CN104497755A - High-weather-resistance and wide-construction-environment environmental-protection white gloss furniture paint - Google Patents

High-weather-resistance and wide-construction-environment environmental-protection white gloss furniture paint Download PDF

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Publication number
CN104497755A
CN104497755A CN201410697002.0A CN201410697002A CN104497755A CN 104497755 A CN104497755 A CN 104497755A CN 201410697002 A CN201410697002 A CN 201410697002A CN 104497755 A CN104497755 A CN 104497755A
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China
Prior art keywords
white light
environmental protection
paint
construction environment
adopts
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Pending
Application number
CN201410697002.0A
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Chinese (zh)
Inventor
黄维
徐水龙
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JIANGXI JINXIU MODERN CHEMICAL Co Ltd
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JIANGXI JINXIU MODERN CHEMICAL Co Ltd
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Priority to CN201410697002.0A priority Critical patent/CN104497755A/en
Publication of CN104497755A publication Critical patent/CN104497755A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/54Silicon-containing compounds
    • C08K5/5406Silicon-containing compounds containing elements other than oxygen or nitrogen
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/47Levelling agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention provides a high-weather-resistance and wide-construction-environment environmental-protection white gloss furniture paint prepared from three ingredients of a main paint, a curing agent and a diluent according to the ratio of 1:0.6-0.8:0.5 and through a general white gloss paint production process; the main paint is composed of acrylic resin and titanium dioxide as main ingredients cooperating with some other auxiliary agents; the curing agent is a mixture of an HDI curing agent, an HDI and TDI mixed trimer curing agent and a composite environment-friendly solvent; the diluent is a mixture of butyl acetate, propylene glycol monomethyl ether acetate and propylene glycol propyl ether acetate. The invention aims to provide the environmental-protection white gloss furniture paint which has wide construction environment, does not generate bubbles and prickly heat during a drying process, meets environmental-protection requirements and has the advantages of fast drying speed, good fullness, high hardness, high gloss, and extremely excellent collapse resistance and weather resistance.

Description

The white light furniture lacquer of high durable wide construction environment environmental protection
Technical field
The invention belongs to furniture and paint technical field, particularly color inhibition requires high, and the environment protection white light furniture lacquer that construction environment latitude is high, specifically relates to the white light furniture lacquer of a kind of high durable wide construction environment environmental protection.
Background technology
Environmental protection white light furniture is the classic products of honorable, succinct, pure and fresh, the lucid and lively modern trend furniture of tool, in today of furniture Events change, it is more and more subject to the favor in client and market, but white furniture lacquer for a long time as stringent that is new and construction environment causes white light furniture in production with after sale in process, there are product drawback, after sale complaint etc.
In the prior art, Brilliant white paint construction environment requires harsh, and the height of humiture has a strong impact on the end properties of white light.
Chinese patent CN201210116208.0 discloses a kind of Water white matt lacquer furniture paint and preparation method thereof, and Water white matt lacquer furniture paint comprises ethylene modified ACRYLIC EMULSION, wetting dispersing agent, defoamer, rutile titanium white powder, film coalescence aid, dumb light powder, modified waxes, thickening material and water.This furniture lacquer is non-toxic, environmental friendly, and uses water as primary solvent, can reduce the waste of Nonrenewable resources, belong to energy saving and environment friendly product.But this furniture lacquer film formation time is long, and after film forming, hardness is lower.
Chinese patent CN200510013515.6 discloses a kind of acrylic resin dispersion type aqueous woodware paint for decoration, and its compositing formula is that methacrylic acid three butoxy silane base third is cruel, and vinylformic acid second is cruel, vinylformic acid first is cruel, vinyl toluene, dimethyl styrene, i-butyl is cruel, Vinylstyrene, 4,4 '-azo dicyano valeric acid, emulsifying agent, emulsifying agent, deionized water.The content of this fancy paint volatile organic compounds (VOC) is low, to human body and environment without harm and pollute.Not containing triphen and free TDI, have cross-linking process significantly, after film forming drying, hardness improves constantly.But this furniture lacquer weathering resistance after furniture surface filming is bad, still there will be flavescence phenomenon after certain hour.
Summary of the invention
The object of this invention is to provide a kind of construction environment broad, do not play dark bubble, prickly heat, meet environmental requirement in drying process, have dry speed fast, fullness ratio is good, and hardness is high, and gloss is high, the white light furniture lacquer of environmental protection of collapse, excellent in weather.
The present invention adopts following technical scheme to realize above-mentioned purpose:
The white light furniture lacquer of a kind of high durable wide construction environment environmental protection, it is characterized in that: described furniture lacquer is by main paint, solidifying agent and thinner three kinds of component 1:0.6-0.8:0.5 in mass ratio, form with the configuration of the manufacture craft of general white clear lacquer, wherein the concrete composition of main paint and solidifying agent and proportioning as follows by mass percentage:
Main paint
Solidifying agent
(1) HDI type solidifying agent 40
(2) HDI and TDI mixed trimer curing agent 40
(3) composite environmental-friendly solvent 20.
HDI solidifying agent adopts the import environment friendly curing agent of 100% solid content to be main body, and main component is hexamethylene diisocyanate; Be equipped with HDI and TDI mixed trimer curing agent, its main component is hexamethylene diisocyanate and aromatic diisocyanate class, free TDI < 0.5%, complete compound country GB 18581-2009 industry standard;
Add high speed dispersion during configuration successively to full and uniform, viscosity controller is at 4500 ± 500cps/25 DEG C, and fineness controls at≤15 μm.
In a preferred technical scheme, the concrete composition of described thinner and proportioning are as follows by mass percentage:
Butylacetate 65
1-Methoxy-2-propyl acetate 25
Propylene glycol propyl ether acetic ester 10.
In a preferred technical scheme, described titanium dioxide adopts Rutile type Titanium Dioxide.Have good dispersity, color inhibition is effective, the advantage that whiteness is high.
In a preferred technical scheme, described defoamer adopts urethane dedicated defoamer, and main component is fluorosilicone solution.Its consistency is good, and antifoam performance is excellent, has certain help to the elimination of dark bubble.
In a preferred technical scheme, described flow agent adopts fluorine-carbon modified polyacrylic acid esters of gallic acid flow agent and a small amount of polyethers siloxane co-polymer flow agent to coordinate to arrange in pairs or groups.Levelling is effective, and has certain deaeration effect, thus avoids in foam seal and paint film, not easily produces dark bubble and prickly heat.
In a preferred technical scheme, described dispersion moisture agent adopts the resin solution containing silanol functional group.Have dispersion effect good, wettability is good, and has certain levelling property.
In a preferred technical scheme, described siccative adopts organo-bismuth and organic amine mix and match.Urge dry excellent effect.
In a preferred technical scheme, described composite environmental-friendly solvent adopts N-BUTYL ACETATE, 1-Methoxy-2-propyl acetate mixed configuration.Have hypotoxicity, smell is little, without the advantage of benzene homologues, VOC content meets national standard.
In a preferred technical scheme, described acrylic resin is that tertiary carbonic acid glycidyl ester is acrylic resin modified.Have fullness ratio good, solvent release is good, and gloss is high, and hardness is high, and rate of drying is fast.
Environmental protection of the present invention white light furniture lacquer construction environment is broad, does not play dark bubble, prickly heat, meet environmental requirement in drying process, and have dry speed fast, fullness ratio is good, and hardness is high, and gloss is high, the advantage of collapse, excellent in weather.
Embodiment
The present invention be directed to existing white light under humiture change, easily produce drawback and improved, this paint, is formed by the manufacture craft configuration of general clear lacquer in 1:0.6 ~ 0.8:0.5 ratio by main paint, solidifying agent, thinner.The concrete moiety of host, solidifying agent, thinner and proportioning as follows by mass percentage:
Embodiment one
Main paint
Solidifying agent
HDI type solidifying agent 40
HDI and TDI mixed trimer curing agent 40
Composite environmental-friendly solvent 20;
Thinner
Butylacetate 65
1-Methoxy-2-propyl acetate 25
Propylene glycol propyl ether acetic ester 10.
Described titanium dioxide adopts Rutile type Titanium Dioxide; Described defoamer adopts urethane dedicated defoamer, and main component is fluorosilicone solution; Described flow agent adopts fluorine-carbon modified polyacrylic acid esters of gallic acid flow agent and a small amount of polyethers siloxane co-polymer flow agent to coordinate to arrange in pairs or groups; Described dispersion moisture agent adopts the resin solution containing silanol functional group; Described siccative adopts organo-bismuth and organic amine mix and match; Described composite environmental-friendly solvent adopts N-BUTYL ACETATE, 1-Methoxy-2-propyl acetate mixed configuration; Described acrylic resin is that tertiary carbonic acid glycidyl ester is acrylic resin modified.
Embodiment two
Main paint
Other component is with embodiment one.
Embodiment three
Main paint
Other component is with embodiment one.
Finished product is made, with main paint: solidifying agent: thinner=1:0.8:0.5 sprays four blocks of sheet materials under following humiture environment by above-mentioned formula
After sheet material spraying, be positioned in respective environment and wait to parch, environmental simulation completes by constant temperature and humidity machine.
White finish paint of the present invention and on the market common white finish paint Performance comparision, as shown in table 1:
Table 1 white finish paint of the present invention and on the market common white finish paint performance comparison
Technical indicator of the present invention is as shown in table 2:
The technical indicator of table 2 furniture lacquer of the present invention
From table 1 and table 2 can obviously find out Brilliant white paint of the present invention spraying drying after not dark bubble, prickly heat, paint film is full, smooth, lasting non yellowing, extraneous construction humiture is on film performance without impact, and VOC content and free TDI content reach or be better than GB 18581-2009 standard, meet environment protection health requirement, safe and reliable.
Although the present invention has done detailed description, and provide some specific exampless, those skilled in the art are said, only otherwise leaving the spirit and scope of the present invention can do various change or correction is obvious.

Claims (9)

1. the white light furniture lacquer of high durable wide construction environment environmental protection, it is characterized in that: described furniture lacquer is by main paint, solidifying agent and thinner three kinds of component 1:0.6-0.8:0.5 in mass ratio, form with the configuration of the manufacture craft of general white clear lacquer, wherein the concrete composition of main paint and solidifying agent and proportioning as follows by mass percentage:
Main paint
Solidifying agent
(1) HDI type solidifying agent 40
(2) HDI and TDI mixed trimer curing agent 40
(3) composite environmental-friendly solvent 20;
HDI solidifying agent adopts the import environment friendly curing agent of 100% solid content to be main body, and main component is hexamethylene diisocyanate; Be equipped with HDI and TDI mixed trimer curing agent, its main component is hexamethylene diisocyanate and aromatic diisocyanate class, free TDI < 0.5%, complete compound country GB 18581-2009 industry standard;
Add high speed dispersion during configuration successively to full and uniform, viscosity controller is at 4500 ± 500cps/25 DEG C, and fineness controls at≤15 μm.
2. the white light furniture lacquer of a kind of high durable according to claim 1 wide construction environment environmental protection, is characterized in that: the concrete composition of described thinner and proportioning are as follows by mass percentage:
Butylacetate 65
1-Methoxy-2-propyl acetate 25
Propylene glycol propyl ether acetic ester 10.
3. the white light furniture lacquer of a kind of high durable according to claim 1 wide construction environment environmental protection, is characterized in that: described titanium dioxide adopts Rutile type Titanium Dioxide.
4. the white light furniture lacquer of a kind of high durable according to claim 1 wide construction environment environmental protection, is characterized in that: described defoamer adopts urethane dedicated defoamer, and main component is fluorosilicone solution.
5. the white light furniture lacquer of a kind of high durable according to claim 1 wide construction environment environmental protection, is characterized in that: described flow agent adopts fluorine-carbon modified polyacrylic acid esters of gallic acid flow agent and a small amount of polyethers siloxane co-polymer flow agent to coordinate to arrange in pairs or groups.
6. the white light furniture lacquer of a kind of high durable according to claim 1 wide construction environment environmental protection, is characterized in that: described dispersion moisture agent adopts the resin solution containing silanol functional group.
7. the white light furniture lacquer of a kind of high durable according to claim 1 wide construction environment environmental protection, is characterized in that: described siccative adopts organo-bismuth and organic amine mix and match.
8. the white light furniture lacquer of a kind of high durable according to claim 1 wide construction environment environmental protection, is characterized in that: described composite environmental-friendly solvent adopts N-BUTYL ACETATE, 1-Methoxy-2-propyl acetate mixed configuration.
9. the white light furniture lacquer of a kind of high durable according to claim 1 wide construction environment environmental protection, is characterized in that: described acrylic resin is that tertiary carbonic acid glycidyl ester is acrylic resin modified.
CN201410697002.0A 2014-11-27 2014-11-27 High-weather-resistance and wide-construction-environment environmental-protection white gloss furniture paint Pending CN104497755A (en)

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CN201410697002.0A CN104497755A (en) 2014-11-27 2014-11-27 High-weather-resistance and wide-construction-environment environmental-protection white gloss furniture paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410697002.0A CN104497755A (en) 2014-11-27 2014-11-27 High-weather-resistance and wide-construction-environment environmental-protection white gloss furniture paint

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CN104497755A true CN104497755A (en) 2015-04-08

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105505179A (en) * 2015-12-21 2016-04-20 惠州市彩森环保涂料有限公司 Environment-friendly polyurethane paint and preparation method thereof
CN108410295A (en) * 2015-12-22 2018-08-17 上海韬鸿化工科技有限公司 Antibacterial damage resistant paint

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101619194A (en) * 2008-07-02 2010-01-06 紫荆花制漆(上海)有限公司 Yellowing-resistant quick-drying polyurethane wood paint and using method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101619194A (en) * 2008-07-02 2010-01-06 紫荆花制漆(上海)有限公司 Yellowing-resistant quick-drying polyurethane wood paint and using method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105505179A (en) * 2015-12-21 2016-04-20 惠州市彩森环保涂料有限公司 Environment-friendly polyurethane paint and preparation method thereof
CN108410295A (en) * 2015-12-22 2018-08-17 上海韬鸿化工科技有限公司 Antibacterial damage resistant paint
CN108410295B (en) * 2015-12-22 2020-09-25 江门市蓬江区巨匠涂料化工有限公司 Antibacterial scratch-resistant paint

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Application publication date: 20150408

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