CN105431129A - 透明的防晒剂化合物和其应用 - Google Patents
透明的防晒剂化合物和其应用 Download PDFInfo
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- CN105431129A CN105431129A CN201480041727.2A CN201480041727A CN105431129A CN 105431129 A CN105431129 A CN 105431129A CN 201480041727 A CN201480041727 A CN 201480041727A CN 105431129 A CN105431129 A CN 105431129A
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- sunscreen
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- ester
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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Abstract
本发明的主题是透明的防晒剂化合物,其包括α-羟基羧酸的酯和固态的有机UV过滤物,所述有机UV过滤物处于溶解状态下,并且所述防晒剂化合物基本上没有水和乙醇,并且本发明还涉及将所述防晒剂化合物作为防晒剂、尤其是防晒凝胶或防晒喷雾的应用。
Description
技术领域
本发明涉及一种透明的防晒剂化合物,其包括α-羟基羧酸的酯和固态的有机UV过滤物,所述有机UV过滤物处于溶解状态下,并且所述防晒剂化合物基本上没有水和乙醇,并且本发明还涉及将所述防晒剂化合物作为防晒剂、尤其是防晒凝胶或防晒喷雾的应用。
背景技术
太阳晒黑皮肤的趋势是长年未被减弱的。为了达到该情况,人们将其皮肤暴漏于太阳辐射下。替选地则寻找日光浴工作室。然而,太阳光的UVA和UVB辐射也对皮肤具有损害性的作用。当人类皮肤在较长的时间段暴露于太阳时,这能够导致不同的损伤。例如列举红斑、皮肤病、皮肤发言、皮肤加速老化以及皮肤癌。因此,为了保护皮肤提供多种防晒剂。所述防晒剂还包含能够使用在化妆配置品中的光保护过滤物。该UVA和UVB过滤物在大多数国家以白名单的形式总结,如编号为1223/2009的关于化妆试剂的欧洲法规的附件VI。
大量市售的防晒剂不应当掩盖现有技术的准备具有一系列缺点的事实。因此,得到大量膏和乳液形式的防晒剂,其中与本发明不同地涉及O/W或W/O乳剂。根据经验,这种类型的防晒剂的用户通常将过少的量涂抹到皮肤上,使得没有达到在包装上说明的防晒系数。此外,多种根据现有技术已知的防晒剂除了有机的UV过滤物之外包含无机的UV过滤物,例如TiO2或ZnO,所述无机的UV过滤物以小固态颗粒的形式存在,因此其作为分散剂存在进而不产生透明的防晒剂化合物,并且在应用到皮肤上时通常形成白色的、对于使用者感觉为是干扰性的沉淀物。
因为与本发明不同,所提出的防晒剂为乳剂以及分散剂,所以其包含乳化剂或者分散剂。所述乳化剂或者分散剂在将防晒剂涂抹到皮肤上之后在湿度高的情况下,例如因流汗或洗澡引起的湿度高的情况下显著份额的UVA和UVB过滤物再次乳化并且脱离皮肤,使得其不再提供防晒保护。
替选地,DE20200006005U1以及DE102005059742A1提出透明的、含醇的防晒凝胶或喷雾,所述防晒凝胶或喷雾由大量用户由于其外观而被增加地使用,所述外观与新鲜、透彻和自然联系在一起。所述透明的防晒凝胶或喷雾包含至少20重量百分比的乙醇。乙醇的存在由于令人感觉新鲜凉爽的感觉而获益。但是已知的是:乙醇将皮肤干燥并且能够刺激皮肤。此外,将包含乙醇的防晒剂被禁止用于特定的使用人群,如婴儿和小孩。
替选地,DE602004009901T2尤其要求保护包含透明的且凝胶状的防晒剂的载体。该载体为油,例如肉豆蔻酸异丙酯,棕榈酸异丙酯,苯甲酸烷基酯,优选矿物油。所述油所具有的唯一目的是溶解有机UV过滤物。所述油没有对于暴露于阳光的皮肤具有显著优点的保湿和皮肤舒缓的作用。将软化剂的附加的功能归于矿物油。但是已知的是:矿物油封闭毛孔进而将皮肤呼吸最小化。
EP0685226B1要求保护化妆化合物,所述化妆化合物还包含固态有机UV过滤物乙基己基三嗪酮以及α-羟基羧酸的酯。其未说明所要求保护的化妆化合物为透明的,相反地,其为含水的乳液,总的来看为防晒配方。
EP0904776B1要求保护由至少一种过滤物类型的UV过滤物与酒石酸二烷基酯混合构成的化合物,所述UV过滤物从苄叉基樟脑,二苯甲酰甲烷和/或三嗪中导出。在此也没有任何关于所要求保护的化合物适合于制备透明的防晒剂的说明。
EP0800816B1要求保护由三嗪衍生物作为UV过滤物和α,β-二羟基羧酸的一种或多种二烷基酯构成的起防晒作用的活性材料组合。其没有关于所要求保护的化合物适合于制备透明的防晒剂的任何说明,相反其为含水的乳液。
发明内容
本发明的目的在于,消除上述缺点。令人惊讶地发现:根据权利要求的防晒剂化合物或其应用弥补了上述缺点。
发明总述
本发明涉及透明的防晒剂化合物,其包括α-羟基羧酸的酯。在另一实施方式中,本发明涉及将防晒剂化合物作为可喷雾到皮肤上的防晒喷雾和作为用手可施加到皮肤上的凝胶的应用。由于防晒剂化合物为透明液体的事实,所述防晒剂组合不作为乳液和/或分散剂存在。不需要使用表面活性剂,并且透明的防晒剂化合物因此优选是无表面活性剂的。
本发明详细地涉及透明的防晒剂化合物,其包含
(a)α-羟基羧酸的至少一种酯,其在此优选为5至95重量百分比、尤其优选10至85重量百分比并且特别优选15至80重量百分比;
(b)至少一种不可水溶的且固态的有机UV过滤物,尤其是UVA和UVB过滤物;
(c)最多1重量百分比的水,和
(d)最多1重量百分比的乙醇;
并且可选地
(e)0-10重量百分比的一种或多种增稠剂,其包含硅酸盐、亲水的无定形的硅酸酯或疏水的无定形的硅酸酯或其混合物;
并且独立于(e)必要时还可选地尤其包括
(f)0至60重量百分比的、优选5至50重量百分比的、尤其优选10至40重量百分比的饱和的或不饱和的、支化的或直链的、10至30个碳原子链长的醇或其混合物、优选C10至C30格尔伯特醇。
当可以在日光中通过填充有根据本发明的防晒剂化合物的一次性玻璃管(BrandGmbH公司,Wertheim/德国,尺寸12.5×12.5×45mm,波长范围300nm-900nm)用裸眼观察时,根据本发明的防晒剂化合物感觉是透明的。直接位于一次性玻璃管后方的文字(子体:Arial,字号:8)必须是可清楚识别和可读的。“在水中不可溶”或“不溶于水”表示:有机的UV过滤物在25℃的情况下在水中溶解小于0.5重量百分比。“固态”表示:有机的UV过滤物在25℃的情况下是固体;尤其当前以结晶的形式存在。
本申请的更详细的说明
α-羟基羧酸,即例如乳酸、柠檬酸、苹果酸、酒石酸在化妆准备中具有广泛应用。其还用作为保湿剂并且用于针对紧张的和衰老的皮肤激发在皮肤中的细胞代谢。因为α-羟基羧酸在浓度低的情况下已经引起皮肤刺激,所以其在化妆配置品中的使用是极其受限的。α-羟基羧酸的酯对其进行补救,所述酯能够视作为α-羟基羧酸的载体,并且缓慢地通过存在于皮肤中和其上的酯酶在释放α-羟基羧酸的情况下裂解。
该裂解缓慢地进行,使得α-羟基羧酸的酯对皮肤施加长期护肤作用。通过在皮肤上缓慢释放α-羟基羧酸,与游离的α-羟基羧酸相比借助于化妆配置品有可能将大量的α-羟基羧酸的酯涂覆到皮肤上,在那里其起到保湿和舒缓的租用。根据本发明使用的α-羟基羧酸的全部酸基团因此被酯化。
根据本发明的透明的防晒剂组分包含α-羟基羧酸的至少一种酯作为酸组分和具有饱和的或不饱和的、直链的或支化的具有R=C8-C20烷基的R-OH或他们的混合物作为醇组分。尤其优选地,酯为乳酸的、柠檬酸的、苹果酸的、酒石酸的酯或其混合物作为酸组分,并且饱和的或不饱和的、直链的或支化的具有R=C8-C20烷基的R-O(H)或他们的混合物作为醇组分。
α-羟基羧酸的这种酯以如下名称提供:ELI(INCI:C12-13乳酸烷基),ECI(INCl:Tri-C12-13柠檬酸烷基),ECL(INCI:Tri-C14-15柠檬酸烷基),EMI(INCI:Di-C12-13苹果酸烷基),ETI(INCI:Di-C12-13酒石酸烷基)以及ETLP(INCI:酒石酸双肉豆蔻)。除了对于太阳损伤的皮肤的保湿和舒缓作用之外,该酯的特征在于:其为对于有机UV过滤物、尤其固态的有机UV过滤物的良好的溶剂。
此外,根据本发明的防晒剂化合物包含至少一个不可水溶的且固态的有机的UVA和/或UVB过滤物,如其在编号为1223/2009的关于化妆试剂的欧洲法规的附件VI中提出。尤其优选的是,二乙基氨基羟基苯甲酰苯甲酸己酯(APlus,BASF)、甲氧基肉桂酸乙基己酯(例如EusoleMerck),乙基三嗪酮(T150,BASF),双-乙基己氧基苯酚甲氧基苯基三嗪(S,BASF)和丁基甲氧基二苯甲酰基甲烷(EusoleMerck)。
不可水溶的且固态的有机UV过滤物是在α-羟基羧酸的酯中或其混合物和防晒剂化合物中是可溶的。因此,防晒剂化合物也是透明的。除了至少一种不可水溶的且固态的有机的UVA和/或UVB过滤物或其混合物之外,例如也能够存在液态的可溶的UVA或UVB过滤物或其混合物。
根据本发明的透明的防晒剂化合物包含最多1重量百分比的水和最多1重量百分比的乙醇进而基本上没有水并且基本上没有乙醇。此外,根据本发明的透明的防晒剂化合物优选包含最多1重量百分比的C3醇和优选最多1重量百分比的C4醇。
在本发明的另一设计方案中,能够通过使用一种或多种增稠剂来制备透明的且明胶状的防晒剂化合物,所述增稠剂包含硅酸盐、亲水的无定形的硅酸酯或疏水的无定形的硅酸酯或其混合物。示例地列举出:Evonik工业公司的-和型号产品和Wacker化学品公司的HDK型号产品。
根据本发明的透明的防晒剂化合物当其用作为喷雾时包含0至2重量百分比、尤其0至1重量百分比、如0.01至0.1重量百分比的上述增稠剂。根据本发明的透明的防晒剂化合物当其用作为凝胶时包含0-10重量百分比、尤其1至8重量百分比并且尤其优选1.5至4重量百分比的上述增稠剂。
此外,根据本发明的透明的防晒剂化合物除了α-羟基羧酸的酯之外包含油或蜡或其混合物。有利地,油和/或蜡选自下述物质的组:6至24链长的、特别是12至18个碳原子的饱和或不饱和的支化和/或直链的烷基羧酸的甘油三酯、卵磷脂,其中包括它们的混合物。
卵磷脂能够有利地是合成的、半合成的或天然的油和/或蜡,如三异硬脂精(三异硬脂酸甘油酯,triisostearin),大豆油,蓖麻油,橄榄油,红花油,小麦胚芽油,葡萄籽油,花生油,葵花油,杏仁油,棕榈油,棕榈仁油,椰子油,红花油,月见草油,油菜籽油和类似物。
此外,油和/或蜡能够由下述物质的组构成:支化的和/或直链的烃,例如石蜡,凡士林(矿脂),矿物油,石蜡油,异十六烷,十二烷,十四烷,十六烷,十八烷,二十二烷和聚烯烃。就本发明而言,油和/或蜡还能够有利地选自下述物质的组:链长为3至30个C原子的饱和的和/或不饱和的、支化的和/或直链的烷基羧酸和链长为3至30个C原子的饱和的或不饱和的支化的或直链的醇,包括其混合物。示例地列举出:霍霍巴油,肉豆蔻酸异丙酯,棕榈酸异丙酯,硬脂酸异丙酯,油酸异丙酯,硬脂酸正丁基,月桂酸正己酯,油酸正癸酯,硬脂酸异辛酯,硬脂酸异壬酯,异壬酸异壬酯,棕榈酸2-乙基己基酯,月桂酸2-乙基己基酯,硬脂酸2-己基癸酯,棕榈酸2-辛基十二烷基酯,油酸油酯(oleyloleate),芥酸油醇酯、油酸芥酯(erucyloleate)和芥酸芥酯(erucylerucate)。此外,根据本发明的乳剂能够包含选自下述物质的组的油和/或蜡:硅油(环状和/或直链的)和二烷基醚,如二辛基醚或二硬脂基醚,或碳酸二烯丙酯。具有链长为3至30个C原子的饱和的或不饱和的、支化的或直链的醇的芳香族的碳酸的酯能够应用在根据本发明的透明的防晒剂中,其中包括其混合物,例如C12-15烷基苯甲酸酯。就本发明而言,能够有利地使用这种油和蜡组分的任意的混合。
根据本发明的透明的防晒剂化合物优选包含链长10至30个C原子的饱和的或不饱和的、支化的或直链的醇,其中包括其混合物。尤其优选的是:格尔伯特醇,如12(INCI:丁基辛醇,Sasol德国),16(INCI:己基癸醇),18T(INCI:辛基癸醇)或者20(INCI:辛基十二醇),其中包括其混合物。
此外,根据本发明的透明的防晒剂化合物能够包含其他的化妆和/或制药学的辅助材料、附加材料和/或活性材料。这例如是:例如薄荷醇的清爽材料,染料,香料,抗氧化剂,植物提取物,防汗剂,防晒剂,成膜剂,蛋白质水解物,维生素,抗微生物剂和类似物。
实例
下面的实例应解释本发明,而不对其进行限制。全部量说明都以重量计和以配置品的总量计。
相A加热至60℃并且被搅拌,直至试样变得清澈。使试样冷却到大约30℃并且添加相B和均匀化。为了制备凝胶,添加相C并且借助于高速分散机均匀化。随后,将凝胶在真空下消泡。
确定清澈熔点:用5-10mL要检测的、清澈的产物填充试管或Shukoff小烧瓶并且设有零下温度计。试样在低温池中冷却到至少-20℃,直到试样完全冻结。随后,试样在室温下缓慢地解冻。将其中试样不再显示出可识别的浑浊的温度视作为清澈熔点。结果,只要其差值不超过1℃,就从两个确定数中得出算数平均值。
研究的相应的配方和结果在表格1a、1b、2a和2b中示出。
表格1b透明的防晒喷雾-特性
表格2b透明的防晒凝胶-特性
表格1a和2a的表格说明
*)制造商:(1)=SasolGermanyGmbH(2)=SasolItalyS.p.A.
(3)=BASFAG(4)=MerckKgaA
(5)=InnolexChemicalCo.(6)=DSMNutritionalProductsLtd.
(7)=EvonikInd.AG
1)www.sunscreensimulator.basf.com/Sunscreen_Simulator/Login_show.action
Claims (10)
1.一种透明的防晒剂化合物,包含
(a)α-羟基羧酸的至少一种酯,
(b)至少一种不可水溶的且固态的有机UV过滤物,
(c)最多1重量百分比的水,和
(d)最多1重量百分比的乙醇。
2.根据权利要求1所述的防晒剂化合物,还包含
(e)0-10重量百分比的一种或多种增稠剂,所述增稠剂包含硅酸盐、亲水的或疏水的、无定形的硅酸酯或所述硅酸盐和所述硅酸酯的混合物。
3.根据权利要求1所述的防晒剂化合物,还包含
(f)0至60重量百分比的、优选5至50重量百分比的、尤其优选10至40重量百分比的饱和的或不饱和的、支化的或直链的、10至30个C原子链长的醇或它们的混合物、优选C10至C30格尔伯特醇。
4.根据权利要求1所述的防晒剂化合物,其中,α-羟基羧酸的所述酯具有带有RC8-C20烷基的、饱和的或不饱和的、直链的或支化的R-O-(H)醇或它们的混合物作为醇组分。
5.根据权利要求1或2所述的防晒剂化合物,其中,α-羟基羧酸的所述酯(a)具有乳酸、柠檬酸、苹果酸、酒石酸或这些酸的混合物作为酸组分。
6.根据权利要求1、4或5所述的防晒剂化合物,其中,在所述防晒剂化合物中包含5至95重量百分比的、优选10至85重量百分比的并且尤其优选15至80重量百分比的α-羟基羧酸的所述酯。
7.根据权利要求1所述的防晒剂化合物,其中,所述不可水溶的且固态的有机UV过滤物是或者包括二乙基氨基羟基苯甲酰苯甲酸己酯、甲氧基肉桂酸乙基己酯、乙基三嗪酮、双-乙基己氧基苯酚甲氧基苯基三嗪、丁基甲氧基二苯甲酰基甲烷或它们的混合物。
8.根据权利要求1所述的防晒剂化合物,还包含
(g)油或者蜡或所述油和所述蜡的混合物。
9.一种将根据上述权利要求中任一项所述的防晒剂化合物作为防晒剂的应用,尤其作为防晒喷雾,所述防晒喷雾优选能够借助手动泵喷射。
10.一种将根据权利要求1至8中任一项所述的防晒剂化合物作为防晒凝胶的应用。
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DE202013103395U DE202013103395U1 (de) | 2013-07-26 | 2013-07-26 | Transparente Sonnenschutzmittelzusammensetzungen und deren Verwendung |
DE202013103395.2 | 2013-07-26 | ||
PCT/DE2014/000371 WO2015010679A1 (de) | 2013-07-26 | 2014-07-23 | Transparente sonnenschutzmittelzusammensetzungen und deren verwendung |
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US (1) | US20160166485A1 (zh) |
EP (1) | EP3024433A1 (zh) |
CN (1) | CN105431129A (zh) |
AU (1) | AU2014295502B2 (zh) |
BR (1) | BR112016001715B1 (zh) |
CA (1) | CA2917737A1 (zh) |
DE (2) | DE202013103395U1 (zh) |
MX (1) | MX2016001129A (zh) |
MY (1) | MY183624A (zh) |
RU (1) | RU2684776C2 (zh) |
WO (1) | WO2015010679A1 (zh) |
ZA (1) | ZA201600140B (zh) |
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CN112165975A (zh) * | 2018-05-18 | 2021-01-01 | 帝斯曼知识产权资产管理有限公司 | 局部组合物 |
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DE102014207919A1 (de) * | 2014-04-28 | 2015-10-29 | Beiersdorf Ag | Sonnenschutzmittel mit reduzierter Neigung zur Textilverfleckung I |
WO2020088778A1 (en) * | 2018-11-02 | 2020-05-07 | Symrise Ag | A liquid and transparent blend of uv filters |
EP4000692A1 (en) | 2020-11-17 | 2022-05-25 | Beiersdorf AG | Two component sunscreen |
CN114177111A (zh) * | 2021-12-20 | 2022-03-15 | 中山中研化妆品有限公司 | 防晒喷雾剂及其制备方法 |
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MY183624A (en) | 2021-03-03 |
RU2684776C2 (ru) | 2019-04-15 |
CA2917737A1 (en) | 2015-01-29 |
MX2016001129A (es) | 2016-07-26 |
ZA201600140B (en) | 2017-04-26 |
BR112016001715A2 (pt) | 2017-09-19 |
RU2016105514A3 (zh) | 2018-05-31 |
AU2014295502A1 (en) | 2016-01-28 |
RU2016105514A (ru) | 2017-08-31 |
BR112016001715B1 (pt) | 2020-08-11 |
DE112014003462A5 (de) | 2016-06-23 |
DE202013103395U9 (de) | 2014-08-28 |
US20160166485A1 (en) | 2016-06-16 |
WO2015010679A1 (de) | 2015-01-29 |
DE202013103395U1 (de) | 2013-08-13 |
EP3024433A1 (de) | 2016-06-01 |
AU2014295502B2 (en) | 2019-10-17 |
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