CN105361242A - Multifunctional cigarette cracking capsule based on liquid marble and preparation method of multifunctional cigarette cracking capsule - Google Patents
Multifunctional cigarette cracking capsule based on liquid marble and preparation method of multifunctional cigarette cracking capsule Download PDFInfo
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- CN105361242A CN105361242A CN201510741940.0A CN201510741940A CN105361242A CN 105361242 A CN105361242 A CN 105361242A CN 201510741940 A CN201510741940 A CN 201510741940A CN 105361242 A CN105361242 A CN 105361242A
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Abstract
The invention provides a multifunctional cigarette cracking capsule based on a liquid marble and a preparation method of the multifunctional cigarette cracking capsule, and belongs to the fields of colloid and interface science and micro-nano encapsulating. The multifunctional cigarette cracking capsule has a structure as shown below. The preparation method of the multifunctional cigarette cracking capsule comprises the following steps: I. dropwise adding liquid drops above a stabilizing agent which is hydrophobic powder, and preparing the liquid marble by virtue of a rolling dropping method; and II. immersing the liquid marble in a photo-curable coating which contains an initiating agent or spraying the photo-curable coating containing the initiating agent outside the liquid marble, and curing through ultraviolet radiation, so that a microcapsule is obtained. The multifunctional cigarette cracking capsule based on the liquid marble disclosed by the invention is simple and mild in preparation process, and is excellent in stability, water retention and moisture preserving properties, and disinfecting property; harmful ingredients in inhaled gas of a cigarette can be removed and cigarette taste can be enhanced; therefore, the multifunctional cigarette cracking capsule has broad application prospect.
Description
Technical field:
The present invention relates to the quick-fried pearl of a kind of Mobyneb cigarette, specifically a kind of multi-functional microcapsules with characteristics such as water conservation moisturizing, sterilizations based on liquid hoodle.These multi-functional microcapsules have the excellent performance such as stability, water conservation moisturizing, sterilization, effectively can remove the harmful components in cigarette in suction gas and increase to suck mouthfeel.The invention further relates to the preparation method of the quick-fried pearl of described Mobyneb cigarette.The invention belongs to colloid and interface science and micro-nano encapsulation field.
Background technology:
As everyone knows, Smoking is harmful to your health, this is because there is a large amount of polycyclic aromatic hydrocarbons (PAH)s and derivative thereof and nitrosamine in tobacco, these materials bring out the Analyses of major carcinogens in mainstream thing that smoker produces pathology.Have 5,400,000 people to die from smoking every year according to World Health Organization's investigation whole world, and these data still annual with very fast in sustainable growth.
Current conventional commercial cigarette filter is made up of cellulose acetate, but the filter tip of these cigarettes only plays partial obstruction effect to the poisonous and carcinogen in tobacco.Meanwhile, cigarettes flue gas is comparatively dry, easily cause smoker's throat dry, itch, Long-Time Service also makes smoker easily suffer from the problems such as chronic pharyngitis.Therefore, the focus that Toxic and carcinogenic content in cigarette smoke are research at present how is reduced.
Through finding the patent retrieval of prior art, be used successfully as at present and reduced Toxic and carcinogenic method in cigarette smoke and mainly comprise and include disinfectant acetate filter (Chinese patent, the patent No.: 97195540.9), include the functional filter tip (United States Patent (USP) of microcapsules, the patent No.: 08/534,050; Chinese patent, the patent No.: 97195540.9).But the preparation process of these existing functional filter tips is comparatively complicated, cost is high and poor stability, usually can not realize large-scale mass production.Therefore, how poisonous the and carcinogenic substance effectively reduced in cigarette smoke is still a challenging difficult problem.
Summary of the invention:
The object of the invention is to remove the harmful substance in smoke from cigarette and the mouthfeel of increase suction smog, a kind of quick-fried pearl of Mobyneb cigarette based on liquid hoodle and preparation method thereof is provided.The present invention is stabilizing agent with hydrophobic powder, above stabilizing agent, drip drop, drips legal system for liquid hoodle by rolling; Liquid hoodle is immersed in the photocureable coating containing initator or in liquid hoodle outside and sprays the photocureable coating containing initator, obtain microcapsules by cured with ultraviolet radiation; Microcapsules are placed in filter and prepare a kind of Mobyneb cigarette filter, racked by microcapsules before using, microcapsules inclusion flows in acetate filter and plays the functions such as sterilization, moisturizing.This Mobyneb cigarette quick-fried pearl preparation process is simply gentle, is conducive to realizing suitability for industrialized production.The prepared quick-fried pearl of Mobyneb cigarette has excellent mechanical property, water conservation moisturizing and antiseptic property, can remove the harmful components in cigarette in suction gas and increase cigarette mouthfeel, having broad application prospects.
The present invention is achieved by the following technical solutions, the present invention relates to a kind of quick-fried pearl of Mobyneb cigarette based on liquid hoodle, and the preparation method of the quick-fried pearl of described Mobyneb cigarette, comprises the steps:
Step one, take hydrophobic powder as stabilizing agent, above stabilizing agent, drips drop, drips legal system for liquid hoodle by rolling;
Step 2, is immersed in liquid hoodle in the photocureable coating containing initator or in liquid hoodle outside and sprays the photocureable coating containing initator, by cured with ultraviolet radiation, obtain microcapsules.
In step, described hydrophobic powder (5) is polytetrafluoroethylene (PTFE), one or more in ferriferrous oxide nano-particle, carbon black, CNT, PLA, graphite powder, Graphene, polyphosphazene, silica, titanium dioxide, calcium carbonate, polystyrene colloid particle, hydrophobic organic molecule etc., but the present invention is not limited to the scope of above-mentioned citing.
In step, the solvent (6) of described drop is water, the mixed solvent of one or more in glycerine, ethanol, dimethyl sulfoxide (DMSO), diiodomethane, dodecane, octane, toluene, ionic liquid etc., but the present invention is not limited to the scope of above-mentioned citing.
In step, the solute (6) of described drop is wetting agent (potassium acetate, lithium chloride, lithium fluoride, lithium bromide, cesium fluoride, magnesium chloride, potash, magnesium nitrate, calcium chloride, glycerine, hyaluronic acid, shitosan, sorbierite, propane diols, sodium lactate, potassium phosphate, sodium pyrophosphate or sodium polyphosphate, calcium citrate, calcium gluconate, potassium citrate, grape acid potassium, potassium tartrate etc.), adsorbent (active carbon, containing copper porphyrin and analog thereof, imvite), other additive (Natural menthol, Radix Glycyrrhizae or Radix Platycodonis extract, cocoa, sugar) etc. in the mixing solute of one or more, but the present invention is not limited to the scope of above-mentioned citing.
In step 2, described photocureable coating is one or more compound systems in epoxy acrylate, urethane acrylate, polyester acrylate, polyether acrylate, pure acrylate, silicone oligomer, photocuring polybutadiene oligomer, organic-inorganic hybrid resin etc., but the present invention is not limited to the scope of above-mentioned citing.
In step 2, described light trigger acyloin and derivative (styrax, benzoin dimethylether, benzoin ethyl ether, benzoin isopropyl ether, benzoin isobutyl ether), benzil class (diphenylethan, α, alpha, alpha-dimethyl oxygen base-α-phenyl acetophenone), alkylbenzene ketone (α, α-diethoxy acetophenone, alpha-hydroxyalkyl benzophenone, α-amine alkyl phenones), acyl group phosphorous oxides (aroyl phosphine oxide, two benzoylphenyl phosphine oxide), benzophenone (benzophenone, 2, 4-dihydroxy benaophenonel, Michler's keton), thioxanthones (sulfo-propoxyl group thioxanthone, isopropyl thioxanthone), cationic photoinitiator (diaryl group iodized salt, triaryl salt compounded of iodine, alkyl salt compounded of iodine, the luxuriant iron hexafluorophosphate of isopropylbenzene etc.) etc. in one or more compound systems, but the present invention is not limited to the scope of above-mentioned citing.
Compared with prior art, tool of the present invention has the following advantages: the preparation method of (1) quick-fried pearl of Mobyneb cigarette based on liquid hoodle of the present invention is quick, simple and gentle, and easy lot-sizeization is produced; (2) the quick-fried pearl of Mobyneb cigarette based on liquid hoodle of the present invention has excellent stability, water conservation performance of keeping humidity, can preserve for a long time and can not break; (3) the quick-fried pearl of Mobyneb cigarette based on liquid hoodle of the present invention is with low cost, and function Modulatory character is strong, is conducive to suitability for industrialized production.
Accompanying drawing illustrates:
Fig. 1 is the syntheti c route schematic diagram of the microcapsules that embodiment 1 obtains;
Fig. 2 is the digital photograph of the liquid hoodle that embodiment 1 obtains;
Fig. 3 is the cross section digital photograph of the liquid hoodle different time sections that embodiment 1 obtains;
Fig. 4 is the mass-change curve figure of the liquid hoodle different time sections that embodiment 1 obtains;
Fig. 5 is the schematic diagram of the quick-fried pearl of Mobyneb cigarette in cigarette.
Detailed description of the invention:
Following instance will the invention will be further described by reference to the accompanying drawings.The present embodiment is implemented under premised on technical solution of the present invention, gives detailed embodiment and process, but protection scope of the present invention is not limited to following embodiment.The experimental technique of unreceipted actual conditions in the following example, usually conveniently condition, or according to the condition that manufacturer advises.
Embodiment 1:
On the plastic base being scattered with hydrophobic powder, drip the saturated potassium acetate drop of 10 μ L with microsyringe, then rock substrate and make drop surface fully cladding powder formation liquid hoodle.
Epoxidized soybean oil acrylic resin and diluent are made into mixture by volume at 1: 5, then add the I-184 type light trigger of mass fraction 3%, be sprayed onto liquid shell bead surface after being uniformly mixed and solidify 3min under UV photo solidification machine, obtain microcapsules.
The implementation result of the present embodiment: Fig. 1 is the syntheti c route schematic diagram of microcapsules.Take hydrophobic powder as stabilizing agent, dripping legal system for liquid hoodle by rolling, spraying the photocureable coating containing initator in liquid hoodle outside, by cured with ultraviolet radiation, obtaining capsule.
Fig. 2 is the digital photograph of the liquid hoodle of preparation.As shown in the figure, the liquid hoodle of preparation has ball shape structure, and can stably be present in hydrophilic base surface.
Fig. 3 is the cross section digital photograph of liquid hoodle different time sections.Can find out, liquid hoodle has good water conservation performance of keeping humidity, even if still can keep good ball shape structure after 90min, can not subside, and this is that follow-up encapsulation process provides reliable basis.
Fig. 4 is the mass-change curve figure of liquid hoodle different time sections.As seen from the figure, compared with naked drop, after drip gauge bread coating particle, weight loss rate obviously slows down.And when being saturated potassium acetate solution mutually in liquid hoodle, liquid hoodle can keep constant quality in long-time, weightlessness can not be there is.
Embodiment 2:
On the plastic base being scattered with hydrophobic powder, drip the saturated potassium acetate drop of 10 μ L with microsyringe, then rock substrate and make drop surface fully cladding powder formation liquid hoodle.
Epoxidized soybean oil acrylic resin and diluent are made into mixture by volume at 1: 3, then add the I-184 type light trigger of mass fraction 4%, be sprayed onto liquid shell bead surface after being uniformly mixed and solidify 4min under UV photo solidification machine, obtain microcapsules.
Embodiment 3:
On the plastic base being scattered with hydrophobic powder, drip the saturated potassium acetate drop of 10 μ L with microsyringe, then rock substrate and make drop surface fully cladding powder formation liquid hoodle.
Epoxidized soybean oil acrylic resin and diluent are made into mixture by volume at 1: 1, then add the I-184 type light trigger of mass fraction 4%, be sprayed onto liquid shell bead surface after being uniformly mixed and solidify 2min under UV photo solidification machine, obtain microcapsules.
Claims (8)
1. the quick-fried pearl of Mobyneb cigarette based on liquid hoodle, the harmful substance in smog can be eliminated and increase the humidity sucking smog, improving while sucking mouthfeel really to stop the nuisance materials such as burnt tobacco tar to enter human body, it is characterized in that, the described quick-fried pearl of Mobyneb cigarette and tobacco body and cigaratte filter are the concentric bodies of one, be connected by functional form filter (2) between filter tip (3) with tobacco (1), wherein the top of functional form filter is connected with tobacco body (1) by one deck porous membrane, bottom is connected with filter tip (3) by one deck porous membrane.
2. a kind of quick-fried pearl of Mobyneb cigarette based on liquid hoodle according to claim 1, it is characterized in that, cigaratte filter front portion (2) are containing one or more functional form microcapsules.
3. a kind of quick-fried pearl of Mobyneb cigarette based on liquid hoodle according to claim 2 and preparation method thereof, is characterized in that, comprise the steps:
Step one, take hydrophobic powder as stabilizing agent, above stabilizing agent, drips drop, drips legal system for liquid hoodle by rolling;
Step 2, is immersed in liquid hoodle in the photocureable coating containing initator or in liquid hoodle outside and sprays the photocureable coating containing initator, by cured with ultraviolet radiation, obtain microcapsules.
4. a kind of quick-fried pearl of Mobyneb cigarette based on liquid hoodle according to claim 3 and preparation method thereof, it is characterized in that, in step, described hydrophobic powder (5) is polytetrafluoroethylene (PTFE), one or more in ferriferrous oxide nano-particle, carbon black, CNT, PLA, graphite powder, Graphene, polyphosphazene, silica, titanium dioxide, calcium carbonate, polystyrene colloid particle, hydrophobic organic molecule etc., but the present invention is not limited to the scope of above-mentioned citing.
5. a kind of quick-fried pearl of Mobyneb cigarette based on liquid hoodle according to claim 3 and preparation method thereof, it is characterized in that, in step, the solvent (6) of described drop is water, the mixed solvent of one or more in glycerine, ethanol, dimethyl sulfoxide (DMSO), diiodomethane, dodecane, octane, toluene, ionic liquid etc., but the present invention is not limited to the scope of above-mentioned citing.
6. a kind of quick-fried pearl of Mobyneb cigarette based on liquid hoodle according to claim 3 and preparation method thereof, it is characterized in that, in step, the solute (6) of described drop is wetting agent (potassium acetate, lithium chloride, lithium fluoride, lithium bromide, cesium fluoride, magnesium chloride, potash, magnesium nitrate, calcium chloride, glycerine, hyaluronic acid, shitosan, sorbierite, propane diols, sodium lactate, potassium phosphate, sodium pyrophosphate or sodium polyphosphate, calcium citrate, calcium gluconate, potassium citrate, grape acid potassium, potassium tartrate etc.), adsorbent (active carbon, containing copper porphyrin and analog thereof, imvite), other additive (Natural menthol, Radix Glycyrrhizae or Radix Platycodonis extract, cocoa, sugar) etc. in the mixing solute of one or more, but the present invention is not limited to the scope of above-mentioned citing.
7. a kind of quick-fried pearl of Mobyneb cigarette based on liquid hoodle according to claim 3 and preparation method thereof, it is characterized in that, in step 2, described photocureable coating is one or more compound systems in epoxy acrylate, urethane acrylate, polyester acrylate, polyether acrylate, pure acrylate, silicone oligomer, photocuring polybutadiene oligomer, organic-inorganic hybrid resin etc., but the present invention is not limited to the scope of above-mentioned citing.
8. a kind of quick-fried pearl of Mobyneb cigarette based on liquid hoodle according to claim 3 and preparation method thereof, is characterized in that, in step 2, described light trigger is acyloin and derivative (styrax, benzoin dimethylether, benzoin ethyl ether, benzoin isopropyl ether, benzoin isobutyl ether), benzil class (diphenylethan, α, alpha, alpha-dimethyl oxygen base-α-phenyl acetophenone), alkylbenzene ketone (α, α-diethoxy acetophenone, alpha-hydroxyalkyl benzophenone, α-amine alkyl phenones), acyl group phosphorous oxides (aroyl phosphine oxide, two benzoylphenyl phosphine oxide), benzophenone (benzophenone, 2,4-DihydroxyBenzophenone, Michler's keton), thioxanthones (sulfo-propoxyl group thioxanthone, isopropyl thioxanthone), cationic photoinitiator (diaryl group iodized salt, triaryl salt compounded of iodine, alkyl salt compounded of iodine, the luxuriant iron hexafluorophosphate of isopropylbenzene etc.) etc. in one or more compound systems, but the present invention is not limited to the scope of above-mentioned citing.
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| CN201510741940.0A CN105361242A (en) | 2015-11-02 | 2015-11-02 | Multifunctional cigarette cracking capsule based on liquid marble and preparation method of multifunctional cigarette cracking capsule |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106136312A (en) * | 2016-06-28 | 2016-11-23 | 云南瑞升烟草技术（集团）有限公司 | A kind of capsule filter stick reducing harmful substances from flue gases burst size |
| CN106360803A (en) * | 2016-11-29 | 2017-02-01 | 将军烟草集团有限公司 | Pulse-cutting production method and pulse-cutting production system of tobacco blast beads |
| CN106914196A (en) * | 2017-04-11 | 2017-07-04 | 江南大学 | It is a kind of that the method for carrying water microcapsules is prepared based on liquid hoodle |
| CN108479870A (en) * | 2018-03-26 | 2018-09-04 | 中国科学院力学研究所 | A method of utilizing light-catalyzed reaction and liquid hoodle model realization liquid drop movement |
| CN109645561A (en) * | 2019-02-18 | 2019-04-19 | 重庆中烟工业有限责任公司 | Cigarette capsule and preparation method thereof and cigarette filter |
| CN109680511A (en) * | 2018-12-04 | 2019-04-26 | 浙江理工大学 | A kind of preparation method of the aromatic micro-capsule for brand textile coating |
| CN109793275A (en) * | 2019-02-18 | 2019-05-24 | 重庆中烟工业有限责任公司 | A kind of preparation method and cigarette filter of cigarette packet capsule with diuresis promoting function |
| CN110367575A (en) * | 2019-08-19 | 2019-10-25 | 翟泰山 | A kind of betel nut companion and preparation method thereof |
| CN110419775A (en) * | 2019-07-10 | 2019-11-08 | 云南巴菰生物科技有限公司 | A kind of quick-fried pearl of anti-seep water and preparation method thereof |
| CN112284055A (en) * | 2019-07-10 | 2021-01-29 | 云南巴菰生物科技有限公司 | Drying equipment for water blasting bead black box |
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| CN106136312A (en) * | 2016-06-28 | 2016-11-23 | 云南瑞升烟草技术（集团）有限公司 | A kind of capsule filter stick reducing harmful substances from flue gases burst size |
| CN106360803A (en) * | 2016-11-29 | 2017-02-01 | 将军烟草集团有限公司 | Pulse-cutting production method and pulse-cutting production system of tobacco blast beads |
| CN106914196A (en) * | 2017-04-11 | 2017-07-04 | 江南大学 | It is a kind of that the method for carrying water microcapsules is prepared based on liquid hoodle |
| CN108479870A (en) * | 2018-03-26 | 2018-09-04 | 中国科学院力学研究所 | A method of utilizing light-catalyzed reaction and liquid hoodle model realization liquid drop movement |
| CN109680511B (en) * | 2018-12-04 | 2021-09-14 | 浙江理工大学 | Preparation method of fragrant microcapsule for trademark fabric coating |
| CN109680511A (en) * | 2018-12-04 | 2019-04-26 | 浙江理工大学 | A kind of preparation method of the aromatic micro-capsule for brand textile coating |
| CN109793275A (en) * | 2019-02-18 | 2019-05-24 | 重庆中烟工业有限责任公司 | A kind of preparation method and cigarette filter of cigarette packet capsule with diuresis promoting function |
| CN109645561A (en) * | 2019-02-18 | 2019-04-19 | 重庆中烟工业有限责任公司 | Cigarette capsule and preparation method thereof and cigarette filter |
| CN109793275B (en) * | 2019-02-18 | 2022-04-22 | 重庆中烟工业有限责任公司 | Preparation method of water-containing capsule for cigarettes and cigarette filter |
| CN110419775A (en) * | 2019-07-10 | 2019-11-08 | 云南巴菰生物科技有限公司 | A kind of quick-fried pearl of anti-seep water and preparation method thereof |
| CN112284055A (en) * | 2019-07-10 | 2021-01-29 | 云南巴菰生物科技有限公司 | Drying equipment for water blasting bead black box |
| CN112284055B (en) * | 2019-07-10 | 2021-12-31 | 云南巴菰生物科技股份有限公司 | Drying equipment for water blasting bead black box |
| CN110367575A (en) * | 2019-08-19 | 2019-10-25 | 翟泰山 | A kind of betel nut companion and preparation method thereof |
| CN110367575B (en) * | 2019-08-19 | 2021-06-01 | 翟泰山 | Areca mate and preparation method thereof |
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Application publication date: 20160302 |