WO2013187245A1 - Cigarette - Google Patents

Cigarette Download PDF

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Publication number
WO2013187245A1
WO2013187245A1 PCT/JP2013/065105 JP2013065105W WO2013187245A1 WO 2013187245 A1 WO2013187245 A1 WO 2013187245A1 JP 2013065105 W JP2013065105 W JP 2013065105W WO 2013187245 A1 WO2013187245 A1 WO 2013187245A1
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WO
WIPO (PCT)
Prior art keywords
filter
capsule
paper
thickness
cigarette
Prior art date
Application number
PCT/JP2013/065105
Other languages
French (fr)
Japanese (ja)
Inventor
哲也 本溜
石川 悦朗
Original Assignee
日本たばこ産業株式会社
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Filing date
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Application filed by 日本たばこ産業株式会社 filed Critical 日本たばこ産業株式会社
Publication of WO2013187245A1 publication Critical patent/WO2013187245A1/en

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    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/02Cigars; Cigarettes with special covers
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/04Tobacco smoke filters characterised by their shape or structure
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/061Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes

Definitions

  • This invention relates to the cigarette which improved the ease of crushing of the capsule contained in a filter.
  • Patent Documents 1 and 2 Conventionally, a fragrance capsule is incorporated into a cigarette filter, the fragrance capsule is crushed with a finger during use, and the scent of the contents liquid is enjoyed during smoking, and the smell of the butt after being extinguished is masked ( Patent Documents 1 and 2). The details of the fragrance capsule are described in Patent Document 3, for example.
  • the perfume capsule is directly embedded in the filter medium constituting the filter, or is disposed in a hollow portion formed between a plurality of filter plugs (see FIGS. 1A and 1B). In any case, since the fragrance capsule is located in the filter, it is crushed by pressing with a finger on the paper (winding paper or molding paper) and chip paper on which the filter is packaged.
  • the present inventors have focused on improving the ease of crushing of capsules contained in a filter, and the present invention provides a cigarette with improved ease of crushing of capsules contained in a filter. For the purpose.
  • the present inventors when crushing a capsule with a finger from a paper having both a specific density and a specific thickness, can crush the capsule with a small force, and the pressure on the finger is difficult to concentrate locally, The present inventors have found that it can be dispersed on a wider contact surface and have completed the present invention.
  • a tobacco rod including a tobacco filler and a wrapping paper wound around the tobacco filler;
  • a filter including a filter plug including a filter medium, a filter wrapping paper wound around the filter plug, and a capsule located in the filter and encapsulating and holding the contents with a film;
  • a cigarette is provided in which at least one of the filter wrapping paper and the chip paper has a density of 0.5 to 1.0 g / cm 3 and a thickness of 100 to 250 ⁇ m.
  • the capsule can be crushed with a small force and a short pushing distance. Moreover, since the cigarette of this invention can disperse
  • Sectional drawing which shows the cigarette which concerns on the 1st aspect of this invention.
  • Sectional drawing which shows the cigarette which concerns on the 2nd aspect of this invention.
  • the disassembled perspective view which shows the cigarette which concerns on the 1st aspect of this invention.
  • the figure which shows typically the measuring system using a rheometer.
  • the graph which shows the relationship between the indentation distance of a capsule, and a load (Example 1).
  • the figure (example 1) which shows typically the mode of the test paper when the same load is applied.
  • the graph which shows the relationship between the thickness of paper and the ease of transmission of the force to a capsule (example 1).
  • the figure which shows the pressure distribution added to the test paper (Example 2).
  • the figure which shows the mode of the test paper when the same load is applied (example 2).
  • the figure which shows the size of a capsule containing filter (Example 3).
  • the figure which shows a mode that a capsule containing filter and a capsule are pressurized (Example 3).
  • the graph which shows the relationship between the indentation distance of a capsule containing filter and a capsule, and a load (Example 3).
  • the capsule may be disposed in a hollow portion formed between a plurality of filter plugs (first aspect), or may be directly embedded in a filter medium constituting the filter (first). Second embodiment).
  • the cigarette according to the first aspect of the present invention is as shown in FIG.
  • a tobacco rod (11) including a tobacco filler (11a) and a wrapping paper (11b) wound around the tobacco filler;
  • At least one of the filter wrapping paper and the chip paper has a density of 0.5 to 1.0 g / cm 3 and a thickness of 100 to 250 ⁇ m.
  • FIG. 2 shows a state in which the cigarette according to the first aspect of the present invention is disassembled.
  • two filter plugs (12a) are arranged apart from each other, and a filter wrapping paper (12b) and a chip paper (13) are wound around them, so that a hollow portion is formed between the filter plugs (12a). It shows that it is formed and the capsule (12c) is located in such a hollow part.
  • a tobacco rod (11) including a tobacco filler (11a) and a wrapping paper (11b) wound around the tobacco filler;
  • a filter (12) comprising: Including the tobacco rod and chip paper (13) wound on the filter so as to connect the tobacco rod and the filter; At least one of the filter wrapping paper and the chip paper has a density of 0.5 to 1.0 g / cm 3 and a thickness of 100 to 250 ⁇ m.
  • the properties of the paper cause the capsules.
  • the ease of crushing can be improved.
  • Paper having a density of 0.5 to 1.0 g / cm 3 and a thickness of 100 to 250 ⁇ m has a higher density and thickness compared to the paper generally used for filter wrapping paper and chip paper. High capsule crushing performance due to thickness. Therefore, the characteristic paper used in the present invention, that is, paper having a density of 0.5 to 1.0 g / cm 3 and a thickness of 100 to 250 ⁇ m is also referred to as “the high performance paper of the present invention”.
  • the high performance paper of the present invention when used as the filter wrapping paper, the same high performance paper may be used as the chip paper, and it has a normal density and thickness generally used as chip paper. Paper may be used.
  • the filter wrapping paper when the high-performance paper of the present invention is used as the chip paper, the filter wrapping paper may use the same high-performance paper, and has a normal density and thickness generally used as filter wrapping paper. Paper may be used.
  • At least one of filter wrapping paper and chip paper has a density of 0.5 to 1.0 g / cm 3 and a thickness of 100 to 250 ⁇ m, preferably 0.7 to 1.0 g. Having a density of / cm 3 and a thickness of 180 to 250 ⁇ m, more preferably a density of 0.8 to 1.0 g / cm 3 and a thickness of 240 to 250 ⁇ m.
  • the ruled paper is arranged so that the ruled line is parallel to the longitudinal direction of the cigarette. Further, the ruled paper is preferably arranged so that the ruled surface faces inward in the cigarette.
  • the ruled line processing can be performed by putting ruled lines (folded lines) on the surface of the paper at regular intervals by a ruled line machine.
  • the ruled line processing is preferably performed at a depth of 60 to 90% of the paper thickness and at intervals of 2 mm or less.
  • the thickness of the paper is in the range of 100 to 250 ⁇ m, if the density is less than 0.5 g / cm 3 , the paper tends to deform and break when the capsule is crushed, and the pressure on the finger is concentrated locally. Therefore, it becomes difficult to crush the capsule.
  • the density is greater than 1.0 g / cm 3 , the paper production cost increases, which is not preferable.
  • the density of the paper is desirably large in the range of 0.5 to 1.0 g / cm 3 in order to prevent leakage of the capsule contents (for example, leakage of the capsule contents liquid).
  • the density of the paper is within the range of 0.5 to 1.0 g / cm 3 , if the thickness is smaller than 100 ⁇ m, the paper is easily deformed and broken when the capsule is crushed, and the pressure on the finger is locally Because it concentrates on the capsule, it becomes difficult to crush the capsule.
  • the thickness is larger than 250 ⁇ m, it is difficult to perform a winding process for manufacturing cigarettes, and it becomes difficult to obtain a feeling of breaking the capsule.
  • the filter wrapping paper (12b in FIG. 1A) in the first embodiment is also called a molded paper.
  • the basis weight is generally 50 to 250 g / m 2
  • the capsule since the capsule is located in the hollow portion of the filter, it is particularly preferable to set the air permeability of the filter wrapping paper to 0 for the purpose of preventing the liquid in the capsule from oozing out of the cigarette.
  • the basis weight is 50 to 250 g / m 2 and the air permeability is It can be 0 to 30000 CU.
  • the air permeability of the filter wrapping paper can be set to 0 for the same purpose as described above.
  • the chip paper can be a paper having a normal density and thickness generally used as a chip paper.
  • the basis weight is 20 to 60 g / m 2 and thickness can be 20 to 60 ⁇ m.
  • the capsule is accommodated in the hollow portion between the filter plugs or embedded in the filter plug.
  • One capsule may be present in the filter, or a plurality (for example, 2 to 10) of capsules may be present.
  • one capsule may be accommodated per one hollow part, or a plurality of (for example, 2 to 10) capsules may be accommodated.
  • Capsule is composed of film and contents.
  • the film for example, starch, dextrin, polysaccharides, agar, gellan gum, gelatin, various natural gelling agents, glycerin, sorbitol, calcium chloride, and the like can be used, and flavors and coloring agents can be further included.
  • the capsule is preferably colored so that a smoker can recognize it when crushing the capsule even if it is surrounded by filter wrapping paper or chip paper having opacity, and a colorant such as Blue No. 1 is applied to the film. It is preferable to include.
  • any substance can be used, and the shape thereof can be any shape such as solid, liquid, and gas.
  • a solid adsorbent such as activated carbon or a solid fragrance can be used as the contents.
  • any liquid can be used as the contents, for example, a liquid containing a fragrance can be used.
  • a liquid containing any fragrance used in smoking articles such as menthol and plant essential oil can be used.
  • a cigarette containing such a fragrance-containing capsule in a filter can enjoy the fragrance by crushing the fragrance-containing capsule during smoking.
  • water can be used as the contents.
  • a cigarette including such a water-containing capsule in a filter can be smoked by pulverizing the water capsule during smoking and passing smoke through the water like a cigarette.
  • a gas fragrance can be used as the contents.
  • the main flavors used in the contents include menthol, leaf tobacco extract, natural plant flavors (for example, cinnamon, sage, herbs, chamomile, kuzuka, sweet tea, clove, lavender, cardamom, clove, nutmeg, bergamot, Geranium, honey essence, rose oil, lemon, orange, cinnamon, caraway, jasmine, ginger, coriander, vanilla extract, spearmint, peppermint, cassia, coffee, celery, cascarilla, sandalwood, cocoa, ylang ylang, fennel, anise , Licorice, St.
  • natural plant flavors for example, cinnamon, sage, herbs, chamomile, kuzuka, sweet tea, clove, lavender, cardamom, clove, nutmeg, bergamot, Geranium, honey essence, rose oil, lemon, orange, cinnamon, caraway, jasmine, ginger, coriander, vanilla extract, spearmint, peppermint, cassia, coffee, celery, cascarilla, sandalwood
  • John's bread, plum extract, peach extract, etc. saccharides (eg, glucose, fructose, isomerized sugar, caramel, etc.), cocoa (powder, extract, etc.), esters (eg, isoamyl acetate, Linalyl acid, isoamyl propionate, linalyl butyrate, etc.), ketones (eg, menthone, ionone, damacenone, ethylmaltol, etc.), alcohols (eg, geraniol, linalool, anethole, eugenol, etc.), aldehydes (eg, vanillin, Benzaldehyde, anisaldehyde, etc.), lactones (eg, ⁇ -undecalactone, ⁇ -nonalactone, etc.), animal perfumes (eg, musk, ambergris, civet, castrium, etc.), hydrocarbons (eg, limon
  • a solvent suitable for the fragrance can be used as the solvent, and medium chain fatty acid triglyceride (MCT) (specifically, tricapryl / glyceryl caprate), propylene glycol Water, ethanol, etc. can be used.
  • MCT medium chain fatty acid triglyceride
  • the liquid containing a fragrance may further contain other additives such as other solvents, pigments, emulsifiers and thickeners.
  • the method for producing the capsule is not particularly limited. For example, if a dropping method is used, a capsule having a seamless film can be produced. In this method, by using a double nozzle and simultaneously discharging the contents from the inner nozzle and the liquid film substance from the outer nozzle, the film liquid can wrap the contents without having a seam.
  • the capsule can have, for example, a spherical or cylindrical shape, where the sphere includes both a sphere having a substantially circular cross section and an ellipsoid having a elliptical cross section.
  • the capsule preferably has a spherical shape with a substantially circular cross section.
  • the capsule can have a diameter of 1.0 to 8.0 mm, for example, and in the case of an ellipsoid, the capsule has a maximum diameter of 1.0 to 7.0 mm and a minimum diameter of 1.0 to
  • the diameter of the circle may be 1.0 to 7.0 mm and the height may be 1.0 to 7.0 mm.
  • the diameter is more preferably 3.0 mm or more, and in the case of an ellipsoid, the minimum diameter is Is more preferably 3.0 mm or more, and in the case of a cylindrical body, the diameter of the circle is more preferably 3.0 mm or more.
  • the capsule itself can be broken at a strength of about 10 to 35 [N].
  • relatively hard capsules such as capsules that can be broken at a strength higher than about 25 [N] and lower than about 30 [N] can be crushed with a small force and a short indentation distance. Is possible.
  • Harder capsules have the advantage that the encapsulated cigarettes are less likely to break when exposed to high temperatures or when transported.
  • the filter plug can be composed of a filter medium of acetate tow, like a normal cigarette with a filter.
  • the filter plug may be composed only of the filter medium, or may be composed of the filter medium and a plug web wound around the filter medium.
  • the cut-side filter plug and the suction-side filter plug may have the same material and structure, or may have different materials and structures.
  • Acetate tow has, for example, a single yarn fineness of 1.9 to 8.6 (g / 9000m), a total fineness of 17000 to 44000 (g / 9000m), a number of fibers of 2400 to 23500 (piece), and a ventilation resistance of 100 to 600 (mmH2O / 120mm).
  • a plasticizer such as triacetin may be added to acetate tow, and the plasticizer can be added in an amount of 6 to 10% by weight based on the weight of acetate tow.
  • When activated carbon is added to acetate tow The plasticizer can be added in an amount of 2 to 20% by weight based on the weight of acetate tow.
  • the filter medium is too hard, the repulsive force by the filter plug when the capsule-containing filter is crushed with a finger increases, so the single yarn fineness is more than 3.0 (g / 9000m).
  • the total fineness is preferably 35000 (g / 9000 m) or less.
  • the filter has a circumference of, for example, about 14 to 26 mm, and the length can be, for example, 17 to 31 mm, similar to a normal filter.
  • the length of the hollow portion may be not less than the size of the capsule, for example, 3 to 7 mm, and the length of each filter plug may be 5 to 20 mm.
  • n is an integer of 2 or more
  • filter plugs are arranged through (n ⁇ 1) hollow portions.
  • n is 2 to 4, preferably n is 2 to 3, and more preferably n is 2.
  • the filter is composed of a single filter plug, but according to the known art, a plurality of filter plugs, eg 2-4, preferably 2-3, more preferably 2 filters. Plugs may be connected. When a plurality of filter plugs are connected, capsules may be embedded in all filter plugs, or capsules may be embedded in some filter plugs.
  • the cigarette rod is composed of a cigarette filler and cigarette paper wound around the cigarette filler, like a normal cigarette, and has, for example, a circumference of about 14 to 26 mm and a length of 53 to 67 mm. Can do.
  • Example 1 Effect of paper thickness and density on indentation distance when crushing capsules
  • the following six types of test papers were used (the parentheses are the source of each test paper). The characteristics of each test paper are shown in Table 1 below. Each test paper was 2 cm square and used for the experiment.
  • Test paper 50NFB is a molded paper currently used in capsule-containing cigarettes.
  • breaking strength represents the load [N] applied to the capsule when the capsule is broken
  • movement distance represents the pushing distance [mm] when the capsule is broken.
  • the capsule was prepared by mixing the film substance (15% by weight) and the content liquid (85% by weight), and dropping.
  • the main components of the coating substance and the content liquid constituting the capsule were as follows.
  • ii Contents liquid Medium chain fatty acid triglyceride (tricapryl / glycol caprate) (83 wt%)
  • the prepared capsule was a sphere having a diameter of about 4.5 mm.
  • the hardness of the capsule was about 30N.
  • the content liquid of the capsule is composed only of a solvent and does not contain a fragrance, but it has been demonstrated that the presence or absence of the fragrance does not affect the ease of crushing the capsule.
  • the relationship between the indentation distance and the load when the capsule was crushed was examined. That is, a capsule was placed on a test paper placed on an elastic rubber, and the capsule was crushed by applying pressure from above with a pressure sensitive shaft of a rheometer. The capsules were crushed under the conditions of 60% humidity and a temperature of 22 degrees. The indentation distance (mm) (also referred to as the movement distance) and the load (N) at that time were measured. The measurement was performed using a Sun RHEO METER CR3000EX (Sun Science Co., Ltd.).
  • the measurement results are shown in FIG. 3B. 3B, (1) is 50NFB, (2) is HS, (3) is AT, (4) is HS120, (5) is S80, and (6) is resistance paper.
  • FIG. 3B shows that HS, AT, HS120, and S80 have a smaller pushing distance (movement distance) required to reach the same load than test paper 50NFB.
  • the resistance paper has a larger pressing distance (movement distance) necessary to reach the same load than 50 NFB.
  • FIG. 3C schematically shows this state, that is, the state when the same load is applied to 50 NFB, resistance paper, and S80.
  • the arrow extending from the test paper schematically represents the state of pressure that will be applied to the finger when the capsule is crushed with the finger.
  • FIG. 3C shows that when a paper having a predetermined density and thickness, such as S80, is used, the same load can be applied to the capsule with a smaller pressing distance, and the paper is not easily broken when the load is applied. It shows that the pressure at the time of crushing can be disperse
  • FIG. 3C shows that when a low density paper (resistance paper) or a low thickness paper (50NFB) is used, the pressing distance required to give a predetermined load is large, and the paper is not loaded when a load is applied. Because it is easy to break, it shows that the pressure when crushing the capsule tends to concentrate on one point.
  • a paper having a predetermined density and thickness such as S80
  • FIG. 3D the relationship between the thickness of the paper and the ease of transmission of force to the capsule is shown in FIG. 3D.
  • breaking strength means a load [N] applied to the capsule when the capsule is broken
  • movement distance means a pushing distance [mm] when the capsule is broken.
  • a large breaking strength [N] / moving distance [mm] means that a large load can be applied to the capsule with a small pushing distance, that is, a force can be easily transmitted to the capsule with a small pushing distance.
  • the graph of FIG. 3D (1) represents 50NFB, (2) represents HS, (3) represents AT, (4) represents HS120, (5) represents S80, and (6) represents resistance paper.
  • the graph of FIG. 3D prepares 20 samples for each test paper, measures the indentation distance (mm) and the load (N), and plots the average value of the obtained data.
  • the graph of FIG. 3B shows a typical example selected from the data obtained from 20 samples.
  • the maximum point of load (the load necessary for crushing the capsule) should be the same for any test paper. . Therefore, the difference in the maximum load point observed in FIG. 3B is considered to be due to a slight difference in the hardness of the capsule.
  • Example 2 Effect of paper thickness on pressure distribution when crushing capsules
  • Capsule is placed on each test paper placed on elastic rubber according to the same method as in Example 1, and from above the pressure sensitive axis of rheometer The capsule was crushed under pressure. The capsules were crushed under the conditions of 60% humidity and a temperature of 22 degrees. When the capsule collapsed, the pressure distribution applied to the test paper was measured. The pressure distribution was measured using the measurement system and Inastomer (Inaba Rubber Co., Ltd.) shown in FIG. 3A. As the test paper, 50NFB and S80 used in Example 1 were used.
  • FIG. 4A shows that the pressure is higher at the center of the pressure distribution, and gradually decreases concentrically as the distance from the center increases.
  • the central portion (blacked portion) observed with the test paper 50NFB has the highest pressure, and then the pressure in the portion with the rough hatching is high, and then the fine hatching is applied. Part pressure is high.
  • FIG. 4A shows that S80 has a larger pressurization area as a whole and lower pressure at the center than 50 NFB.
  • test paper S80 having a predetermined density and thickness is less likely to concentrate the pressure on the finger locally when crushing the capsule, and can be distributed over a wider contact surface. It shows that the burden on is small.
  • FIG. 4B schematically shows this state, that is, the state when the same load is applied to the test paper.
  • the arrow extending from the test paper schematically represents the state of pressure that will be applied to the finger when the capsule is crushed with the finger.
  • FIG. 4B shows that the test paper 50NFB not having the predetermined thickness is more likely to concentrate the pressure on the finger locally, is higher at the center, and the test paper S80 has a wider pressure on the finger. It is easy to disperse and shows low in the center.
  • Example 1 and 2 the experiment was conducted by directly placing the capsule on the test paper. For this reason, it is considered that the experimental results of Examples 1 and 2 directly reflect the first aspect of the present invention (the aspect in which the capsule is accommodated in the hollow portion between the filter plugs). In addition, the capsule is sufficiently harder than the filter medium constituting the filter plug. In the second aspect of the present invention (an aspect in which the capsule is embedded in the filter medium in the filter plug), the capsule indicates the hardness of the capsule when the capsule is crushed. Therefore, the experimental results of Examples 1 and 2 are considered to reflect the second aspect of the present invention (the aspect in which the capsule is embedded in the filter medium in the filter plug).
  • Example 3 A filter capsule in which the capsule is disposed in the hollow portion between the filter plugs was prepared according to the same method as in Example 1, and a filter in which the capsule was disposed in the hollow portion between the filter plugs was prepared.
  • the size of the filter was as shown in FIG. 5A.
  • the filter plugs on the suction side and the cut side were as follows.
  • Suction side filter plug (acetate filter wound up with web) Single yarn fineness 2.8 (g / 9000m) Total fineness 35000 (g / 9000m) Number of fibers 12500 (pieces) Ventilation resistance 360 (mmH2O / 120mm) Engraved side filter plug (NWA: non-wrap acetate filter) Single yarn fineness 2.5 (g / 9000m) Total fineness 31000 (g / 9000m) Number of fibers 12400 (pieces) Ventilation resistance 300 (mmH2O / 120mm) A plasticizer (triacetin) was added to each tow in an amount of 9% by weight based on the tow weight. S80 was used as a molding paper (test paper) for connecting two filter plugs.
  • the prepared capsule-containing filter was placed on an elastic rubber according to the same method as in Example 1, and the capsule was crushed by applying pressure from above with a pressure sensitive shaft of a rheometer (see FIG. 5B).
  • the capsule alone was placed on an elastic rubber according to the same method as in Example 1, and the capsule was crushed by applying pressure from above the pressure-sensitive axis of the rheometer (see FIG. 5B).
  • the capsules were crushed under the conditions of 60% humidity and a temperature of 22 degrees. Each indentation distance (mm) and load (N) were measured.
  • the capsule-containing filter has a repulsive force due to the filter plug compared to the capsule alone, so it is difficult to apply a load until the test paper reaches the capsule by pressing, and after the test paper reaches the capsule by pressing (After the indentation distance exceeded about 3 mm), the load was easily applied. For this reason, in the case of the capsule alone, the capsule was crushed when a load of about 25.3 N was applied at an indentation distance of about 2.1 mm, whereas the capsule-containing filter had an indentation distance of about 4.4 mm. The capsule crushed when a load of 37.2 N was applied.
  • the pushing distance until the test paper reaches the capsule may be shortened. It turns out that it is preferable.
  • the pushing distance until the test paper reaches the capsule can be shortened by increasing the size of the capsule, thereby further improving the ease of crushing the capsule.
  • Example 4 Filter with Capsule Arranged in the Hollow Part Between Filter Plugs A capsule-containing filter was prepared in the same manner as in Example 3 except that the toe of the filter plug on the suction side and the cut side was changed as follows.
  • Suction side and carved side filter plugs Single yarn fineness 5.0 (g / 9000m) Total fineness 35000 (g / 9000m) 7000 fibers Ventilation resistance 270 (mmH2O / 120mm) No plasticizer (triacetin) was added to the tow.
  • the prepared capsule-containing filter was placed on an elastic rubber according to the same method as in Example 3, the capsule was crushed, and the indentation distance (mm) and load (N) were measured.
  • the capsules were crushed under the conditions of 60% humidity and a temperature of 22 degrees. The measurement results are shown in FIG.
  • the capsule-containing filter of this example since a soft tow was used, the repulsive force by the filter plug could be made smaller than that of the capsule-containing filter of Example 3. For this reason, the capsule-containing filter of Example 3 was crushed when a load of about 37.2 N was applied at an indentation distance of about 4.4 mm, whereas the capsule-containing filter of this example was about 4.5 mm. The capsule was crushed when a load of about 23.2 N was applied at an indentation distance of.
  • Cigarette 11 ... Tobacco rod 11a ... Tobacco filler 11b ... Tobacco wrapping paper 12 ... Filter 12a ... Filter plug 12b ... Filter wrapping paper 12c ... Capsule 12d ⁇ Plug roll paper 13 ... chip paper

Abstract

This cigarette includes: a tobacco rod that contains tobacco filling material and wrapping paper wrapped around the tobacco filling material; a filter that includes a filter plug that includes filter material, filter packaging paper wound around the filter plug, and a capsule that is positioned within the filter, covers the contents with a membrane, and holds the same; and tipping paper wrapped on the tobacco rod and the filter so as to make the tobacco rod and the filter continuous. At least one paper of the filter packaging paper and the tipping paper has a density of 0.5 - 1.0 g/cm3 and a thickness of 100 - 250 µm.

Description

シガレットcigarette
 本発明は、フィルター内に含有されるカプセルの破砕しやすさを向上させたシガレットに関する。 This invention relates to the cigarette which improved the ease of crushing of the capsule contained in a filter.
 従来から、シガレット用フィルターに香料カプセルを組み込み、使用時に香料カプセルを指で破砕し、喫煙時に内容液の香りを楽しんだり、消火後の吸殻のにおいをマスキングしたりすることが行われている(特許文献1および2)。香料カプセルの詳細については、たとえば特許文献3に記載されている。 Conventionally, a fragrance capsule is incorporated into a cigarette filter, the fragrance capsule is crushed with a finger during use, and the scent of the contents liquid is enjoyed during smoking, and the smell of the butt after being extinguished is masked ( Patent Documents 1 and 2). The details of the fragrance capsule are described in Patent Document 3, for example.
 香料カプセルは、フィルターを構成する濾材に直接埋め込まれたり、複数のフィルタープラグ間に形成された中空部に配置されたりする(図1Aおよび1B参照)。何れの場合も、香料カプセルは、フィルター内に位置するため、フィルターを包装する紙(巻取紙または成形紙)とチップペーパーの上から指で押して破砕する。 The perfume capsule is directly embedded in the filter medium constituting the filter, or is disposed in a hollow portion formed between a plurality of filter plugs (see FIGS. 1A and 1B). In any case, since the fragrance capsule is located in the filter, it is crushed by pressing with a finger on the paper (winding paper or molding paper) and chip paper on which the filter is packaged.
特開平7-250665号公報Japanese Patent Laid-Open No. 7-250665 特表2007-520204号公報Special table 2007-520204 特表2008-546400号公報Special table 2008-546400 gazette
 本発明者らは、フィルター内に含有されるカプセルの破砕しやすさを改善することに着目し、本発明は、フィルター内に含有されるカプセルの破砕しやすさを向上させたシガレットを提供することを目的とする。 The present inventors have focused on improving the ease of crushing of capsules contained in a filter, and the present invention provides a cigarette with improved ease of crushing of capsules contained in a filter. For the purpose.
 本発明者らは、特定の密度と特定の厚さを併せ持つ紙の上から指でカプセルを破砕すると、小さい力でカプセルを破砕することができ、かつ指にかかる圧力が局所に集中しにくく、より広い接触面に分散させることができることを見出し、本発明を完成させるに至った。 The present inventors, when crushing a capsule with a finger from a paper having both a specific density and a specific thickness, can crush the capsule with a small force, and the pressure on the finger is difficult to concentrate locally, The present inventors have found that it can be dispersed on a wider contact surface and have completed the present invention.
 本発明によれば、
 たばこ充填材および該たばこ充填材の周囲を巻装する巻紙を含むたばこロッドと、
 濾材を含むフィルタープラグと、前記フィルタープラグの周囲に巻かれたフィルター包装紙と、フィルター内に位置し、内容物を皮膜で被覆して保持するカプセルとを含むフィルターと、
 前記たばこロッドと前記フィルターとを接続するように該たばこロッドと該フィルター上に巻かれたチップペーパーと
を含み、
 前記フィルター包装紙および前記チップペーパーの少なくとも一方の紙が、0.5~1.0g/cm3の密度および100~250μmの厚さを有することを特徴とするシガレット
が提供される。
According to the present invention,
A tobacco rod including a tobacco filler and a wrapping paper wound around the tobacco filler;
A filter including a filter plug including a filter medium, a filter wrapping paper wound around the filter plug, and a capsule located in the filter and encapsulating and holding the contents with a film;
Including the tobacco rod and chip paper wound on the filter so as to connect the tobacco rod and the filter;
A cigarette is provided in which at least one of the filter wrapping paper and the chip paper has a density of 0.5 to 1.0 g / cm 3 and a thickness of 100 to 250 μm.
 本発明のシガレットによれば、小さい力かつ短い押込み距離で、カプセルを破砕することが可能である。また、本発明のシガレットは、カプセルを破砕する際に、指にかかる圧力をより広い接触面に分散させることが可能であるため、指にかかる負担が小さいという利点を有する。 According to the cigarette of the present invention, the capsule can be crushed with a small force and a short pushing distance. Moreover, since the cigarette of this invention can disperse | distribute the pressure concerning a finger to a wider contact surface when crushing a capsule, it has the advantage that the burden concerning a finger is small.
本発明の第1の態様に係るシガレットを示す断面図。Sectional drawing which shows the cigarette which concerns on the 1st aspect of this invention. 本発明の第2の態様に係るシガレットを示す断面図。Sectional drawing which shows the cigarette which concerns on the 2nd aspect of this invention. 本発明の第1の態様に係るシガレットを示す分解斜視図。The disassembled perspective view which shows the cigarette which concerns on the 1st aspect of this invention. レオメーターを用いた測定系を模式的に示す図。The figure which shows typically the measuring system using a rheometer. カプセルの押込み距離と荷重との関係を示すグラフ(例1)。The graph which shows the relationship between the indentation distance of a capsule, and a load (Example 1). 同じ荷重をかけたときの試験紙の様子を模式的に示す図(例1)。The figure (example 1) which shows typically the mode of the test paper when the same load is applied. 紙の厚さとカプセルへの力の伝わり易さとの関係を示すグラフ(例1)。The graph which shows the relationship between the thickness of paper and the ease of transmission of the force to a capsule (example 1). 試験紙に加えられた圧力分布を示す図(例2)。The figure which shows the pressure distribution added to the test paper (Example 2). 同じ荷重をかけたときの試験紙の様子を模式的に示す図(例2)。The figure which shows the mode of the test paper when the same load is applied (example 2). カプセル含有フィルターのサイズを示す図(例3)。The figure which shows the size of a capsule containing filter (Example 3). カプセル含有フィルターおよびカプセルに圧力をかける様子を示す図(例3)。The figure which shows a mode that a capsule containing filter and a capsule are pressurized (Example 3). カプセル含有フィルターおよびカプセルの押込み距離と荷重との関係を示すグラフ(例3)。The graph which shows the relationship between the indentation distance of a capsule containing filter and a capsule, and a load (Example 3). 例3および例4のカプセル含有フィルターの押込み距離と荷重との関係を示すグラフ。The graph which shows the relationship between the indentation distance of the capsule containing filter of Example 3 and Example 4, and a load.
 以下、本発明を説明するが、以下の説明は、本発明を詳説することを目的とし、本発明を限定することを意図しない。 Hereinafter, the present invention will be described, but the following description is intended to explain the present invention in detail and is not intended to limit the present invention.
 本発明のシガレットにおいて、カプセルは、複数のフィルタープラグ間に形成された中空部に配置されていてもよいし(第1の態様)、フィルターを構成する濾材に直接埋め込まれていてもよい(第2の態様)。 In the cigarette of the present invention, the capsule may be disposed in a hollow portion formed between a plurality of filter plugs (first aspect), or may be directly embedded in a filter medium constituting the filter (first). Second embodiment).
 本発明の第1の態様に係るシガレットは、図1Aに示されるとおり、
 たばこ充填材(11a)および該たばこ充填材の周囲を巻装する巻紙(11b)を含むたばこロッド(11)と、
 互いに離間し中空部を介して配置された2つのフィルタープラグ(12a)と、前記フィルタープラグ間に中空部を形成するように前記フィルタープラグの周囲に巻かれたフィルター包装紙(12b)と、前記中空部内に位置し、内容物を皮膜で被覆して保持するカプセル(12c)とを含むフィルター(12)と、
 前記たばこロッドと前記フィルターとを接続するように該たばこロッドと該フィルター上に巻かれたチップペーパー(13)と
を含み、
 前記フィルター包装紙および前記チップペーパーの少なくとも一方の紙が、0.5~1.0g/cm3の密度および100~250μmの厚さを有する。なお、図1Aにおいて、フィルタープラグ(12a)は、プラグ巻取紙(12d)により巻き取られているが、プラグ巻取紙(12d)は存在していてもよいし、存在していなくてもよい。図2は、本発明の第1の態様に係るシガレットを分解した状態を示す。図2は、2つのフィルタープラグ(12a)を互いに離間させて配置し、これらの周囲にフィルター包装紙(12b)およびチップペーパー(13)を巻き、これによりフィルタープラグ(12a)間に中空部が形成されること、およびかかる中空部内にカプセル(12c)が位置することを示す。
The cigarette according to the first aspect of the present invention is as shown in FIG.
A tobacco rod (11) including a tobacco filler (11a) and a wrapping paper (11b) wound around the tobacco filler;
Two filter plugs (12a) spaced apart from each other through a hollow portion, filter wrapping paper (12b) wound around the filter plug so as to form a hollow portion between the filter plugs, A filter (12) including a capsule (12c) located in the hollow portion and covering and holding the contents with a film;
Including the tobacco rod and chip paper (13) wound on the filter so as to connect the tobacco rod and the filter;
At least one of the filter wrapping paper and the chip paper has a density of 0.5 to 1.0 g / cm 3 and a thickness of 100 to 250 μm. In FIG. 1A, the filter plug (12a) is wound by the plug web (12d), but the plug web (12d) may or may not be present. FIG. 2 shows a state in which the cigarette according to the first aspect of the present invention is disassembled. In FIG. 2, two filter plugs (12a) are arranged apart from each other, and a filter wrapping paper (12b) and a chip paper (13) are wound around them, so that a hollow portion is formed between the filter plugs (12a). It shows that it is formed and the capsule (12c) is located in such a hollow part.
 本発明の第2の態様に係るシガレットは、図1Bに示されるとおり、
 たばこ充填材(11a)および該たばこ充填材の周囲を巻装する巻紙(11b)を含むたばこロッド(11)と、
 フィルタープラグ(12a)と、前記フィルタープラグの周囲に巻かれたフィルター包装紙(12b)と、前記フィルタープラグ内に埋め込まれて位置し、内容物を皮膜で被覆して保持するカプセル(12c)とを含むフィルター(12)と、
 前記たばこロッドと前記フィルターとを接続するように該たばこロッドと該フィルター上に巻かれたチップペーパー(13)と
を含み、
 前記フィルター包装紙および前記チップペーパーの少なくとも一方の紙が、0.5~1.0g/cm3の密度および100~250μmの厚さを有する。
The cigarette according to the second aspect of the present invention is as shown in FIG.
A tobacco rod (11) including a tobacco filler (11a) and a wrapping paper (11b) wound around the tobacco filler;
A filter plug (12a), a filter wrapping paper (12b) wound around the filter plug, and a capsule (12c) which is located embedded in the filter plug and which covers and holds the contents with a film. A filter (12) comprising:
Including the tobacco rod and chip paper (13) wound on the filter so as to connect the tobacco rod and the filter;
At least one of the filter wrapping paper and the chip paper has a density of 0.5 to 1.0 g / cm 3 and a thickness of 100 to 250 μm.
 以下の説明は、特に明示しない限り、上述の2つの態様についての説明である。 The following description is about the above two aspects unless otherwise specified.
 本発明において、フィルター包装紙およびチップペーパーの少なくとも一方の紙が、0.5~1.0g/cm3の密度および100~250μmの厚さを有していれば、かかる紙の特性により、カプセルの破砕しやすさを向上させることができる。 In the present invention, if at least one of the filter wrapping paper and the chip paper has a density of 0.5 to 1.0 g / cm 3 and a thickness of 100 to 250 μm, the properties of the paper cause the capsules. The ease of crushing can be improved.
 0.5~1.0g/cm3の密度および100~250μmの厚さを有する紙は、フィルター包装紙やチップペーパーに一般に使用される紙と比較して、密度および厚さが大きく、かかる密度と厚さにより高いカプセル破砕性能を有する。したがって、本発明で使用される特徴的な紙、すなわち0.5~1.0g/cm3の密度および100~250μmの厚さを有する紙を「本発明の高性能紙」ともいう。 Paper having a density of 0.5 to 1.0 g / cm 3 and a thickness of 100 to 250 μm has a higher density and thickness compared to the paper generally used for filter wrapping paper and chip paper. High capsule crushing performance due to thickness. Therefore, the characteristic paper used in the present invention, that is, paper having a density of 0.5 to 1.0 g / cm 3 and a thickness of 100 to 250 μm is also referred to as “the high performance paper of the present invention”.
 本明細書において、紙の密度は、シガレット作成の原料となる紙の坪量および厚さを、それぞれJIS P 8124およびJIS P 8118に規定される方法により測定し、得られた値を下記式に当てはめることにより求めた値を指す:式:密度(g/cm3)=坪量(g/m2)/厚さ(mm)×1000。また、本明細書において、紙の厚みは、JIS P 8118に規定される方法により測定した値を指す。 In this specification, the density of paper is measured by the methods specified in JIS P 8124 and JIS P 8118, respectively. It refers to the value determined by fitting: Formula: Density (g / cm 3 ) = Basis weight (g / m 2 ) / Thickness (mm) × 1000. Moreover, in this specification, the thickness of paper refers to the value measured by the method prescribed | regulated to JISP8118.
 本発明では、フィルター包装紙として本発明の高性能紙を使用した場合、チップペーパーは、同様の高性能紙を使用してもよいし、一般にチップペーパーとして使用される通常の密度と厚みを有する紙を使用してもよい。同様に、チップペーパーとして本発明の高性能紙を使用した場合、フィルター包装紙は、同様の高性能紙を使用してもよいし、一般にフィルター包装紙として使用される通常の密度と厚みを有する紙を使用してもよい。 In the present invention, when the high performance paper of the present invention is used as the filter wrapping paper, the same high performance paper may be used as the chip paper, and it has a normal density and thickness generally used as chip paper. Paper may be used. Similarly, when the high-performance paper of the present invention is used as the chip paper, the filter wrapping paper may use the same high-performance paper, and has a normal density and thickness generally used as filter wrapping paper. Paper may be used.
 本発明において、フィルター包装紙およびチップペーパーの少なくとも一方の紙が、0.5~1.0g/cm3の密度および100~250μmの厚さを有し、好ましくは、0.7~1.0g/cm3の密度および180~250μmの厚さを有し、より好ましくは、0.8~1.0g/cm3の密度および240~250μmの厚さを有する。 In the present invention, at least one of filter wrapping paper and chip paper has a density of 0.5 to 1.0 g / cm 3 and a thickness of 100 to 250 μm, preferably 0.7 to 1.0 g. Having a density of / cm 3 and a thickness of 180 to 250 μm, more preferably a density of 0.8 to 1.0 g / cm 3 and a thickness of 240 to 250 μm.
 厚みが大きい紙、たとえば240~250μmの厚さを有する紙を使用する場合、シガレット製造の巻き工程を行いやすくするため、紙に罫線加工を行うことが好ましい。罫線加工された紙は、罫線がシガレットの長手方向に平行になるように配置される。また、罫線加工された紙は、罫線加工された面がシガレットにおいて内側を向くように配置されることが好ましい。罫線加工は、罫線機により、一定間隔で、紙の表面に罫線(折れ線)を入れることにより行うことができる。罫線加工は、紙の厚みの60~90%の深さで、2mm以下の間隔で行うことが好ましい。 When using thick paper, for example, paper having a thickness of 240 to 250 μm, it is preferable to perform ruled line processing on the paper in order to facilitate the winding process of cigarette manufacture. The ruled paper is arranged so that the ruled line is parallel to the longitudinal direction of the cigarette. Further, the ruled paper is preferably arranged so that the ruled surface faces inward in the cigarette. The ruled line processing can be performed by putting ruled lines (folded lines) on the surface of the paper at regular intervals by a ruled line machine. The ruled line processing is preferably performed at a depth of 60 to 90% of the paper thickness and at intervals of 2 mm or less.
 紙の厚さが100~250μmの範囲内であったとしても、密度が0.5g/cm3より小さいと、カプセルの破砕時に、紙が変形して折れやすく、指にかかる圧力が局所に集中するため、カプセルを破砕しにくくなる。また、密度が1.0g/cm3より大きいと、紙の製造コストが高くなるため好ましくない。紙の密度は、カプセル内容物の漏出(たとえばカプセル内容液の染み出し)を防止するためには、0.5~1.0g/cm3の範囲内において大きいことが望ましい。 Even if the thickness of the paper is in the range of 100 to 250 μm, if the density is less than 0.5 g / cm 3 , the paper tends to deform and break when the capsule is crushed, and the pressure on the finger is concentrated locally. Therefore, it becomes difficult to crush the capsule. On the other hand, if the density is greater than 1.0 g / cm 3 , the paper production cost increases, which is not preferable. The density of the paper is desirably large in the range of 0.5 to 1.0 g / cm 3 in order to prevent leakage of the capsule contents (for example, leakage of the capsule contents liquid).
 紙の密度が0.5~1.0g/cm3の範囲内であったとしても、厚さが100μmより小さいと、カプセルの破砕時に、紙が変形して折れやすく、指にかかる圧力が局所に集中するため、カプセルを破砕しにくくなる。また、厚さが250μmより大きいと、シガレット製造の巻き工程を行うことが難しくなるとともに、カプセルを割った感触を得にくくなる。 Even if the density of the paper is within the range of 0.5 to 1.0 g / cm 3 , if the thickness is smaller than 100 μm, the paper is easily deformed and broken when the capsule is crushed, and the pressure on the finger is locally Because it concentrates on the capsule, it becomes difficult to crush the capsule. On the other hand, when the thickness is larger than 250 μm, it is difficult to perform a winding process for manufacturing cigarettes, and it becomes difficult to obtain a feeling of breaking the capsule.
 第1の態様におけるフィルター包装紙(図1Aの12b)は、成形紙とも呼ばれ、成形紙に本発明の高性能紙を採用した場合、一般に、坪量は50~250g/m、通気度は0~30000CUとすることができる。第1の態様では、カプセルがフィルターの中空部に位置するため、カプセル内の液体がシガレット外部に染み出すことを防止する目的で、フィルター包装紙の通気度を0とすることが特に好ましい。第2の態様におけるフィルター包装紙(図1Bの12b)は、巻取紙とも呼ばれ、同様に、巻取紙に本発明の高性能紙を採用した場合、坪量は50~250g/m、通気度は0~30000CUとすることができる。第2の態様においても、上記と同じ目的のために、フィルター包装紙の通気度を0とすることができる。成形紙や巻取紙に本発明の高性能紙を採用した場合、チップペーパーは、一般にチップペーパーとして使用される通常の密度と厚みを有する紙とすることができ、たとえば、坪量は20~60g/m、厚みは20~60μmとすることができる。 The filter wrapping paper (12b in FIG. 1A) in the first embodiment is also called a molded paper. When the high-performance paper of the present invention is adopted as the molded paper, the basis weight is generally 50 to 250 g / m 2 , and the air permeability Can be between 0 and 30000 CU. In the first aspect, since the capsule is located in the hollow portion of the filter, it is particularly preferable to set the air permeability of the filter wrapping paper to 0 for the purpose of preventing the liquid in the capsule from oozing out of the cigarette. The filter wrapping paper (12b in FIG. 1B) in the second embodiment is also called a web, and similarly, when the high-performance paper of the present invention is adopted for the web, the basis weight is 50 to 250 g / m 2 and the air permeability is It can be 0 to 30000 CU. Also in the second embodiment, the air permeability of the filter wrapping paper can be set to 0 for the same purpose as described above. When the high-performance paper of the present invention is used as a forming paper or a web, the chip paper can be a paper having a normal density and thickness generally used as a chip paper. For example, the basis weight is 20 to 60 g / m 2 and thickness can be 20 to 60 μm.
 本発明の態様において、カプセルは、上述のとおり、フィルタープラグ間の中空部に収容されているか、あるいはフィルタープラグ内に埋め込まれている。カプセルは、フィルター内に1個存在していてもよいし、複数個(たとえば2~10個)存在していてもよい。カプセルが中空部に収容されている場合、中空部1つあたり1個のカプセルが収容されていてもよいし、複数個(たとえば2~10個)のカプセルが収容されていてもよい。 In the embodiment of the present invention, as described above, the capsule is accommodated in the hollow portion between the filter plugs or embedded in the filter plug. One capsule may be present in the filter, or a plurality (for example, 2 to 10) of capsules may be present. When the capsule is accommodated in the hollow part, one capsule may be accommodated per one hollow part, or a plurality of (for example, 2 to 10) capsules may be accommodated.
 カプセルは、皮膜と内容物とから構成される。 Capsule is composed of film and contents.
 皮膜には、たとえばデンプン、デキストリン、多糖類、寒天、ジェランガム、ゼラチン、各種天然ゲル化剤、グリセリン、ソルビトール、塩化カルシウムなどを用いることができ、さらに香料や着色料を含むことができる。カプセルは、不透明度を有するフィルター包装紙やチップペーパーに囲まれていてもカプセルをつぶす際に喫煙者が認識できるように着色されていることが好ましく、皮膜に着色料、たとえば青色1号等を含むことが好ましい。 For the film, for example, starch, dextrin, polysaccharides, agar, gellan gum, gelatin, various natural gelling agents, glycerin, sorbitol, calcium chloride, and the like can be used, and flavors and coloring agents can be further included. The capsule is preferably colored so that a smoker can recognize it when crushing the capsule even if it is surrounded by filter wrapping paper or chip paper having opacity, and a colorant such as Blue No. 1 is applied to the film. It is preferable to include.
 カプセルの内容物としては、任意の物質を用いることができ、その形状は、固体、液体、気体など任意の形状であり得る。たとえば、内容物として、固体の吸着剤、たとえば活性炭、または固体の香料を用いることができる。あるいは、内容物として、任意の液体を用いることができ、たとえば、香料を含有する液体を用いることができる。具体的には、メンソール、植物精油などの喫煙物品に用いられる任意の香料を含有する液体を用いることができる。かかる香料含有カプセルをフィルターに含むシガレットは、喫煙時に香料含有カプセルを破砕して香りを楽しむことができる。あるいは、内容物として、水を用いることができる。かかる水含有カプセルをフィルターに含むシガレットは、喫煙時に水カプセルを破砕して水たばこのように煙を水に通過させて喫煙することができる。あるいは、内容物として、気体の香料を用いることもできる。 As the contents of the capsule, any substance can be used, and the shape thereof can be any shape such as solid, liquid, and gas. For example, a solid adsorbent such as activated carbon or a solid fragrance can be used as the contents. Alternatively, any liquid can be used as the contents, for example, a liquid containing a fragrance can be used. Specifically, a liquid containing any fragrance used in smoking articles such as menthol and plant essential oil can be used. A cigarette containing such a fragrance-containing capsule in a filter can enjoy the fragrance by crushing the fragrance-containing capsule during smoking. Alternatively, water can be used as the contents. A cigarette including such a water-containing capsule in a filter can be smoked by pulverizing the water capsule during smoking and passing smoke through the water like a cigarette. Alternatively, a gas fragrance can be used as the contents.
 内容物で使用される主な香料としては、メンソール、葉たばこ抽出エキス、天然植物性香料(例えば、シナモン、セージ、ハーブ、カモミール、葛草、甘茶、クローブ、ラベンダー、カルダモン、チョウジ、ナツメグ、ベルガモット、ゼラニウム、蜂蜜エッセンス、ローズ油、レモン、オレンジ、ケイ皮、キャラウェー、ジャスミン、ジンジャー、コリアンダー、バニラエキス、スペアミント、ペパーミント、カシア、コーヒー、セロリー、カスカリラ、サンダルウッド、ココア、イランイラン、フェンネル、アニス、リコリス、セントジョンズブレッド、スモモエキス、ピーチエキス等)、糖類(例えば、グルコース、フルクトース、異性化糖、カラメル等)、ココア類(パウダー、エキス等)、エステル類(例えば、酢酸イソアミル、酢酸リナリル、プロピオン酸イソアミル、酪酸リナリル等)、ケトン類(例えば、メントン、イオノン、ダマセノン、エチルマルトール等)、アルコール類(例えば、ゲラニオール、リナロール、アネトール、オイゲノール等)、アルデヒド類(例えば、バニリン、ベンズアルデヒド、アニスアルデヒド等)、ラクトン類(例えば、γ-ウンデカラクトン、γ-ノナラクトン等)、動物性香料(例えば、ムスク、アンバーグリス、シベット、カストリウム等)、炭化水素類(例えば、リモネン、ピネン等)が挙げられる。これら香料は、単独で用いてもよいし、混合して用いてもよい。 The main flavors used in the contents include menthol, leaf tobacco extract, natural plant flavors (for example, cinnamon, sage, herbs, chamomile, kuzuka, sweet tea, clove, lavender, cardamom, clove, nutmeg, bergamot, Geranium, honey essence, rose oil, lemon, orange, cinnamon, caraway, jasmine, ginger, coriander, vanilla extract, spearmint, peppermint, cassia, coffee, celery, cascarilla, sandalwood, cocoa, ylang ylang, fennel, anise , Licorice, St. John's bread, plum extract, peach extract, etc.), saccharides (eg, glucose, fructose, isomerized sugar, caramel, etc.), cocoa (powder, extract, etc.), esters (eg, isoamyl acetate, Linalyl acid, isoamyl propionate, linalyl butyrate, etc.), ketones (eg, menthone, ionone, damacenone, ethylmaltol, etc.), alcohols (eg, geraniol, linalool, anethole, eugenol, etc.), aldehydes (eg, vanillin, Benzaldehyde, anisaldehyde, etc.), lactones (eg, γ-undecalactone, γ-nonalactone, etc.), animal perfumes (eg, musk, ambergris, civet, castrium, etc.), hydrocarbons (eg, limonene, pinene) Etc.). These fragrances may be used alone or in combination.
 内容物が、香料を含有する液体である場合、溶媒としては、香料に適した溶媒を用いることができ、中鎖脂肪酸トリグリセリド(MCT)(具体的には、トリカプリル/カプリン酸グリセリン)、プロピレングリコール、水、エタノールなどを用いることができる。香料を含有する液体は、さらに他の溶媒、色素、乳化剤、増粘剤などの他の添加剤を含有していてもよい。 When the content is a liquid containing a fragrance, a solvent suitable for the fragrance can be used as the solvent, and medium chain fatty acid triglyceride (MCT) (specifically, tricapryl / glyceryl caprate), propylene glycol Water, ethanol, etc. can be used. The liquid containing a fragrance may further contain other additives such as other solvents, pigments, emulsifiers and thickeners.
 カプセルの製造方法は特に限定されないが、たとえば滴下法を用いればシームレスな皮膜を有するカプセルを製造することができる。この方法では、二重ノズルを用い、内側ノズルから内容物を、外側ノズルから液状の皮膜物質を同時に吐出させることにより、皮膜液が、継ぎ目を有することなく内容物を包み込むことができる。 The method for producing the capsule is not particularly limited. For example, if a dropping method is used, a capsule having a seamless film can be produced. In this method, by using a double nozzle and simultaneously discharging the contents from the inner nozzle and the liquid film substance from the outer nozzle, the film liquid can wrap the contents without having a seam.
 カプセルは、たとえば、球体または円筒体の形状を有することができ、ここで球体は、断面がほぼ円である球体および断面が楕円である楕円体の何れも含む。カプセルは、好ましくは、断面がほぼ円である球体の形状を有する。カプセルは、断面がほぼ円である球体の場合、たとえば直径1.0~8.0mmとすることができ、楕円体の場合、たとえば最大直径1.0~7.0mm、最小直径1.0~7.0mmとすることができ、円筒体の場合、円の直径1.0~7.0mm、高さ1.0~7.0mmとすることができる。後述の例3より、カプセルのサイズが、小さすぎると、カプセル破砕時の押込み距離が長くなるため、球体の場合、直径が3.0mm以上であることがより好ましく、楕円体の場合、最小直径が3.0mm以上であることがより好ましく、円筒体の場合、円の直径が3.0mm以上であることがより好ましい。 The capsule can have, for example, a spherical or cylindrical shape, where the sphere includes both a sphere having a substantially circular cross section and an ellipsoid having a elliptical cross section. The capsule preferably has a spherical shape with a substantially circular cross section. In the case of a sphere having a substantially circular cross section, the capsule can have a diameter of 1.0 to 8.0 mm, for example, and in the case of an ellipsoid, the capsule has a maximum diameter of 1.0 to 7.0 mm and a minimum diameter of 1.0 to In the case of a cylindrical body, the diameter of the circle may be 1.0 to 7.0 mm and the height may be 1.0 to 7.0 mm. From Example 3 to be described later, if the capsule size is too small, the pushing distance at the time of capsule crushing becomes longer. Therefore, in the case of a sphere, the diameter is more preferably 3.0 mm or more, and in the case of an ellipsoid, the minimum diameter is Is more preferably 3.0 mm or more, and in the case of a cylindrical body, the diameter of the circle is more preferably 3.0 mm or more.
 また、カプセルは、それ自体、約10~35[N]の強度で破壊され得るものが好ましい。本発明の高性能紙を使用すると、比較的硬いカプセル、たとえば約25[N]より高く、約30[N]以下の強度で破壊され得るカプセルなども、小さい力かつ短い押込み距離で破砕することが可能である。より硬いカプセルは、カプセル入りシガレットが高温に晒された際や搬送される時に割れにくいという利点を有する。 Further, it is preferable that the capsule itself can be broken at a strength of about 10 to 35 [N]. When the high-performance paper of the present invention is used, relatively hard capsules such as capsules that can be broken at a strength higher than about 25 [N] and lower than about 30 [N] can be crushed with a small force and a short indentation distance. Is possible. Harder capsules have the advantage that the encapsulated cigarettes are less likely to break when exposed to high temperatures or when transported.
 後述の実施例で実証されるとおり、約30[N]の強度で破壊され得るカプセルを、直接指で破砕した場合や現行の成形紙(50NFB)の上から破砕した場合、局所的な指圧を感じるが、本発明の高性能紙の上から破砕した場合、局所的な指圧を感じることなく、カプセルを容易に破砕することが可能である。 As demonstrated in the examples described later, when a capsule that can be broken at a strength of about 30 [N] is crushed directly with a finger or is crushed from the top of an existing paper (50NFB), local acupressure is applied. Although it feels, when it crushes from on the high performance paper of this invention, it is possible to crush a capsule easily, without feeling local finger pressure.
 本発明の態様において、フィルタープラグは、通常のフィルター付シガレットと同様、アセテートトウの濾材により構成され得る。フィルタープラグは、濾材のみから構成されていてもよいし、濾材とその周囲に巻かれたプラグ巻取紙とから構成されていてもよい。フィルターが複数のフィルタープラグを含む場合、刻側のフィルタープラグと吸口側のフィルタープラグは、同じ素材および構造を有していてもよいし、異なる素材および構造を有していてもよい。 In the embodiment of the present invention, the filter plug can be composed of a filter medium of acetate tow, like a normal cigarette with a filter. The filter plug may be composed only of the filter medium, or may be composed of the filter medium and a plug web wound around the filter medium. When the filter includes a plurality of filter plugs, the cut-side filter plug and the suction-side filter plug may have the same material and structure, or may have different materials and structures.
 アセテートトウは、たとえば、単糸繊度1.9~8.6(g/9000m)、総繊度17000~44000(g/9000m)、繊維本数2400~23500(本)、通気抵抗100~600(mmH2O/120mm)とすることができる。アセテートトウに、トリアセチン等の可塑剤を添加してもよく、可塑剤は、アセテートトウの重量に対して6~10重量%の量で添加することができ、アセテートトウに活性炭を添加した場合、可塑剤は、アセテートトウの重量に対して2~20重量%の量で添加することができる。 Acetate tow has, for example, a single yarn fineness of 1.9 to 8.6 (g / 9000m), a total fineness of 17000 to 44000 (g / 9000m), a number of fibers of 2400 to 23500 (piece), and a ventilation resistance of 100 to 600 (mmH2O / 120mm). A plasticizer such as triacetin may be added to acetate tow, and the plasticizer can be added in an amount of 6 to 10% by weight based on the weight of acetate tow. When activated carbon is added to acetate tow, The plasticizer can be added in an amount of 2 to 20% by weight based on the weight of acetate tow.
 後述の例4より、濾材が硬すぎると、カプセル含有フィルターを指でつぶした際のフィルタープラグによる反発力が大きくなるため、単糸繊度は3.0(g/9000m)以上であることがより好ましく、総繊度は35000(g/9000m)以下であることがより好ましい。 From Example 4 to be described later, if the filter medium is too hard, the repulsive force by the filter plug when the capsule-containing filter is crushed with a finger increases, so the single yarn fineness is more than 3.0 (g / 9000m). The total fineness is preferably 35000 (g / 9000 m) or less.
 フィルターは、たとえば、約14~26mmの円周を有し、長さは、通常のフィルターと同様、例えば17~31mmであり得る。第一の態様のフィルターにおいて、中空部の長さは、カプセルのサイズ以上であればよく、たとえば3~7mmであり、各フィルタープラグの長さは、5~20mmであり得る。 The filter has a circumference of, for example, about 14 to 26 mm, and the length can be, for example, 17 to 31 mm, similar to a normal filter. In the filter of the first aspect, the length of the hollow portion may be not less than the size of the capsule, for example, 3 to 7 mm, and the length of each filter plug may be 5 to 20 mm.
 図1Aのシガレットでは、2つのフィルタープラグが1つの中空部を介して配置されているが、n個(nは2以上の整数)のフィルタープラグが(n-1)個の中空部を介して配置されていてもよく、たとえばnは2~4であり、好ましくはnは2~3であり、より好ましくはnは2である。 In the cigarette of FIG. 1A, two filter plugs are arranged through one hollow portion, but n (n is an integer of 2 or more) filter plugs are arranged through (n−1) hollow portions. For example, n is 2 to 4, preferably n is 2 to 3, and more preferably n is 2.
 図1Bのシガレットでは、フィルターは、単一のフィルタープラグから構成されているが、公知技術に従って、複数のフィルタープラグ、たとえば2~4個、好ましくは2~3個、より好ましくは2個のフィルタープラグが連結されていてもよい。複数のフィルタープラグが連結されている場合、すべてのフィルタープラグにカプセルが埋め込まれていてもよいし、一部のフィルタープラグにカプセルが埋め込まれていてもよい。 In the cigarette of FIG. 1B, the filter is composed of a single filter plug, but according to the known art, a plurality of filter plugs, eg 2-4, preferably 2-3, more preferably 2 filters. Plugs may be connected. When a plurality of filter plugs are connected, capsules may be embedded in all filter plugs, or capsules may be embedded in some filter plugs.
 本発明の態様において、たばこロッドは、通常のシガレットと同様、たばこ充填材とその周囲を巻装するたばこ巻紙からなり、例えば、約14~26mmの円周および53~67mmの長さを有することができる。 In the embodiment of the present invention, the cigarette rod is composed of a cigarette filler and cigarette paper wound around the cigarette filler, like a normal cigarette, and has, for example, a circumference of about 14 to 26 mm and a length of 53 to 67 mm. Can do.
 例1:カプセルを破砕する際の押込み距離に対する紙の厚さおよび密度の効果
 本例では、以下の6タイプの試験紙を使用した(かっこ書きは各試験紙の入手先)。各試験紙の特性を下記表1に示す。各試験紙は、2cm四方の大きさで実験に使用した。
Example 1: Effect of paper thickness and density on indentation distance when crushing capsules In this example, the following six types of test papers were used (the parentheses are the source of each test paper). The characteristics of each test paper are shown in Table 1 below. Each test paper was 2 cm square and used for the experiment.
(1)50NFB(日本製紙パピリア株式会社)
(2)HS(新巴川製紙株式会社)
(3)AT(新巴川製紙株式会社)
(4)HS120(新巴川製紙株式会社)
(5)S80(日本製紙パピリア株式会社)
(6)抵抗紙(日本製紙パピリア株式会社)
Figure JPOXMLDOC01-appb-T000001
(1) 50NFB (Nippon Paper Papillia Co., Ltd.)
(2) HS (Shinyodogawa Paper Co., Ltd.)
(3) AT (Shinyodogawa Paper Co., Ltd.)
(4) HS120 (Shinyodogawa Paper Co., Ltd.)
(5) S80 (Nippon Paper Papillia Co., Ltd.)
(6) Resistance paper (Nippon Paper Papillia Co., Ltd.)
Figure JPOXMLDOC01-appb-T000001
 試験紙50NFBは、カプセル含有シガレットで現在使用されている成形紙である。表1において、「破壊強度」は、カプセルが破壊されたときにカプセルに加えられた荷重[N]を表し、「移動距離」は、カプセルが破壊されたときの押込み距離[mm]を表す。 Test paper 50NFB is a molded paper currently used in capsule-containing cigarettes. In Table 1, “breaking strength” represents the load [N] applied to the capsule when the capsule is broken, and “movement distance” represents the pushing distance [mm] when the capsule is broken.
 カプセルは、皮膜物質(15重量%)と内容液(85重量%)を混合し、滴下法により調製した。カプセルを構成する皮膜物質および内容液の主要成分は、それぞれ下記のとおりとした。 
(i)皮膜物質
 ゼラチン、ジェランガム、デンプン、グリセリン、およびソルビトール
(ii)内容液
 中鎖脂肪酸トリグリセリド(トリカプリル/カプリン酸グリセリン)(83重量%)
 調製されたカプセルは、直径約4.5mmの球体であった。また、カプセルの硬さは、約30Nであった。なお、本実施例では、カプセルの内容液は溶媒のみから構成され、香料を含有しないが、香料の有無が、カプセルの破砕し易さに影響を及ぼさないことは実証されている。
The capsule was prepared by mixing the film substance (15% by weight) and the content liquid (85% by weight), and dropping. The main components of the coating substance and the content liquid constituting the capsule were as follows.
(I) Coating material Gelatin, gellan gum, starch, glycerin, and sorbitol (ii) Contents liquid Medium chain fatty acid triglyceride (tricapryl / glycol caprate) (83 wt%)
The prepared capsule was a sphere having a diameter of about 4.5 mm. Moreover, the hardness of the capsule was about 30N. In this example, the content liquid of the capsule is composed only of a solvent and does not contain a fragrance, but it has been demonstrated that the presence or absence of the fragrance does not affect the ease of crushing the capsule.
 図3Aに示す測定系を用いて、カプセルを破砕する際の押込み距離と荷重との関係を調べた。すなわち、弾性ゴム上に置かれた試験紙の上に、カプセルを置き、上方からレオメーターの感圧軸により圧力をかけてカプセルを破砕した。カプセルの破砕は、湿度60%、温度22度の条件下で行った。そのときの押込み距離(mm)(移動距離ともいう)と荷重(N)を測定した。測定は、Sun RHEO METER CR3000EX(株式会社サン科学)を用いて行った。 Using the measurement system shown in FIG. 3A, the relationship between the indentation distance and the load when the capsule was crushed was examined. That is, a capsule was placed on a test paper placed on an elastic rubber, and the capsule was crushed by applying pressure from above with a pressure sensitive shaft of a rheometer. The capsules were crushed under the conditions of 60% humidity and a temperature of 22 degrees. The indentation distance (mm) (also referred to as the movement distance) and the load (N) at that time were measured. The measurement was performed using a Sun RHEO METER CR3000EX (Sun Science Co., Ltd.).
 測定結果を図3Bに示す。図3Bにおいて、(1)は50NFB、(2)はHS、(3)はAT、(4)はHS120、(5)はS80、(6)は抵抗紙を表す。 The measurement results are shown in FIG. 3B. 3B, (1) is 50NFB, (2) is HS, (3) is AT, (4) is HS120, (5) is S80, and (6) is resistance paper.
 図3Bの結果から、HS、AT、HS120およびS80は、試験紙50NFBと比べて、同じ荷重に到達するのに必要な押込み距離(移動距離)が小さいことがわかる。一方、抵抗紙は、50NFBと比べて、同じ荷重に到達するのに必要な押込み距離(移動距離)が大きい。この様子、すなわち50NFB、抵抗紙、S80に同じ荷重をかけたときの様子を模式的に図3Cに示す。図3Cにおいて、試験紙から伸びる矢印は、カプセルを指で破砕した際に指にかかるであろう圧力の様子を模式的に表す。図3Cは、所定の密度と厚さを有する紙、たとえばS80などを使用すると、より小さい押込み距離でカプセルに同じ荷重を与えることができ、かつ荷重をかけた際に紙が折れにくいため、カプセルを破砕する際の圧力を、より広い接触面に分散させることができることを示す。一方、図3Cは、密度が小さい紙(抵抗紙)や厚さが小さい紙(50NFB)を使用すると、所定の荷重を与えるのに必要な押込み距離が大きく、かつ荷重をかけた際に紙が折れやすいため、カプセルを破砕する際の圧力が一点に集中しやすいことを示す。 3B shows that HS, AT, HS120, and S80 have a smaller pushing distance (movement distance) required to reach the same load than test paper 50NFB. On the other hand, the resistance paper has a larger pressing distance (movement distance) necessary to reach the same load than 50 NFB. FIG. 3C schematically shows this state, that is, the state when the same load is applied to 50 NFB, resistance paper, and S80. In FIG. 3C, the arrow extending from the test paper schematically represents the state of pressure that will be applied to the finger when the capsule is crushed with the finger. FIG. 3C shows that when a paper having a predetermined density and thickness, such as S80, is used, the same load can be applied to the capsule with a smaller pressing distance, and the paper is not easily broken when the load is applied. It shows that the pressure at the time of crushing can be disperse | distributed to a wider contact surface. On the other hand, FIG. 3C shows that when a low density paper (resistance paper) or a low thickness paper (50NFB) is used, the pressing distance required to give a predetermined load is large, and the paper is not loaded when a load is applied. Because it is easy to break, it shows that the pressure when crushing the capsule tends to concentrate on one point.
 これら結果を基に、紙の厚さとカプセルへの力の伝わり易さとの関係を図3Dに示す。図3Dにおいて、横軸は、紙の厚さ[μm]を示し、縦軸は、破壊強度[N]/移動距離[mm]を示す。ここで「破壊強度」は、カプセルが破壊されたときにカプセルに加えられた荷重[N]を意味し、「移動距離」は、カプセルが破壊されたときの押込み距離[mm]を意味する。破壊強度[N]/移動距離[mm]が大きいことは、小さい押込み距離でカプセルに大きい荷重を与えることができること、すなわち小さい押込み距離でカプセルに力を伝え易いことを意味する。図3Dにおいて、(1)は50NFB、(2)はHS、(3)はAT、(4)はHS120、(5)はS80、(6)は抵抗紙を表す。なお、図3Dのグラフは、各試験紙につき、20個のサンプルを準備して押込み距離(mm)と荷重(N)を測定し、得られたデータの平均値をプロットしたものであり、上述の図3Bのグラフは、20個のサンプルで得られたデータのうち、典型的な一例を選んで示したものである。 Based on these results, the relationship between the thickness of the paper and the ease of transmission of force to the capsule is shown in FIG. 3D. In FIG. 3D, the horizontal axis indicates the paper thickness [μm], and the vertical axis indicates the breaking strength [N] / movement distance [mm]. Here, “breaking strength” means a load [N] applied to the capsule when the capsule is broken, and “movement distance” means a pushing distance [mm] when the capsule is broken. A large breaking strength [N] / moving distance [mm] means that a large load can be applied to the capsule with a small pushing distance, that is, a force can be easily transmitted to the capsule with a small pushing distance. In FIG. 3D, (1) represents 50NFB, (2) represents HS, (3) represents AT, (4) represents HS120, (5) represents S80, and (6) represents resistance paper. In addition, the graph of FIG. 3D prepares 20 samples for each test paper, measures the indentation distance (mm) and the load (N), and plots the average value of the obtained data. The graph of FIG. 3B shows a typical example selected from the data obtained from 20 samples.
 図3Dより、0.5~1.0g/cm3の密度を有する紙、すなわち50NFB、HS、AT、HS120、S80の場合、紙の厚さが増すにつれ、破壊強度[N]/移動距離[mm]の値は増大し、小さい押込み距離でカプセルに力を伝え易くなる。ただし、紙の厚さが約250μmになると、破壊強度[N]/移動距離[mm]は頭打ちになっている。一方、430μmの厚さを有するが0.27g/cm3の密度を有する抵抗紙は、破壊強度[N]/移動距離[mm]の値は小さく、カプセルに力を伝えにくい。 From FIG. 3D, in the case of paper having a density of 0.5 to 1.0 g / cm 3 , that is, 50NFB, HS, AT, HS120, and S80, as the paper thickness increases, the breaking strength [N] / movement distance [ The value of [mm] increases, and it becomes easier to transmit the force to the capsule with a small pushing distance. However, when the paper thickness is about 250 μm, the breaking strength [N] / movement distance [mm] reaches a peak. On the other hand, a resistance paper having a thickness of 430 μm but a density of 0.27 g / cm 3 has a small value of breaking strength [N] / movement distance [mm] and is difficult to transmit force to the capsule.
 以上の結果より、0.5~1.0g/cm3の密度を有し、かつ100μm以上の厚さを有する紙を使用すると、より小さい押込み距離で、カプセルを破砕するのに必要な荷重を与えられることがわかる。実際に、0.5~1.0g/cm3の密度を有し、かつ100μm以上の厚さを有する紙を使用した場合、指にかかる圧力が小さい上に、小さい力でカプセルを破砕しやすいという感触を得た。一方、0.5g/cm3未満の密度を有する紙や、100μm未満の厚さを有する紙を使用すると、カプセルを破砕するのに必要な荷重を与えるためには大きな押込み距離が必要であることがわかる。実際に、0.5g/cm3未満の密度を有する紙や、100μm未満の厚さを有する紙を使用した場合、指にかかる圧力が大きい上に、紙が変形したり折れやすかったりして、カプセルを破砕しにくいという感触を得た。 From the above results, when a paper having a density of 0.5 to 1.0 g / cm 3 and a thickness of 100 μm or more is used, the load necessary for crushing the capsule with a smaller pushing distance is obtained. You can see that it is given. Actually, when a paper having a density of 0.5 to 1.0 g / cm 3 and a thickness of 100 μm or more is used, the pressure on the finger is small and the capsule is easily crushed with a small force. I got a feel. On the other hand, when paper having a density of less than 0.5 g / cm 3 or paper having a thickness of less than 100 μm is used, a large indentation distance is required to give a load necessary for crushing the capsule. I understand. Actually, when a paper having a density of less than 0.5 g / cm 3 or a paper having a thickness of less than 100 μm is used, the pressure applied to the finger is large and the paper is easily deformed or broken. The feeling that the capsule was difficult to break was obtained.
 なお、本例では、同様に調製したカプセルを各試験紙に適用したため、荷重の最大到達点(カプセルを破砕するのに必要な荷重)は、いずれの試験紙の場合も同じになるはずである。したがって、図3Bで観察される荷重の最大到達点の違いは、カプセルの硬さの微差によるものであると考えられる。 In addition, in this example, since the capsule prepared similarly was applied to each test paper, the maximum point of load (the load necessary for crushing the capsule) should be the same for any test paper. . Therefore, the difference in the maximum load point observed in FIG. 3B is considered to be due to a slight difference in the hardness of the capsule.
 例2.カプセルを破砕する際の圧力分布に対する紙の厚さの効果
 例1と同様の手法に従って、弾性ゴム上に置かれた各試験紙の上に、カプセルを置き、上方からレオメーターの感圧軸により圧力をかけてカプセルを破砕した。カプセルの破砕は、湿度60%、温度22度の条件下で行った。カプセルが崩壊した時点において、試験紙に加えれらた圧力分布を測定した。圧力分布の測定は、図3Aに示す測定系およびイナストマー(株式会社イナバゴム)を用いて行った。試験紙として、例1で使用した50NFBおよびS80を使用した。
Example 2. Effect of paper thickness on pressure distribution when crushing capsules Capsule is placed on each test paper placed on elastic rubber according to the same method as in Example 1, and from above the pressure sensitive axis of rheometer The capsule was crushed under pressure. The capsules were crushed under the conditions of 60% humidity and a temperature of 22 degrees. When the capsule collapsed, the pressure distribution applied to the test paper was measured. The pressure distribution was measured using the measurement system and Inastomer (Inaba Rubber Co., Ltd.) shown in FIG. 3A. As the test paper, 50NFB and S80 used in Example 1 were used.
 測定結果を図4Aに示す。 The measurement results are shown in FIG. 4A.
 図4Aは、圧力分布の中心部ほど圧力が高く、中心部から離れるほど同心円状に順次圧力が低下することを示す。図4Aにおいて、試験紙50NFBで観察される中心部(黒塗り部分)が最も圧力が高く、その次に粗い斜線のハッチングを施した部分の圧力が高く、その次に細かい斜線のハッチングを施した部分の圧力が高い。 FIG. 4A shows that the pressure is higher at the center of the pressure distribution, and gradually decreases concentrically as the distance from the center increases. In FIG. 4A, the central portion (blacked portion) observed with the test paper 50NFB has the highest pressure, and then the pressure in the portion with the rough hatching is high, and then the fine hatching is applied. Part pressure is high.
 図4Aの結果は、S80が、50NFBと比べて、加圧面積が全体として大きく、中心部の圧力が低いことを示す。これは、所定の密度と厚さを有する試験紙S80の方が、カプセルを破砕する際に、指にかかる圧力が局所に集中しにくく、より広い接触面に分散させることが可能であり、指にかかる負担が小さいことを示す。この様子、すなわち試験紙に同じ荷重をかけたときの様子を模式的に図4Bに示す。図4Bにおいて、試験紙から伸びる矢印は、カプセルを指で破砕した際に指にかかるであろう圧力の様子を模式的に表す。図4Bは、所定の厚さを有していない試験紙50NFBの方が、指にかかる圧力が局所に集中しやすく、中心部で高く、試験紙S80の方が指にかかる圧力が広い接触面に分散しやすく、中心部で低いことを示す。 The result of FIG. 4A shows that S80 has a larger pressurization area as a whole and lower pressure at the center than 50 NFB. This is because test paper S80 having a predetermined density and thickness is less likely to concentrate the pressure on the finger locally when crushing the capsule, and can be distributed over a wider contact surface. It shows that the burden on is small. FIG. 4B schematically shows this state, that is, the state when the same load is applied to the test paper. In FIG. 4B, the arrow extending from the test paper schematically represents the state of pressure that will be applied to the finger when the capsule is crushed with the finger. FIG. 4B shows that the test paper 50NFB not having the predetermined thickness is more likely to concentrate the pressure on the finger locally, is higher at the center, and the test paper S80 has a wider pressure on the finger. It is easy to disperse and shows low in the center.
 例1および2では、試験紙の上にカプセルを直接置いて実験を行った。このため、例1および2の実験結果は、本発明の第1の態様(カプセルがフィルタープラグ間の中空部に収容されている態様)を直接反映していると考える。また、カプセルは、フィルタープラグを構成する濾材より十分に硬く、本発明の第2の態様(カプセルがフィルタープラグ内の濾材に埋め込まれている態様)において、カプセルの破砕時にカプセルの硬さを指で直接感じるため、例1および2の実験結果は、本発明の第2の態様(カプセルがフィルタープラグ内の濾材に埋め込まれている態様)も反映していると考える。 In Examples 1 and 2, the experiment was conducted by directly placing the capsule on the test paper. For this reason, it is considered that the experimental results of Examples 1 and 2 directly reflect the first aspect of the present invention (the aspect in which the capsule is accommodated in the hollow portion between the filter plugs). In addition, the capsule is sufficiently harder than the filter medium constituting the filter plug. In the second aspect of the present invention (an aspect in which the capsule is embedded in the filter medium in the filter plug), the capsule indicates the hardness of the capsule when the capsule is crushed. Therefore, the experimental results of Examples 1 and 2 are considered to reflect the second aspect of the present invention (the aspect in which the capsule is embedded in the filter medium in the filter plug).
 例3.カプセルがフィルタープラグ間の中空部に配置されたフィルター
 カプセルを例1と同様の手法に従って調製し、カプセルがフィルタープラグ間の中空部に配置されたフィルターを調製した。フィルターのサイズは、図5Aに示すとおりとした。吸口側および刻側のフィルタープラグは下記のとおりとした。
Example 3 A filter capsule in which the capsule is disposed in the hollow portion between the filter plugs was prepared according to the same method as in Example 1, and a filter in which the capsule was disposed in the hollow portion between the filter plugs was prepared. The size of the filter was as shown in FIG. 5A. The filter plugs on the suction side and the cut side were as follows.
吸口側フィルタープラグ(巻取紙で巻き取られたアセテートフィルター)
 単糸繊度  2.8(g/9000m)
 総繊度   35000(g/9000m)
 繊維本数  12500(本)
 通気抵抗  360(mmH2O/120mm)
刻側フィルタープラグ(NWA:ノンラップアセテートフィルター)
 単糸繊度  2.5(g/9000m)
 総繊度   31000(g/9000m)
 繊維本数  12400(本)
 通気抵抗  300(mmH2O/120mm)
 それぞれのトウに可塑剤(トリアセチン)を、トウ重量に対して9重量%の量で添加した。2つのフィルタープラグを連結するための成形紙(試験紙)としてS80を使用した。
Suction side filter plug (acetate filter wound up with web)
Single yarn fineness 2.8 (g / 9000m)
Total fineness 35000 (g / 9000m)
Number of fibers 12500 (pieces)
Ventilation resistance 360 (mmH2O / 120mm)
Engraved side filter plug (NWA: non-wrap acetate filter)
Single yarn fineness 2.5 (g / 9000m)
Total fineness 31000 (g / 9000m)
Number of fibers 12400 (pieces)
Ventilation resistance 300 (mmH2O / 120mm)
A plasticizer (triacetin) was added to each tow in an amount of 9% by weight based on the tow weight. S80 was used as a molding paper (test paper) for connecting two filter plugs.
 調製されたカプセル含有フィルターを、例1と同様の手法に従って、弾性ゴム上に置き、上方からレオメーターの感圧軸により圧力をかけてカプセルを破砕した(図5B参照)。比較例として、カプセルを単独で、例1と同様の手法に従って、弾性ゴム上に置き、上方からレオメーターの感圧軸により圧力をかけてカプセルを破砕した(図5B参照)。カプセルの破砕は、湿度60%、温度22度の条件下で行った。それぞれの押込み距離(mm)と荷重(N)を測定した。 The prepared capsule-containing filter was placed on an elastic rubber according to the same method as in Example 1, and the capsule was crushed by applying pressure from above with a pressure sensitive shaft of a rheometer (see FIG. 5B). As a comparative example, the capsule alone was placed on an elastic rubber according to the same method as in Example 1, and the capsule was crushed by applying pressure from above the pressure-sensitive axis of the rheometer (see FIG. 5B). The capsules were crushed under the conditions of 60% humidity and a temperature of 22 degrees. Each indentation distance (mm) and load (N) were measured.
 測定結果を図5Cに示す。 The measurement results are shown in FIG. 5C.
 カプセル含有フィルターは、カプセル単独の場合と比較して、フィルタープラグによる反発力があるため、押圧により試験紙がカプセルに到達するまでは荷重がかかりにく、押圧により試験紙がカプセルに到達した後(押込み距離が約3mmを超えた後)、荷重がかかりやすくなった。このため、カプセル単独の場合は、約2.1mmの押込み距離で約25.3Nの荷重がかかったときにカプセルが破砕したのに対し、カプセル含有フィルターは、約4.4mmの押込み距離で約37.2Nの荷重がかかったときにカプセルが破砕した。 The capsule-containing filter has a repulsive force due to the filter plug compared to the capsule alone, so it is difficult to apply a load until the test paper reaches the capsule by pressing, and after the test paper reaches the capsule by pressing (After the indentation distance exceeded about 3 mm), the load was easily applied. For this reason, in the case of the capsule alone, the capsule was crushed when a load of about 25.3 N was applied at an indentation distance of about 2.1 mm, whereas the capsule-containing filter had an indentation distance of about 4.4 mm. The capsule crushed when a load of 37.2 N was applied.
 この結果から、フィルター内のカプセルを試験紙の上から指で押すと、試験紙がカプセルに到達するまでは荷重がかかりにくいため、試験紙がカプセルに到達するまでの押込み距離は短くすることが好ましいことがわかる。試験紙がカプセルに到達するまでの押込み距離は、カプセルのサイズを大きくすることにより短くすることができ、これにより、カプセルの破砕しやすさを更に向上させることもできる。 From this result, if the capsule in the filter is pressed with a finger from the top of the test paper, it will be difficult to apply a load until the test paper reaches the capsule, so the pushing distance until the test paper reaches the capsule may be shortened. It turns out that it is preferable. The pushing distance until the test paper reaches the capsule can be shortened by increasing the size of the capsule, thereby further improving the ease of crushing the capsule.
 例4.カプセルがフィルタープラグ間の中空部に配置されたフィルター
 吸口側および刻側のフィルタープラグのトウを下記のとおり変更した以外は、例3と同様にカプセル含有フィルターを調製した。
Example 4 Filter with Capsule Arranged in the Hollow Part Between Filter Plugs A capsule-containing filter was prepared in the same manner as in Example 3 except that the toe of the filter plug on the suction side and the cut side was changed as follows.
吸口側および刻側のフィルタープラグ
 単糸繊度  5.0(g/9000m)
 総繊度   35000(g/9000m)
 繊維本数  7000(本)
 通気抵抗  270(mmH2O/120mm)
 トウに可塑剤(トリアセチン)は、添加しなかった。
Suction side and carved side filter plugs Single yarn fineness 5.0 (g / 9000m)
Total fineness 35000 (g / 9000m)
7000 fibers
Ventilation resistance 270 (mmH2O / 120mm)
No plasticizer (triacetin) was added to the tow.
 調製されたカプセル含有フィルターを、例3と同様の手法に従って、弾性ゴム上に置いてカプセルを破砕し、押込み距離(mm)と荷重(N)を測定した。カプセルの破砕は、湿度60%、温度22度の条件下で行った。測定結果を図6に示す。 The prepared capsule-containing filter was placed on an elastic rubber according to the same method as in Example 3, the capsule was crushed, and the indentation distance (mm) and load (N) were measured. The capsules were crushed under the conditions of 60% humidity and a temperature of 22 degrees. The measurement results are shown in FIG.
 本例のカプセル含有フィルターでは、やわらかいトウを使用したため、例3のカプセル含有フィルターよりも、フィルタープラグによる反発力を小さくすることができた。このため、例3のカプセル含有フィルターは、約4.4mmの押込み距離で約37.2Nの荷重がかかったときにカプセルが破砕したのに対し、本例のカプセル含有フィルターは、約4.5mmの押込み距離で約23.2Nの荷重がかかったときにカプセルが破砕した。 In the capsule-containing filter of this example, since a soft tow was used, the repulsive force by the filter plug could be made smaller than that of the capsule-containing filter of Example 3. For this reason, the capsule-containing filter of Example 3 was crushed when a load of about 37.2 N was applied at an indentation distance of about 4.4 mm, whereas the capsule-containing filter of this example was about 4.5 mm. The capsule was crushed when a load of about 23.2 N was applied at an indentation distance of.
 この結果から、やわらかい濾材を使用すると、カプセル含有フィルターを指で押した際のフィルタープラグによる反発力は小さいため、カプセル破砕時の荷重を低減できることがわかる。このようにやわらかい濾材の使用によりカプセルの破砕しやすさを更に向上させることもできる。 From this result, it can be seen that when a soft filter medium is used, the repulsive force caused by the filter plug when the capsule-containing filter is pushed with a finger is small, so that the load at the time of capsule crushing can be reduced. Thus, the ease of crushing of the capsule can be further improved by using a soft filter medium.
10・・・シガレット
11・・・たばこロッド
11a・・・たばこ充填材
11b・・・たばこ巻紙
12・・・フィルター
12a・・・フィルタープラグ
12b・・・フィルター包装紙
12c・・・カプセル
12d・・・プラグ巻取紙
13・・・チップペーパー
10. Cigarette 11 ... Tobacco rod 11a ... Tobacco filler 11b ... Tobacco wrapping paper 12 ... Filter 12a ... Filter plug 12b ... Filter wrapping paper 12c ... Capsule 12d・ Plug roll paper 13 ... chip paper

Claims (7)

  1.  たばこ充填材および該たばこ充填材の周囲を巻装する巻紙を含むたばこロッドと、
     濾材を含むフィルタープラグと、前記フィルタープラグの周囲に巻かれたフィルター包装紙と、フィルター内に位置し、内容物を皮膜で被覆して保持するカプセルとを含むフィルターと、
     前記たばこロッドと前記フィルターとを接続するように該たばこロッドと該フィルター上に巻かれたチップペーパーと
    を含み、
     前記フィルター包装紙および前記チップペーパーの少なくとも一方の紙が、0.5~1.0g/cm3の密度および100~250μmの厚さを有することを特徴とするシガレット。
    A tobacco rod including a tobacco filler and a wrapping paper wound around the tobacco filler;
    A filter including a filter plug including a filter medium, a filter wrapping paper wound around the filter plug, and a capsule located in the filter and encapsulating and holding the contents with a film;
    Including the tobacco rod and chip paper wound on the filter so as to connect the tobacco rod and the filter;
    A cigarette wherein at least one of the filter wrapping paper and the chip paper has a density of 0.5 to 1.0 g / cm 3 and a thickness of 100 to 250 μm.
  2.  前記フィルター包装紙および前記チップペーパーの少なくとも一方の紙が、0.7~1.0g/cm3の密度および180~250μmの厚さを有することを特徴とする請求項1に記載のシガレット。 2. The cigarette according to claim 1, wherein at least one of the filter wrapping paper and the chip paper has a density of 0.7 to 1.0 g / cm 3 and a thickness of 180 to 250 μm.
  3.  前記フィルター包装紙および前記チップペーパーの少なくとも一方の紙が、0.8~1.0g/cm3の密度および240~250μmの厚さを有することを特徴とする請求項2に記載のシガレット。 3. The cigarette according to claim 2, wherein at least one of the filter wrapping paper and the chip paper has a density of 0.8 to 1.0 g / cm 3 and a thickness of 240 to 250 μm.
  4.  前記フィルター包装紙および前記チップペーパーの少なくとも一方の紙が、240~250μmの厚さを有し、罫線加工されていることを特徴とする請求項1に記載のシガレット。 2. The cigarette according to claim 1, wherein at least one of the filter wrapping paper and the chip paper has a thickness of 240 to 250 μm and is processed into a ruled line.
  5.  前記カプセルが、球体の形状を有することを特徴とする請求項1~4の何れか1項に記載のシガレット。 The cigarette according to any one of claims 1 to 4, wherein the capsule has a spherical shape.
  6.  前記フィルターが、互いに離間し中空部を介して配置された複数のフィルタープラグと、前記フィルタープラグ間に中空部を形成するように前記フィルタープラグの周囲に巻かれたフィルター包装紙と、前記中空部内に位置し、内容物を皮膜で被覆して保持するカプセルとを含むことを特徴とする請求項1~5の何れか1項に記載のシガレット。 A plurality of filter plugs spaced apart from each other through a hollow portion; filter wrapping paper wound around the filter plug so as to form a hollow portion between the filter plugs; The cigarette according to any one of claims 1 to 5, wherein the cigarette is contained in a capsule and holds the content covered with a film.
  7.  前記フィルターが、フィルタープラグと、前記フィルタープラグの周囲に巻かれたフィルター包装紙と、前記フィルタープラグ内に埋め込まれて位置し、内容物を皮膜で被覆して保持するカプセルとを含むことを特徴とする請求項1~5の何れか1項に記載のシガレット。 The filter includes a filter plug, a filter wrapping paper wound around the filter plug, and a capsule that is embedded in the filter plug and that covers and holds the contents with a film. The cigarette according to any one of claims 1 to 5.
PCT/JP2013/065105 2012-06-11 2013-05-30 Cigarette WO2013187245A1 (en)

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