CN105358767A - Absorption and desorption wallpaper and method of manufacturing the same - Google Patents
Absorption and desorption wallpaper and method of manufacturing the same Download PDFInfo
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- CN105358767A CN105358767A CN201480035907.XA CN201480035907A CN105358767A CN 105358767 A CN105358767 A CN 105358767A CN 201480035907 A CN201480035907 A CN 201480035907A CN 105358767 A CN105358767 A CN 105358767A
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- layer
- inorganic
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/30—Multi-ply
Landscapes
- Laminated Bodies (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Paper (AREA)
Abstract
Disclosed herein is inorganic-substance absorption and desorption wallpaper using bio resin capable of preventing various kinds of diseases, such as a sick house syndrome, by controlling humidity using environment-friendly materials, and a method of manufacturing the same. A method of manufacturing absorption and desorption wallpaper may include forming a base layer, coating and stacking a bio resin layer over the base layer, forming an inorganic binder layer by spraying and coating an inorganic binder on the bio resin layer, forming an inorganic powder layer by scattering an inorganic substance on the inorganic binder layer, and forming a the surface protection layer over the inorganic powder layer using a wiping method.
Description
Technical field
The present invention relates to adsorption and desorption wallpaper and preparation method thereof, more specifically, relating to use can by the inorganic substances adsorption and desorption wallpaper utilizing environment-friendly materials controlled humidity to prevent the bio-resin of various disease (building of such as causing a disease syndrome).
Background technology
Along with the concern of recent harmless product increases, to environmental protection, the concern of organic agriculture and pollution-free product category is also in increase.Especially, because the infringement being attributable to the noxious material produced by construction material is in increase, therefore to for preventing the concern of the syndromic construction material of so-called pathogenic building to become higher.
Wallpaper, i.e. a kind of construction material, be marked as one of product category that can provide the syndromic cause of disease of building of causing a disease.Which increase the concern to Environment-friendlywallpaper wallpaper.
In addition, suitably maintaining internal temperature and humidity is one of most primary demand of the internal environment of Creating Comfort, and its importance increases the needs pursuing the quality of life improved along with modern.
But it is limited for maintaining comfortable environment by means of only inner ventilation controlled humidity.Therefore, by sticking the ceramic tile with moisture control function in the inner wall surface of house or building or wallpaper controls interior humidity.
Fig. 1 is the side cross-sectional view of the stacked structure that the conventional wallpaper with moisture control function is shown.
With reference to figure 1, conventional wallpaper 1 has such structure: wherein stacking bottom non-woven fabric layer 10, adhesive phase 20, top non-woven fabric layer 30, printed layers 40, acrylate resin layer 50 and silicon dioxide layer 60 from bottom.
That is, manufacture by the following method there is the conventional wallpaper of described structure: the non-woven fabric layer connecting a pair supatex fabric wherein forms printed layers; Carry out stamp; Use on the product of wipe method after stamp and apply acrylic resin; By being scattered in by silica to make the silica with repetition adsorption and desorption (i.e. moisture control function) characteristic be attached on acrylate resin layer on acrylate resin layer, thus moisture control function is applied to common wallpaper extraneous adornment effect.
But the manufacture method of this type of conventional wallpaper is very complicated, and the cost intensive of the method.In addition the possibility that, the problem of this wallpaper is because wallpaper is made up of chemical substance, therefore exists and can produce various noxious material---that is, cause a disease and build the syndromic cause of disease---, and be difficult to maintain interior humidity.
Summary of the invention
Technical problem
Therefore, make the present invention in view of the above problems, and the object of this invention is to provide and can realize comfortable internal environment by using environment-friendly materials controlled humidity and prevent the adsorption and desorption wallpaper of various disease (as pathogenic building syndrome), described environment-friendly materials are the humidity control material be such as made up of bio-resin and mineral matter, and provide the method preparing described wallpaper.
Technical scheme
According to an aspect of the present invention; adsorption and desorption wallpaper is configured to comprise basalis, stacking bio-resin layer, the inorganic bond oxidant layer be stacked on bio-resin layer, the inorganic powder last layer be stacked in inorganic bond oxidant layer on the base layer, and is stacked on the sealer in inorganic powder last layer.
According to another aspect of the present invention; adsorption and desorption wallpaper is configured to comprise basalis, stacking bio-resin layer, the first inorganic bond oxidant layer be stacked on bio-resin layer, the first inorganic powder last layer be stacked in the first inorganic bond oxidant layer, the second inorganic bond oxidant layer be stacked in the first inorganic powder last layer, the second inorganic powder last layer be stacked in the second inorganic bond oxidant layer on the base layer, and is stacked on the sealer in the second inorganic powder last layer.
In addition, basalis is made up of supatex fabric, and described supatex fabric is made up of paper pulp and polyester, ceramic paper or glassine paper.
In addition, the per unit area quality that basalis has is 60-80g/m
2.
In addition, bio-resin layer is formed from a resin, described resin comprises and is selected from following one or more: cellulose, chitin, starch, PLA (PLA), polyhydroxyalkanoatefrom (PHA), hydroxybutyric acid valerate (PHBV), polyvinyl alcohol (PVA), polyglycolic acid (PGA), polybutylene succinate (PBS), poly adipate succinic acid ester-copolymerization-butylene succinate (PBSA), poly-adipic acid mutual-phenenyl two acid bromide two alcohol ester (PBAT), polycaprolactone (PCL), poly-(ester-acid amide) and poly-(ester-carbamate).
In addition, bio-resin layer is formed by the following method: the citric acid of the 10-50 weight portion of the PLA resin of 100 weight portions, the CaCo of 10-150 weight portion will be used for
3, the acrylic copolymer of 1-10 weight portion and the stearic acid of 1-5 weight portion mix; Grinder milled mixtures is used at the temperature of 90-200 DEG C; And carry out rolling process or extrusion molding.
In addition, inorganic bond oxidant layer comprises mineral grain, and described mineral grain comprises and is selected from following one or more: talcum, mica, clay, Woelm Alumina, sodium metasilicate and calcium silicates, and described inorganic bond oxidant layer is formed by spraying.
In addition, inorganic powder last layer comprises mineral grain, and described mineral grain comprises and is selected from following one or more: talcum, mica, clay, Woelm Alumina, sodium metasilicate and calcium silicates, and described inorganic powder last layer is formed by scattering.
In addition, usage ratio is acrylic resin and the methyl ethyl ketone formation sealer of 2:8.
According to an aspect of the present invention, the method preparing adsorption and desorption wallpaper comprises: form basalis; Coating and stacking bio-resin layer on the base layer; Inorganic bond oxidant layer is formed by spraying inorganic bond on bio-resin layer; Inorganic powder last layer is formed by scattering inorganic substances in inorganic bond oxidant layer; And use wipe method to form sealer in inorganic powder last layer.
According to another aspect of the present invention, the method preparing adsorption and desorption wallpaper comprises: form basalis; Coating and stacking bio-resin layer on the base layer; By spraying inorganic bond to be formed the first inorganic bond oxidant layer on bio-resin layer; The first inorganic powder last layer is formed by scattering inorganic substances in the first inorganic bond oxidant layer; By spraying inorganic bond to be formed the second inorganic bond oxidant layer in the first inorganic powder last layer; The second inorganic powder last layer is formed by scattering inorganic substances in the second inorganic bond oxidant layer; And use wipe method to form sealer in the second inorganic powder last layer.
Beneficial effect of the present invention
According to the present invention, because employ environment-friendly materials, as the humidity control material be made up of bio-resin and mineral matter, there is following advantage: can controlled humidity, comfortable internal environment can be realized, and various disease thus can be prevented as pathogenic building syndrome.
Accompanying drawing explanation
Fig. 1 is the side cross-sectional view of the stacked structure that the conventional wallpaper with moisture control function is shown;
Fig. 2 illustrates the stacked structure of the adsorption and desorption wallpaper of one embodiment of the invention;
Fig. 3 is the flow chart preparing the method for adsorption and desorption wallpaper that one embodiment of the invention are shown; And
Fig. 4 illustrates the stacked structure of the adsorption and desorption wallpaper of another embodiment of the invention.
The explanation > of the reference number of essential element in < accompanying drawing
100: wallpaper
110: basalis
120: bio-resin layer
130: inorganic bond oxidant layer
140: inorganic powder last layer
150: sealer
Detailed description of the invention
Hereinafter, according to some embodiments, hereafter describing structure of the present invention and operation in detail with reference to the accompanying drawings.
It should be noted that in whole accompanying drawing, identical reference number represents identical element, even if when element is shown in different accompanying drawings when for element assignment reference number in accompanying drawing.
Fig. 2 illustrates the stacked structure of the adsorption and desorption wallpaper of one embodiment of the invention, and Fig. 3 is the flow chart preparing the method for adsorption and desorption wallpaper that one embodiment of the invention are shown.
With reference to figure 2; the adsorption and desorption wallpaper 100 of one embodiment of the invention is configured to comprise: basalis 110, the bio-resin layer 120 be stacked on basalis 110, the inorganic bond oxidant layer 130 be stacked on bio-resin layer 120, the inorganic powder last layer 140 be stacked in inorganic bond oxidant layer 130, and is stacked on the sealer 150 in inorganic powder last layer 140.
Hereafter describe the structure of adsorption and desorption wallpaper 100 in detail.
Basalis 110 is the most basic layers making the upper and lower of wallpaper keep overall crimp balance.Basalis 110 can be made up of supatex fabric or cotton goods, and described supatex fabric or cotton goods are made up of brown paper, paper pulp and polyester.Or basalis 110 can be made up of the ceramic paper of adsorption and desorption effect or glassine paper that can improve wallpaper.
In the case, the per unit area quality that basalis 110 can have is 60-80g/m
2.That is, if the per unit area quality that basalis 110 has is less than 60g/m
2, then the intensity of wallpaper can not be ensured fully.If the per unit area quality that basalis 110 has is greater than 80g/m
2, then Problems existing is for the preparation of the raw-material cost of the per unit area needed for wallpaper unnecessarily increases and does not have the change of physical characteristic.
Bio-resin layer 120 is stacked on basalis 110.Bio-resin layer 120 can be formed from a resin, described resin comprises and is selected from following one or more: cellulose, chitin, starch, PLA (PLA), polyhydroxyalkanoatefrom (PHA), hydroxybutyric acid valerate (PHBV), polyvinyl alcohol (PVA), polyglycolic acid (PGA), polybutylene succinate (PBS), poly adipate succinic acid ester-copolymerization-butylene succinate (PBSA), poly-adipic acid mutual-phenenyl two acid bromide two alcohol ester (PBAT), polycaprolactone (PCL), poly-(ester-acid amide) and poly-(ester-carbamate).
In addition, bio-resin layer 120 also can comprise the nanometer mineral matters of the above-mentioned resin for 100 weight portions of 5-20 weight portion, thus improves the compatibility between the heat resistance of wallpaper and resistance to net (web-proofproperty) and resin.In the case, described nanometer mineral matters can comprise mica, talcum or nanoclay, but the present invention is not limited thereto.
Such nanometer mineral matters can have the average-size of 1-100nm.That is, if the size of nanometer mineral matters is less than 1nm, then dispersibility can be deteriorated, such as, in bio-resin layer 120, less desirable clustering phenomena occurs.If the size of nanometer mineral matters is more than 100nm, then the performance of nanometer mineral matters can decline.
Inorganic bond oxidant layer 130 make use of following principle: when water mixes with inorganic substances, makes inorganic substances have the character of adhesive due to chemical reaction.Such inorganic bond oxidant layer 130 is used as adhesive for the upper surface inorganic powder be made up of mineral grain last layer 140 being adhered to bio-resin layer 120.In the case, inorganic bond oxidant layer 130 can be made up of more than one the following mineral grain that is selected from, and described mineral grain is such as talcum, mica, clay, Woelm Alumina, sodium metasilicate and calcium silicates.
Inorganic powder last layer 140 is stacked on bio-resin layer 120 usually, inserts inorganic bond oxidant layer 130 therebetween with the smell reduced in indoor noxious material and life and improves the humid control effect of wallpaper.In the case, what inorganic powder last layer 140 can comprise more than one is selected from following mineral grain, and described mineral grain is such as talcum, mica, clay, Woelm Alumina, sodium metasilicate and calcium silicates.Such inorganic powder last layer 140 uses scattering method to be formed, and can be embodied as the design with character close friend.
Sealer 150 to be stacked in inorganic powder last layer 140 and to have poisture-penetrability.Sealer 150 can use wipe method to pass through coating and be formed.In the case, sealer 150 is by carrying out mixing with the ratio of 2:8 by acrylic resin and methyl ethyl ketone and formed.The upper surface of the inorganic powder last layer 140 that such sealer 150 uses coating processes method to be formed to be made up of adsorption and desorption material, thus the scratch resistance of wallpaper, ABRASION RESISTANCE and durability can be improved.
Fig. 4 illustrates the stacked structure of the adsorption and desorption wallpaper of another embodiment of the invention.
With reference to figure 4, the adsorption and desorption wallpaper 100 of another embodiment of the invention comprises the inorganic bond oxidant layer 130 of repeatedly stacking on bio-resin layer 120 and inorganic powder last layer 140, thus increases humid control amount of substance and improve adsorption and desorption function.
The adsorption and desorption wallpaper 100 (100 ') of embodiment of the present invention can controlled humidity realize comfortable internal environment because using environment-friendly materials (as bio-resin and mineral matter), and various disease thus can be prevented as pathogenic building syndrome.
< embodiment >
1. basalis
The supatex fabric be made up of the paper pulp of 70% and the polyester of 30% is used to prepare basalis.
2. form inorganic bond oxidant layer
Use more than one the following mineral grain that is selected to form inorganic bond oxidant layer on the base layer, described mineral grain is such as talcum, mica, clay, Woelm Alumina, sodium metasilicate and calcium silicates.
3. form bio-resin layer
The citric acid of the 10-50 weight portion of the PLA resin of 100 weight portions, the CaCo of 10-150 weight portion will be used for
3, the acrylic copolymer of 1-10 weight portion and the stearic acid of 1-5 weight portion carry out mixing and formed over the binder layer.At the temperature of 90-200 DEG C, use grinder to grind this mixture, and use rolling process or extrusion molding to prepare the bio-resin layer that thickness is about 0.15mm.
4. form sealer
By the methyl ethyl ketone of the acrylic resin of 20 % by weight and 80 % by weight is carried out mixing for the preparation of the coating solution of Surface Machining.Then, use wipe method at the surperficial coating surface protective layer of bio-resin layer.
Claims (13)
1. adsorption and desorption wallpaper, comprising:
Basalis;
Be stacked on the inorganic bond oxidant layer on described basalis;
Be stacked on the bio-resin layer on described adhesive phase; With
Be stacked on the sealer on described bio-resin layer.
2. adsorption and desorption wallpaper, comprising:
Basalis;
Be stacked on the bio-resin layer on described basalis;
Be stacked on the inorganic bond oxidant layer on described bio-resin layer;
Be stacked on the inorganic powder last layer in described inorganic bond oxidant layer; With
Be stacked on the sealer in described inorganic powder last layer.
3. adsorption and desorption wallpaper, comprising:
Basalis;
Be stacked on the bio-resin layer on described basalis;
Be stacked on the first inorganic bond oxidant layer on described bio-resin layer;
Be stacked on the first inorganic powder last layer in described first inorganic bond oxidant layer;
Be stacked on the second inorganic bond oxidant layer in described first inorganic powder last layer;
Be stacked on the second inorganic powder last layer in described second inorganic bond oxidant layer;
Be stacked on the sealer in described second inorganic powder last layer.
4. the adsorption and desorption wallpaper any one of claims 1 to 3, wherein said basalis is made up of supatex fabric, and described supatex fabric is made up of paper pulp and polyester, ceramic paper or glassine paper.
5. the adsorption and desorption wallpaper of claim 4, the per unit area quality that wherein said basalis has is 60-80g/m
2.
6. the adsorption and desorption wallpaper any one of claims 1 to 3, wherein said bio-resin layer is formed from a resin, described resin comprises and is selected from following one or more: cellulose, chitin, starch, PLA (PLA), polyhydroxyalkanoatefrom (PHA), hydroxybutyric acid valerate (PHBV), polyvinyl alcohol (PVA), polyglycolic acid (PGA), polybutylene succinate (PBS), poly adipate succinic acid ester-copolymerization-butylene succinate (PBSA), poly-adipic acid mutual-phenenyl two acid bromide two alcohol ester (PBAT), polycaprolactone (PCL), poly-(ester-acid amide) and poly-(ester-carbamate).
7. the adsorption and desorption wallpaper any one of claims 1 to 3, wherein said bio-resin layer is formed by the following method: will be used for the citric acid of the 10-50 weight portion of the PLA resin of 100 weight portions, the CaCo of 10-150 weight portion
3, the acrylic copolymer of 1-10 weight portion and the stearic acid of 1-5 weight portion mix; At the temperature of 90-200 DEG C, use grinder to grind this mixture; And carry out rolling process or extrusion molding.
8. the adsorption and desorption wallpaper any one of claims 1 to 3, wherein: described inorganic bond oxidant layer or multilayer inorganic bond oxidant layer comprise mineral grain, described mineral grain comprises and is selected from following one or more: talcum, mica, clay, Woelm Alumina, sodium metasilicate and calcium silicates, and
Described inorganic bond oxidant layer is formed by spraying.
9. the adsorption and desorption wallpaper of Claims 2 or 3, wherein:
Described inorganic powder last layer comprises mineral grain, and described mineral grain comprises and is selected from following one or more: talcum, mica, clay, Woelm Alumina, sodium metasilicate and calcium silicates, and
Described inorganic powder last layer is formed by scattering.
10. the adsorption and desorption wallpaper any one of claims 1 to 3, wherein said sealer usage ratio is acrylic resin and the methyl ethyl ketone formation of 2:8.
The adsorption and desorption wallpaper of 11. claims 10, wherein said sealer has poisture-penetrability and uses wipe method to pass through coating formation.
12. methods preparing adsorption and desorption wallpaper, comprising:
Form basalis;
Described basalis applies and stacking bio-resin layer;
Inorganic bond oxidant layer is formed by spraying inorganic bond on described bio-resin layer;
Inorganic powder last layer is formed by scattering inorganic substances in described inorganic bond oxidant layer; And
Wipe method is used to form sealer in described inorganic powder last layer.
13. methods preparing adsorption and desorption wallpaper, comprising:
Form basalis;
Coating and stacking bio-resin layer on described basalis;
By spraying inorganic bond to be formed the first inorganic bond oxidant layer on described bio-resin layer;
The first inorganic powder last layer is formed by scattering inorganic substances in described first inorganic bond oxidant layer;
By spraying inorganic bond to be formed the second inorganic bond oxidant layer in described first inorganic powder last layer;
The second inorganic powder last layer is formed by scattering inorganic substances in described second inorganic bond oxidant layer;
Wipe method is used to form sealer in described second inorganic powder last layer.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020130072131A KR101848949B1 (en) | 2013-06-24 | 2013-06-24 | Absorption-desorption wallpaper |
| KR10-2013-0072131 | 2013-06-24 | ||
| PCT/KR2014/005463 WO2014208934A1 (en) | 2013-06-24 | 2014-06-20 | Absorption and desorption wallpaper and method of manufacturing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105358767A true CN105358767A (en) | 2016-02-24 |
| CN105358767B CN105358767B (en) | 2017-10-17 |
Family
ID=52142212
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480035907.XA Active CN105358767B (en) | 2013-06-24 | 2014-06-20 | Adsorption and desorption wallpaper and preparation method thereof |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP2976461B1 (en) |
| JP (1) | JP6168437B2 (en) |
| KR (1) | KR101848949B1 (en) |
| CN (1) | CN105358767B (en) |
| WO (1) | WO2014208934A1 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105586809A (en) * | 2016-01-29 | 2016-05-18 | 太仓卡斯特姆新材料有限公司 | Environment-friendly adsorption type moisture-proof wallpaper |
| CN107556536B (en) * | 2017-09-12 | 2021-02-12 | 江苏金聚合金材料有限公司 | Low-cost bio-based fully-degradable film and preparation method thereof |
| CN108951299B (en) * | 2018-07-26 | 2020-08-18 | 罗仙花 | Brown-black environment-friendly wallpaper and preparation method thereof |
| CN108914707B (en) * | 2018-07-26 | 2020-08-18 | 罗仙花 | Environment-friendly wallpaper capable of adsorbing photocatalytic degradation organic matters and preparation method thereof |
| CN108951300A (en) * | 2018-07-26 | 2018-12-07 | 武汉菡美洛建筑材料有限公司 | A kind of Environment-friendlywallpaper wallpaper with photocatalysis performance |
| CN108914706B (en) * | 2018-07-26 | 2020-06-16 | 山东汇高智慧纺织科技有限公司 | Environment-friendly wallpaper capable of adsorbing formaldehyde |
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| CN102345249A (en) * | 2010-08-06 | 2012-02-08 | 范晓星 | Photocatalytic wallpaper for indoor air purification |
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| JP2000320026A (en) * | 1999-05-07 | 2000-11-21 | Ykk Architectural Products Inc | Gas adsorption panel for construction |
| WO2007102647A1 (en) * | 2006-03-06 | 2007-09-13 | Lg Chem, Ltd. | Breathable wall covering including olefin material and production method thereof |
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2013
- 2013-06-24 KR KR1020130072131A patent/KR101848949B1/en active IP Right Grant
-
2014
- 2014-06-20 CN CN201480035907.XA patent/CN105358767B/en active Active
- 2014-06-20 JP JP2016513885A patent/JP6168437B2/en active Active
- 2014-06-20 EP EP14817141.6A patent/EP2976461B1/en active Active
- 2014-06-20 WO PCT/KR2014/005463 patent/WO2014208934A1/en active Application Filing
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|---|---|---|---|---|
| JP2008184729A (en) * | 1995-04-27 | 2008-08-14 | Johnson & Johnson Gmbh | Process and apparatus for continuous production of length portions from strand of fluid-absorbing material |
| CN1489624A (en) * | 2000-12-27 | 2004-04-14 | 爱斯旺株式会社 | Water-based coating composition for wall paper and wall paper thereof |
| CN102197178A (en) * | 2008-10-30 | 2011-09-21 | 乐金华奥斯有限公司 | Wallpaper and method for manufacturing same |
| CN102345249A (en) * | 2010-08-06 | 2012-02-08 | 范晓星 | Photocatalytic wallpaper for indoor air purification |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2976461B1 (en) | 2018-10-24 |
| KR20150000127A (en) | 2015-01-02 |
| KR101848949B1 (en) | 2018-05-28 |
| CN105358767B (en) | 2017-10-17 |
| EP2976461A1 (en) | 2016-01-27 |
| JP6168437B2 (en) | 2017-07-26 |
| JP2016525960A (en) | 2016-09-01 |
| EP2976461A4 (en) | 2016-12-21 |
| WO2014208934A1 (en) | 2014-12-31 |
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