica is added in Ceramic Tiles overglaze or fabric butt, superfine silicon dioxide is evenly distributed on Ceramic Tiles face In glaze or fabric, when ceramic ink jet seeps flower ink spraying in ceramic brick surface, it is close that infiltration flower ink penetrates into superfine silicon dioxide In the hole configurations of collection, with the raising of firing temperature, the organic salt in infiltration flower ink, which is decomposed into metal oxide, to be continued to stay in In superfine silicon dioxide duct.Since silica has biggish specific surface area and higher sintering activity, with firing temperature Degree further increases, and superfine silicon dioxide particle is gradually sintered before red and yellow metal oxide decomposes, thus It realizes effective cladding to color development metal oxide, high-temperature calcination environment is avoided to issue non-ferrous metal oxide and ceramic body generation Reaction, is reduced or is converted to other substances, to guarantee that color development metal oxide can stablize colour generation at high temperature.But two The additive amount of silica is limited to be usually no more than 5%, and otherwise will destroy original blank structure can not produce.Therefore the depth of color development Limited to, it is difficult to meet the needs of color development.It can be to the flowing of slurry adding ultra-fine porous silica on a small quantity Property etc. generate deleterious effect, and as silica dispersing uniformity in the slurry is different, the final depth for influencing color development It is shallow also unstable.
Summary of the invention
Flower Ceramic Tiles ink-jet infiltration flower blank, which is seeped, the purpose of the present invention is to provide a kind of ink-jet helps toner and its application method, It aims to solve the problem that existing ink-jet permeates to spend Ceramic Tiles existing color development when using flower ink is seeped unstable or even be unable to color development etc. to ask Topic.
The present invention is implemented as follows:
A kind of ink-jet, which seeps flower Ceramic Tiles ink-jet and seeps flower blank, helps toner, and described to help toner be alpha-type aluminum oxide, in aluminium hydroxide At least one.
Correspondingly, the flower hyperchromic blank of Ceramic Tiles is seeped in a kind of ink-jet, and the hyperchromic blank is described to help the toner to be containing helping toner Described above helps toner.
And a kind of ink-jet seeps flower Ceramic Tiles ink-jet and seeps the application method that flower blank helps toner, at least includes the following steps:
It helps toner to be added in Ceramic Tiles fabric for described, obtains the hyperchromic blank of Ceramic Tiles;
The hyperchromic blank of the Ceramic Tiles is imposed on into ceramic brick surface, and using infiltration flower ink and helps ink bleed water to the ceramics Brick carries out decoration processing;
The resulting Ceramic Tiles of decoration processing are calcined, are polished, ink-jet is obtained and seeps flower Ceramic Tiles.
Beneficial effects of the present invention are as follows:
Compared with the existing technology, the ingredient provided by the invention for helping toner is alpha-type aluminum oxide or aluminium hydroxide, in Ceramic Tiles All become alpha-type aluminum oxide in calcination process, and alpha-type aluminum oxide can with seep metal salt in flower ink decompose the chromium generated, manganese, Solid phase reaction occurs for the metal oxides such as iron, titanium, to generate red or yellow color development, guarantees color development metal oxide in height Colour generation can be stablized under temperature, and colour generation depth consistency is good.
The flower hyperchromic blank of Ceramic Tiles is seeped in ink-jet provided by the invention, due to described helping color containing aforementioned in hyperchromic blank Powder can occur solid phase reaction with the color development metal oxide for seeping flower ink generation in calcining, obtain stable hair color effect, And colour generation depth consistency is good.
Ink-jet provided by the invention seeps flower Ceramic Tiles ink-jet and seeps the application method that flower blank helps toner, helps toner calcined Cheng Zhong, alpha-type aluminum oxide therein can decompose the generation of the metal oxides such as chromium, manganese, iron, the titanium generated with metal salt in flower ink is seeped Solid phase reaction guarantees that color development metal oxide can stablize colour generation at high temperature to generate red or yellow color development, and its In aluminium hydroxide also generate alpha-type aluminum oxide in calcining, same realize stablizes colour generation, due to seeping flower ink bleed depth one It causes, Ceramic Tiles is finally made to show the good feature of colour generation depth consistency.
Specific embodiment
In order to which technical problems, technical solutions and advantageous effects to be solved by the present invention are more clearly understood, below in conjunction with Embodiment, the present invention will be described in further detail.It should be appreciated that specific embodiment described herein is only used to explain The present invention is not intended to limit the present invention.
The present invention, which provides a kind of ink-jet, seeps flower Ceramic Tiles ink-jet and seeps flower blank and help toner.
It is described to help toner at least one of alpha-type aluminum oxide, aluminium hydroxide.
It has been investigated that alpha-type aluminum oxide seeps in flower processing sintering process in the ink-jet that flower Ceramic Tiles are seeped in ink-jet, with organic salt Solid phase reaction occurs for the metal oxides such as color development metal oxide such as chromium, manganese, iron, titanium that metal generates, thus generate it is red or The hair color effect of person's yellow.Specifically, it is red that sending is reacted with chromium metal oxide, manganese Metal oxide, aluminum metal oxide Color and issue yellow with the reactive aluminum in ferroelectric metal oxide, titanium oxide and green body, and color development stability is very Well.It therefore, can be using alpha-type aluminum oxide as helping toner.And in Ceramic Tiles firing, it is contemplated that temperature is generally more than 950 DEG C, More than this temperature, aluminium hydroxide can be sintered into alpha-type aluminum oxide, therefore, provided by the present invention to help toner for α type oxygen Change at least one of aluminium, aluminium hydroxide, can be and only contain alpha-type aluminum oxide, be also possible to only contain aluminium hydroxide, either Alpha-type aluminum oxide and aluminium hydroxide exist simultaneously, and when helping toner is the mixture of the two, the ratio of the two is not wanted particularly It asks, only in Ceramic Tiles sintering process, pays particular attention to its firing temperature and at least need more than 950 DEG C.
In addition, assistant toner is also possible to desiliconization aluminium powder.
Preferably, the present invention helps the partial size of toner no more than 50 μm, that is, can pass through the sieve not less than 300 mesh. Partial size is excessive, and the metal oxide that can not be generated completely with organic metal salt thoroughly reacts, and causes that toner is helped to waste, is unfavorable for It makes full use of and helps toner.
It is further preferred that helping the partial size of toner is 6.5~23 μm, that is, by the screenings of 600 mesh after 2000 mesh Sieve, take the oversize of 2000 mesh.
Preferably, the mass ratio for helping toner shared in Ceramic Tiles fabric butt is 1~30%.Here fabric is dry Base refers to moisture free Ceramic Tiles fabric.Help toner content too low, with the color development reactive metal oxide amount for seeping flower ink Deficiency, hair color effect is unobvious, and if too high levels, color development metal oxide amount is insufficient, causes that toner is helped to waste.
The present invention also provides a kind of ink-jets to seep the flower hyperchromic blank of Ceramic Tiles as a result, which seeps the flower hyperchromic blank of Ceramic Tiles In containing it is aforementioned it is described help toner, that is, it is at least one of alpha-type aluminum oxide, aluminium hydroxide that this, which helps toner,.The ink-jet Ceramic brick surface can be applied to by seeping the flower hyperchromic blank of Ceramic Tiles, then is carried out seeping colored ink and helped the inkjet printing of ink bleed water, be passed through Calcining, polishing treatment can be obtained with the Ceramic Tiles for stablizing color development.
Preferably, the ink-jet is seeped in the flower hyperchromic blank of Ceramic Tiles, helps the mass content of toner not less than 1%.If contained Amount is lower than 1%, then subsequent insufficient with the amount for the color development reactive metal oxide for seeping flower ink, hair color effect is unobvious.
It is further preferred that the mass content for helping toner is 1~30%, too high levels cause that toner is helped to waste, and And ink-jet is seeped the hyperchromic blank adhesiveness of flower Ceramic Tiles and is reduced.
The flower hyperchromic blank of Ceramic Tiles is seeped in the ink-jet, due to containing helping at least one of alpha-type aluminum oxide, aluminium hydroxide Toner effectively can occur solid phase reaction with the color development metal oxide for seeping flower ink generation, keep color development golden in calcination process Belong to oxide and realizes stable color development.
Under the premise of ink-jet above-mentioned seeps flower Ceramic Tiles ink-jet infiltration flower blank and helps toner, the present invention furthermore provides this Help the application method of toner.
In one embodiment, this help the application method of toner the following steps are included:
(1) helps toner to be added in Ceramic Tiles fabric for described, and the two carries out mixing treatment, obtains the hyperchromic blank of Ceramic Tiles;
(2) the hyperchromic blank of the Ceramic Tiles can be imposed on ceramic brick surface by leaching slurry processes or half dry pressing by, be obtained Surface is attached with the Ceramic Tiles of the hyperchromic blank of Ceramic Tiles;
(3) seeps flower ink using ceramic ink jet printer spraying and helps ink bleed water, makes to seep colored ink and helps ink bleed water to institute Ceramic Tiles are stated to be decorated;
(4) handles resulting Ceramic Tiles to decoration and carries out calcination processing, subsequent polished place at 950~1300 DEG C Reason obtains ink-jet and seeps flower Ceramic Tiles.
In above-mentioned application process, alpha-type aluminum oxide or aluminium hydroxide with reactivity work as pottery in Ceramic Tiles fabric Porcelain ink-jet seeps flower ink spraying in ceramic brick surface, seep flower ink penetrate into green body and with alpha-type aluminum oxide therein or Aluminium hydroxide contact, with the raising of calcination temperature, the organic metal salt seeped in flower ink resolves into metal oxide, with green body In dissociate alpha-type aluminum oxide or aluminium hydroxide decompose generate alpha-type aluminum oxide carry out solid phase reaction.Since alpha-type aluminum oxide has There is higher sintering activity, with further increasing for calcination temperature, alpha-type aluminum oxide and the chromium, manganese, iron, the titanium that touch etc. are golden Belong to oxide and solid phase reaction occurs, to generate red and yellow color development, ensure that color development metal can be stablized at high temperature Colour generation.
Infiltration flower ink of the present invention is ionic liquid ink, and color development metallic element therein is gone out with ionic forms It is existing, ceramic green surface layer can be infiltrated through;Helping ink bleed water to refer to can help to permeate what ink was further permeated into ceramic green Ink, itself not color development, only assist infiltration ink seep deeper into.
The present invention also obtains a kind of ink-jet infiltration flower Ceramic Tiles as a result,.Specifically, which seeps flower Ceramic Tiles in process In, when decoration, the material used contains the toner that helps of the invention, and its processing method includes that flower Ceramic Tiles spray is seeped in above-mentioned ink-jet Ink seeps the application method step that flower blank helps toner.Flower Ceramic Tiles are seeped in thus obtained ink-jet, and color development is stable, color development weight is equal One, and there is good imitative stone, imitation wood, 3D and other effects.
Technical solution in order to better illustrate the present invention, is illustrated combined with specific embodiments below.
Embodiment 1
A kind of ink-jet, which seeps flower Ceramic Tiles ink-jet and seeps flower blank, helps toner, and it is aluminium hydroxide that this, which helps the ingredient of toner, and the hydrogen Aluminium oxide crosses 400 mesh.
It is as follows based on the processing method for helping the ink-jet of toner to seep flower Ceramic Tiles:
(1) toner is helped to mix with Ceramic Tiles fabric in aluminium hydroxide, it is described that the aluminium hydroxide of addition helps the quality of toner to account for The 15% of Ceramic Tiles fabric butt;Ceramic Tiles upper surface is then imposed in such a way that base bottom is successively pressed into, and passes through ceramics spray Black printer spraying seeps flower ink and ink bleed water is helped to decorate Ceramic Tiles;Wherein, the Ceramic Tiles fabric butt is main Ingredient are as follows: kaolin 10%, ball clay 10%, raw ore mud 15%, bentonite 5%, albite 25%, potassium feldspar 15%, Weathered Sand 15%, talcum 3%, titanium dioxide 2%.
(2) Ceramic Tiles that step (1) obtains are placed in polishing brick kiln and are calcined, calcination temperature is 950~1300 DEG C, continuous roller kilns, burnout cycle 75min, with furnace temperature natural cooling after calcining.
(3) Ceramic Tiles in step (2) are processed by shot blasting using polishing machine, finished product is made.
Embodiment 2
A kind of ink-jet, which seeps flower Ceramic Tiles ink-jet and seeps flower blank, helps toner, and it is aluminium hydroxide, hydroxide that this, which helps the ingredient of toner, Aluminium crosses 1500 mesh.
It is as follows based on the processing method for helping the ink-jet of toner to seep flower Ceramic Tiles:
(1) toner is helped to mix with Ceramic Tiles fabric in aluminium hydroxide, it is described that the aluminium hydroxide of addition helps the quality of toner to account for The 10% of Ceramic Tiles fabric butt;Ceramic Tiles upper surface is then imposed in such a way that base bottom is successively pressed into, and passes through ceramics spray Black printer spraying seeps flower ink and ink bleed water is helped to decorate Ceramic Tiles;Wherein, the Ceramic Tiles fabric butt is main Ingredient are as follows: kaolin 15%, ball clay 5%, raw ore mud 15%, bentonite 10%, albite 20%, potassium feldspar 20%, Weathered Sand 10%, talcum 2.5%, titanium dioxide 2.5%.
(2) Ceramic Tiles that step (1) obtains are placed in polishing brick kiln and are calcined, calcination temperature is 950~1300 DEG C, burnout cycle 75min, with furnace temperature natural cooling after calcining.
(3) Ceramic Tiles in step (2) are processed by shot blasting using polishing machine, finished product is made.
Embodiment 3
A kind of ink-jet, which seeps flower Ceramic Tiles ink-jet and seeps flower blank, helps toner, and it is alpha-type aluminum oxide that this, which helps the ingredient of toner, and mistake The processing of 800 meshes.
It is as follows based on the processing method for helping the ink-jet of toner to seep flower Ceramic Tiles:
(1) toner is helped to mix with Ceramic Tiles fabric alpha-type aluminum oxide, the alpha-type aluminum oxide of addition helps the quality of toner to account for institute State the 6% of Ceramic Tiles fabric butt;Ceramic Tiles upper surface is then imposed in such a way that base bottom is successively pressed into, and passes through ceramics spray Black printer spraying seeps flower ink and ink bleed water is helped to decorate Ceramic Tiles;Wherein, the Ceramic Tiles fabric butt is main Ingredient are as follows: kaolin 5%, ball clay 25%, raw ore mud 5%, bentonite 10%, albite 20%, potassium feldspar 5%, Weathered Sand 25%, talcum 2.0%, titanium dioxide 3%.
(2) Ceramic Tiles that step (1) obtains are placed in polishing brick kiln and are calcined, calcination temperature is 950~1300 DEG C, burnout cycle 75min, with furnace temperature natural cooling after calcining.
(3) Ceramic Tiles in step (2) are processed by shot blasting using polishing machine, finished product is made.
Embodiment 4
A kind of ink-jet, which seeps flower Ceramic Tiles ink-jet and seeps flower blank, helps toner, and it is that alpha-type aluminum oxide forms that this, which helps the ingredient of toner, mistake 1500 mesh.
It is as follows based on the processing method for helping the ink-jet of toner to seep flower Ceramic Tiles:
(1) toner is helped to mix with Ceramic Tiles fabric alpha-type aluminum oxide, the alpha-type aluminum oxide of addition helps the quality of toner to account for institute State the 2% of Ceramic Tiles fabric butt;Ceramic Tiles upper surface is then imposed in such a way that base bottom is successively pressed into, and passes through ceramics spray Black printer spraying seeps flower ink and ink bleed water is helped to decorate Ceramic Tiles;Wherein, the Ceramic Tiles fabric butt is main Ingredient are as follows: kaolin 28%, ball clay 5%, raw ore mud 5%, bentonite 5%, albite 30%, potassium feldspar 5%, Weathered Sand 15%, talcum 5%, titanium dioxide 2%.
(2) Ceramic Tiles that step (1) obtains are placed in polishing brick kiln and are calcined, calcination temperature is 950~1300 DEG C, burnout cycle 75min, with furnace temperature natural cooling after calcining.
(3) Ceramic Tiles in step (2) are processed by shot blasting using polishing machine, finished product is made.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.

Claims (10)

1. a kind of ink-jet seeps flower Ceramic Tiles ink-jet and seeps flower blank and helps toner, which is characterized in that it is described help toner be alpha-type aluminum oxide, At least one of aluminium hydroxide.
2. flower Ceramic Tiles ink-jet infiltration flower blank is seeped in ink-jet as described in claim 1 helps toner, which is characterized in that described to help toner Partial size be not more than 50 μm.
3. flower Ceramic Tiles ink-jet infiltration flower blank is seeped in ink-jet as described in claim 1 helps toner, which is characterized in that described to help toner Shared mass ratio is 1~30% in Ceramic Tiles fabric butt.
4. flower Ceramic Tiles ink-jet infiltration flower blank is seeped in ink-jet as described in claim 1 helps toner, which is characterized in that described to help toner When containing aluminium hydroxide, the calcination processing by 950~1300 DEG C of temperature is needed in use.
5. the flower hyperchromic blank of Ceramic Tiles is seeped in a kind of ink-jet, which is characterized in that the hyperchromic blank, which contains, helps toner, described to help toner Toner is helped for Claims 1 to 4 is described in any item.
6. the flower hyperchromic blank of Ceramic Tiles is seeped in ink-jet as claimed in claim 5, which is characterized in that the mass content for helping toner Not less than 1%.
7. a kind of seep the application side that flower Ceramic Tiles ink-jet infiltration flower blank helps toner such as the described in any item ink-jets of Claims 1 to 4 Method, which is characterized in that at least include the following steps:
It helps toner to be added in Ceramic Tiles fabric for described, obtains the hyperchromic blank of Ceramic Tiles;
The hyperchromic blank of the Ceramic Tiles is imposed on into ceramic brick surface, and using seep flower ink and help ink bleed water to the Ceramic Tiles into The processing of luggage decorations;
The resulting Ceramic Tiles of decoration processing are calcined, are polished, ink-jet is obtained and seeps flower Ceramic Tiles.
8. ink-jet as claimed in claim 7 seeps flower Ceramic Tiles ink-jet and seeps the application method that flower blank helps toner, which is characterized in that It is described to help mass content of the toner in Ceramic Tiles fabric not less than 1%.
9. ink-jet as claimed in claim 7 seeps flower Ceramic Tiles ink-jet and seeps the application method that flower blank helps toner, which is characterized in that The calcination temperature is 950~1300 DEG C.
10. flower Ceramic Tiles are seeped in a kind of ink-jet, which is characterized in that the ink-jet is seeped flower Ceramic Tiles and obtained by the method for claim 7~9 ?.
CN201811130208.XA 2018-09-27 2018-09-27 Ink-jet seeps flower Ceramic Tiles ink-jet infiltration flower blank and helps toner and its application method Pending CN109180147A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113800954A (en) * 2021-09-29 2021-12-17 清远顺昌陶瓷有限公司 Ink-jet printing process for polished tiles

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Application publication date: 20190111