CN105379780A - Pesticide, as well as preparation method and application thereof - Google Patents
Pesticide, as well as preparation method and application thereof Download PDFInfo
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- CN105379780A CN105379780A CN201510701647.1A CN201510701647A CN105379780A CN 105379780 A CN105379780 A CN 105379780A CN 201510701647 A CN201510701647 A CN 201510701647A CN 105379780 A CN105379780 A CN 105379780A
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- insecticide
- aloe
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/48—Zingiberaceae [Ginger family], e.g. ginger or galangal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Abstract
The invention discloses a pesticide, as well as a preparation method and application thereof, and belongs to the technical field of preparation of pesticides. The pesticide comprises the following raw materials in parts by weight: 30-60 parts of Chinese arborvitae twigs and leaves, 30-60 parts of mint, 30-60 parts of lettuces, 30-40 parts of anabasis aphylla, 30-40 parts of paulownia leaves, 30-40 parts of sophora alopecuroides, 20-30 parts of absinthium, 20-30 parts of yellow ginger, 20-30 parts of aloe and 1000-4000 parts of water. The pesticide is prepared through the steps of extraction of liquid medicines, concentration, drying, crushing, screening, sterilization and the like. The pesticide disclosed by the invention is non-toxic in ingredients, free from residues, pollution-free and environment-friendly; the pesticide disclosed by the invention is simple in production method, low in cost, and good in application effect; the pesticide disclosed by the invention can effectively prevent and treat plant pests including citrus bud mites, aonidiella aurantii, papilionidae, leaf rollers and the like, the one-time kill ratio reaches 90.12% or above, and drug tolerance is not caused.
Description
[technical field]
The invention belongs to insecticide preparing technical field, be specifically related to a kind of insecticide, preparation method and application thereof.
[background technology]
Current control pest all use chemical insecticide mostly, along with the raising of living standards of the people, require high, not only will eat, and will eat health agricultural product quality.The Pesticide Residue that high malicious chemical pesticide causes more and more becomes the focus of social concerns.High-toxic pesticide is the core and the key that affect agricultural product quality and safety, not only affects agricultural product quality, directly endangers the healthy of the people, also affects increasing peasant income.Because the toxicity of high-toxic pesticide is large, the event of person poultry poisoning was caused to happen occasionally in the past.Very big on the impact of women and children, the children that teratogenesis is disabled are a lot.In addition, along with the protective awareness of countries in the world to environment for human survival and natural, ecological strengthens day by day, high malicious high residue insecticide will be restricted further.The quality safety of unreasonable use to agricultural product of agricultural chemicals constitutes a threat to, therefore, reduce Pesticide use particularly high-toxic pesticide use, to raising agricultural product quality and the market competitiveness, promote China's agricultural sustainable development, ensure the life security of broad masses of the people and very great meaning of building a harmonious society.
Because chemical pesticide is easy to the pesticide resistance causing insect; dosage is made in order to control efficiency well constantly increases; a lot of natural enemy and beneficial organism are murdered; and pollute us and to depend on for existence living environment; the more and more attention of Environmental protection; will be further strict to the Detecting Pesticide in agricultural product, therefore, greatly develop the direction that non-toxic and non-pollution high-efficiency plant source pesticide is Agrochemicals from now on.
[summary of the invention]
The invention provides a kind of insecticide, preparation method and application thereof, use chemical pesticide control insect to cause the problem such as pest resistance to insecticide and contaminated environment to solve, insecticide ingredient of the present invention is nontoxic, and noresidue is nuisanceless, environmental protection; Insecticide production method of the present invention is simple, and cost is low, and effect is good; Insecticide of the present invention can effectively prevent and treat the plant insects such as knurl tick, California red scale, swallowtail butterfly, leaf roller, and one time killing rate all reaches more than 90.12%, and does not have drug resistance.
For solving above technical problem, the present invention by the following technical solutions:
A kind of insecticide, in units of weight portion, comprise following raw material: cacumen biotae 30-60 part, peppermint 30-60 part, lettuce 30-60 part, Herba Anabasis aphyllae 30-40 part, paulownia leaves 30-40 part, Sophora alopecuroide 30-40 part, absinth 20-30 part, yellow ginger 20-30 part, aloe 20-30 part, water 1000-4000 part.
Preferably, described insecticide, in units of weight portion, comprise following raw material: cacumen biotae 40-50 part, peppermint 40-50 part, lettuce 40-50 part, Herba Anabasis aphyllae 32-38 part, paulownia leaves 32-38 part, Sophora alopecuroide 32-38 part, absinth 22-28 part, yellow ginger 22-28 part, aloe 22-28 part, water 1500-3500 part.
Preferably, described insecticide, in units of weight portion, comprise following raw material: cacumen biotae 45 parts, peppermint 45 parts, 45 parts, lettuce, Herba Anabasis aphyllae 35 parts, paulownia leaves 35 parts, Sophora alopecuroide 35 parts, absinth 25 parts, yellow ginger 25 parts, aloe 25 parts, 2500 parts, water.
The present invention also provides a kind of method for producing insecticide, comprises the following steps:
S1: by cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe co-grinding, obtain mixture A, mixture A is added to the water, extract liquid under ultrasonic assistant extraction method;
S2: by medical filtration obtained for step S1, concentrated, obtain mixture B, gained mixture B be dry, pulverize, sieve, sterilizing, obtained insecticide.
Preferably, the condition of the extraction method of ultrasonic assistant described in step S1 extraction liquid is: ultrasonic power is 140-180W, and concentration of alcohol is 55%-75%, and Extracting temperature is 55-65 DEG C, and extraction time is 90-120min.
Preferably, step S2 herb liquid filters, and is concentrated into water content≤25%.
Preferably, in step S2, mixture B is dried to water content≤6% at 90-100 DEG C.
Preferably, the condition of sieving in step S2 is: cross 100-200 mesh sieve.
Preferably, the condition of sterilizing in step S2 is: temperature is 134-136 DEG C, and pressure is 210-230KPa, and the time is 3-5min.
The application of described insecticide in one or more plant insects preventing and treating knurl tick, California red scale, swallowtail butterfly, leaf roller.
Pharmacology of the present invention is as follows:
Containing volatile oil, flavones, tannic acid and tannin class phenolic constituent in cacumen biotae, there is the effects such as anti-inflammatory, anti-oxidant, hemostasis, antibacterial desinsection.
Peppermint has the effects such as desinsection, antibacterial, sterilization, anti-inflammatory, has stronger inhibitory action to shigella dysenteriae, typhoid bacillus and Escherichia coli.
Lettuce profit the five internal organs, qualcomm meridian, diuresis, improving eyesight sharps teeth, promoting lactation, hard muscles and bones, has the effect of antibacterial desinsection.
Herba Anabasis aphyllae belongs to chenopod, is dicotyledon, has the effects such as clearing heat and detoxicating, anti-inflammation, pain relieving desinsection, can be used for rural area preparation agricultural chemicals of eliminating the four pests--rats, bedbugs, flies and mosquitoes, the use of disinfestation and deratization.
Paulownia leaves extract has antibacterial and antivirus action, propyl alcohol extract all has antibacterial activity, In vitro Bactericidal Experiments proves, paulownia leaves extract is stronger to staphylococcus aureus, hay bacillus effect, extract panlownin and sesamin, kill insect (fly, the mosquito etc.) effect of this binary to pyrethrins and allyl cinerin has synergistic effect.
The total alkaloid of sophora alopecuroide extracted in Sophora alopecuroide has anti-inflammatory, anticancer, antiallergic action, anti-arrhythmia cordis, antiulcer, increasing leukocyte, relievings asthma, antipyretic, desinsection, calmness, analgesia, the effect such as antiviral; The external application of Sophora alopecuroide powder has suppression or killing action to staphylococcus, Escherichia coli, streptococcus, fungi, bacterium protein of Gardnerella vaginalis and trichomonad; The killing ability of Sophora alopecuroide plant is between anabasine (Anadasine) and lupinine (Lupinine), and sparteine is Biocidal agriculture the effective elements of the medicine.
Absinth bitter, cold in nature, poisonous, there is heat-clearing and damp-drying drug, drive ascarid, stomach invigorating, the effect such as antibacterial desinsection, all have suppression and killing action to multiple coccus, bacillus, fungi and virus etc.
Turmeric extractive shows certain repellent to multiple grain storage pest, desert locusts and mythimna separata etc., fumigates, tags, stomach toxicity, growth inhibition or oviposition deterrence isoreactivity; Meanwhile, to some agriculture germs, there is very strong bactericidal action.
Aloe contains the multiple nutritional components such as lignin, aloietic acid, saponin, anthraquinone, aloin, vitamin, oxidase, lipase, amylase, lysine, leucine, threonine, isoleucine, phenyl alanine, valine.Extract component tinctura aloes in aloe is the material that antibiotic property is very strong, the germs such as energy killing fungus, mould, bacterium, virus, the growth breeding of suppression and eliminating pathogen, the germ class of aloe antibiotic sterilization has: the germ of the diseases such as diphtheria bacterium, tetanolysin, pulmonitis strain, lactic acid bacteria, dysentery bacillus, colon bacillus, plague bacterium, cholera bacteria and initiation tympanitis, cystitis, pyesis, measles, rabies, polio, epidemic encephalitis.
The present invention has following beneficial effect:
(1) insecticide ingredient of the present invention is nontoxic, and noresidue is nuisanceless, environmental protection, can not bring environmental pollution;
(2) insecticide of the present invention can effectively prevent and treat the plant insects such as knurl tick, California red scale, swallowtail butterfly, leaf roller, and one time killing rate all reaches more than 90.12%, and does not have resistance to medical, can use by 3-5;
(3) insecticide production method of the present invention is simple, and cost is low, easy to use, and effect is good, is conducive to applying.
[embodiment]
Be specifically described below in conjunction with specific embodiment.
Embodiment 1
A kind of insecticide, in units of weight portion, comprises following raw material: cacumen biotae 30 parts, peppermint 30 parts, 30 parts, lettuce, Herba Anabasis aphyllae 30 parts, paulownia leaves 30 parts, Sophora alopecuroide 30 parts, absinth 20 parts, yellow ginger 20 parts, aloe 20 parts, 1000 parts, water.
Described method for producing insecticide, comprises the following steps:
S1: by cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe co-grinding, obtain mixture A, mixture A is added to the water, liquid is extracted under ultrasonic assistant extraction method, condition is: ultrasonic power is 140W, concentration of alcohol is 55%, and Extracting temperature is 55 DEG C, and extraction time is 120min;
S2: by medical filtration obtained for step S1, to be concentrated into water content be 25%, and obtain mixture B, it is 6% that gained mixture B is dried to water content at 90 DEG C, then pulverize, cross 100 mesh sieve, gained powder is 134 DEG C in temperature, pressure is sterilizing 5min under 210KPa, obtained insecticide.
Embodiment 2
A kind of insecticide, in units of weight portion, comprises following raw material: cacumen biotae 60 parts, peppermint 60 parts, 60 parts, lettuce, Herba Anabasis aphyllae 40 parts, paulownia leaves 40 parts, Sophora alopecuroide 40 parts, absinth 30 parts, yellow ginger 30 parts, aloe 30 parts, 4000 parts, water.
Described method for producing insecticide, comprises the following steps:
S1: by cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe co-grinding, obtain mixture A, mixture A is added to the water, liquid is extracted under ultrasonic assistant extraction method, condition is: ultrasonic power is 180W, concentration of alcohol is 75%, and Extracting temperature is 65 DEG C, and extraction time is 90min;
S2: by medical filtration obtained for step S1, to be concentrated into water content be 18%, and obtain mixture B, it is 4% that gained mixture B is dried to water content at 100 DEG C, then pulverize, cross 200 mesh sieve, gained powder is 136 DEG C in temperature, pressure is sterilizing 3min under 230KPa, obtained insecticide.
Embodiment 3
A kind of insecticide, in units of weight portion, comprises following raw material: cacumen biotae 45 parts, peppermint 45 parts, 45 parts, lettuce, Herba Anabasis aphyllae 35 parts, paulownia leaves 35 parts, Sophora alopecuroide 35 parts, absinth 25 parts, yellow ginger 25 parts, aloe 25 parts, 2500 parts, water.
Described method for producing insecticide, comprises the following steps:
S1: by cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe co-grinding, obtain mixture A, mixture A is added to the water, liquid is extracted under ultrasonic assistant extraction method, condition is: ultrasonic power is 160W, concentration of alcohol is 65%, and Extracting temperature is 60 DEG C, and extraction time is 105min;
S2: by medical filtration obtained for step S1, to be concentrated into water content be 20%, and obtain mixture B, it is 5% that gained mixture B is dried to water content at 95 DEG C, then pulverize, cross 200 mesh sieve, gained powder is 135 DEG C in temperature, pressure is sterilizing 4min under 220KPa, obtained insecticide.
Embodiment 4
A kind of insecticide, in units of weight portion, comprises following raw material: cacumen biotae 40 parts, peppermint 40 parts, 40 parts, lettuce, Herba Anabasis aphyllae 32 parts, paulownia leaves 32 parts, Sophora alopecuroide 32 parts, absinth 22 parts, yellow ginger 22 parts, aloe 22 parts, 1500 parts, water.
Described method for producing insecticide, comprises the following steps:
S1: by cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe co-grinding, obtain mixture A, mixture A is added to the water, liquid is extracted under ultrasonic assistant extraction method, condition is: ultrasonic power is 150W, concentration of alcohol is 60%, and Extracting temperature is 55 DEG C, and extraction time is 110min;
S2: by medical filtration obtained for step S1, to be concentrated into water content be 22%, and obtain mixture B, it is 6% that gained mixture B is dried to water content at 90 DEG C, then pulverize, cross 100 mesh sieve, gained powder is 134 DEG C in temperature, pressure is sterilizing 5min under 210KPa, obtained insecticide.
Embodiment 5
A kind of insecticide, in units of weight portion, comprises following raw material: cacumen biotae 50 parts, peppermint 50 parts, 50 parts, lettuce, Herba Anabasis aphyllae 38 parts, paulownia leaves 38 parts, Sophora alopecuroide 38 parts, absinth 28 parts, yellow ginger 28 parts, aloe 28 parts, 3500 parts, water.
Described method for producing insecticide, comprises the following steps:
S1: by cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe co-grinding, obtain mixture A, mixture A is added to the water, liquid is extracted under ultrasonic assistant extraction method, condition is: ultrasonic power is 170W, concentration of alcohol is 70%, and Extracting temperature is 65 DEG C, and extraction time is 100min;
S2: by medical filtration obtained for step S1, to be concentrated into water content be 20%, and obtain mixture B, it is 5% that gained mixture B is dried to water content at 100 DEG C, then pulverize, cross 200 mesh sieve, gained powder is 136 DEG C in temperature, pressure is sterilizing 3min under 230KPa, obtained insecticide.
Embodiment 6
A kind of insecticide, in units of weight portion, comprises following raw material: cacumen biotae 55 parts, peppermint 55 parts, 55 parts, lettuce, Herba Anabasis aphyllae 35 parts, paulownia leaves 35 parts, Sophora alopecuroide 35 parts, absinth 25 parts, yellow ginger 25 parts, aloe 25 parts, 3000 parts, water.
Described method for producing insecticide, comprises the following steps:
S1: by cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe co-grinding, obtain mixture A, mixture A is added to the water, liquid is extracted under ultrasonic assistant extraction method, condition is: ultrasonic power is 160W, concentration of alcohol is 70%, and Extracting temperature is 60 DEG C, and extraction time is 110min;
S2: by medical filtration obtained for step S1, to be concentrated into water content be 23%, and obtain mixture B, it is 5% that gained mixture B is dried to water content at 95 DEG C, then pulverize, cross 100 mesh sieve, gained powder is 136 DEG C in temperature, pressure is sterilizing 3min under 230KPa, obtained insecticide.
For verifying the effect of insecticide of the present invention, by following experimental verification.
Adopt the insecticide of embodiment 1-6, the ratio of joining 40g water in 1g insecticide uses, and once prevents and treats the test of the plant insects such as knurl tick, California red scale, swallowtail butterfly, leaf roller, the results are shown in following table.
From upper table, the insecticide of embodiment of the present invention 1-6 is to a killing rate of the plant insects such as knurl tick, California red scale, swallowtail butterfly, leaf roller all more than 90.12%, and result of use is good.Due to insecticide nonhazardous of the present invention, do not pollute, do not remain, it is efficient to add control efficiency, therefore, can widely popularize application.
Above content can not assert that the present invention specifically implements to be confined to these explanations; for general technical staff of the technical field of the invention; do not departing under concept thereof of the present invention; some simple deduction or replace can also be made, all should be considered as belonging to the scope of patent protection that the present invention is determined by submitted to claims.
Claims (10)
1. an insecticide, it is characterized in that, in units of weight portion, comprise following raw material: cacumen biotae 30-60 part, peppermint 30-60 part, lettuce 30-60 part, Herba Anabasis aphyllae 30-40 part, paulownia leaves 30-40 part, Sophora alopecuroide 30-40 part, absinth 20-30 part, yellow ginger 20-30 part, aloe 20-30 part, water 1000-4000 part.
2. insecticide according to claim 1, it is characterized in that, in units of weight portion, comprise following raw material: cacumen biotae 40-50 part, peppermint 40-50 part, lettuce 40-50 part, Herba Anabasis aphyllae 32-38 part, paulownia leaves 32-38 part, Sophora alopecuroide 32-38 part, absinth 22-28 part, yellow ginger 22-28 part, aloe 22-28 part, water 1500-3500 part.
3. insecticide according to claim 1, it is characterized in that, in units of weight portion, comprise following raw material: cacumen biotae 45 parts, peppermint 45 parts, 45 parts, lettuce, Herba Anabasis aphyllae 35 parts, paulownia leaves 35 parts, Sophora alopecuroide 35 parts, absinth 25 parts, yellow ginger 25 parts, aloe 25 parts, 2500 parts, water.
4. the method for producing insecticide according to any one of claim 1-3, is characterized in that, comprises the following steps:
S1: by cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe co-grinding, obtain mixture A, mixture A is added to the water, extract liquid under ultrasonic assistant extraction method;
S2: by medical filtration obtained for step S1, concentrated, obtain mixture B, gained mixture B be dry, pulverize, sieve, sterilizing, obtained insecticide.
5. method for producing insecticide according to claim 4, it is characterized in that, the condition that the extraction method of ultrasonic assistant described in step S1 extracts liquid is: ultrasonic power is 140-180W, and concentration of alcohol is 55%-75%, Extracting temperature is 55-65 DEG C, and extraction time is 90-120min.
6. method for producing insecticide according to claim 4, is characterized in that, step S2 herb liquid filters, and is concentrated into water content≤25%.
7. method for producing insecticide according to claim 4, is characterized in that, in step S2, mixture B is dried to water content≤6% at 90-100 DEG C.
8. method for producing insecticide according to claim 4, is characterized in that, the condition of sieving in step S2 is: cross 100-200 mesh sieve.
9. method for producing insecticide according to claim 4, is characterized in that, the condition of sterilizing in step S2 is: temperature is 134-136 DEG C, and pressure is 210-230KPa, and the time is 3-5min.
10. the application of the insecticide according to any one of claim 1-3 in one or more plant insects preventing and treating knurl tick, California red scale, swallowtail butterfly, leaf roller.
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| CN201510701647.1A CN105379780A (en) | 2015-10-26 | 2015-10-26 | Pesticide, as well as preparation method and application thereof |
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| CN201510701647.1A CN105379780A (en) | 2015-10-26 | 2015-10-26 | Pesticide, as well as preparation method and application thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105794465A (en) * | 2016-03-28 | 2016-07-27 | 许五妮 | Chinese cabbage planting method |
| CN106172559A (en) * | 2016-07-29 | 2016-12-07 | 安徽徽王农业有限公司 | Disease resistance medicament for blue berry and its preparation method and application |
| CN106259562A (en) * | 2016-07-22 | 2017-01-04 | 莫春辉 | A kind of tea oil tree insecticide |
| CN107333814A (en) * | 2017-06-14 | 2017-11-10 | 合肥助航生态农业科技有限公司 | Vegetable insecticide and preparation method thereof |
| CN107927005A (en) * | 2017-12-25 | 2018-04-20 | 湖南宇山玉月农业科技有限公司 | A kind of sweet potato leaf folder insecticide |
| CN109221274A (en) * | 2018-10-25 | 2019-01-18 | 桂阳金盾南方苹果有限公司 | A kind of apple tree insecticide and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105794465A (en) * | 2016-03-28 | 2016-07-27 | 许五妮 | Chinese cabbage planting method |
| CN106259562A (en) * | 2016-07-22 | 2017-01-04 | 莫春辉 | A kind of tea oil tree insecticide |
| CN106172559A (en) * | 2016-07-29 | 2016-12-07 | 安徽徽王农业有限公司 | Disease resistance medicament for blue berry and its preparation method and application |
| CN107333814A (en) * | 2017-06-14 | 2017-11-10 | 合肥助航生态农业科技有限公司 | Vegetable insecticide and preparation method thereof |
| CN107927005A (en) * | 2017-12-25 | 2018-04-20 | 湖南宇山玉月农业科技有限公司 | A kind of sweet potato leaf folder insecticide |
| CN109221274A (en) * | 2018-10-25 | 2019-01-18 | 桂阳金盾南方苹果有限公司 | A kind of apple tree insecticide and preparation method thereof |
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