CN105461884B - Children's antibacterial damage resistant furniture and preparation method thereof - Google Patents
Children's antibacterial damage resistant furniture and preparation method thereof Download PDFInfo
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- CN105461884B CN105461884B CN201510979458.0A CN201510979458A CN105461884B CN 105461884 B CN105461884 B CN 105461884B CN 201510979458 A CN201510979458 A CN 201510979458A CN 105461884 B CN105461884 B CN 105461884B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/45—Heterocyclic compounds having sulfur in the ring
- C08K5/46—Heterocyclic compounds having sulfur in the ring with oxygen or nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
Abstract
The invention discloses a kind of children's antibacterial damage resistant furniture and preparation method thereof, and the preparation method comprises the following steps：(1) plate pre-processes；(2) brush seal coat；(3) ash is scraped；(4) polish；(5) priming；(6) dry sand；(7) one layer of antibacterial damage resistant paint is brushed on plate.Children's antibacterial damage resistant furniture of the present invention, finishing coat used have cleverly disperseed various difficult scattered raw material, have had the function of good antibacterial damage resistant, brush in furniture surface, can effectively inhibit bacteria growth, prevent furniture from going mouldy by selecting reasonable auxiliary agent；Preparation process of the present invention is simple, is a kind of environmentally friendly, energy saving, long lifespan, very beautiful furniture, and practicability is good, can intersperse and beautify the living environment.
Description
Technical field
The present invention relates to furniture processing technology fields, and in particular to a kind of children's antibacterial damage resistant furniture and its preparation side
Method.
Background technology
In the China of 21 century, with the further opening in market, there is the furniture of more and more new styles.In base
After this life requirement obtains satisfaction, some start to focus on the quality of home life, and particularly family product is for health
It influences, therefore environmentally friendly furniture is valued by the people gradually, green consumption agitation has also promoted the development of environmentally friendly furniture.
On the basis of environmentally friendly furniture refers to those based on ecological industry, reasonable development is produced using nature material
Disclosure satisfy that user's particular demands, be beneficial to user's health, and the family with high cultural deposits and scientific and technological content
Tool.Wherein include several layers of meanings：First, furniture itself is pollution-free, nonhazardous；2nd, there is higher artistic connotation and aesthetic function,
It is mutually echoed with indoor design, creates a harmonious graceful telecommuting environment；3rd, it is main convenient for recycling, handling, recycling
Tool is not used when being handled, and not can cause environmental pollution.
Plate fitment refers to that using wood-based plate be main base material, the assembling-disassembling furniture using plate as basic structure.It is common
Artificial board have glued board, core-board, particieboard, medium density fibre board (MDF) etc..Glued board (clamping plate) is usually used in making needs
The furniture of flexural deformation；Core-board performance is influenced sometimes by plate core material；Particieboard (being called particle board, bagasse board) material
It is loose, it is only used for low-grade furniture.Cost performance highest, the most commonly used is medium density fibre board (MDF) (MDF).The common facing of plate fitment
Material has veneer (being commonly called as patch wood skin), woodgrained paper (being commonly called as paster), PVC offset plates, polyester lacquer painting (being commonly called as baking vanish) etc..
Furniture lacquer can make woodenware DELICATE AND SIMPLE BAMBOO more attractive beautiful, improve furniture per se with harsh hand, make furniture not
Climate is influenced with Drought-wet change, not only acts as the effect of Preservation woodenware DELICATE AND SIMPLE BAMBOO, and can also give birth to entire family
It is living to become more comfortable.
The immunity of children, self-protection ability are all lower than being grown up, as the children furniture contacted for a long time with children, one
Denier there are hidden danger, will undoubtedly evolve into product quality and environmental-protecting performance etc. and be imbedded in " time bomb " of children at one's side,
Children may be damaged at any time.For the general status of current domestic children furniture industry, big and small brand adds
Can do not get up any more 200, but product is irregular, unification than more serious, the feature of environmental protection, security also in the prevalence of
Defect.
The present invention provides a kind of children's antibacterial damage resistant furniture, have excellent antibacterial scratch resistant performance, protect children
Safety.
The content of the invention
For above-mentioned deficiency in the prior art, the first technical problem to be solved by the present invention is to provide a kind of youngster
The preparation method of virgin antibacterial damage resistant furniture.
The second technical problem to be solved by the present invention is to provide children's antibacterial damage resistant furniture of above method preparation.
The present invention seeks to what is be achieved through the following technical solutions：
A kind of preparation method of children's antibacterial damage resistant furniture, comprises the following steps：
(1) plate pre-processes；
(2) brush seal coat
(3) ash is scraped；
(4) polish；
(5) priming；
(6) dry sand；
(7) one layer of antibacterial damage resistant paint is brushed on plate.
Preferably,
The antibacterial damage resistant paint is 1 in mass ratio by mian paint, curing agent, diluent:(0.6-0.9):(0.4-0.8)
It is formulated；
The mian paint is prepared by the raw material of following weight parts：88-92 parts of acrylic resin, titanium dioxide 12-18
Part, 0.4-0.6 parts of coupling agent, 2-3 parts of sodium cetanesulfonate, 0.4-0.6 parts of dimethicone, 1.8-2.2 parts of antiseptic, vinegar
Sour N-butyl 8-12 parts, 8-12 parts of propylene glycol monomethyl ether acetate；
The coupling agent is by vinyl dimethylethoxysilane, methyl vinyl diethoxysilane, vinyl three
Three (2- methoxy ethoxies) silane mixture of (2- methoxy ethoxies) silane methyl vinyl diethoxysilane vinyl and
Into the vinyl dimethylethoxysilane, methyl vinyl diethoxysilane, vinyl three (2- methoxy ethoxies)
The mass ratio of silane is (1-3)：(1-3)：(1-3).
The antiseptic is pungent by 40-60wt%2- octyl group -4- isothiazoline -3- ketone and bis- chloro- N- of 40-60wt%4,5-
Base -4- isothiazoline -3- ketone forms.
The Desmodur N-75 hexamethylene diisocyanates contracting of German Bayer companies may be employed in the curing agent
Two ureas or the Desmodur N-3390 hexamethylene diisocyanate trimers of Bayer companies of Germany.
Further, the curing agent can be by 50-60wt% n-butyl acetates and the own diisocyanate of 40-50wt%1,6-
Ester is prepared.
The omnipotent board polyester lacquer diluent of Yongkang City navigation chemical industry operation may be employed in the diluent or Shanghai day reaches
The model XSSJ-8 diluents of coating Co., Ltd
Further, the diluent is by 50-60wt% n-butyl acetates and 40-50wt% propylene glycol monomethyl ether acetate systems
It is standby to form.
The Desmophen AXP 2412 of German Bayer companies, hydroxyl value 66 may be employed in the acrylic resin.
The present invention also provides the preparation methods of above-mentioned mian paint, comprise the following steps：
(1) titanium dioxide with coupling agent is uniformly mixed, obtains modifying titanium dioxide；
(2) by acrylic resin, modifying titanium dioxide, sodium cetanesulfonate, dimethicone, antiseptic, acetic acid just
Butyl ester is added in high speed dispersor and is uniformly mixed；It is 25-35 μm to be sanded again through sand mill to fineness；Add propylene glycol monomethyl ether third
Acid esters is uniformly mixed to get the mian paint.
Preferably, the step (1) is in high-speed mixer, and temperature is 70-90 DEG C, and rotating speed is 300-500 revs/min
Clock, stirring 10-30min are uniformly mixed, and obtain modifying titanium dioxide.
The present invention also provides the preparation methods of above-mentioned curing agent：N-butyl acetate and hexamethylene diisocyanate are mixed
Uniformly to get the curing agent.
The present invention also provides the preparation methods of above-mentioned diluent：N-butyl acetate and propylene glycol monomethyl ether acetate are mixed
Uniformly to get the diluent.
The present invention also provides a kind of children's antibacterial damage resistant furniture, are prepared using the above method.
Specifically, in the present invention：
1, hexamethylene-diisocyanate, No. CAS：822-06-0.
N-butyl acetate, No. CAS：123-86-4.
Propylene glycol monomethyl ether acetate, No. CAS：148462-57-1.
Sodium cetanesulfonate, No. CAS：15015-81-3.
Dimethicone, No. CAS：63148-62-9.
2- octyl group -4- isothiazoline -3- ketone, No. CAS：26530-20-1.
4,5- bis- chloro- N- octyl groups -4- isothiazoline -3- ketone, No. CAS：64359-81-5.
Vinyl dimethylethoxysilane, No. CAS：5356-83-2.
Methyl vinyl diethoxysilane, No. CAS：5507-44-8.
Vinyl three (2- methoxy ethoxies) silane, No. CAS：1067-53-4.
Children's antibacterial damage resistant furniture of the present invention, finishing coat used have cleverly disperseed various difficulties by selecting reasonable auxiliary agent
Scattered raw material have the function of good antibacterial damage resistant, brush in furniture surface, can effectively inhibit bacteria growth, prevent
Furniture goes mouldy；Preparation process of the present invention is simple, is a kind of environmentally friendly, energy saving, long lifespan, very beautiful furniture, practicability is good, energy
It intersperses and beautifies the living environment.
Specific embodiment
With reference to embodiment, the present invention is described further, as described below, is only the preferable implementation to the present invention
Example, not limits the present invention, any person skilled in the art is possibly also with the disclosure above
Technology contents be changed to the equivalent embodiment changed on an equal basis.It is every without departing from the present invention program content, according to the present invention
Any simple modification for being made to following embodiment of technical spirit or equivalent variations, all fall in protection scope of the present invention.
Embodiment raw material introduction：
Titanium dioxide, No. CAS：13463-67-7, using Du Pont, the rutile titanium dioxide of model R-960.
Acrylic resin, No. CAS：9003-01-4.The model provided using Shenzhen Jin Fengyuan high molecular materials Co., Ltd
For the thermoplastic acrylic resin of RS-68P.
Medium density fibre board (MDF) uses Suzhou City's Tian Ye wood industries Co., Ltd specification as 4*10*12, pine medium density fiber
Plate.
Sand paper, using South Korea's deer board DEERFOS sand paper, model ACM66, granularity 240,400,600 3 kind of specification.
Embodiment 1
Mian paint raw material：Acrylic resin 90kg, titanium dioxide 15kg, coupling agent 0.45kg, sodium cetanesulfonate 2.5kg
Part, dimethicone 0.5kg, antiseptic 2kg, n-butyl acetate 10kg, propylene glycol monomethyl ether acetate 10kg.
The coupling agent is by 0.15kg vinyl dimethylethoxysilanes, 0.15kg methyl ethylene diethoxy silicon
Alkane, 0.15kg vinyl three (2- methoxy ethoxies) silane mixture form.
The antiseptic by bis- chloro- N- octyl groups -4- isothiazolines of 1kg2- octyl group -4- isothiazoline -3- ketone and 1kg4,5- -
3- ketone forms.
The preparation method of mian paint, comprises the following steps：
(1) titanium dioxide and coupling agent being added in high-speed mixer, temperature is 75 DEG C, and rotating speed is 500 revs/min,
Stirring 15min is uniformly mixed, and obtains modifying titanium dioxide.
(2) by acrylic resin, modifying titanium dioxide, sodium cetanesulfonate, dimethicone, antiseptic, acetic acid just
The linear velocity high speed dispersion that butyl ester adds in 25m/s in high speed dispersor is uniformly mixed for 25 minutes；It is sanded again through sand mill to fineness
For 30 μm；Propylene glycol monomethyl ether acetate is added to be uniformly mixed to get the mian paint.
Curing agent is prepared by 55kg n-butyl acetates and 45kg1,6- hexamethylene diisocyanates.By n-butyl acetate and 1,
Hexamethylene-diisocyanate adds in stirrer for mixing uniformly to get the curing agent.
The diluent is prepared by 55kg n-butyl acetates and 45kg propylene glycol monomethyl ether acetates.By n-butyl acetate
Stirrer for mixing is added in uniformly to get the diluent with propylene glycol monomethyl ether acetate.
The preparation method of children's antibacterial damage resistant furniture, comprises the following steps：
(1) plate pre-processes, and medium density fibre board (MDF) is carried out sanding polishing with the sand paper that granularity is 240, rear surface of polishing
Dedusting；
(2) brush seal coat uniformly brushes one layer of seal coat (using Hebei morning sun work using painting way on plate
The 2L woodenware sealing waxes seal coat of trade Group Co., Ltd production), japanning amount 100g/m2；
(3) ash is scraped, is 9 in mass ratio by fresh pig blood and titanium dioxide:1 is uniformly mixed, and one is uniformly brushed on plate
Fresh pig blood and titanium dioxide after layer mixing, applying amount 50g/m2；
(4) polish；Sanding polishing is carried out with the sand paper that granularity is 400, rear surface dedusting of polishing；
(5) priming, by the mian paint of the excellent clear priming paint of PU woodenware of obliging of Zijinghua Paint's production, admittedly
Agent, diluent are 2 in mass ratio:1:0.8 be uniformly mixed, using painting way on plate uniform priming, japanning amount
100g/m2；
(6) dry sand：Sanding polishing is carried out with the sand paper that granularity is 600, rear surface dedusting of polishing；
(7) mian paint of antibacterial damage resistant paint, curing agent, diluent are 1 in mass ratio by finishing coat on:0.8:0.6 mixing is equal
It is even, one layer of antibacterial damage resistant paint, japanning amount 200g/m are uniformly brushed on plate using painting way2, it is uniform using halogen lamp
1h on plate is radiated at, is dried, you can children's antibacterial damage resistant furniture of the present invention is made.
Embodiment 2
Children's antibacterial damage resistant furniture is prepared as described in Example 1, is differed only in：The coupling agent by
0.225kg vinyl dimethylethoxysilanes, 0.225kg methyl vinyl diethoxysilanes mix.Implemented
Children's antibacterial damage resistant furniture of example 2.
Embodiment 3
Children's antibacterial damage resistant furniture is prepared as described in Example 1, is differed only in：The coupling agent by
0.225kg vinyl dimethylethoxysilanes, 0.225kg vinyl three (2- methoxy ethoxies) silane mixture form.
To children's antibacterial damage resistant furniture of embodiment 3.
Embodiment 4
The clear taste furniture of high color inhibition draft is prepared as described in Example 1, is differed only in：The coupling agent by
0.225kg methyl vinyl diethoxysilanes, 0.225kg vinyl three (2- methoxy ethoxies) silane mixture form.
To the clear taste furniture of high color inhibition draft of embodiment 4.
Embodiment 5
Children's antibacterial damage resistant furniture is prepared as described in Example 1, is differed only in：The antiseptic is pungent for 2kg2-
Base -4- isothiazoline -3- ketone.Obtain children's antibacterial damage resistant furniture of embodiment 5.
Embodiment 6
Children's antibacterial damage resistant furniture is prepared as described in Example 1, is differed only in：The antiseptic is 2kg4,5-
Two chloro- N- octyl groups -4- isothiazoline -3- ketone.Obtain children's antibacterial damage resistant furniture of embodiment 6.
Test case 1
The obtained furniture of above-described embodiment 1-6 is tested for the property.
Wear-resisting property presses the measure of GB/T1768-2006 paint and varnish wearabilities, rotation rubber emery wheel method, in 1000g
Under normal force effect, after 1000 Xun Huans (1000 turns), the weightlessness (abrasion) of coating is measured, is represented with mg.
Anti-microbial property presses GB/T21866-2008 antibiotic paint anti-microbial property assay methods and antibacterial effect, HG/T 3980-
2007 antibiotic paints measure, and detection project is antibacterial test and fungus-proof test.
Antibacterial test：Escherichia coli ATYCC 25922, staphylococcus aureus ATCC 6538.
Fungus-proof test：Aspergillus niger AS3.4463, Aspergillus terreus AS3.3935, paecilomyces varioti AS3.4253, penicillium funiculosum
AS3.3875, Aureobasidium pullulans AS3.3984, Chaetomium globosum AS3.4254.Fungus-proof test evaluation criterion includes：0 grade is not grown,
Amplify observation under 50 times under microscope and have no growth；1 grade of i.e. trace growth, i.e. naked eyes visible growth, but it is small to grow area coverage
In 10%；2 grades of i.e. growth area coverages are more than 10%；Specific test result is as shown in table 1-3：
Table 1：Children's antibacterial damage resistant furniture performance test results table
| Sample name | Abrasion loss, mg | Antibiotic rate, % | Mould proof rank |
| Embodiment 1 | 9.3 | 99.99 | 0 |
| Embodiment 2 | 11.6 | 99.75 | 1 |
| Embodiment 3 | 12.5 | 99.64 | 1 |
| Embodiment 4 | 12.1 | 99.86 | 1 |
| Embodiment 5 | 10.0 | 99.17 | 1 |
| Embodiment 6 | 10.2 | 99.02 | 2 |
Comparing embodiment 1-4, embodiment 1 (vinyl dimethylethoxysilane, methyl vinyl diethoxysilane,
Vinyl three (2- methoxy ethoxies) silane compounds) wear-resisting property is substantially better than embodiment 2-4 (vinyl-dimethyl base oxethyls
Both arbitrary compounding in silane, methyl vinyl diethoxysilane, vinyl three (2- methoxy ethoxies) silane)；Compare
Embodiment 1 and embodiment 5-6, embodiment 1 (antiseptic using bis- chloro- N- octyl groups of 2- octyl group -4- isothiazoline -3- ketone and 4,5- -
4- isothiazoline -3- ketone compound) anti-microbial property be substantially better than embodiment 5-6 (antiseptic use 2- octyl group -4- isothiazolines -3-
Single raw material in bis- chloro- N- octyl groups -4- isothiazoline -3- ketone of ketone and 4,5-).
The storage stability of antibacterial damage resistant paint is good used in the present invention, and the content of harmful substance is GB18581-2009's
Within claimed range, the present invention has enough safety in utilization；Paint film water white transparency, flat smooth, resistance to acid and alkali are good, right
Coated family has good defencive function.
Claims (3)
1. a kind of preparation method of children's antibacterial damage resistant furniture, which is characterized in that comprise the following steps：
(1) plate pre-processes；
(2) brush seal coat；
(3) ash is scraped；
(4) polish；
(5) priming；
(6) dry sand；
(7) one layer of antibacterial damage resistant paint is brushed on plate；
The antibacterial damage resistant paint is 1 in mass ratio by mian paint, curing agent, diluent:(0.6-0.9):(0.4-0.8) is prepared
It forms；
The mian paint is prepared by the raw material of following weight parts：88-92 parts of acrylic resin, 12-18 parts of titanium dioxide, idol
Join 0.4-0.6 parts of agent, 2-3 parts of sodium cetanesulfonate, 0.4-0.6 parts of dimethicone, 1.8-2.2 parts of antiseptic, acetic acid just
8-12 parts of butyl ester, 8-12 parts of propylene glycol monomethyl ether acetate；
The coupling agent is by vinyl dimethylethoxysilane, methyl vinyl diethoxysilane, (the 2- first of vinyl three
Oxygroup ethyoxyl) silane mixture forms, the vinyl dimethylethoxysilane, methyl vinyl diethoxysilane, second
The mass ratio of alkenyl three (2- methoxy ethoxies) silane is (1-3)：(1-3)：(1-3)；
The antiseptic by bis- chloro- N- octyl groups of 40-60wt%2- octyl group -4- isothiazoline -3- ketone and 40-60wt%4,5- -
4- isothiazoline -3- ketone forms；
The curing agent is prepared by 50-60wt% n-butyl acetates and 40-50wt%1,6- hexamethylene diisocyanates.
2. the preparation method of children's antibacterial damage resistant furniture as described in claim 1, which is characterized in that the diluent by
50-60wt% n-butyl acetates and 40-50wt% propylene glycol monomethyl ether acetates are prepared.
3. a kind of children's antibacterial damage resistant furniture, which is characterized in that using method preparation any one of claim 1-2
Into.
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| CN201810230708.4A CN108410295B (en) | 2015-12-22 | 2015-12-22 | Antibacterial scratch-resistant paint |
| CN201510979458.0A CN105461884B (en) | 2015-12-22 | 2015-12-22 | Children's antibacterial damage resistant furniture and preparation method thereof |
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|---|---|---|---|---|
| JP2006016528A (en) * | 2004-07-02 | 2006-01-19 | Dainippon Ink & Chem Inc | Coating composition for decorative sheet and decorative sheet |
| CN102669179B (en) * | 2012-05-30 | 2014-03-12 | 北京崇高纳米科技有限公司 | Antibacterial antiviral treating agent, preparation method and application thereof |
| CN104497755A (en) * | 2014-11-27 | 2015-04-08 | 江西锦绣现代化工有限公司 | High-weather-resistance and wide-construction-environment environmental-protection white gloss furniture paint |
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2015
- 2015-12-22 CN CN201810230708.4A patent/CN108410295B/en active Active
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101497698A (en) * | 2009-01-22 | 2009-08-05 | 南京大学 | Preparation of chitosan-polyurethane ion complex elastomer material |
| CN103827177A (en) * | 2011-07-22 | 2014-05-28 | 伊诺科雷技术有限公司 | Biodegradable, semi-crystalline, phase separated, thermoplastic multi block copolymers for controlled release of biologically active compounds |
| CN103113828A (en) * | 2013-01-18 | 2013-05-22 | 上海金强粘合剂有限公司 | Water-based paint special for pinewood of furniture for children |
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| CN105461884A (en) | 2016-04-06 |
| CN108410295A (en) | 2018-08-17 |
| CN108410295B (en) | 2020-09-25 |
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