CN103802416B - High bright wear-resisting building materials and ornaments film and production method thereof - Google Patents
High bright wear-resisting building materials and ornaments film and production method thereof Download PDFInfo
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- CN103802416B CN103802416B CN201410040838.3A CN201410040838A CN103802416B CN 103802416 B CN103802416 B CN 103802416B CN 201410040838 A CN201410040838 A CN 201410040838A CN 103802416 B CN103802416 B CN 103802416B
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Abstract
A kind of high bright wear-resisting building materials and ornaments film production method is undertaken by following seven steps: one is get the raw materials ready; two is the dissolving of polyurethane resin and the preparation of parting liquid; three is preparations of UV oil; four is that the control of high-accuracy sleeve colour temperature is printed; five is basement membrane bottom-surface coated Chemical Decomposition liquid; six is coating UV oil, and seven is paste PET protection film.This decorating film is five layer stacked structure films, PET protection film layer from top to bottom successively, UV oil reservoir, ink printed layer, base membrane layer and polyurethane parting liquid coating, this decorating film is flexible strong, waterproof and mildew resistance good, widen the construction material kind being suitable for posting, except timber, bamboo wood, outside plastics and wood-base fibre and particle panel material, also be suitable for posting the material such as metal and cement, wide application, print clear open cylinder volume product time, the positive and negative of film is not adhered mutually, the texture of emulation is strong, cover amonang plate making furniture and exempt from paint, phenol is not discharged after dry, aldehyde and benzene, especially the decorating film making the concavo-convex imitative grain board of texture is suitable for.
Description
Technical field
The present invention relates to a kind of improve brightness and abrasion resistance post plastic sheeting matter decorating film in building material surface and production method thereof.
Background technology
For building materials veneer, at present extensive use be facing paper, mainly be used on the building materials such as plank, bamboo clappers, plastic plate, synthetic wood-based board and post, decorative building material surface is come with the pattern that facing paper prints, reach and beautify or the effect such as emulation, but facing paper is more crisp easily to be split, insecure, non-watertight, easily go mouldy.CN103276631A discloses one " feature of environmental protection bathroom composite decoration paper and manufacture method thereof " patent application, matrix is made with titanium valve paper, surface sprays wear-resistant medium layer, printing ink layer, melamine layer and acrylate layer successively thereon, improve flexibility and water proofing property, since but or facing paper, the defect of its papery is difficult to the greatest extent de-, also some fragility and easily split, mildew resistance is high not enough, firmness is desirable not enough.Through market adjustment and retrieval, not yet find that the wear-resisting plastics matter decorating film of height light for posting building materials is reported in market sale and data.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of high bright wear-resisting building materials and ornaments film and production method thereof.
The technical scheme solving this technical problem employing is: the bright wear-resisting building materials and ornaments film production method of this height follows these steps to carry out:
(1) get the raw materials ready: buy enough (1) polyvinyl chloride and polypropylene mixed plastic film makes basement membrane, (2) solid content is 18%-25%, heatproof 200 DEG C, ink are adhered to anticol band more than 10 times high strength without peeling in blue wool value >=6 grade of sun-proof, (3) polyurethane, (4) dimethylbenzene, (5) butyl acetate, (6) ink adhesion accelerant B K-750, (7) ABS anti-adhesion agent, (8) polysiloxane defoamers DF-805, (9) acroleic acid polyurethane, (10) acrylic acid epoxy fat, (11) toluene, (12) benzoin methyl ether, (13) BYK-341 levelling agent, (14) STA-505T Ca-Zn composite heat stabilizer, (15) DMP-30 epoxy promoter,
(2) dissolving of polyurethane resin and the preparation of parting liquid: the dimethylbenzene that 80 parts by weight of polyurethane and 20 weight portions make solvent mixes by (1), dissolves under 30-50 DEG C of condition; (2) put adhesion promoter BK-750,7 weight portion ABS anti-adhesion agents and 3 weight portion DF-805 defoamers with the polyurethane xylene solution that above-mentioned 50 weight portion mass concentrations are 80% with 35 parts by weight acetic acid butyl esters, 5 weight portion oil again to mix, after moderate-speed mixer 1h, obtained polyurethane resin parting liquid is for subsequent use;
(3) high bright wear-resisting oil is ultraviolet-curing paint, industry claims the preparation of UV oil: (1) is by the acrylic acid epoxy fat mix and blend 1h of the acroleic acid polyurethane of 35 weight portions and 65 weight portions, mixture becomes photosensitive resin, (2) by 90 parts by weight acetic acid butyl esters and 10 parts by weight of toluene mix and blends 20 minutes, mixture becomes organic solvent, (3) benzoin methyl ether is selected to make sensitising agent, (4) STA-505T Ca-Zn composite heat stabilizer used as stabilizers is selected, (5) BYK-341 is selected to make levelling agent, (6) DMP-30 epoxy promoter is selected to do promoter, (7) promoter of the levelling agent of the sensitising agent of the solvent of the photosensitive resin of 73 weight portions, 23 weight portions, 0.4 weight portion, 0.3 weight portion, the stabilizing agent of 1-7 weight portion and 1-6 weight portion is finally used, add in reactor, stir 1h under normal temperature and pressure, obtained high bright wear-resisting oil and UV oil for subsequent use,
(4) high-accuracy sleeve colour temperature control printing: (1) carries out high-voltage corona process to membrane surface, makes membrane surface energy reach 50-600 dyne; (2) with high-accuracy sleeve colour temperature control press printing, temperature control 80-120 DEG C, 25 DEG C that regulate printing-ink are coated with 4 glasss of viscositys respectively: the first look viscosity is 14-16s, the second look 14.5-16.5s, the 3rd look 15-17s, the 4th look 16-18s;
(5) basement membrane bottom-surface coated Chemical Decomposition liquid: regulated by the polyurethane resin parting liquid that step (two) is obtained 25 DEG C to be coated with 4 glasss of viscositys to 16-17s, be coated on basement membrane bottom surface, coating weight 2-3g/m
2;
(6) coating UV oil on ink printed layer: select the import UV coating machine that German Bei Gao institutional advertising manufactures and designs, by three roller height light coating methods, regulating 25 DEG C of paintings, 4 glasss of viscositys is 15-18-S, and solid content 95%, coating weight is 5-7g/gm
2, adopt the solidification of UV cure lamp after coating, solidification wave band 400nm, and exothermic temperature be down to 30 ± 2 DEG C, to solidifying drying with cold wind absorption heat sink;
(7) one deck length and width PET protection film consistent with basement membrane is pasted on its surface, film thickness 1-1.5 silk after UV oil reservoir being pasted PET and PET diaphragm: UV oil solidification drying; Last rolling, check, dispatch from the factory.
The height light wear-resisting building materials and ornaments film film body obtained by described production method is five layer stacked structure, is followed successively by PET protection film layer, UV oil reservoir, ink printed layer, base membrane layer and polyurethane parting liquid coating from top to bottom; Film body thickness 0.02-0.05mm, quantitative 32-50gsm, resistance to water >48hrs, the >200 of resistance to butanone time, wearability >200 turns, and under D60 light conditions, the height light process on surface reaches 99-100 degree.
The invention has the beneficial effects as follows: the building materials and ornaments film adopting this method to produce is flexible strong, waterproof and mildew resistance good, when opening cylinder volume product, the positive and negative of film is not adhered mutually, widen the construction material kind being suitable for posting, as metal and cement etc., the texture of printing clear emulation is strong, and pasting board makees furniture can exempt from paint, distribute without free phenol, aldehyde and benzene after dry, what be especially suitable for doing the concavo-convex imitative grain board of texture posts film.
Detailed description of the invention
The present invention is described in further detail below in conjunction with embodiment: the bright wear-resisting building materials and ornaments film production method of this height follows these steps to carry out:
(1) get the raw materials ready: buy enough (1) polyvinyl chloride and polypropylene mixed plastic film makes basement membrane, (2) solid content is 18%-25%, heatproof 200 DEG C, ink are adhered to anticol band more than 10 times high strength without peeling in blue wool value >=6 grade of sun-proof, (3) polyurethane, (4) dimethylbenzene, (5) butyl acetate, (6) ink adhesion accelerant B K-750, (7) ABS anti-adhesion agent, (8) polysiloxane defoamers DF-805, (9) acroleic acid polyurethane, (10) acrylic acid epoxy fat, (11) toluene, (12) benzoin methyl ether, (13) BYK-341 levelling agent, (14) STA-505T Ca-Zn composite heat stabilizer, (15) DMP-30 epoxy promoter,
(2) dissolving of polyurethane resin and the preparation of parting liquid: the dimethylbenzene that 80 parts by weight of polyurethane and 20 weight portions make solvent mixes by (1), dissolves under 30-50 DEG C of condition; (2) put adhesion promoter BK-750,7 weight portion ABS anti-adhesion agents and 3 weight portion DF-805 defoamers with the polyurethane xylene solution that above-mentioned 50 weight portion mass concentrations are 80% with 35 parts by weight acetic acid butyl esters, 5 weight portion oil again to mix, after moderate-speed mixer 1h, obtained polyurethane resin parting liquid is for subsequent use;
(3) high bright wear-resisting oil is ultraviolet-curing paint, industry claims the preparation of UV oil: (1) is by the acrylic acid epoxy fat mix and blend 1h of the acroleic acid polyurethane of 35 weight portions and 65 weight portions, mixture becomes photosensitive resin, (2) by 90 parts by weight acetic acid butyl esters and 10 parts by weight of toluene mix and blends 20 minutes, mixture becomes organic solvent, (3) benzoin methyl ether is selected to make sensitising agent, (4) STA-505T Ca-Zn composite heat stabilizer used as stabilizers is selected, (5) BYK-341 is selected to make levelling agent, (6) DMP-30 epoxy promoter is selected to do promoter, (7) promoter of the levelling agent of the sensitising agent of the solvent of the photosensitive resin of 73 weight portions, 23 weight portions, 0.4 weight portion, 0.3 weight portion, the stabilizing agent of 1-7 weight portion and 1-6 weight portion is finally used, add in reactor, stir 1h under normal temperature and pressure, obtained high bright wear-resisting oil and UV oil for subsequent use,
(4) high-accuracy sleeve colour temperature control printing: (1) carries out high-voltage corona process to membrane surface, makes membrane surface energy reach 50-600 dyne; (2) with high-accuracy sleeve colour temperature control press printing, temperature control 80-120 DEG C, 25 DEG C that regulate printing-ink are coated with 4 glasss of viscositys respectively: the first look viscosity is 14-16s, the second look 14.5-16.5s, the 3rd look 15-17s, the 4th look 16-18s;
(5) basement membrane bottom-surface coated Chemical Decomposition liquid: regulated by the polyurethane resin parting liquid that step (two) is obtained 25 DEG C to be coated with 4 glasss of viscositys to 16-17s, be coated on basement membrane bottom surface, coating weight 2-3g/m
2;
(6) coating UV oil on ink printed layer: select the import UV coating machine that German Bei Gao institutional advertising manufactures and designs, by three roller height light coating methods, regulating 25 DEG C of paintings, 4 glasss of viscositys is 15-18S, and solid content 95%, coating weight is 5-7g/gm
2, adopt the solidification of UV cure lamp after coating, solidification wave band 400nm, and exothermic temperature be down to 30 ± 2 DEG C, to solidifying drying with cold wind absorption heat sink;
(7) paste one deck length and width PET protection film consistent with basement membrane on its surface, film thickness 1-1.5 silk after UV oil reservoir being pasted PET and PET diaphragm: UV oil solidification drying, last rolling, check, dispatch from the factory.
2, with the wear-resisting building materials and ornaments film of height light that production method described in claim 1 is obtained, it is characterized in that film body is five layer stacked structure, be followed successively by PET protection film layer, UV oil reservoir, ink printed layer, base membrane layer and polyurethane parting liquid coating from top to bottom; Film body thickness 0.02-0.05mm, quantitative 32-50gsm, resistance to water >48hrs, the >200 of resistance to butanone time, wearability >200 turns, and under D60 light conditions, the height light process on surface reaches 99-100 degree.
It should be noted that in above steps, important technological parameters is monodrome, embodiment is most preferred embodiment.The solution temperature condition of all the other steps (two) (1), the membrane surface energy value of step (four) (1), step (four) (2) though printing temperature control value and ink viscosity value etc. be interval value, but be all open-and-shut, the each point value understood in this number range is all feasible and can realizes goal of the invention, therefore also just lists embodiment no longer one by one.
The BK-750 type that ink adhesion promoter in getting the raw materials ready selects Guangzhou Run Fu Chemical Co., Ltd. to produce, anti-adhesion agent selects the ABS i.e. two-9-octadecylene acid amides of (Z, Z)-N, N '-1,2-second two subunit, makes plastics remover and in-lubricant.The DF-805 type defoamer that polysiloxane defoamers selects Dongguan De Feng Chemical Co., Ltd. to produce, the levelling agent in getting the raw materials ready, stabilizing agent and promoter all can be buied from the wooden company in Jiangsu three, and industrial chemicals all selects industrial pure material.All the other each raw materials are obtained by commercial or net purchase.
The effect of this film bottom and polyurethane parting liquid coating need be wound into tubular when being product export, the positive and negative of film mutually near, when user use open reel time, the positive and negative of film is not adhered.Ink printed layer is coated with UV oil and can improves wearability and brightness; The PET protection film of the most top layer of this film is to protect UV oil reservoir not frayed completely, guarantees brightness, reaches the effect that furniture surfacing exempts to paint, need pull except this diaphragm when therefore user uses.
Claims (2)
1. the wear-resisting building materials and ornaments film production method of high light, is characterized in that following these steps to carry out:
(1) get the raw materials ready: buy enough (1) polyvinyl chloride and polypropylene mixed plastic film makes basement membrane, (2) solid content is 18%-25%, heatproof 200 DEG C, ink are adhered to anticol band more than 10 times high strength without peeling in blue wool value >=6 grade of sun-proof, (3) polyurethane, (4) dimethylbenzene, (5) butyl acetate, (6) ink adhesion accelerant B K-750, (7) ABS anti-adhesion agent, (8) polysiloxane defoamers DF-805, (9) acroleic acid polyurethane, (10) acrylic acid epoxy fat, (11) toluene, (12) benzoin methyl ether, (13) BYK-341 levelling agent, (14) STA-505T Ca-Zn composite heat stabilizer, (15) DMP-30 epoxy promoter,
(2) dissolving of polyurethane resin and the preparation of parting liquid: the dimethylbenzene that 80 parts by weight of polyurethane and 20 weight portions make solvent mixes by (1), dissolves under 30-50 DEG C of condition; (2) mix with 35 parts by weight acetic acid butyl esters, 5 weight portion ink adhesion accelerant B K-750,7 weight portion ABS anti-adhesion agents and 3 weight portion DF-805 defoamers with the polyurethane xylene solution that above-mentioned 50 weight portion mass concentrations are 80%, after moderate-speed mixer 1h, obtained polyurethane resin parting liquid is for subsequent use again;
(3) high bright wear-resisting oil is ultraviolet-curing paint, industry claims the preparation of UV oil: (1) is by the acrylic acid epoxy fat mix and blend 1h of the acroleic acid polyurethane of 35 weight portions and 65 weight portions, mixture becomes photosensitive resin, (2) by 90 parts by weight acetic acid butyl esters and 10 parts by weight of toluene mix and blends 20 minutes, mixture becomes organic solvent, (3) benzoin methyl ether is selected to make sensitising agent, (4) STA-505T Ca-Zn composite heat stabilizer used as stabilizers is selected, (5) BYK-341 is selected to make levelling agent, (6) DMP-30 epoxy promoter is selected to do promoter, (7) promoter of the levelling agent of the sensitising agent of the solvent of the photosensitive resin of 73 weight portions, 23 weight portions, 0.4 weight portion, 0.3 weight portion, the stabilizing agent of 1-7 weight portion and 1-6 weight portion is finally used, add in reactor, stir 1h under normal temperature and pressure, obtained high bright wear-resisting oil and UV oil for subsequent use,
(4) high-accuracy sleeve colour temperature control printing: (1) carries out high-voltage corona process to membrane surface, makes membrane surface energy reach 50-600 dyne; (2) with high-accuracy sleeve colour temperature control press printing, temperature control 80-120 DEG C, 25 DEG C that regulate printing-ink are coated with 4 glasss of viscositys respectively: the first look viscosity is 14-16s, the second look 14.5-16.5s, the 3rd look 15-17s, the 4th look 16-18s;
(5) basement membrane bottom-surface coated Chemical Decomposition liquid: regulated by the polyurethane resin parting liquid that step (two) is obtained 25 DEG C to be coated with 4 glasss of viscositys to 16-17s, be coated on basement membrane bottom surface, coating weight 2-3g/m
2;
(6) coating UV oil on ink printed layer: select the import UV coating machine that German Bei Gao institutional advertising manufactures and designs, by three roller height light coating methods, regulating 25 DEG C of paintings, 4 glasss of viscositys is 15-18s, and solid content 95%, coating weight is 5-7g/m
2, adopt the solidification of UV cure lamp after coating, solidification wave band 400nm, and exothermic temperature be down to 30 ± 2 DEG C, to solidifying drying with cold wind absorption heat sink;
(7) one deck length and width PET protection film consistent with basement membrane is pasted on its surface, film thickness 1-1.5 silk after UV oil reservoir being pasted PET and PET diaphragm: UV oil solidification drying; Last rolling, check, dispatch from the factory.
2., with the wear-resisting building materials and ornaments film of height light that production method described in claim 1 is obtained, it is characterized in that film body is five layer stacked structure, be followed successively by PET protection film layer, UV oil reservoir, ink printed layer, base membrane layer and polyurethane parting liquid coating from top to bottom; Film body thickness 0.02-0.05mm, quantitative 32-50gsm, resistance to water > 48hrs, the > of resistance to butanone 200 times, wearability > 200 turns, under D60 light conditions, the height light process on surface reaches 99-100 degree.
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| CN106183285A (en) * | 2016-08-30 | 2016-12-07 | 天津达因建材有限公司 | A kind of composite membrane, sheet material and preparation of plates method |
| CN106427260A (en) * | 2016-08-30 | 2017-02-22 | 天津达因建材有限公司 | Panel and preparing method thereof |
| CN111452440A (en) * | 2020-05-11 | 2020-07-28 | 景德镇陶瓷大学 | Environment-friendly paint-spraying-free fireproof water printing film and water film watermark printing process |
| CN114752311B (en) * | 2021-11-03 | 2024-05-03 | 东莞市雄林新材料科技股份有限公司 | TPU protective film and preparation method thereof |
| CN116444837B (en) * | 2023-03-08 | 2024-02-23 | 河源市万利科技有限公司 | Furniture decoration highlight film and preparation method thereof |
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| CN202463093U (en) * | 2011-12-27 | 2012-10-03 | 浙江博泰塑胶有限公司 | High bright flame retardant decorative film |
| CN202640907U (en) * | 2012-04-23 | 2013-01-02 | 曾聪 | PVC (Poly Vinyl Chloride)-PET (Polyethylene Terephthalate) composite bright film |
| CN203282943U (en) * | 2013-06-14 | 2013-11-13 | 江苏立霸实业股份有限公司 | Environment-friendly PET-PVB light membrane |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6984440B2 (en) * | 2002-02-07 | 2006-01-10 | C.I. Kasei Company, Limited | Decorative sheet and method for producing the same |
| JP2007327065A (en) * | 2007-07-31 | 2007-12-20 | Mitsubishi Polyester Film Copp | Laminated polyester film |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202463093U (en) * | 2011-12-27 | 2012-10-03 | 浙江博泰塑胶有限公司 | High bright flame retardant decorative film |
| CN202640907U (en) * | 2012-04-23 | 2013-01-02 | 曾聪 | PVC (Poly Vinyl Chloride)-PET (Polyethylene Terephthalate) composite bright film |
| CN203282943U (en) * | 2013-06-14 | 2013-11-13 | 江苏立霸实业股份有限公司 | Environment-friendly PET-PVB light membrane |
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Denomination of invention: High gloss and wear-resistant building material decorative film and its production method Effective date of registration: 20230914 Granted publication date: 20151202 Pledgee: Hangzhou branch of Bank of Nanjing Co.,Ltd. Pledgor: ZHEJIANG SHENGLONG DECORATION MATERIAL Co.,Ltd. Registration number: Y2023330002040 |
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