CN105440926A - Children antibacterial anti-scratching furniture and preparation method thereof - Google Patents

Children antibacterial anti-scratching furniture and preparation method thereof Download PDF

Info

Publication number
CN105440926A
CN105440926A CN201510967550.5A CN201510967550A CN105440926A CN 105440926 A CN105440926 A CN 105440926A CN 201510967550 A CN201510967550 A CN 201510967550A CN 105440926 A CN105440926 A CN 105440926A
Authority
CN
China
Prior art keywords
preparation
children
furniture
damage resistant
paint
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201510967550.5A
Other languages
Chinese (zh)
Other versions
CN105440926B (en
Inventor
李蒙川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lianjiang Xingye Wood Industry Co.,Ltd.
Original Assignee
Sichuan Nuke Household Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sichuan Nuke Household Co Ltd filed Critical Sichuan Nuke Household Co Ltd
Priority to CN201510967550.5A priority Critical patent/CN105440926B/en
Publication of CN105440926A publication Critical patent/CN105440926A/en
Application granted granted Critical
Publication of CN105440926B publication Critical patent/CN105440926B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

Abstract

The invention discloses children antibacterial anti-scratching furniture and a preparation method thereof. The preparation method comprises the following steps: (1) pre-treating a sheet material; (2) brushing with a seal primer; (3) scraping ash; (4) polishing; (5) painting with a base coat; (6) sanding with sand paper; and (7) brushing the sheet material with a layer of anti-bacterial anti-scratching paint. By employing the anti-bacterial anti-scratching paint, the prepared furniture possesses excellent anti-bacterial anti-scratching performances, harmful polluting substances such as VOC and the like in indoor air can be effectively removed, indoor air quality is improved, and air is refreshing. Also, by performing analysis, research, test, experiment and data analysis on the operation, main factors influencing the operation quality are found, the operation quality is controlled at an optimum state, appropriate indexes are determined, optimum technology standards are determined, and thus the children anti-bacterial anti-scratching furniture with excellent quality is produced. The preparation method is simple and convenient, is beneficial for reducing industrialized production cost, is capable of substantially reducing environment pollution, is friendly to environment, and possesses wide application prospect.

Description

Antibacterial damage resistant furniture of children and preparation method thereof
Technical field
The present invention relates to furniture processing technology field, be specifically related to antibacterial damage resistant furniture of a kind of children and preparation method thereof.
Background technology
The world today, due to regionalization, grouping of the world economy expanding economy, trade war is day by day fierce, makes national governments and export enterprise recognize the sense of urgency of improving the quality of products all deeply, and the competition of quality product has become the most important factor of trade war.
As everyone knows, China has become one of important in the world Furniture manufacturing base, and be also an important consumption big country, can China furniture industry keep the occupation rate of domestic market, open up new world market, is a stern challenge concerning upholstery simultaneously.Will win victory in challenge, only improve the quality of products, quality is the life of enterprise.The international competition of Future Society is the competition of knowledge, information, manpower, and the net result of these competitions is exactly the quality in order to improve product, there is quality just can create famous brand name, just can seize the vitality that market, market, just meeting are profitable, just have enterprise.
The quality condition of China's upholstery, can say compared with several years ago, China's furniture quality is greatly improved, and a lot of enterprise all recognizes that quality is all of enterprise, does not have quality enterprise just not have market.But from quality product, environmental protection aspect, domestic client more trusts imported product, this illustrates that domestic furniture is compared with International Furniture, also has a certain distance qualitatively.The annual export amount of more than tens, 100 hundred million of China's upholstery is all the main contributor using cheap labor force as outlet mostly, instead of to resemble what lean on Haier's electrical equipment be the product of high-quality.This outlet does not have competitive power.The furniture quality selective examination that nearest Liaoning is carried out, spot-check 153 batch products, wherein 48 batch products are qualified, and qualified degree is only 31.4% (comprise and measure objectionable impurities), result is troubling, and quality product meets the demands far away, and how such product is in the face of international competition.
Plate fitment refers to and is main base material with wood-based plate, take plate as the assembling-disassembling furniture of basic structure.Common artificial board has glued board, core-board, shaving board, medium density fibre board (MDF) etc.Glued board (clamping plate) is usually used in making the diastrophic furniture of needs; Core-board performance affects by board core material matter sometimes; Shaving board (being again particle board, bagasse board) material is loosened, only for low-grade furniture.That cost performance is high, the most the most frequently used is medium density fibre board (MDF) (MDF).The common finishing material of plate fitment has veneer (be commonly called as and paste wooden skin), woodgrained paper (being commonly called as paster), PVC offset plate, polyester lacquer painting (being commonly called as baking vanish) etc.
Medium density fibre board (MDF) be by timber or vegetable fibre through mechanical separation and chemical treatment means, mix tackiness agent and water-resisting agent etc., then through a kind of artificial board that high temperature, high-pressure molding are made, be make the ideal artificial board of furniture.The structural rate natural timber of medium density fibre board (MDF) is even, and it also avoid rotten, the problem such as to damage by worms, its swell-shrink characteristic is little simultaneously, is convenient to processing.Due to medium density fibre board (MDF) surfacing, be easy to paste various facing, finished product furniture can be made more attractive in appearance.In flexural strength and shock strength, be all better than shaving board.
The inferior sound development that seriously govern upholstery of furniture quality, weaken furniture competitive power in the international market, result in the waste of resource and the low of economic benefit, a lot of bad product is had to be produced, flow to market, bad product cost accounts for the ratio brought a high price usually, shows that it accounts for about 30% of price according to related data research.This financial loss caused due to quality problems is huge, and some foreign scholars estimate that the loss caused because of quality problems every year in the whole world is about about 5%.And the productivity of our upholstery is far below the product of domestic other industry, as electronic product, simultaneously also lower than Hesperian productivity, so the mass loss of upholstery is much larger than 5%.Liaoning Province's furniture item quality selective examination above also illustrates this problem.This means that upholstery is while flourish, is also producing a large amount of bad products, is causing the low one of the main reasons of this quality level to be exactly that Furniture manufacture Process Quality Monitoring is ineffective, lack necessary Quality Control means.Cause too much waster to produce, repair rate remains high.
The present invention is intended to according to standard, by the analysis to operation, research, and test, experiment, data analysis, finds the principal element affecting process quality, by process relativity in optimum regime, determine its suitable index, best technological specification, produces the antibacterial damage resistant furniture of children.
Summary of the invention
For above shortcomings in prior art, one of technical problem to be solved by this invention is to provide the preparation method of the antibacterial damage resistant furniture of a kind of children.
Two of technical problem to be solved by this invention is to provide the antibacterial damage resistant furniture of children prepared by aforesaid method.
The present invention seeks to be achieved through the following technical solutions:
A preparation method for the antibacterial damage resistant furniture of children, comprises the following steps:
(1) sheet material pre-treatment;
(2) brush seal coat
(3) ash is scraped;
(4) polish;
(5) priming;
(6) dry sand;
(7) the antibacterial damage resistant paint of brush one deck on sheet material.
Preferably,
Described antibacterial damage resistant paint is 1:(0.5-1 by main paint, solidifying agent, thinner in mass ratio): (0.3-1) is formulated.
Described main paint is prepared from by the raw material of following weight parts: acrylic resin 85-95 part, titanium dioxide 10-20 part, coupling agent 0.3-0.7 part, sodium laurylsulfonate 0.5-1.5 part, dimethyl silicone oil 0.3-0.8 part, flow agent 1-2 part, antiseptic-germicide 1.5-2.5 part, n-butyl acetate 5-15 part, 1-Methoxy-2-propyl acetate 5-15 part.
Described flow agent is one or more the mixture in Aerosol OT, polyacrylic ester, chain alkyl or aralkyl modified polydimethylsiloxane, PSI, polyfluorinated organic polyene hydrocarbon, fluorin modified crylic acid, organic silicon acrylic ester, polyvinyl butyral acetal, 3-butoxy-1-propyl alcohol.
Described coupling agent is mixed by 3-methacryloyloxypropyl methyl dimethoxysilane, 3-TSL 8330, APTES, and the mass ratio of described 3-methacryloyloxypropyl methyl dimethoxysilane, 3-TSL 8330, APTES is (1-3): (1-3): (1-3).
Described antiseptic-germicide is made up of 40-60wt%1,3-dihydroxymethyl-5,5-dimethyl hydantion and 40-60wt%1,3-dihydroxy ethyl-5,5-dimethyl hydantion.
Described solidifying agent, can adopt the DesmodurN-3390 hexamethylene diisocyanate trimer of the DesmodurN-75 hexamethylene diisocyanate biruet of German Bayer company or German Bayer company.
Further, described solidifying agent can by 50-60wt% n-butyl acetate and 40-50wt%1, and hexamethylene-diisocyanate is prepared from.
Described thinner can adopt the omnipotent board Polyester Paint thinner of Yongkang City navigation chemical industry operation or the model of Shanghai Tian Da coating company limited to be XSSJ-8 thinner
Further, described thinner is prepared from by 50-60wt% n-butyl acetate and 40-50wt% 1-Methoxy-2-propyl acetate.
Described flow agent is one or more the mixture in Aerosol OT, polyacrylic ester, chain alkyl or aralkyl modified polydimethylsiloxane, PSI, polyfluorinated organic polyene hydrocarbon, fluorin modified crylic acid, organic silicon acrylic ester, polyvinyl butyral acetal, 3-butoxy-1-propyl alcohol.
Described acrylic resin can adopt the DesmophenAXP2412 of German Bayer company, and hydroxyl value is 66.
Present invention also offers the preparation method of above-mentioned main paint, comprise the following steps:
(1) titanium dioxide is mixed with coupling agent, obtain modifying titanium dioxide;
(2) acrylic resin, modifying titanium dioxide, sodium laurylsulfonate, dimethyl silicone oil, antiseptic-germicide, n-butyl acetate are added in high speed dispersor mix; Again through sand mill sand milling to fineness be 25-35 μm; Add 1-Methoxy-2-propyl acetate again, flow agent mixes, obtain described main paint.
Preferably, described step (1) is in high-speed mixer, and temperature is 70-90 DEG C, and rotating speed is 300-500 rev/min, stirs 10-30min and mixes, obtain modifying titanium dioxide.
Present invention also offers the preparation method of above-mentioned solidifying agent: n-butyl acetate and hexamethylene diisocyanate are mixed, obtain described solidifying agent.
Present invention also offers the preparation method of above-mentioned thinner: n-butyl acetate and 1-Methoxy-2-propyl acetate are mixed, obtain described thinner.
Present invention also offers the antibacterial damage resistant furniture of a kind of children, adopt aforesaid method to be prepared from.
Concrete, in the present invention:
Hexamethylene diisocyanate, No. CAS: 822-06-0.
N-butyl acetate, No. CAS: 123-86-4.
1-Methoxy-2-propyl acetate, No. CAS: 108-65-6.
Sodium laurylsulfonate, No. CAS: 2386-53-0.
Dimethyl silicone oil, No. CAS: 63148-62-9.
1,3-dihydroxymethyl-5,5-dimethyl hydantion, No. CAS: 6440-58-0.
1,3-dihydroxy ethyl-5,5-dimethyl hydantion, No. CAS: 26850-24-8.
3-methacryloyloxypropyl methyl dimethoxysilane, No. CAS: 14513-34-9.
3-TSL 8330, No. CAS: 13822-56-5.
APTES, No. CAS: 919-30-2.
The present invention adopts antibacterial damage resistant paint, effectively to dispel in room air the harmful pollutants such as VOC, improve IAQ (indoor air quality), with fresh air, has excellent antibacterial scratch resistant performance; Simultaneously by the analysis to operation, research, test, experiment, data analysis, finds the principal element affecting process quality, by process relativity in optimum regime, determine its suitable index, best technological specification, produces the antibacterial damage resistant furniture of children of good quality.Preparation method of the present invention is simple, convenient, is conducive to reducing industrial production cost, significantly can reduces environmental pollution, environmental friendliness, have broad application prospects.
Embodiment
Below in conjunction with embodiment, the present invention is described further, the following stated, only to preferred embodiment of the present invention, not do other forms of restriction to the present invention, any those skilled in the art may utilize the technology contents of above-mentioned announcement to be changed to the Equivalent embodiments of equal change.Everyly do not depart from the present invention program's content, any simple modification done following examples according to technical spirit of the present invention or equivalent variations, all drop in protection scope of the present invention.
Embodiment raw material is introduced:
Titanium dioxide, No. CAS: 13463-67-7, adopt Du Pont, model is the rutile titanium dioxide of R-960.
Flow agent adopts Aerosol OT, and No. CAS: 577-11-7.
Acrylic resin, No. CAS: 9003-01-4.The model adopting Shenzhen Jin Fengyuan macromolecular material company limited to provide is the thermoplastic acrylic resin of RS-68P.
Medium density fibre board (MDF), adopts Suzhou City Tian Yemu industry company limited specification to be 4*10*12, pine medium density fibre board (MDF).
Sand paper, adopt Korea S deer board DEERFOS sand paper, model is ACM66, granularity is 240,400,600 3 kind of specification.
Embodiment 1
Main raw materials for varnish: acrylic resin 90kg, titanium dioxide 15kg, coupling agent 0.45kg, sodium laurylsulfonate 1kg part, dimethyl silicone oil 0.5kg, Aerosol OT 1.5kg, antiseptic-germicide 2kg, n-butyl acetate 10kg, 1-Methoxy-2-propyl acetate 10kg.
Described coupling agent is mixed by 0.15kg3-methacryloyloxypropyl methyl dimethoxysilane, 0.15kg3-TSL 8330,0.15kg3-aminopropyltriethoxywerene werene.
Described antiseptic-germicide is made up of 1kg1,3-dihydroxymethyl-5,5-dimethyl hydantion and 1kg1,3-dihydroxy ethyl-5,5-dimethyl hydantion.
The preparation method of main paint, comprises the following steps:
(1) join in high-speed mixer by titanium dioxide and coupling agent, temperature is 80 DEG C, and rotating speed is 400 revs/min, stirs 20min and mixes, obtain modifying titanium dioxide.
(2) linear velocity high speed dispersion acrylic resin, modifying titanium dioxide, sodium laurylsulfonate, dimethyl silicone oil, antiseptic-germicide, n-butyl acetate being added 20m/s in high speed dispersor mixes for 30 minutes; Again through sand mill sand milling to fineness be 30 μm; Add 1-Methoxy-2-propyl acetate again, Aerosol OT is uniformly mixed, obtain described main paint.
Solidifying agent is by 55kg n-butyl acetate and 45kg1, and hexamethylene-diisocyanate is prepared from.N-butyl acetate and hexamethylene diisocyanate are added stirrer for mixing even, obtain described solidifying agent.
Described thinner is prepared from by 55kg n-butyl acetate and 45kg 1-Methoxy-2-propyl acetate.N-butyl acetate and 1-Methoxy-2-propyl acetate are added stirrer for mixing even, obtain described thinner.
The preparation method of the antibacterial damage resistant furniture of children, comprises the following steps:
(1) medium density fibre board (MDF) granularity is that the sand paper of 240 carries out sanding polishing by sheet material pre-treatment, polishing rear surface dedusting;
(2) brush seal coat, adopts painting way uniform brush one deck seal coat (adopting the 2L woodenware sealing wax seal coat that Hebei Chenyang IndustrialL&trade Group Co., Ltd. produces) on sheet material, japanning amount 100g/m 2;
(3) ash is scraped, by fresh pig blood and titanium dioxide in mass ratio for 9:1 mixes, fresh pig blood and titanium dioxide after uniform brush one deck mixing on sheet material, applying amount 50g/m 2;
(4) polish; Sanding polishing is carried out, polishing rear surface dedusting with the sand paper that granularity is 400;
(5) priming; by the main paint of the clear priming paint of the excellent PU of obliging woodenware of Zijinghua Paint's production, solidifying agent, thinner in mass ratio for 2:1:0.8 mixes; adopt painting way uniform priming on sheet material, japanning amount 100g/m 2;
(6) dry sand: carry out sanding polishing with the sand paper that granularity is 600, polishing rear surface dedusting;
(7) upper finish paint, mixes for 1:0.7:0.5 in mass ratio by the main paint of antibacterial damage resistant paint, solidifying agent, thinner, adopts painting way antibacterial damage resistant paint of uniform brush one deck on sheet material, japanning amount 200g/m 2, adopt halogen lamp uniform irradiation 1h on sheet material, dry, the antibacterial damage resistant furniture of children of the present invention can be obtained.
Embodiment 2
Prepare the antibacterial damage resistant furniture of children by the method for embodiment 1, difference is only: described coupling agent is mixed by 0.225kg3-methacryloyloxypropyl methyl dimethoxysilane, 0.225kg3-TSL 8330.Obtain the antibacterial damage resistant furniture of children of embodiment 2.
Embodiment 3
Prepare the antibacterial damage resistant furniture of children by the method for embodiment 1, difference is only: described coupling agent is mixed by 0.225kg3-methacryloyloxypropyl methyl dimethoxysilane, 0.225kg3-aminopropyltriethoxywerene werene.Obtain the antibacterial damage resistant furniture of children of embodiment 3.
Embodiment 4
Prepare the clear taste furniture of high color inhibition draft by the method for embodiment 1, difference is only: described coupling agent is mixed by 0.225kg3-TSL 8330,0.225kg3-aminopropyltriethoxywerene werene.Obtain the clear taste furniture of high color inhibition draft of embodiment 4.
Embodiment 5
Prepare the antibacterial damage resistant furniture of children by the method for embodiment 1, difference is only: described antiseptic-germicide is 2kg1,3-dihydroxymethyl-5,5-dimethyl hydantion.Obtain the antibacterial damage resistant furniture of children of embodiment 5.
Embodiment 6
Prepare the antibacterial damage resistant furniture of children by the method for embodiment 1, difference is only: described antiseptic-germicide is 2kg1,3-dihydroxy ethyl-5,5-dimethyl hydantion.Obtain the antibacterial damage resistant furniture of children of embodiment 6.
Test case 1
The obtained furniture of above-described embodiment 1-6 is carried out performance test.
Wear resisting property presses the mensuration of GB/T1768-2006 paint and varnish wear resistance, rotation rubber emery wheel method, under the effect of 1000g normal force, after 1000 circulations (1000 turns), measures the weightlessness (abrasion) of coating, represents with mg.
Anti-microbial property presses GB/T21866-2008 antibiotic paint anti-microbial property measuring method and antibacterial effect, HG/T3980-2007 antibiotic paint measure, and test item is antibacterial test and fungus-proof test.
Antibacterial test: intestinal bacteria ATYCC25922, streptococcus aureus ATCC6538.
Fungus-proof test: aspergillus niger AS3.4463, terreus AS3.3935, paecilomyces varioti AS3.4253, penicillium funiculosum AS3.3875, Aureobasidium pullulans AS3.3984, Chaetomium globosum AS3.4254.Fungus-proof test judgement criteria comprises: 0 grade is not namely long, amplifies 50 times of lower observations and have no growth under microscope; 1 grade of i.e. vestige growth, i.e. naked eyes visible growth, but growth area coverage is less than 10%; Namely 2 grades grow area coverage and be greater than 10%; Concrete test-results is as shown in table 1-3:
Table 1: children's antibacterial damage resistant furniture performance test results table
Sample name Wear loss, mg Antibiotic rate, % Mildew-resistant rank
Embodiment 1 9.8 99.99 0
Embodiment 2 12.7 99.81 1
Embodiment 3 12.2 99.90 1
Embodiment 4 11.8 99.73 1
Embodiment 5 10.1 99.24 1
Embodiment 6 10.0 99.01 1
Comparing embodiment 1-4, embodiment 1 (3-methacryloyloxypropyl methyl dimethoxysilane, 3-TSL 8330, APTES are composite) wear resisting property is obviously better than embodiment 2-4 (in 3-methacryloyloxypropyl methyl dimethoxysilane, 3-TSL 8330, APTES, both are composite arbitrarily); Comparing embodiment 1 and embodiment 5-6, (antiseptic-germicide adopts 1 to embodiment 1,3-dihydroxymethyl-5,5-dimethyl hydantion and 1,3-dihydroxy ethyl-5,5-dimethyl hydantion composite) anti-microbial property be obviously better than embodiment 5-6 (antiseptic-germicide adopt 1,3-dihydroxymethyl-5, single raw material in 5-dimethyl hydantion and 1,3-dihydroxy ethyl-5,5-dimethyl hydantion).
The stability in storage of the present invention's antibacterial damage resistant paint used is good, and the content of objectionable impurities is all within the claimed range of GB18581-2009, and the present invention has enough safety in utilization; Paint film water white transparency, flat smooth, resistance to acids and bases are good, have good defencive function to coated family, are applicable to the places such as such as family, office, school; The purifying property of PARA FORMALDEHYDE PRILLS(91,95) and decontamination effect improving persistence all meet the requirement of JC/T1074-2008, and clean aldehyde excellent is described, can rapidly, efficiently, purify air enduringly in free formaldehyde, and there is excellent antibacterial scratch resistant performance.

Claims (7)

1. a preparation method for the antibacterial damage resistant furniture of children, is characterized in that, comprise the following steps:
(1) sheet material pre-treatment;
(2) brush seal coat;
(3) ash is scraped;
(4) polish;
(5) priming;
(6) dry sand;
(7) the antibacterial damage resistant paint of brush one deck on sheet material.
Described antibacterial damage resistant paint is 1:(0.5-1 by main paint, solidifying agent, thinner in mass ratio): (0.3-1) is formulated;
Described main paint is prepared from by the raw material of following weight parts: acrylic resin 85-95 part, titanium dioxide 10-20 part, coupling agent 0.3-0.7 part, sodium laurylsulfonate 0.5-1.5 part, dimethyl silicone oil 0.3-0.8 part, flow agent 1-2 part, antiseptic-germicide 1.5-2.5 part, n-butyl acetate 5-15 part, 1-Methoxy-2-propyl acetate 5-15 part;
Described flow agent is one or more the mixture in Aerosol OT, polyacrylic ester, chain alkyl or aralkyl modified polydimethylsiloxane, PSI, polyfluorinated organic polyene hydrocarbon, fluorin modified crylic acid, organic silicon acrylic ester, polyvinyl butyral acetal, 3-butoxy-1-propyl alcohol.
2. the preparation method of the antibacterial damage resistant furniture of children as claimed in claim 1, it is characterized in that, described coupling agent is mixed by 3-methacryloyloxypropyl methyl dimethoxysilane, 3-TSL 8330, APTES, and the mass ratio of described 3-methacryloyloxypropyl methyl dimethoxysilane, 3-TSL 8330, APTES is (1-3): (1-3): (1-3).
3. the preparation method of the antibacterial damage resistant furniture of children as claimed in claim 1 or 2, is characterized in that, described antiseptic-germicide is made up of 40-60wt%1,3-dihydroxymethyl-5,5-dimethyl hydantion and 40-60wt%1,3-dihydroxy ethyl-5,5-dimethyl hydantion.
4. the preparation method of the antibacterial damage resistant furniture of children as claimed in claim 1 or 2, it is characterized in that, described solidifying agent can by 50-60wt% n-butyl acetate and 40-50wt%1, and hexamethylene-diisocyanate is prepared from.
5. the preparation method of the antibacterial damage resistant furniture of children as claimed in claim 1 or 2, it is characterized in that, described thinner is prepared from by 50-60wt% n-butyl acetate and 40-50wt% 1-Methoxy-2-propyl acetate.
6. the preparation method of the antibacterial damage resistant furniture of children as claimed in claim 1 or 2, it is characterized in that, the preparation method of described main paint, comprises the following steps:
(1) titanium dioxide is mixed with coupling agent, obtain modifying titanium dioxide;
(2) acrylic resin, modifying titanium dioxide, sodium laurylsulfonate, dimethyl silicone oil, antiseptic-germicide, n-butyl acetate are added in high speed dispersor mix; Again through sand mill sand milling to fineness be 25-35 μm; Add 1-Methoxy-2-propyl acetate again, flow agent mixes, obtain described main paint.
7. the antibacterial damage resistant furniture of children, is characterized in that, adopts method according to any one of claim 1-6 to be prepared from.
CN201510967550.5A 2015-12-21 2015-12-21 Children's antibacterial damage resistant furniture and preparation method thereof Active CN105440926B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510967550.5A CN105440926B (en) 2015-12-21 2015-12-21 Children's antibacterial damage resistant furniture and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510967550.5A CN105440926B (en) 2015-12-21 2015-12-21 Children's antibacterial damage resistant furniture and preparation method thereof

Publications (2)

Publication Number Publication Date
CN105440926A true CN105440926A (en) 2016-03-30
CN105440926B CN105440926B (en) 2018-05-25

Family

ID=55551586

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510967550.5A Active CN105440926B (en) 2015-12-21 2015-12-21 Children's antibacterial damage resistant furniture and preparation method thereof

Country Status (1)

Country Link
CN (1) CN105440926B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113337203A (en) * 2021-07-17 2021-09-03 江西安鹏家具有限公司 Coating formula and processing technology for furniture surface antibiosis
WO2022234062A1 (en) * 2021-05-07 2022-11-10 Soremartec S.A. Packaging material having anti-microbial properties

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04304276A (en) * 1991-03-30 1992-10-27 Nippon Paint Co Ltd Water-based coating composition
CN101486861A (en) * 2008-01-18 2009-07-22 深圳市海川实业股份有限公司 Environment friendly antibacterial waterborne paint and preparation thereof
CN101619194A (en) * 2008-07-02 2010-01-06 紫荆花制漆(上海)有限公司 Yellowing-resistant quick-drying polyurethane wood paint and using method thereof
CN102443333A (en) * 2011-09-20 2012-05-09 嘉宝莉化工集团股份有限公司 High solid content acrylic varnish, and preparation method and application thereof
CN103113828A (en) * 2013-01-18 2013-05-22 上海金强粘合剂有限公司 Water-based paint special for pinewood of furniture for children
CN104592840A (en) * 2014-12-30 2015-05-06 三棵树涂料股份有限公司 Scratch-endurable high-performance aqueous semi-dumb white paint for woodwork and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04304276A (en) * 1991-03-30 1992-10-27 Nippon Paint Co Ltd Water-based coating composition
CN101486861A (en) * 2008-01-18 2009-07-22 深圳市海川实业股份有限公司 Environment friendly antibacterial waterborne paint and preparation thereof
CN101619194A (en) * 2008-07-02 2010-01-06 紫荆花制漆(上海)有限公司 Yellowing-resistant quick-drying polyurethane wood paint and using method thereof
CN102443333A (en) * 2011-09-20 2012-05-09 嘉宝莉化工集团股份有限公司 High solid content acrylic varnish, and preparation method and application thereof
CN103113828A (en) * 2013-01-18 2013-05-22 上海金强粘合剂有限公司 Water-based paint special for pinewood of furniture for children
CN104592840A (en) * 2014-12-30 2015-05-06 三棵树涂料股份有限公司 Scratch-endurable high-performance aqueous semi-dumb white paint for woodwork and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
刘登良: "《涂料工艺 第四版 下册》", 31 January 2010, 化学工业出版社 *
高传涛等: "四针状纳米ZnO/丙烯酸树脂复合多功能涂料", 《涂料工业》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022234062A1 (en) * 2021-05-07 2022-11-10 Soremartec S.A. Packaging material having anti-microbial properties
CN113337203A (en) * 2021-07-17 2021-09-03 江西安鹏家具有限公司 Coating formula and processing technology for furniture surface antibiosis

Also Published As

Publication number Publication date
CN105440926B (en) 2018-05-25

Similar Documents

Publication Publication Date Title
CN109355968B (en) Wear-resistant environment-friendly impregnated paper and preparation method thereof
CN104263214B (en) The transparent woodenware combination paints of PU and its coating process
CN101591969A (en) Solid wood and hardwood composite floor printing are covered with paint, lacquer, colour wash, etc. technology
CN105331271B (en) A kind of water-based two-in-one woodcare paint and preparation method thereof
CN103194136A (en) Epoxy self-leveling floor coating and preparation method thereof
CN107138376A (en) A kind of modifying cotton wood material solid wood furniture surface wood wax oil coating method
CN104403553A (en) Sprayed and coated odorless polyurethane floor paint
CN109746176B (en) Spraying method of bamboo product
CN105440926A (en) Children antibacterial anti-scratching furniture and preparation method thereof
CN105032744A (en) Brush coating construction process of transparent aqueous dye
CN103802416B (en) High bright wear-resisting building materials and ornaments film and production method thereof
CN103224738B (en) Aqueous, environmental protective edge band ink and preparation method thereof
CN104532677A (en) Manufacturing method of melamine impregnated paper
CN101831227B (en) Water-based conglutination primer for solid-wood products and preparation method thereof
CN110922833B (en) Matte varnish for scientific wood veneer and preparation method thereof
CN104293129A (en) Tasteless high-transparency full-matt top-coat paint and preparation method thereof
CN102864911A (en) Solvent-free epoxy colorful artistic floor and preparation method thereof
CN106243868A (en) A kind of fork truck steel ring antifouling paint
CN104559620A (en) PU matte color repairing golden oil and preparation process thereof
CN110256945A (en) A kind of open air high-weatherability wood wax oil and preparation method thereof
CN105400333A (en) High yellowing-resistant herbaceous refreshing furniture and preparation method thereof
CN105385331A (en) Environment-friendly odorless furniture and manufacturing method thereof
CN105461884B (en) Children's antibacterial damage resistant furniture and preparation method thereof
CN105419605B (en) Environmentally friendly net taste furniture and preparation method thereof
CN105599095B (en) High clear taste furniture of color inhibition draft and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20210127

Address after: 524000 Building 1 / 4, Shatang Industrial Zone, Shiling Town, Lianjiang City, Zhanjiang City, Guangdong Province

Patentee after: Lianjiang Xingye Wood Industry Co.,Ltd.

Address before: No. 602, 6th floor, unit 1, building 3, No. 387, Tianren Road, high tech Zone, Chengdu, Sichuan 610041

Patentee before: SICHUAN NUKE HOUSEHOLD Co.,Ltd.

TR01 Transfer of patent right