CN105451896B - 具有附加的单色辐照源的紫外线辐照装置 - Google Patents
具有附加的单色辐照源的紫外线辐照装置 Download PDFInfo
- Publication number
- CN105451896B CN105451896B CN201480029899.8A CN201480029899A CN105451896B CN 105451896 B CN105451896 B CN 105451896B CN 201480029899 A CN201480029899 A CN 201480029899A CN 105451896 B CN105451896 B CN 105451896B
- Authority
- CN
- China
- Prior art keywords
- top coat
- paint
- crosslinking
- ultraviolet
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003973 paint Substances 0.000 claims abstract description 53
- 238000004132 cross linking Methods 0.000 claims abstract description 22
- 239000011248 coating agent Substances 0.000 claims abstract description 21
- 238000000576 coating method Methods 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 14
- 229910052753 mercury Inorganic materials 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 8
- 238000005240 physical vapour deposition Methods 0.000 description 12
- 239000000758 substrate Substances 0.000 description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- PLXMOAALOJOTIY-FPTXNFDTSA-N Aesculin Natural products OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)[C@H]1Oc2cc3C=CC(=O)Oc3cc2O PLXMOAALOJOTIY-FPTXNFDTSA-N 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/58—After-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
- B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
- B05D3/065—After-treatment
- B05D3/067—Curing or cross-linking the coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/56—Three layers or more
- B05D7/57—Three layers or more the last layer being a clear coat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2490/00—Intermixed layers
- B05D2490/50—Intermixed layers compositions varying with a gradient perpendicular to the surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
- B05D3/0209—Multistage baking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
- B05D7/53—Base coat plus clear coat type
Landscapes
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
- Optical Elements Other Than Lenses (AREA)
Abstract
本发明涉及零部件，其表面至少部分覆有涂层，其中，该涂层包括设于第一漆层和第二漆层之间的PVD涂层，并且该第一漆层构成该表面上的打底涂层且该第二漆层构成在该PVD涂层上的具有顶面涂层厚度的顶面涂层，其中，至少所述顶面涂层利用紫外线固化漆制成。从该PVD涂层的界面起，在小于该顶面涂层厚度的区域内，该顶面涂层具有比在该顶面涂层的与该区域相接的部分内更低的紫外线致交联度。本发明尤其涉及制造这种零部件的方法。
Description
技术领域
本发明涉及用于漆层的紫外线交联的方法。本发明还涉及执行该方法的辐照装置。
背景技术
通过紫外线交联，涂覆于基材上的漆被固化和干燥。该漆在交联之前都保持可流动并且能够在被施加至基材之后突然凝固。
作为紫外线辐照源，在大多数情况下采用这样的辐照源，其不仅发出紫外线，还发出可见光和百分比含量高的红外线(红外光)。高含量的红外线导致高加工温度，其可能损伤待照射基材。作为这种辐照源的例子可举出高压汞灯。尤其当上漆的基材是塑料基材时，通常借助常见辐射装置将达到临界温度。例如在以名称ABS已知的塑料材料情况下不应高出85℃温度。
但在这种漆交联时，人们对两种相互竞争的效果纠结不已：一方面，人们想要尽量耐刮划地构成这种表面，尤其在汽车业领域中，例如与耐自动洗车线相关的耐微刮划性能是总在重复的主旋律；但另一方面，所述层必须也良好附着于该表面上。
通常，安装在车辆外部区域内的零部件如镶边或冷却栅格应具有金属外观。但这些零部件通常基于塑料基材，其通过涂覆而提供金属外观。根据一种大有希望的方法，在基材上先施加漆层(打底层)，尤其为了平整该表面。接着，例如借助PVD(物理气相沉积)施加一个或多个尤其金属层。这些层赋予零部件以金属外观。随后，该PVD层借助紫外线固化的基本透明的漆(顶面涂层)被高光或哑光覆盖。
一方面，外漆层(顶面涂层)现在须具有上述耐微刮划性能。
这例如可利用提高的交联度来获得。但此时不利的是，增强的漆层交联导致漆层更高脆性，这尤其由在聚合时增强的收缩而引起。
另一方面，顶面涂层和PVD层具有不同的热胀系数。即，在增强交联时的上述脆裂例如在温度变化或有机械载荷时造成：当下方材料根据不同的热胀系数就其膨胀而言变化时，该漆不再附着于该材料并因此脱落。尤其是也与碎石撞击问题相关地，这样的易碎的漆还可能导致漆的致命剥裂。
因此，人们期望提供一种漆，它具有良好的耐微刮划性能而不会脆裂。
发明内容
因此，本发明基于以下任务，即提出一种漆，它具有良好的耐微刮划性能，而不会出现脆裂的缺点。
本发明还基于以下任务，即提出一种可据此制造漆层的方法，该漆层具有良好的耐微刮划性能而不会出现脆裂的缺点。该方法可以尤其在大气条件下执行，即不需要惰性气氛。
根据本发明，如此完成该任务，相对于从现有技术中已知的高压汞灯，在规定时间后接通附加的单色UV-C灯(例如直接照射向物体)。
很简单地讲，这有以下效果，多色汞灯使大部分交联，而短波的UV-C灯以其很浅的侵入深度使表面强烈交联。因此，产生高许多的表面硬度，而整个漆不会脆裂。
具体实施方式
现在将结合附图来举例详述本发明。
图1示出装置1，其用于交联涂有UV漆的基材，所述基材设置在轴3上。如箭头所示，轴缓慢地顺时针转动。在轴上方设有高压汞灯5，所述高压汞灯发出宽广的光谱，包含紫外线、可见光和红外线，由带有交叉阴影线的箭头端表示。所述射线照射到相对主照射方向转过45°的冷光反射镜7上。冷光反射镜7以基本向下朝着该轴的方式反射紫外线并且基本上透过可见光和红外线。
“从高压汞灯5照射到设于轴上的涂漆基材表面”的紫外线被该漆层吸收并导致漆内的聚合物基本均匀地交联至特定程度。例如，该基材接受汞灯紫外线照射约120秒。该光照的通断是通过汞灯的通断或通过冷光反射镜7进入或离开汞灯光路(最好绕位于光路外的轴9转动)来进行的。
另外，图1示出UV-C灯11，其朝向轴表面基本发出254纳米波长的单色光。但是，该基材额外受到所述光线的照射，就汞灯5的“宽谱”光线而言，这是在晚些时刻进行的。例如这在回转轴的情况下是如此做到的，即UV-C灯11极为频繁地如此通电断电，即在50％的时间内没有UV-C光照到轴上。另一种可能性在于，在轴和UV-C灯之间设有光阑，它吸收UV-C灯的光线。周期性加入UV-C灯的光路中的反射镜也是合适的。也可以将多个反射镜例如组装成一个回转的反射筒镜。
单色UV-C光侵入漆表面的深度很浅，因此附加地只使漆表面区交联。通过这种方式，出现了很硬的且进而很耐微刮划的表面，而整个漆层不会脆裂。
如果例如现在出现温度变化或机械载荷，则位于其尺寸变化的漆底层和附加交联且因而变硬的漆表面区之间的交联较少的漆导致了一种弹性“缓冲”。另外，该漆附着于底层，没有出现剥裂。另一方面，附加交联且因而变硬的表面比下方的漆层要耐刮划许多倍。
于是，当未交联的漆所具有的温度明显高出室温时，最好如上所述地与UV-C灯相结合地将冷光反射镜用于汞灯光线是尤其有利的。这种情况例如是：当在施加漆之后，该漆遇到强烈红外射线以加速可能有的溶剂挥发之时。在此情况下，通过红外线预处理很快就达到了70℃。在汞灯的未经滤光的射线的照射下，漆的温度将升高超过容许程度。通过使用冷光反射镜，就不存在这种危险。通过提高的启动温度，交联速度被加快。但因为光线中缺少可见光成分和红外成分，故没有出现多余的进一步加热。
将公开一种零部件，其表面至少部分覆有涂层，其中，该涂层包括设于第一漆层和第二漆层之间的PVD涂层，并且该第一漆层构成该表面上的打底涂层且该第二漆层构成在该PVD涂层上的具有顶面涂层厚度的顶面涂层，其中，至少所述顶面涂层利用紫外线固化漆制成。从该PVD涂层的界面起，在小于顶面涂层厚度的区域内，该顶面涂层具有比之“与该区域相接的顶面涂层部分内”更低的紫外线致交联度。
该顶面涂层的交联度最好在至环境的界面处是最高的。
该打底涂层也可以用紫外线固化漆来制造。
PVD层可以包括两个层并且最好由多个PVD层制造。
已经公开一种制造具有金属光洁度的零部件的方法，其具有以下步骤：
-提供具有待涂覆表面的塑料基材，
-给该表面涂上打底涂层，
-对涂有该打底涂层的表面施加PVD涂层，
-给该PVD涂层涂上紫外线固化顶面涂层，
-对该顶面涂层施以紫外线，在这里，作为辐照源，首先采用汞灯并随后采用窄带(最好单色)的紫外线辐照源。
借助该方法，可以制造上述的本发明的零部件。
在该方法中，该汞灯的光最好在其照射顶面涂层之前借助冷光反射镜被滤光。
Claims (7)
1.一种零部件，其表面至少部分覆有涂层，
其中，该涂层包括设于第一漆层和第二漆层之间的PVD涂层，并且该第一漆层构成该表面上的打底涂层且该第二漆层构成在该PVD涂层上的具有顶面涂层厚度的顶面涂层，
其中，至少所述顶面涂层是利用紫外线固化漆制成的，该打底涂层也用紫外线固化漆制成，
其特征是，
从该PVD涂层的界面起，在小于该顶面涂层厚度的区域内，该顶面涂层具有比之与该区域相接的该顶面涂层部分内更低的紫外线致交联度，
该顶面涂层在汞灯的第一紫外线影响下仅被交联至特定程度，并且该顶面涂层在借助UV-C灯的第二辐照影响下被照射，使得交联较少的漆位于其尺寸变化的漆底层和附加交联且因而变硬的漆表面区之间，该交联较少的漆构成一种弹性缓冲。
2.根据权利要求1的零部件，其特征是，该顶面涂层的交联度在至环境的界面处是最高的。
3.根据权利要求2的零部件，其特征是，该PVD涂层包括至少两个层。
4.根据权利要求2的零部件，其特征是，该PVD涂层由多个PVD层制成。
5.一种制造具有金属光洁度的零部件的方法，其具有以下步骤：
-提供具有待涂覆表面的塑料基材，
-给该表面涂上打底涂层，
-对涂有该打底涂层的表面施加PVD涂层，
-给该PVD涂层涂上紫外线固化顶面涂层，
-对该顶面涂层施以紫外线，在这里，作为辐照源，首先采用汞灯并随后采用窄带的紫外线辐照源，
该顶面涂层在汞灯的第一紫外线影响下仅被交联至特定程度，并且该顶面涂层随后仅借助UV-C灯被照射，使得交联较少的漆位于其尺寸变化的漆底层和附加交联且因而变硬的漆表面区之间，该交联较少的漆构成一种弹性缓冲。
6.根据权利要求5的方法，其特征是，该汞灯的光在其作用于该顶面涂层之前是借助冷光反射镜被滤光的。
7.根据权利要求5的方法，其特征是，作为辐照源，首先采用汞灯并随后采用窄带的且单色的紫外线辐照源。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361813216P | 2013-04-18 | 2013-04-18 | |
| US61/813216 | 2013-04-18 | ||
| PCT/EP2014/000990 WO2014170004A1 (de) | 2013-04-18 | 2014-04-14 | Uv-bestrahlungsvorrichtung mit zusätzlicher monochromatischer strahlungsquelle |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105451896A CN105451896A (zh) | 2016-03-30 |
| CN105451896B true CN105451896B (zh) | 2018-12-21 |
Family
ID=50630745
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480029899.8A Expired - Fee Related CN105451896B (zh) | 2013-04-18 | 2014-04-14 | 具有附加的单色辐照源的紫外线辐照装置 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US9994952B2 (zh) |
| EP (1) | EP2986396B1 (zh) |
| JP (1) | JP6444987B2 (zh) |
| KR (1) | KR20160002932A (zh) |
| CN (1) | CN105451896B (zh) |
| BR (1) | BR112015026485A2 (zh) |
| CA (1) | CA2914109A1 (zh) |
| MX (1) | MX2015014651A (zh) |
| RU (1) | RU2663758C2 (zh) |
| WO (1) | WO2014170004A1 (zh) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107690486A (zh) | 2015-04-15 | 2018-02-13 | 欧瑞康表面解决方案股份公司，普费菲孔 | 具有金属外观覆层的可无线充电的设备 |
| DE102016207163A1 (de) * | 2016-04-27 | 2017-11-02 | Samvardhana Motherson Innovative Autosystems B.V. & Co. KG | Beschichtetes kunststoffbauteil und verfahren zur herstellung des beschichteten kunststoffbauteils |
| EP3903948A1 (en) | 2020-04-30 | 2021-11-03 | Plastal Industri AB | A metallized laminate and a method for forming and adjustably coloring a metallized laminate |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS575870A (en) * | 1980-06-16 | 1982-01-12 | Sanyo Shinku Kogyo Kk | Decorating method by sputtering |
| CH660489A5 (de) | 1984-08-31 | 1987-04-30 | Bernhard Glaus | Verfahren und vorrichtung zum aushaerten polymerisierbarer beschichtungsmassen auf nicht textilen substraten. |
| JP2918960B2 (ja) * | 1990-02-28 | 1999-07-12 | ランテクニカルサービス株式会社 | 紫外線硬化型素材の硬化方法及びその装置 |
| US5106651A (en) * | 1991-02-21 | 1992-04-21 | Ppg Industries, Inc. | Method for improving resistance to water spotting and acid etching of coatings by exposure to UV radiation |
| FR2765346B1 (fr) | 1997-06-26 | 1999-09-24 | Alsthom Cge Alcatel | Procede de fabrication d'un conducteur optique |
| DE19913446C2 (de) * | 1999-03-25 | 2002-10-31 | Herberts Gmbh & Co Kg | Verfahren zur Mehrschichtlackierung |
| US6399152B1 (en) * | 2000-07-27 | 2002-06-04 | Goodrich Technology Corporation | Vacuum metalization process for chroming substrates |
| US6890625B2 (en) * | 2001-02-05 | 2005-05-10 | Awi Licensing Company | Surface covering having gloss in-register and method of making |
| US7151123B2 (en) * | 2004-02-04 | 2006-12-19 | Ecology Coating, Inc. | Environmentally friendly, 100% solids, actinic radiation curable coating compositions and coated surfaces and coated articles thereof |
| JP4344638B2 (ja) | 2004-03-26 | 2009-10-14 | 富士フイルム株式会社 | 反射防止フィルム及びその製造方法、製造装置 |
| DE102004022859B4 (de) * | 2004-05-06 | 2006-04-13 | Kalle Gmbh | Künstliche Nahrungsmittelhülle sowie Verfahren zu deren Herstellung |
| DE102005003802A1 (de) * | 2004-12-10 | 2006-06-14 | Nütro Maschinen- und Anlagenbau GmbH & Co. KG | Strahlungsgerät sowie Pulverauftragsstation und Anordnung zur Beschichtung von temperatursensiblen Materialien und Verfahren hierzu |
| US7132130B1 (en) * | 2005-05-20 | 2006-11-07 | Innovative Systems Engineering Inc. | Method for providing a chrome finish on a substrate |
| FR2890967A1 (fr) * | 2005-09-16 | 2007-03-23 | Rhodia Recherches & Tech | Procede de preparation de revetements organiques reticules sur un support |
| FR2890970B1 (fr) * | 2005-09-16 | 2008-03-14 | Rhodia Recherches & Tech | Procede de preparation d'un revetement silicone anti- adherent |
| US20070111007A1 (en) * | 2005-11-14 | 2007-05-17 | Uwe Wilkenhoener | Process for the preparation of coatings with specific surface properties |
| JP5014862B2 (ja) * | 2007-03-30 | 2012-08-29 | オリジン電気株式会社 | 紫外線硬化性上塗り被覆組成物およびその塗装品 |
| CN101687372A (zh) * | 2007-07-03 | 2010-03-31 | 3M创新有限公司 | 形成复合光学薄膜的方法 |
| RU2401703C2 (ru) * | 2008-04-22 | 2010-10-20 | Владислав Юрьевич Мирчев | Способ отверждения вещества уф-излучением и устройство для его осуществления |
| CN101742842B (zh) | 2008-11-06 | 2013-06-05 | 深圳富泰宏精密工业有限公司 | 壳体及其制作方法 |
| WO2013002842A1 (en) * | 2011-06-30 | 2013-01-03 | Mikron Industries, Inc. | Low heat build-up uv-cured vacuum coatiing system in dark colors |
-
2014
- 2014-04-14 RU RU2015149107A patent/RU2663758C2/ru not_active IP Right Cessation
- 2014-04-14 JP JP2016508034A patent/JP6444987B2/ja not_active Expired - Fee Related
- 2014-04-14 KR KR1020157032711A patent/KR20160002932A/ko not_active Application Discontinuation
- 2014-04-14 CA CA2914109A patent/CA2914109A1/en not_active Abandoned
- 2014-04-14 MX MX2015014651A patent/MX2015014651A/es unknown
- 2014-04-14 US US14/785,602 patent/US9994952B2/en not_active Expired - Fee Related
- 2014-04-14 BR BR112015026485A patent/BR112015026485A2/pt not_active Application Discontinuation
- 2014-04-14 EP EP14720893.8A patent/EP2986396B1/de active Active
- 2014-04-14 CN CN201480029899.8A patent/CN105451896B/zh not_active Expired - Fee Related
- 2014-04-14 WO PCT/EP2014/000990 patent/WO2014170004A1/de active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| EP2986396B1 (de) | 2020-02-12 |
| RU2015149107A (ru) | 2017-05-22 |
| MX2015014651A (es) | 2016-07-18 |
| WO2014170004A1 (de) | 2014-10-23 |
| US9994952B2 (en) | 2018-06-12 |
| RU2663758C2 (ru) | 2018-08-09 |
| JP2016519618A (ja) | 2016-07-07 |
| KR20160002932A (ko) | 2016-01-08 |
| JP6444987B2 (ja) | 2018-12-26 |
| CN105451896A (zh) | 2016-03-30 |
| BR112015026485A2 (pt) | 2017-07-25 |
| EP2986396A1 (de) | 2016-02-24 |
| CA2914109A1 (en) | 2014-10-23 |
| US20160090648A1 (en) | 2016-03-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR102373702B1 (ko) | 변조구조를 갖는 고절연 나노 보호코팅층의 제조방법 | |
| CN105451896B (zh) | 具有附加的单色辐照源的紫外线辐照装置 | |
| KR102299313B1 (ko) | 순환 고듀티비 펄스 방전 다기능성 나노 보호코팅층 제조방법 | |
| WO2015037397A1 (ja) | ハードコートフィルム及びフィルムミラー | |
| WO2008051901A3 (en) | Non-stick coating composition | |
| FR2936240A1 (fr) | Miroir resistant a la corrosion | |
| JP2023082147A (ja) | 保護コーティングを備えた製品およびその製造方法 | |
| CN104411486B (zh) | 带红外线反射功能的透光性基板 | |
| JP6297050B2 (ja) | 埋込みｐｖｄ層で被覆されたプラスチック素材 | |
| CN104136945A (zh) | 红外线反射基板的制造方法 | |
| CA2612448A1 (en) | Method of imparting non-stick property to metal surface | |
| JP7180260B2 (ja) | 化粧シート表面の補修方法 | |
| SU969142A3 (ru) | Способ получени отражающего покрыти | |
| WO2021112116A1 (ja) | 樹脂成形品、車窓用樹脂成形品、および、樹脂成形品の製造方法 | |
| WO2015037549A1 (ja) | 複合フィルム | |
| JP2000071360A (ja) | 多機能材およびその製造方法 | |
| CN104412210B (zh) | 传感器 | |
| CN101870190A (zh) | 具有防刮痕的附膜 | |
| CN105689239A (zh) | 一种塑料件表面喷涂固化工艺 | |
| TH2001006014A (th) | วิธีสำหรับการสร้างฟิล์มเคลือบผิวแบบหลายชั้น และหลายฟิล์มเคลือบผิวแบบหลายชั้น | |
| TW200705065A (en) | Transparent conductive film and fabrication method thereof | |
| TH1801003851A (th) | วิธีการสำหรับการผลิตลามิเนต |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: 120, Kurt street, pevekon, Switzerland Applicant after: OERLIKON SURFACE SOLUTIONS AG TRUBBACH Address before: The Swiss city of Telubahe Applicant before: OERLIKON TRADING AG |
|
| CB02 | Change of applicant information | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20181221 Termination date: 20210414 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |