CN110419775A - A kind of quick-fried pearl of anti-seep water and preparation method thereof - Google Patents
A kind of quick-fried pearl of anti-seep water and preparation method thereof Download PDFInfo
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- CN110419775A CN110419775A CN201910618137.6A CN201910618137A CN110419775A CN 110419775 A CN110419775 A CN 110419775A CN 201910618137 A CN201910618137 A CN 201910618137A CN 110419775 A CN110419775 A CN 110419775A
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- Prior art keywords
- water
- quick
- fried pearl
- liquid
- seep
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Classifications
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
Abstract
The present invention relates to quick-fried pearls of a kind of anti-seep water and preparation method thereof, the quick-fried pearl of the anti-seep water is respectively core liquid layer, the first rubber layer, the second rubber layer to be divided into three-decker from inside to outside, core liquid layer is made of pure water and water-soluble substances, first rubber layer is photosensitive resin layer, second rubber layer is polyacrylic resin layer, and 10 days average permeability rates of the quick-fried pearl of anti-seep water are less than 3%.The cigarette of the aqueous capsule of the addition present invention, aromatic style is obvious, and fragrance is rich, and fresh and sweet perfume feature enhancing, flue gas taste characteristics are promoted, and being embodied in oral cavity and throat's irritation reduces, and has Hui Tian to promote the production of body fluid sense.
Description
[technical field]
The invention belongs to Cigarette processing technique fields.More particularly it relates to a kind of quick-fried pearl of anti-seep water, also
It is related to the preparation method of the quick-fried pearl of the anti-seep water.
[background technique]
All there is cigarette smoking throat comfort and slightly have deficiency in most of conventional cigarette currently on the market, dry sensation is prominent
The shortcomings that；Therefore, it is necessary to make up this defect by the relevant technologies of flue gas humectation or moisturizing, improve the suction comfort of cigarette.
Wherein, glycerol, propylene glycol, xylitol or sorbierite etc., such polyalcohols humectation is usually added in humectation method in the tobacco
Though agent can maintain moisture content of cut tobaccos in process, pipe tobacco resist processing is improved, since such additive is to be directly added into
In pipe tobacco, burning can be participated in suction, cause to introduce other miscellaneous gas in flue gas, influence the organoleptic quality of cigarette.And
Filter segment carries out the flue gas moisturizing then not no defect of this respect.
In cigarette producing technology, in order to keep the tar content of cigarette product low, China's tobacco business meeting idea tries to drop
The tar content of low cigarette product.But tar content gets over the fragrance object for the pleasant that the cigarette product at bottom generates when then
Matter also can be fewer, seriously reduces the mouthfeel of cigarette, and the fragrance that different grades of tobacco generates also is different.For this purpose, existing
Have in technology, while reducing tar in cigarettes content, usually takes and add flavors and fragrances in cigarettes, can thus tie up
The characteristic perfume of cigarette is held, the difference between different grades of tobacco leaf can be also applied and is allowed to mutually coordinated, fragrance is augmented, makes
Cigarette is more plentiful.There are also be exactly the fragrance for increasing cigarette using the quick-fried pearl of cigarette.The quick-fried pearl of cigarette refers to essence packet in soft capsule
It is interior, it is placed in cigarette filter, is destroyed soft capsule using external force before smoking, it is made to discharge essence therein.With tradition
Perfuming process compare, this mode is more stable, can more extend essence duration in cigarettes, from application effect for
More comfortable, the scope of application is wider.Quick-fried pearl is added in cigarette filter as a kind of cigarette new material, and consumer is in due course when aspirating
Broken quick-fried pearl is squeezed, the essence with peat-reek is discharged, reaches foundation interactivity, improves main flume style, enrich the work of cigarette perfume
With.
In view of above-mentioned two o'clock, develops a quick-fried pearl for capableing of coated water-soluble flavors and fragrances and have become pass urgently to be resolved
Key problem, but do not occur up to now such capable of effectively wrapping up water or water-soluble substances core liquid in the market
Product.For presently, there are technological deficiency, the present inventor by lot of experiments and analysis, complete this hair finally
It is bright.
[summary of the invention]
[technical problems to be solved]
The object of the present invention is to provide a kind of quick-fried pearls of anti-seep water.
It is a further object to provide the preparation methods of the quick-fried pearl of the anti-seep water.
[technical solution]
The present invention is achieved through the following technical solutions.
The present invention relates to a kind of quick-fried pearls of anti-seep water.
The quick-fried pearl of the anti-seep water is to be followed successively by core liquid layer, the first photosensitive resin rubber layer and second poly- third from inside to outside
Olefin(e) acid resin glue cortex composition；The core liquid layer is by pure water and water-soluble substances according to weight ratio 1:0.01~1.0 group
At；The quick-fried pearl of anti-seep water is in 10 days permeability rates less than 3%.
A preferred embodiment of the invention, the water-soluble substances are one or more selected from water-soluble fragrant
Smart fragrance, plant extracts, medicinal extract, food flavor substances, water-soluble polysaccharide, propylene glycol, glycerine, honey, sodium chloride, sorb
The water-soluble substances of sour potassium or potassium citrate.
According to another preferred method of implementation of the present invention, the soluble perfume fragrance be ethyl acetate, benzyl carbinol,
Benzyl alcohol or furanone；The plant extracts be alkaloid, volatile oil, tannin, sugar, amino acid, enzyme, organic acid, grease,
The plant extracts of wax or pigment.
According to another preferred method of implementation of the present invention, the medicinal extract is plum medicinal extract, hawthorn extract, tealeaves medicinal extract
Or tamarind medicinal extract；The food flavor substances are malic acid, glutamic acid, sodium chloride or glucose；The water-soluble polysaccharide
It is maltose or sucrose.
According to another preferred method of implementation of the present invention, the photosensitive resin is by 20~70 parts by weight of bisphenol A type rings
Oxygen resin, 30~50 parts by weight are one or more to be selected from urethane acrylate, polyester acrylate resin, polyoxyalkylene acrylate tree
Rouge, other resins of 12 rouge of acrylic acid or acrylic resin and 1~5 parts by weight photosensitizer form.
According to another preferred method of implementation of the present invention, the photosensitizer be it is one or more selected from KIP150,
Omnipol BP、Polymeric 910、Irgacure 127、Irgacure 754、Irgacure OXE01、Rad-StartN-
1414, the macromolecular photosensitizer of CD-1012 or Esacure1187.
The invention further relates to the preparation methods of the quick-fried pearl of the anti-seep water.
The step of preparation method, is as follows:
A, water-soluble substances core liquid is prepared
According to weight ratio 1:0.01~1.0 of pure water and water-soluble substances, the water-soluble substances are dissolved under stiring
In pure water, the water-soluble substances core liquid is obtained；
B, the first photosensitive resin rubber layered material liquid is prepared
By 20~70 parts by weight of bisphenol A type epoxy resin, the other resins of 30~50 parts by weight and 1~5 parts by weight photosensitizer
Stirring mixes well at normal temperature, then is protected from light standing preservation 12h or more and obtains the first photosensitive resin rubber layer to remove bubble
Feed liquid；
C, the second polyacrylic resin rubber layered material liquid is prepared
Under conditions of 50~70 DEG C of temperature, polyacrylic resin is dissolved in ethanol solution, then in the condition of sealing
Lower standing 1h or more obtains the second polyacrylic resin rubber layered material liquid to remove bubble；
D, the pre- dripping of the quick-fried pearl of anti-seep water
According to 1~10 parts by weight the first photosensitive resin rubber layer and 90~99 parts by weight core liquid layers, drop is passed through by constant displacement pump
The first photosensitive resin rubber layered material that the water-soluble substances core liquid and step B that ball device concentric circles water dropper prepares step A are prepared
Drop is added in the pure water conservation liquid of room temperature, in its dropping process carry out light irradiation, the first photosensitive resin rubber layered material liquid by
Gradually curing molding, environmental sealing water-soluble substances core liquid form the quick-fried pearl precursor of anti-seep water；Then pass through charging conduit sieve for institute
It states the quick-fried pearl precursor of anti-seep water to separate with pure water conservation liquid, the quick-fried pearl precursor of the anti-seep water of collection is by volume using concentration
The washing of 90% ethanol water, air-dries, obtains the quick-fried pearl precursor of anti-seep water；
E, the quick-fried pearl overlay film of anti-seep water is dry
Step D is obtained the quick-fried pearl precursor of anti-seep water to be placed in roller coating pan, is prepared step C using sprayer
Second polyacrylic resin rubber layered material liquid is sprayed on the quick-fried pearl precursor of anti-seep water, and roller coating pan gathers in rotation by second
Acrylic size cortex feed liquid is evenly coated on the quick-fried pearl precursor of anti-seep water, is wrapped in such a way that side coated side is dry
It covers, stops coating when the second polyacrylic resin glue skin thickness reaches 0.05~0.2mm, be then dried to obtain described anti-
The quick-fried pearl of percolating water.
A preferred embodiment of the invention, in step, the density of the water-soluble substances core liquid is 0.9
~1.3g/cm3。
According to another preferred method of implementation of the present invention, in stepb, the density of the first photosensitive resin rubber layered material liquid
It is 1.0~1.3g/cm3。
According to another preferred method of implementation of the present invention, in step D, the first photosensitive resin rubber layered material liquid is being protected
Carry out light irradiation in dropping process in liquid is fluorescent lamp, incandescent lamp, LED ultraviolet lamp, LED light or searchlight, the function of lamp
It is 50~100cm that rate, which is 18~500w, light path,.
The present invention is described in more detail below.
The present invention relates to a kind of quick-fried pearls of anti-seep water.
The quick-fried pearl of the anti-seep water is to be followed successively by core liquid layer, the first photosensitive resin rubber layer and second poly- third from inside to outside
Olefin(e) acid resin glue cortex composition；The core liquid layer is by pure water and water-soluble substances according to weight ratio 1:0.01~1.0 group
At；The quick-fried pearl of anti-seep water is in 10 days permeability rates less than 3%.
According to the present invention, the water-soluble substances core liquid is it should be understood that a kind of by containing there are many to cigarette suction quality
The quick-fried bead core that the solution of influential water-soluble substances is constituted, it is to work as with the basic role in the quick-fried pearl of water-soluble substances in cigarette
Flue gas can be moistened when consumer's smoking cigarette and is tarted up.It is all that there is this basic role, and to cigarette water solubility
The quick-fried pearl performance of substance does not have other water-soluble substances of any negative effect can be used in the present invention, all of the invention yet
Within protection scope.
The water-soluble substances are one or more selected from soluble perfume fragrance, plant extracts, medicinal extract, food wind
Taste substance, water-soluble polysaccharide, propylene glycol, glycerine, honey, sodium chloride, potassium sorbate or potassium citrate water-soluble substances.
Wherein, the soluble perfume fragrance is ethyl acetate, benzyl carbinol, benzyl alcohol or furanone；
The plant extracts is alkaloid, volatile oil, tannin, sugar, amino acid, enzyme, organic acid, grease, wax or color
The plant extracts of element.The alkaloid plant extract that the present invention uses is, for example, theophylline, caffeine, arecaline or solanine；This
Inventing the volatile oil plant extracts used is, for example, peppermint oil, caryophyllus oil, perilla herb oil or palchouli oil；The tannin that the present invention uses
Plant extracts is, for example, tea polyphenols, persimmon tannin, Ellagitannins；The sugared plant extracts that the present invention uses is, for example, grape
Sugar, maltose, fructose or sucrose；The amino acid plant extracts that the present invention uses be, for example, glutamic acid, lysine, threonine or
Phenylalanine；The enzyme plant extracts that the present invention uses is, for example, amylase, cellulase, pectase or glycosidase；The present invention
The organic acid plant extracts used is, for example, tartaric acid, oxalic acid, malic acid or citric acid；The oil and fatty plant that the present invention uses mentions
Taking object is, for example, peanut oil, rapeseed oil, sesame oil or soybean lecithin；The wax plant extracts that the present invention uses is, for example, rice bran
Wax, sugarcane wax, Brazil wax or lacquer tree fat；The pigment plant extracts that the present invention uses is, for example, brilliant blue, sunset yellow, chlorophyll
Or phylloerythrin；The medicinal extract that the present invention uses is plum medicinal extract, hawthorn extract, tealeaves medicinal extract or tamarind medicinal extract；The food wind
Taste substance is malic acid, glutamic acid, sodium chloride or glucose；The water-soluble polysaccharide is maltose or sucrose.The present invention makes
Water-soluble substances be all in the art it is usually used, in current market sales of product.
In the present invention, if the weight ratio of pure water and water-soluble substances is greater than 1:0.01, soluble perfume fragrance
Flavor characteristic is unobvious；If the weight ratio of pure water and water-soluble substances is less than 1:1.0, the specific gravity mistake of soluble perfume fragrance
Height is unfavorable for dripping；Therefore, the weight ratio of pure water and water-soluble substances be 1:0.01~1.0 be it is desirable, preferably 1:
0.1~0.5.
According to the present invention, the first photosensitive resin rubber layer is made of photosensitive resin；The light that the present invention uses
Quick resin is one kind by the molecular colloid substance of high score.Hedge netted fragment of these macromolecules such as chain type commissure at random.
Under ultraviolet light irradiation, these macromolecules are combined into cross-linked polymer macromolecule, while polymer is transformed into heavily fortified point by colloid resin
Hard substance.
According to the present invention, the photosensitive resin is by 20~70 parts by weight of bisphenol A type epoxy resin, 30~50 parts by weight one
Kind is a variety of selected from urethane acrylate, polyester acrylate resin, polyoxyalkylene acrylate resin, 12 rouge of acrylic acid or acrylic acid
Other resins of resin and 1~5 parts by weight photosensitizer form.
In the present invention, main function of the bisphenol A type epoxy resin in photosensitive resin is the base that softgel shell is constituted after solidifying
This skeleton.The bisphenol A type epoxy resin that the present invention uses is current market sales of product, such as by the multifarious chemicals in Jiangyin
The product that company, Co., Ltd is sold with trade name bisphenol type epoxy vinyl.
Main function of the other resins in photosensitive resin is the mechanical strength for adjusting softgel shell, improves bisphenol-A type ring
The physical mechanical property of ethylene oxide resin.Other resins that the present invention uses be urethane acrylate, polyester acrylate resin,
Polyoxyalkylene acrylate resin, 12 rouge of acrylic acid or acrylic resin, they are all current market sales of products, such as by Zheng
Urethane acrylate that state great achievement coating Co., Ltd is sold with trade name urethane acrylate, by upper caldron along international trade
Polyester acrylate resin that easy Co., Ltd is sold with trade name polyester acrylate resin, by the three sincere synthetic resin of water Hao of Foshan City
The polyoxyalkylene acrylate resin that company, Co., Ltd is sold with trade name acrylic resin.
In the present invention, main function of the photosensitizer in photosensitive resin is after receiving or absorbing luminous energy, itself changes
Variation is learned, free radical or cation are decomposed into, thus initiated polymerization.KIP150 that the present invention uses, Omnipol BP,
Polymeric 910、Irgacure 127、Irgacure 754、Irgacure OXE01、Rad-StartN-1414、CD-
The macromolecular photosensitizer of 1012 or Esacure1187.They are all current market sales of product, such as the triumphant mattress chemical industry in Shanghai
The KIP150 that Co., Ltd is sold with trade name KIP150.
In the present invention, when the dosage of other resins and photosensitizer is in the range, if bisphenol A type epoxy resin
Dosage be lower than 20 parts by weight, then the intensity of capsule shells is inadequate；If the dosage of bisphenol A type epoxy resin is higher than 70 parts by weight,
Then the intensity of capsule shells is excessively high；Therefore, it is reasonably, preferably that the dosage of bisphenol A type epoxy resin, which is 20~70 parts by weight,
32~58 parts by weight；
When the dosage of bisphenol A type epoxy resin and photosensitizer is in the range, if the dosage of other resins is lower than
30 parts by weight, then the intensity of capsule shells will be excessively high, and toughness is inadequate, and capsule is easily rupturable；If the dosage of other resins is higher than 50
Parts by weight, then capsule shell intensity is inadequate, and toughness is too strong；Therefore, the dosage of other resins be 30~50 parts by weight be it is suitable, it is excellent
Selection of land is 35~45 parts by weight；
When the dosage of bisphenol A type epoxy resin and other resins is in the range, if the dosage of photosensitizer is lower than 1 weight
Part is measured, then Light-Curing Efficiency is too low, causes solidification incomplete；If the dosage of photosensitizer is higher than 5 parts by weight, curing efficiency mistake
Height influences the shape of capsule, will lead to capsule appearance deformity；Therefore, the dosage of photosensitizer be 1~5 parts by weight be it is appropriate, it is excellent
Selection of land is 2~4 parts by weight；
In the present invention, the effect of the second polyacrylic resin rubber layer is the water retention property for improving the quick-fried pearl of water, quick-fried to water
The intensity effect of pearl is smaller.Second polyacrylic resin rubber layer is the polyacrylic resin master made of polyacrylic resin
To be used as tablet, pill, the coating material of granule enteric solubility and film forming agent, the micro-capsule film forming agent of enteric capsule shells etc.,
The coating material and framework material that can be used in sustained release preparation, the polyacrylic resin that the present invention uses are to sell currently on the market
Medical accessory grade product, such as sold by Foshan Sheng Yi Biotechnology Co., Ltd with trade name polyacrylic resin poly- third
Olefin(e) acid resin.
It is detected and is determined according to weight difference assay standard detecting method, the quick-fried pearl of anti-seep water of the present invention is small in 10 days permeability rates
In 3%.
The invention further relates to the preparation methods of the aqueous capsule.
The step of preparation method, is as follows:
A, water-soluble substances core liquid is prepared
According to weight ratio 1:0.01~1.0 of pure water and water-soluble substances, water-soluble substances are dissolved under stiring pure
In water, the core liquid layer is obtained；
In the present invention, it is worthless that the weight ratio of pure water and water-soluble substances, which is more than the range,.If pure water
It is lower than 1:1.0 with the weight ratio of water-soluble substances, then is unable to satisfy the requirement that water-soluble substances core liquid is greater than the density of protection liquid；
The density of water-soluble substances core liquid is less than the density of protection liquid, then the quick-fried pearl of water will not fall in protection liquid；If pure water and water
The weight ratio of soluble substance is higher than 1:0.01, then the polymerization effect of core liquid is bad, and the quick-fried pearl of water will not aggregate into dropping process
It is round.
The case where related water-soluble substances, has been described previously, therefore details are not described herein.
According to the present invention, the density of the water-soluble substances core liquid is 0.9~1.3g/cm3.Water-soluble substances core liquid it is close
Degree is more than that the range is worthless, if the density of water-soluble substances core liquid is less than 0.9g/cm3, then under the quick-fried pearl of water
The whereabouts of water-soluble substances core liquid will be significantly lower than the first photosensitive resin rubber layered material liquid during falling, and occur solid or eccentric
Quick-fried pearl.If the density of water-soluble substances core liquid is greater than 1.3g/cm3, then in the quick-fried pearl dropping process of water, water-soluble substances core liquid
Whereabouts is apparently higher than the first photosensitive resin rubber layered material liquid, also will appear eccentric or solid capsule.Therefore, water-soluble substances core liquid
Density be 0.9~1.3g/cm3It is suitable, preferably 1.0~1.2g/cm3。
B, the first photosensitive resin rubber layered material liquid is prepared
By 20~70 parts by weight of bisphenol A type epoxy resin, the other resins of 30~50 parts by weight and 1~5 parts by weight photosensitizer
Stirring mixes well at normal temperature, then is protected from light standing and saves 12h or more, removes bubble, obtains the first photosensitive resin glue
Cortex；
It has all been described previously in relation to the case where bisphenol A type epoxy resin, other resins and photosensitizer, therefore herein no longer
It repeats.
According to the present invention, the density of the first photosensitive resin rubber layered material liquid is 1.0~1.3g/cm3.The quick-fried pearl first of water is photosensitive
Resin glue cortex feed liquid density is more than that the range is inappropriate, because the density of quick-fried the first photosensitive resin of the pearl rubber layer of water is wanted
Greater than protection liquid density；The protection liquid that the present invention uses is pure water, its density is close to 1.0g/cm3If the first photosensitive tree
Rouge rubber layered material liquid density is less than 1.0g/cm3, then the quick-fried pearl of water protect in liquid fall slowly or will not fall, be unable to complete drop
System.If the first photosensitive resin rubber layered material liquid density is greater than 1.3g/cm3, then the quick-fried pearl of water protect fall in liquid it is too fast, it is unfavorable
In molding and solidification, there is quick-fried pearl of trailing.Therefore, the density of the first photosensitive resin rubber layered material liquid is 1.0~1.3g/cm3It is
Reasonably, preferably 1.1~1.2g/cm3。
C, the second polyacrylic resin rubber layered material liquid is prepared
Under conditions of 50~70 DEG C of temperature, polyacrylic resin is dissolved in ethanol solution, then in the condition of sealing
Lower standing 1h or more obtains the second polyacrylic resin rubber layered material liquid to remove bubble；
According to the present invention, the solution temperature of polyacrylic resin is 50~70 DEG C.If the dissolution temperature of polyacrylic resin
Degree is lower than 50 DEG C, then the solution rate of polyacrylic resin is excessively slow, and ethyl alcohol volatile quantity is high, influences throughput rate, wastes raw material, such as
The solution temperature of fruit polyacrylic resin is higher than 70 DEG C, then ethyl alcohol temperature is excessively high, and volatile quantity is big, therefore, polyacrylic resin
Solution temperature be 50~70 DEG C be it is suitable, preferably 60~65 DEG C.
D, the pre- dripping of the quick-fried pearl of anti-seep water
According to 1~10 parts by weight the first photosensitive resin rubber layer and 90~99 parts by weight core liquid layers, drop is passed through by constant displacement pump
The first photosensitive resin rubber layered material that the water-soluble substances core liquid and step B that ball device concentric circles water dropper prepares step A are prepared
Drop is added in the pure water conservation liquid of room temperature, in its dropping process carry out light irradiation, the first photosensitive resin rubber layered material liquid by
Gradually curing molding, environmental sealing water-soluble substances core liquid form the quick-fried pearl precursor of anti-seep water；Then pass through charging conduit sieve for institute
It states the quick-fried pearl precursor of anti-seep water to separate with pure water conservation liquid, the quick-fried pearl precursor of the anti-seep water of collection is by volume using concentration
The washing of 90% ethanol water, air-dries, obtains the quick-fried pearl precursor of anti-seep water
When the first photosensitive resin rubber layered material liquid and water-soluble substances core drop are added in the pure water conservation liquid of room temperature, not
First photosensitive resin rubber layered material liquid of curing molding is because core liquid cohesive force effect self-assembling formation is spherical, it is in protection liquid
It slowly falls, the first photosensitive resin rubber layered material liquid gradually curing molding, then environmental sealing water-soluble substances core liquid, forms water
Quick-fried pearl precursor.
In the present invention, when water-soluble substances core liquid is 90~99 parts by weight, if the use of the first photosensitive resin rubber layer
Amount is lower than 1 parts by weight, then the quick-fried pearl intensity of water is inadequate, easily broken, is unfavorable for storing；If the dosage of the first photosensitive resin rubber layer
Higher than 10 parts by weight, then the quick-fried pearl intensity of water is excessively high, it is not easy to pinch brokenly.When first photosensitive resin rubber layer is 1~10 parts by weight, such as
The dosage of fruit water-soluble substances core liquid is lower than 90 parts by weight, then the quick-fried pearl intensity of water is excessively high, and the quick-fried pearl circularity of water is inadequate, it is not easy to pinch
It is broken；If the dosage of water-soluble substances core liquid is higher than 99 parts by weight, the quick-fried pearl intensity of water is inadequate, easily broken, is unfavorable for storing.
E, the quick-fried pearl overlay film of anti-seep water is dry
Step D is obtained the quick-fried pearl precursor of anti-seep water to be placed in roller coating pan, is prepared step C using sprayer
Second polyacrylic resin rubber layered material liquid is sprayed on the quick-fried pearl precursor of anti-seep water, and roller coating pan gathers in rotation by second
Acrylic size cortex feed liquid is evenly coated on the quick-fried pearl precursor of anti-seep water, is wrapped in such a way that side coated side is dry
It covers, stops coating when the second polyacrylic resin glue skin thickness reaches 0.05~0.2mm, be then dried to obtain described anti-
The quick-fried pearl of percolating water.
According to the present invention, the second polyacrylic resin glue skin thickness is 0.05~0.20mm.When the second polyacrylic acid tree
When the thickness of rouge rubber layer is less than 0.05mm, then the leak-preventing ability of the quick-fried pearl of water is insufficient, is unfavorable for the storage of the quick-fried pearl of water, when second
When the thickness of polyacrylic resin rubber layer is greater than 0.20mm, then the quick-fried pearl rubber of water is blocked up, influences the partial size of the quick-fried pearl of water, is unfavorable for
Post-production utilizes.
The quick-fried pearl of anti-seep water of the present invention is detected according to weight difference assay standard detecting method and is determined, it is permeable at 10 days
Rate is less than 3%.
The dripping pill device that the present invention uses is referring specifically to attached drawing 1.The dripping pill dripping pill device is by coaxial Double-nozzle sprayer 1, core
Liquid constant displacement pump 21, core liquid bath 3, core liquid pipe 4, the first photosensitive resin rubber layer liquid bath 5, the first photosensitive resin rubber layer liquid pipe 6,
One photosensitive resin rubber layer constant displacement pump 22, protection sap cavity body 7, first light source generator 8, standpipe 9, charging conduit 10, discharge port 11,
First segment is protected liquid refluxing opening 12, protection liquid return pipe 131, the second section protection liquid reflux pump 23, protection liquid return pipe 132, is protected
Protect liquid backflash 14, standpipe 15, the first elevator and mating screw rod 16, molding coil pipe 17, the second elevator and mating screw rod 18
It is formed with second light source generator 19；
Core liquid bath 3 is connected by core liquid constant displacement pump 21 by core liquid pipe 4 with the interior spray head of coaxial Double-nozzle sprayer 1；Meanwhile the
One photosensitive resin rubber layer liquid constant displacement pump 22 passes through the first photosensitive resin rubber layer liquid pipe 6 for the first photosensitive resin rubber layer liquid bath
5 are connected with the outer spray head of coaxial Double-nozzle sprayer 1；Coaxial 1 lower end of Double-nozzle sprayer is located at protection 7 top cavity mouth of sap cavity body
Interior, 15 one end of standpipe passes perpendicularly through protection 7 bottom centre of sap cavity body and is connected with protection sap cavity body 7, the other end and the first lifting electricity
Machine and mating screw rod 16 are fixedly connected；15 lower end of standpipe is connected by hose forming coil pipe 17；Its light is set on the outside of standpipe 15
Directly it is directed at the first light source generator 8 of the cavity, 9 bottom end of standpipe is connected by hose with 17 one end of coil pipe is formed, it another
One end is located at 10 top of charging conduit by hose and perpendicular to the second lifting motor and mating screw rod 18 of horizontal plane；In blanking
10 lower part of slot is arranged first segment and protects liquid refluxing opening 12, and first segment is protected liquid refluxing opening 12 by protection liquid return pipe 131 and protected
14 top of liquid backflash is protected to be connected；Second section protects liquid reflux pump 23 to pass through protection liquid return pipe 132 and protection 7 phase of sap cavity body
Even；At molding 17 center of coil pipe, second light source generator 19 is set；And discharge port 11 is set in 10 bottom of charging conduit, antiseepage is discharged
The quick-fried pearl precursor of leak, it is the washing of 90% alcohol water blend by volume through concentration, air-dries, obtains the quick-fried pearl of anti-seep water
Precursor.
The lamp power of first light source generator 8 and second light source generator 19 that the present invention uses is 18~500w, light path
It is 50~100cm, first light source generator 8 and second light source generator 19 are fluorescent lamp, incandescent lamp, LED ultraviolet lamp, LED light
Or searchlight, these lamps are all current market sales of products.
According to YC/T138-1998 tobacco and tobacco product sensory evaluation criteria, tissue is commented by what 15 experts that smoke panel test formed
Suction group smokes panel test to the cigarette containing the quick-fried pearl of anti-seep water of the present invention and the conventional cigarette without the quick-fried pearl of this water, comments
Result is inhaled these results indicate that aromatic style is obvious, and fragrance is rich after the addition quick-fried pearl of anti-seep water of the present invention, and fresh and sweet perfume is special
Sign enhancing, flue gas taste characteristics are promoted, and being embodied in oral cavity and throat's irritation reduces, and have Hui Tian to promote the production of body fluid sense.
[beneficial effect]
The beneficial effects of the present invention are:
The quick-fried pearl water retention property of the anti-seep water is good, its 10 days permeability rate is less than 3%.The cigarette of the aqueous capsule of the addition present invention
Branch, aromatic style is obvious, and fragrance is rich, and fresh and sweet perfume feature enhancing, flue gas taste characteristics are promoted, and is embodied in oral cavity and larynx
Portion's irritation reduces, and has Hui Tian to promote the production of body fluid sense.
[Detailed description of the invention]
Fig. 1 is the dripping pill apparatus structure schematic diagram with concentric circles water dropper；
In figure:
The coaxial Double-nozzle sprayer of 1-；21- core liquid constant displacement pump；3- core liquid bath；4- core liquid pipe；5- capsule wall material liquid bath；6- glue
Cyst wall material liquid pipe；22- capsule wall material liquid constant displacement pump；7- protects sap cavity body；8- light source generator；9- pipeline；10- charging conduit；11-
Discharge port；12- protects liquid refluxing opening；131- protects liquid return pipe；132- protects liquid return pipe；23- protects liquid reflux pump；14-
Protect liquid backflash；15- standpipe；The first elevator of 16- and mating screw rod；17- forms coil pipe；The second elevator of 18- and mating
Screw rod；19- second light source generator.
[specific embodiment]
It will be better understood that the present invention by following embodiments.
Embodiment 1: the quick-fried pearl preparation of anti-seep water
The preparation step of the preparation method is as follows:
A, water-soluble substances core liquid is prepared
According to the weight ratio 1:1. of pure water and plum medicinal extract, plum medicinal extract is dissolved in pure water under stiring, is obtained close
Degree is 0.9g/cm3Water-soluble substances core liquid；
B, the first photosensitive resin rubber layered material liquid is prepared
By 20 parts by weight of bisphenol A type epoxy resin, 50 parts by weight of polyurethane acrylate and 1 parts by weight KIP150 photosensitizer
Stirring mixes well at normal temperature, then is protected from light standing and saves 12.0h, removes bubble, obtaining density is 0.9g/cm3The first light
Quick resin glue cortex feed liquid；
C, the second polyacrylic resin rubber layered material liquid is prepared
By polyacrylic resin in the ethanol solution of temperature 50 C, 1.0h is stood under air-proof condition, to remove bubble,
Obtain the second polyacrylic resin rubber layered material liquid；
D, the pre- dripping of the quick-fried pearl of anti-seep water
It is same by dripping pill device by constant displacement pump according to 1 parts by weight the first photosensitive resin rubber layer and 99 parts by weight core liquid layers
The first photosensitive resin rubber layered material drop that heart circle water dropper prepares the water-soluble substances core liquid that step A is prepared with step B is added to
In the pure water conservation liquid of room temperature, light is carried out under conditions of power 320w and light path 80cm using fluorescent lamp in its dropping process
Irradiation, gradually curing molding, environmental sealing core liquid layer form the quick-fried pearl precursor of anti-seep water to the first photosensitive resin rubber layer；Then
The quick-fried pearl precursor of anti-seep water is separated with pure water conservation liquid by charging conduit sieve, the quick-fried pearl precursor of the anti-seep water of collection uses
Concentration is the washing of 90% ethanol water by volume, air-dries, obtains the quick-fried pearl precursor of anti-seep water.
E, the quick-fried pearl overlay film of anti-seep water is dry
Step D is obtained the quick-fried pearl precursor of anti-seep water to be placed in roller coating pan, is obtained step C using sprayer
In second polyacrylic resin rubber layer spray solution to coating pan, coating pan drives the quick-fried pearl precursor rolling of anti-seep water in rotation
Dynamic, the second polyacrylic resin rubber layer just uniformly overlays on the quick-fried pearl precursor of anti-seep water, the mode dried in overlay film into
Row overlay film stops overlay film when the second polyacrylic resin glue skin thickness reaches 0.2mm, dry, obtains the antiseep
The quick-fried pearl of water, the quick-fried 10 days permeability rates of pearl of the anti-seep water are 2.2%.
According to the method for smokeing panel test that present specification describes, sensory evaluating smoking is carried out to the aqueous capsule of embodiment preparation,
Its smoking result: the enhancing of flue gas moisture feeling, irritation reduce, and fresh and sweet perfume feature enhancing, flue gas taste characteristics are promoted, and have Hui Tian
It promotes the production of body fluid sense..
Embodiment 2: the quick-fried pearl preparation of anti-seep water
The preparation step of the preparation method is as follows:
A, water-soluble substances core liquid is prepared
According to the weight ratio 1:0.5 of pure water and ethyl acetate, ethyl acetate is dissolved in pure water under stiring, is obtained close
Degree is 1.0g/cm3Water-soluble substances core liquid；
B, the first photosensitive resin rubber layered material liquid is prepared
By 70 parts by weight of bisphenol A type epoxy resin, 30 weight of polyester acrylic resins and 5 parts by weight O mnipol BP light
Quick dose at normal temperature stirring mix well, then be protected from light standing save 12.2h, remove bubble, obtain density be 1.0g/cm3
One photosensitive resin rubber layered material liquid；
C, the second polyacrylic resin rubber layered material liquid is prepared
By polyacrylic resin in 70 DEG C of ethanol solution, 1.1h is stood under air-proof condition, is removed bubble, is obtained institute
The the second polyacrylic resin rubber layered material liquid stated；
D, the pre- dripping of the quick-fried pearl of anti-seep water
It is same by dripping pill device by constant displacement pump according to 10 parts by weight the first photosensitive resin rubber layers and 90 parts by weight core liquid layers
The first photosensitive resin rubber layered material drop that heart circle water dropper prepares the water-soluble substances core liquid that step A is prepared with step B is added to
In the pure water conservation liquid of room temperature, carried out under conditions of power 18w and light path 50cm in its dropping process using LED ultraviolet lamp
Light irradiation, gradually curing molding, environmental sealing core liquid layer form the quick-fried pearl precursor of anti-seep water to the first photosensitive resin rubber layer；It connects
The quick-fried pearl precursor of anti-seep water is separated with pure water conservation liquid by charging conduit sieve, the quick-fried pearl precursor of the anti-seep water of collection makes
It is that 90% ethanol water washs by volume with concentration, air-dries, obtain the quick-fried pearl precursor of anti-seep water.
E, the quick-fried pearl overlay film of anti-seep water is dry
Step D is obtained the quick-fried pearl precursor of anti-seep water to be placed in roller coating pan, is obtained step C using sprayer
In second polyacrylic resin rubber layer spray solution to coating pan, coating pan drives the quick-fried pearl precursor rolling of anti-seep water in rotation
Dynamic, the second polyacrylic resin rubber layer just uniformly overlays on the quick-fried pearl precursor of anti-seep water, the mode dried in overlay film into
Row overlay film stops overlay film when the second polyacrylic resin glue skin thickness reaches 0.05mm, dry, obtains the antiseep
The quick-fried pearl of water, the quick-fried 10 days permeability rates of pearl of the anti-seep water are 2.9%.
According to the method for smokeing panel test that present specification describes, sensory evaluating smoking is carried out to the aqueous capsule of embodiment preparation,
The enhancing of its smoking result flue gas moisture feeling, irritation reduce, and miscellaneous gas reduces.
Embodiment 3: the quick-fried pearl preparation of anti-seep water
The preparation step of the preparation method is as follows:
A, water-soluble substances core liquid is prepared
According to the weight ratio 1:0.4 of pure water and glutamic acid, amino acid is dissolved in pure water under stiring, obtaining density is
1.2g/cm3Water-soluble substances core liquid；
B, the first photosensitive resin rubber layered material liquid is prepared
By 50 parts by weight of bisphenol A type epoxy resin, 40 parts by weight polyoxyalkylene acrylate resins and 3 parts by weight Irgacure 127
Stirring mixes well at normal temperature, then is protected from light standing and saves 12.3h, removes bubble, and obtaining density is 1.2g/cm3The first light
Quick resin glue cortex feed liquid；
C, the second polyacrylic resin rubber layered material liquid is prepared
By polyacrylic resin in 65 DEG C of ethanol solution, 1.2h is stood under air-proof condition, is removed bubble, is obtained institute
The the second polyacrylic resin rubber layered material liquid stated；
D, the pre- dripping of the quick-fried pearl of anti-seep water
It is same by dripping pill device by constant displacement pump according to 8 parts by weight the first photosensitive resin rubber layers and 92 parts by weight core liquid layers
The first photosensitive resin rubber layered material drop that heart circle water dropper prepares the water-soluble substances core liquid that step A is prepared with step B is added to
In the pure water conservation liquid of room temperature, light is carried out under conditions of power 500w and light path 65cm using LED light in its dropping process
Irradiation, gradually curing molding, environmental sealing core liquid layer form the quick-fried pearl precursor of anti-seep water to the first photosensitive resin rubber layer；Then
The quick-fried pearl precursor of anti-seep water is separated with pure water conservation liquid by charging conduit sieve, the quick-fried pearl precursor of the anti-seep water of collection uses
Concentration is the washing of 90% ethanol water by volume, air-dries, obtains the quick-fried pearl precursor of anti-seep water.
E, the quick-fried pearl overlay film of anti-seep water is dry
Step D is obtained the quick-fried pearl precursor of anti-seep water to be placed in roller coating pan, is obtained step C using sprayer
In second polyacrylic resin rubber layer spray solution to coating pan, coating pan drives the quick-fried pearl precursor rolling of anti-seep water in rotation
Dynamic, the second polyacrylic resin rubber layered material liquid is just uniformly coated on the quick-fried pearl precursor of anti-seep water, is dried in overlay film
Mode carries out overlay film, stops overlay film when the second polyacrylic resin glue skin thickness reaches 0.1mm, dry, obtains described
The quick-fried pearl of anti-seep water, the quick-fried 10 days permeability rates of pearl of the anti-seep water are 2.5%.
According to the method for smokeing panel test that present specification describes, sensory evaluating smoking is carried out to the aqueous capsule of embodiment preparation,
The enhancing of its smoking result flue gas moisture feeling, irritation reduce, odor characteristic enhancing, flue gas sweet tea sense enhancing.
Embodiment 4: the quick-fried pearl preparation of anti-seep water
The preparation step of the preparation method is as follows:
A, water-soluble substances core liquid is prepared
According to the weight ratio 1:0.4 of pure water and pectase, amino acid is dissolved in pure water under stiring, obtaining density is
1.3g/cm3Water-soluble substances core liquid；
B, the first photosensitive resin rubber layered material liquid is prepared
By 50 parts by weight of bisphenol A type epoxy resin, 40 parts by weight polyoxyalkylene acrylate resins and 3 parts by weight Irgacure 754
Photosensitizer stirs mix well at normal temperature, then is protected from light standing and saves 12.3h, removes bubble, and obtaining density is 1.3g/cm3's
First photosensitive resin rubber feed liquid；
C, the second polyacrylic resin rubber layered material liquid is prepared
By polyacrylic resin in 65 DEG C of ethanol solution, 1.2h is stood under air-proof condition, is removed bubble, is obtained institute
The the second polyacrylic resin rubber layered material liquid stated；
D, the pre- dripping of the quick-fried pearl of anti-seep water
It is same by dripping pill device by constant displacement pump according to 8 parts by weight the first photosensitive resin rubber layers and 92 parts by weight core liquid layers
The first photosensitive resin rubber layered material drop that heart circle water dropper prepares the water-soluble substances core liquid that step A is prepared with step B is added to
In the pure water conservation liquid of room temperature, carried out under conditions of power 180w and light path 100cm in its dropping process using searchlight
Light irradiation, gradually curing molding, environmental sealing core liquid layer form the quick-fried pearl precursor of anti-seep water to the first photosensitive resin rubber layer；It connects
The quick-fried pearl precursor of anti-seep water is separated with pure water conservation liquid by charging conduit sieve, the quick-fried pearl precursor of the anti-seep water of collection makes
It is that 90% ethanol water washs by volume with concentration, air-dries, obtain the quick-fried pearl precursor of anti-seep water.
E, the quick-fried pearl overlay film of anti-seep water is dry
Step D is obtained the quick-fried pearl precursor of anti-seep water to be placed in roller coating pan, is obtained step C using sprayer
In second polyacrylic resin rubber layer spray solution to coating pan, coating pan drives the quick-fried pearl precursor rolling of anti-seep water in rotation
Dynamic, the second polyacrylic resin rubber layer just uniformly overlays on the quick-fried pearl precursor of anti-seep water, the mode dried in overlay film into
Row overlay film stops overlay film when the second polyacrylic resin glue skin thickness reaches 0.1mm, dry, obtains the antiseep
The quick-fried pearl of water, the quick-fried 10 days permeability rates of pearl of the anti-seep water are 1.9%.
According to the method for smokeing panel test that present specification describes, sensory evaluating smoking is carried out to the aqueous capsule of embodiment preparation,
The enhancing of its smoking result flue gas moisture feeling, irritation reduce, odor characteristic enhancing, flue gas sweet tea sense enhancing.
Claims (10)
1. a kind of quick-fried pearl of anti-seep water, it is characterised in that it is to be followed successively by core liquid layer, the first photosensitive resin rubber layer from inside to outside
With the second polyacrylic resin rubber layer composition；The core liquid layer is by pure water and water-soluble substances according to weight ratio 1:
0.01~1.0 composition；The quick-fried pearl of anti-seep water is in 10 days permeability rates less than 3%.
2. the quick-fried pearl of anti-seep water according to claim 1, it is characterised in that the water-soluble substances are one or more
Selected from soluble perfume fragrance, plant extracts, medicinal extract, food flavor substances, water-soluble polysaccharide, propylene glycol, glycerine, bee
Honey, sodium chloride, potassium sorbate or potassium citrate water-soluble substances.
3. the quick-fried pearl of anti-seep water according to claim 2, it is characterised in that the soluble perfume fragrance is acetic acid second
Ester, benzyl carbinol, benzyl alcohol or furanone；The plant extracts is alkaloid, volatile oil, tannin, sugar, amino acid, enzyme, has
Machine acid, grease, wax or pigment plant extracts.
4. the quick-fried pearl of anti-seep water according to claim 2, it is characterised in that the medicinal extract is plum medicinal extract, hawthorn leaching
Cream, tealeaves medicinal extract or tamarind medicinal extract；The food flavor substances are malic acid, glutamic acid, sodium chloride or glucose；Described
Water-soluble polysaccharide is maltose or sucrose.
5. the quick-fried pearl of anti-seep water according to claim 1, it is characterised in that the photosensitive resin is by 20~70 parts by weight
Bisphenol A type epoxy resin, 30~50 parts by weight are one or more to be selected from urethane acrylate, polyester acrylate resin, polyethers
Acrylic resin, other resins of 12 rouge of acrylic acid or acrylic resin and 1~5 parts by weight photosensitizer form.
6. the quick-fried pearl of anti-seep water according to claim 5, it is characterised in that the photosensitizer is one or more choosings
KIP150、Omnipol BP、Polymeric 910、Irgacure 127、Irgacure 754、Irgacure OXE01、Rad-
The macromolecular photosensitizer of Start N-1414, CD-1012 or Esacure1187.
7. the preparation method of the quick-fried pearl of anti-seep water described in any one of -6 claims according to claim 1, it is characterised in that should
The step of preparation method, is as follows:
A, water-soluble substances core liquid is prepared
According to weight ratio 1:0.01~1.0 of pure water and water-soluble substances, the water-soluble substances are dissolved under stiring pure
In water, the water-soluble substances core liquid is obtained；
B, the first photosensitive resin rubber layered material liquid is prepared
By 20~70 parts by weight of bisphenol A type epoxy resin, the other resins of 30~50 parts by weight with 1~5 parts by weight photosensitizer normal
The lower stirring of temperature mixes well, then is protected from light standing preservation 12h or more and obtains the first photosensitive resin rubber layered material liquid to remove bubble；
C, the second polyacrylic resin rubber layered material liquid is prepared
Under conditions of 50~70 DEG C of temperature, polyacrylic resin is dissolved in ethanol solution, it is then quiet under sealed conditions
1h or more is set, to remove bubble, obtains the second polyacrylic resin rubber layered material liquid；
D, the pre- dripping of the quick-fried pearl of anti-seep water
According to 1~10 parts by weight the first photosensitive resin rubber layer and 90~99 parts by weight core liquid layers, filled by constant displacement pump by dripping pill
Set the water-soluble substances core liquid that concentric circles water dropper prepares step A and the first photosensitive resin rubber layered material drop that step B is prepared
It is added in the pure water conservation liquid of room temperature, light irradiation is carried out in its dropping process, the first photosensitive resin rubber layered material liquid is gradually solid
Chemical conversion type, environmental sealing water-soluble substances core liquid form the quick-fried pearl precursor of anti-seep water；It then will be described anti-by charging conduit sieve
The quick-fried pearl precursor of percolating water is separated with pure water conservation liquid, and the quick-fried pearl precursor of the anti-seep water of collection is by volume 90% using concentration
Ethanol water washing, air-dries, obtains the quick-fried pearl precursor of anti-seep water；
E, the quick-fried pearl overlay film of anti-seep water is dry
Step D is obtained the quick-fried pearl precursor of anti-seep water to be placed in roller coating pan, prepare step C using sprayer second
Polyacrylic resin rubber layered material liquid is sprayed on the quick-fried pearl precursor of anti-seep water, and roller coating pan is in rotation by the second polypropylene
Acid resin rubber layered material liquid is evenly coated on the quick-fried pearl precursor of anti-seep water, is coated in such a way that side coated side is dry, when
Second polyacrylic resin glue skin thickness stops coating when reaching 0.05~0.2mm, is then dried to obtain the antiseep
The quick-fried pearl of water.
8. preparation method according to claim 6, it is characterised in that in step, the water-soluble substances core liquid it is close
Degree is 0.9~1.3g/cm3。
9. preparation method according to claim 6, it is characterised in that in stepb, the first photosensitive resin rubber layered material liquid
Density be 1.0~1.3g/cm3。
10. preparation method according to claim 6, it is characterised in that in step D, the first photosensitive resin rubber layered material liquid
It is fluorescent lamp, incandescent lamp, LED ultraviolet lamp, LED light or searchlight protecting in liquid carry out light irradiation in dropping process,
It is 50~100cm that the power of lamp, which is 18~500w, light path,.
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