CN108951300A - A kind of Environment-friendlywallpaper wallpaper with photocatalysis performance - Google Patents

A kind of Environment-friendlywallpaper wallpaper with photocatalysis performance Download PDF

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Publication number
CN108951300A
CN108951300A CN201810837442.XA CN201810837442A CN108951300A CN 108951300 A CN108951300 A CN 108951300A CN 201810837442 A CN201810837442 A CN 201810837442A CN 108951300 A CN108951300 A CN 108951300A
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CN
China
Prior art keywords
wallpaper
environment
photocatalysis performance
butyl titanate
friendlywallpaper
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201810837442.XA
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Chinese (zh)
Inventor
何洪学
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Wuhan Han Merlot Building Materials Co Ltd
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Wuhan Han Merlot Building Materials Co Ltd
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Application filed by Wuhan Han Merlot Building Materials Co Ltd filed Critical Wuhan Han Merlot Building Materials Co Ltd
Priority to CN201810837442.XA priority Critical patent/CN108951300A/en
Publication of CN108951300A publication Critical patent/CN108951300A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18Paper- or board-based structures for surface covering
    • D21H27/20Flexible structures being applied by the user, e.g. wallpaper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21DTREATMENT OF THE MATERIALS BEFORE PASSING TO THE PAPER-MAKING MACHINE
    • D21D1/00Methods of beating or refining; Beaters of the Hollander type
    • D21D1/02Methods of beating; Beaters of the Hollander type
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10Organic non-cellulose fibres
    • D21H13/20Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H13/24Polyesters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/67Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/675Oxides, hydroxides or carbonates

Abstract

The Environment-friendlywallpaper wallpaper and preparation method thereof with photocatalysis performance that the present invention relates to a kind of, which comprises the following steps: (1) wood pulp cellulose, polyester fiber are added to the water, are beaten with beater, mixed slurry is made;(2) butyl titanate is added to preparation butyl titanate ethanol solution in ethanol solution;(3) mixing slurry is made into wallpaper by copy paper, squeezing, preliminary drying, the butyl titanate ethanol solution for passing through step (2), drying, coiling process, obtains a kind of Environment-friendlywallpaper wallpaper with photocatalysis performance.The process flow of this method is simple, at low cost, and for the wallpaper prepared with preferably having photocatalysis performance performance, feel and flexibility are good.

Description

A kind of Environment-friendlywallpaper wallpaper with photocatalysis performance
Technical field
The present invention relates to building decoration materials more particularly to a kind of with the Environment-friendlywallpaper wallpaper of photocatalysis performance and its preparation side Method.
Background technique
Wallpaper, i.e. wallpaper are a kind of materials for being widely used in interior decoration, original are made after being beaten by wood pulp cellulose Paper is obtained by stamp and post-processing later, can also be directly using non-woven fabrics directly as wallpaper.Wallpaper is because its style is more Become, rich in color, the factors such as easy for construction, it is therefore, deep popular.With the improvement of human lives' condition, people are to day The requirement for the ornament materials being often used is also higher and higher, and people, which have not only required nothing more than wallpaper, has common decorative performance, right The additional properties of the environmental protection of wallpaper, antibiotic property, some column such as anti-flammability have higher performance.
Chinese Patent Application No. is the patent of invention of CN105544306A, discloses a kind of antibacterial and mouldproof containing graphene oxide Wallpaper and preparation method thereof, and specifically disclosing the invention is that the antibacterial mildew inhibitor of preparation is evenly distributed on base through spray processing To get antibacterial and mouldproof enzyme wallpaper on paper.The synergistic effect of nano graphene oxide, rattlebush extract and nano-cerium oxide Under, the effect that its antibacterial and mouldproof eliminates the unusual smell is improved significantly.This method is mainly to pass through the method for post-processing for antibacterial agent Being attached on wallpaper makes wallpaper have antibacterial and mouldproof effect, but by simply spraying, the effect between antibacterial agent and wallpaper Power is smaller, and the adhesion time of antibacterial agent can shorten, and then influence the anti-microbial property of wallpaper.Graphene is a kind of with face simultaneously The substance of color, this substance are easy to influence the overall beautiful of wallpaper.
The patent of invention of Publication No. CN102166871A discloses a kind of manufacturing method of sterilization formaldehyde-removing wallpaper, belongs to Functional building decoration materials manufacturing technology field.Manufacturing method includes following feature: (1) with known rolling process production technology Produce wallpaper;(2) wallpaper laminated construction is to be made of in accordance with the order from top to bottom protective layer and paper layer, by bonding between two layers Agent bonding;(3) color pattern of this wallpaper is directly printed on paper layer;(4) nano-titanium dioxide is added in this wallpaper protective layer Photochemical catalyst using photocatalysis principle decomposing formaldehyde, volatile organic contaminant (VOC), kills bacterium and being capable of decomposer corpse. The sterilization formaldehyde-removing wallpaper of this method manufacture, simple production process, wallpaper laminated construction is simple, and low production cost, wallpaper has It sterilizes, except the function of the purification air such as aldehyde, and is able to maintain the cleaning of wallpaper to a certain extent, do not have to frequently clean, have centainly Self-cleaning function.It is proved by sterilization experiment, bacterial inactivation rate reaches 60% when having natural light irradiation.
CN108166330A discloses one kind except formaldehyde PVC wallpaper and preparation method thereof, and PVC wallpaper superficial layer is equipped with first Aldehyde removes layer;Formaldehyde removal layer includes the component of following parts by weight: 25~40 parts of siloxanes of supermolecule poly cage type, nanoscale is living 4~12 parts of charcoal of property, 5~12 parts of nano diatomite, 5~12 parts of nano-titanium dioxide, 6~15 parts of nano-tourmaline, nano-silica 3~8 parts of SiClx, 2~5 parts of surfactant, 15~30 parts of distilled water, 5~9 parts of rare earth activators;Preparation method is to stir at a slow speed Mix-ball milling-moderate-speed mixer-heating-coating-drying.The present invention has the advantage that: it is not only permanent effectively except formaldehyde, and And long service life;Peculiar smell can also be removed simultaneously, has the function of damping, breathe freely, mould proof deodorization;Effect continues up to 10-15 Nian Guang.
It is all to be adhered to finishing agent using postfinishing process that the research for preparing wallpaper from the prior art, which can be seen that many, Onto wallpaper, but this attachment is influenced by adhesive force, so that except formaldehyde performance is difficult to persistently, and the side by arranging Titanium dioxide is attached on wallpaper by method, and the usage amount of titanium dioxide can also increase, and increases the cost of wallpaper.
The present invention is there are formaldehyde pollution, by changing to finishing material to solve the problems, such as to fit up in the prior art Into, assign wallpaper it is certain there is photocatalysis performance ability, be mainly raw material by using butyl titanate, be prepared Hanging raw stock when, by hanging raw stock by the way that in the ethanol solution of butyl titanate, butyl titanate occurs in situ on wallpaper It hydrolyzes and is attached on wallpaper, assign the performance of wallpaper photocatalysis organic matter.
Summary of the invention
The object of the invention is that providing a kind of Environment-friendlywallpaper wallpaper and preparation method thereof with photocatalysis performance, particularly solve Certainly wallpaper has a single function in the prior art, and product feel is poor, and family wear leads to the problem of formaldehyde and biological organism is not easy to remove, The technical issues of raw material usage amount is big simultaneously, and functional materials are unevenly distributed, the specific method is as follows:
A kind of Environment-friendlywallpaper wallpaper with photocatalysis performance, which is characterized in that the raw material of wallpaper includes 0-30 parts of wood pulp cellulose, 30-100 parts of polyester fiber, 0.5-10 parts of tetrabutyl titanate, water, ethyl alcohol;Water is 50-100 times of wood pulp cellulose and polyester fiber; Butyl titanate is added in ethyl alcohol, and the concentration of butyl titanate is 0.5-5g/L;The tetrabutyl titanate hydrolyzes to obtain dioxy Change titanium, titanium dioxide is adsorbed on wallpaper fiber.
Preferably, a kind of Environment-friendlywallpaper wallpaper with photocatalysis performance, which is characterized in that the raw material of wallpaper includes wood pulp cellulose 0-30 parts, 30-100 parts of polyester fiber, 0.5-8 parts of tetrabutyl titanate, water, ethyl alcohol;Water is the 50- of wood pulp cellulose and polyester fiber 100 times;Butyl titanate is added in ethyl alcohol, and the concentration of butyl titanate is 0.5-5g/L.
Raw material further includes hydrolysis inhibitor, and hydrolysis inhibitor is hydrochloric acid or acetic acid.
It, can be into butyl titanate ethanol solution in order to alleviate hydrolysis rate since tetrabutyl titanate hydrolysis speed is fast Hydrolysis inhibitor is added, inhibits the hydrolysis of butyl titanate.
The present invention uses tetrabutyl titanate in the feed, titanium dioxide is generated using the hydrolysis of tetrabutyl titanate, so that two Titanium oxide can be adsorbed on wallpaper fiber surface,
The thickness of wallpaper is less than 1mm.
The present invention also provides a kind of preparation methods of Environment-friendlywallpaper wallpaper with photocatalysis performance, comprising the following steps: (1) Wood pulp cellulose, polyester fiber are added to the water, are beaten with beater, mixed slurry is made;(2) butyl titanate is added Enter into ethanol solution and prepares butyl titanate ethanol solution;(3) mixing slurry passed through into copy paper, squeezing, preliminary drying, pass through step (2) butyl titanate ethanol solution, drying, coiling process makes wallpaper, obtains a kind of environmentally friendly wall with photocatalysis performance Paper.
The present invention in slurry after copy paper, preliminary drying through four butyl ester ethanol solution of pertitanic acid, the moisture on wallpaper is not at this time Drying completely, when by butyl titanate ethanol solution, butyl titanate carries out in-situ hydrolysis on the wallpaper of moisture content, in turn It is attached on wallpaper, so that can uniformly adhere to layer of titanium dioxide on wallpaper, and titanium dioxide partial size is small, specific surface area Greatly, the organic matter being easy in capture air carries out photocatalytic degradation.
The beating degree of step (2) beating time 0.5-1.5 hours, slurry is controlled in 50~60 ° of SR.
Because the performance of slurry influences whether the performance of final wallpaper, according to test of many times, beating time 0.5-1.5 is found Hour, the beating degree of slurry controls under the conditions of 50~60 ° of SR, and the wallpaper feel prepared is good, and flexibility is good, and quality is high.
One of fire retardant, softening agent, water repellent or a variety of can also be added when being beaten in step (2) into slurry.
According to the demand of wallpaper performance, corresponding functional finish can also be added in the preparation step of slurry, this A little functional finish in pulping process due to being added, and the fixation with wallpaper is preferably.
Hydrolysis temperature in step (3) is 30-60 DEG C.
The temperature of control hydrolysing step can control the hydrolysis rate of butyl titanate, according to demand can be to the temperature of hydrolysis Degree is suitably adjusted.
The preliminary drying temperature of step (3) is 80-95 DEG C, preliminary drying time 2-10min.
Preliminary drying can control the content of moisture on wallpaper, and then can control the hydrolysis rate of butyl titanate.
Technical problem to be solved by the present invention lies in current air there are more toxic organic matter, and it is this kind of Organic matter is usually to pass through absorption to be removed, and with the saturation of adsorbent absorption organic matter, adsorbent can have absorption The phenomenon that ability reduces, for this problem, the present invention, which is prepared for one kind, has photocatalysis performance wallpaper, mainly passes through metatitanic acid four Butyl ester in-situ hydrolysis on wallpaper, and then be attached on wallpaper, the nanometer titanium dioxide day of small size is prepared, utilizes nanometer two The photocatalysis of titanium oxide, it is acquired due to the performance of photochemical catalyst the organic matter in air is adsorbed and be degraded Wallpaper have longer photocatalytic degradation capability.
In addition, the present invention when preparing photocatalytic degradation wallpaper, is attached on wallpaper using butyl titanate Situ Hydrothermal, It can make titanium dioxide is stable to anchor among wallpaper, it is subsequent by the methods of coating, stamp, sprinkling general to avoid use Adsorbent is attached on wallpaper, and preparation process is simple, and carbon ball fixation is stablized, and adsorption capacity is stablized.Also, hydrolysis of tetrabutyl titanate The cost for preparing photocatalytic degradation wallpaper it is more traditional coating it is at low cost.
Specific embodiment
Organic matter light degradation property
It takes muti-piece wallpaper to distinguish formaldehyde adsorption, weighs the wall for waiting parts by weight of example 1-5 and comparative example 1-2 to be prepared Formaldehyde is added in confined space in paper, and the content for controlling formaldehyde is 0.2mg/m3, different embodiment and comparative examples are prepared Wallpaper 50g is placed in the confined space 3 days, ultraviolet light irradiation, after test 3 days in confined space formaldehyde content.
Embodiment 1
A kind of preparation method of the Environment-friendlywallpaper wallpaper with photocatalysis performance, comprising the following steps: (1) by wood pulp cellulose 20 Part, 80 parts of polyester fiber be added to the water, the quality of water is 70 times of other raw materials, is beaten with beater, beating time Mixed slurry is made in 50~60 ° of SR in 1h, the beating degree control of slurry;(2) ethanol solution is added to by 10 parts of butyl titanate The concentration of middle preparation butyl titanate ethanol solution, butyl titanate ethanol solution is 10g/L, and the acetic acid of 1g/L is added;(3) By mixing slurry by copy paper, squeezing, preliminary drying, the butyl titanate ethanol solution for passing through step (2), drying, coiling process production Wallpaper obtains a kind of Environment-friendlywallpaper wallpaper with photocatalysis performance.Wherein preliminary drying temperature is 90 DEG C, preliminary drying time 3min, hydrolysis temperature Degree is 40 DEG C.
The wallpaper prepared is soft, and color is uniform, the content 0.06mg/m of formaldehyde after 3 days3
Embodiment 2
A kind of preparation method of the Environment-friendlywallpaper wallpaper with photocatalysis performance, comprising the following steps: (1) by wood pulp cellulose 20 Part, 80 parts of polyester fiber be added to the water, the quality of water is 70 times of other raw materials, is beaten with beater, beating time Mixed slurry is made in 50~60 ° of SR in 1h, the beating degree control of slurry;(2) ethanol solution is added to by 5 parts of butyl titanate The concentration of middle preparation butyl titanate ethanol solution, butyl titanate ethanol solution is 5g/L, and the acetic acid of 1g/L is added;(3) By mixing slurry by copy paper, squeezing, preliminary drying, the butyl titanate ethanol solution for passing through step (2), drying, coiling process production Wallpaper obtains a kind of Environment-friendlywallpaper wallpaper with photocatalysis performance.Wherein preliminary drying temperature is 90 DEG C, preliminary drying time 3min, hydrolysis temperature Degree is 40 DEG C.
The wallpaper prepared is soft, and color is uniform, the content 0.09mg/m3 of formaldehyde after 3 days.
Embodiment 3
A kind of preparation method of the Environment-friendlywallpaper wallpaper with photocatalysis performance, comprising the following steps: (1) by wood pulp cellulose 20 Part, 80 parts of polyester fiber be added to the water, the quality of water is 70 times of other raw materials, is beaten with beater, beating time Mixed slurry is made in 50~60 ° of SR in 1h, the beating degree control of slurry;(2) ethanol solution is added to by 10 parts of butyl titanate The concentration of middle preparation butyl titanate ethanol solution, butyl titanate ethanol solution is 10g/L, and the acetic acid of 1g/L is added;(3) By mixing slurry by copy paper, squeezing, preliminary drying, the butyl titanate ethanol solution for passing through step (2), drying, coiling process production Wallpaper obtains a kind of Environment-friendlywallpaper wallpaper with photocatalysis performance.Wherein preliminary drying temperature is 90 DEG C, preliminary drying time 3min, hydrolysis temperature Degree is 50 DEG C.
The wallpaper prepared is soft, and color is uniform, the content 0.05mg/m3 of formaldehyde after 3 days.
Embodiment 4
A kind of preparation method of the Environment-friendlywallpaper wallpaper with photocatalysis performance, comprising the following steps: (1) by wood pulp cellulose 30 Part, 70 parts of polyester fiber be added to the water, the quality of water is 70 times of other raw materials, is beaten with beater, beating time Mixed slurry is made in 50~60 ° of SR in 1h, the beating degree control of slurry;(2) ethanol solution is added to by 10 parts of butyl titanate The concentration of middle preparation butyl titanate ethanol solution, butyl titanate ethanol solution is 10g/L, and the acetic acid of 1g/L is added;(3) By mixing slurry by copy paper, squeezing, preliminary drying, the butyl titanate ethanol solution for passing through step (2), drying, coiling process production Wallpaper obtains a kind of Environment-friendlywallpaper wallpaper with photocatalysis performance.Wherein preliminary drying temperature is 90 DEG C, preliminary drying time 3min, hydrolysis temperature Degree is 40 DEG C.
The wallpaper prepared is soft, and color is uniform, the content 0.05mg/m3 of formaldehyde after 3 days.
Embodiment 5
A kind of preparation method of the Environment-friendlywallpaper wallpaper with photocatalysis performance, comprising the following steps: (1) by wood pulp cellulose 20 Part, 80 parts of polyester fiber be added to the water, the quality of water is 70 times of other raw materials, is beaten with beater, beating time Mixed slurry is made in 50~60 ° of SR in 1h, the beating degree control of slurry;(2) ethanol solution is added to by 10 parts of butyl titanate The concentration of middle preparation butyl titanate ethanol solution, butyl titanate ethanol solution is 10g/L, and the hydrochloric acid of 1g/L is added;(3) By mixing slurry by copy paper, squeezing, preliminary drying, the butyl titanate ethanol solution for passing through step (2), drying, coiling process production Wallpaper obtains a kind of Environment-friendlywallpaper wallpaper with photocatalysis performance.Wherein preliminary drying temperature is 90 DEG C, preliminary drying time 3min, hydrolysis temperature Degree is 40 DEG C.
The wallpaper prepared is soft, and color is uniform, the content 0.08mg/m3 of formaldehyde after 3 days.
Embodiment 6
A kind of preparation method of the Environment-friendlywallpaper wallpaper with photocatalysis performance, comprising the following steps: (1) by wood pulp cellulose 20 Part, 80 parts of polyester fiber be added to the water, 4 parts of fire retardants are added, the quality of water is 70 times of other raw materials, is carried out with beater Mixed slurry is made in 50~60 ° of SR in mashing, beating time 1h, the beating degree control of slurry;(2) by 10 parts of butyl titanate It is added to preparation butyl titanate ethanol solution in ethanol solution, the concentration of butyl titanate ethanol solution is 10g/L, and is added The acetic acid of 1g/L;(3) by mixing slurry by copy paper, squeezing, preliminary drying, the butyl titanate ethanol solution by step (2), baking Dry, coiling process makes wallpaper, obtains a kind of Environment-friendlywallpaper wallpaper with photocatalysis performance.Wherein preliminary drying temperature is 80 DEG C, preliminary drying Time 3min, hydrolysis temperature are 40 DEG C.
The wallpaper prepared is soft, and color is uniform, the content 0.05mg/m3 of formaldehyde after 3 days.
Comparative example 1
A kind of preparation method of Environment-friendlywallpaper wallpaper, comprising the following steps: (1) add 20 parts of wood pulp cellulose, 80 parts of polyester fiber Enter water, so that the quality of water is 60 times of other raw materials, be beaten with beater, mixed slurry, beating time 1h, slurry is made The beating degree of material is controlled in 50~60 ° of SR;(2) mixing slurry is made into hanging raw stock by copy paper, squeezing, drying, coiling process; Obtain a kind of Environment-friendlywallpaper wallpaper.
The wallpaper prepared is soft, and color is uniform, the content 0.18mg/m of formaldehyde after 3 days3
Can be seen that wallpaper that embodiment 1-6 is prepared to the light degradation effect of above-mentioned wallpaper PARA FORMALDEHYDE PRILLS(91,95) can be to first Aldehyde organic matter carries out photocatalytic degradation, achievees the effect that remove organic matter.
These are only the preferred embodiment of the present invention, is not intended to restrict the invention, although referring to embodiment to this Invention is described in detail, for those skilled in the art, still can be to recorded in foregoing embodiments Technical solution modify or equivalent replacement of some of the technical features, but it is all in spirit of the invention and Within principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (9)

1. a kind of Environment-friendlywallpaper wallpaper with photocatalysis performance, which is characterized in that the raw material of wallpaper includes 0-30 parts of wood pulp cellulose, is washed 30-100 parts of synthetic fibre fiber, 0.5-10 parts of tetrabutyl titanate, water, ethyl alcohol;Water is 50-100 times of wood pulp cellulose and polyester fiber;Titanium Sour four butyl esters are added in ethyl alcohol, and the concentration of butyl titanate is 0.5-5g/L;The tetrabutyl titanate hydrolyzes to obtain titanium dioxide Titanium, titanium dioxide are adsorbed on wallpaper fiber.
2. a kind of as described in claim 1 with the Environment-friendlywallpaper wallpaper of photocatalysis performance, which is characterized in that the raw material of wallpaper includes 0-30 parts of wood pulp cellulose, 30-100 parts of polyester fiber, 0.5-8 parts of tetrabutyl titanate, water, ethyl alcohol;Water is wood pulp cellulose and terylene 50-100 times of fiber;Butyl titanate is added in ethyl alcohol, and the concentration of butyl titanate is 0.5-2.5g/L.
3. a kind of as described in claim 1 with the Environment-friendlywallpaper wallpaper of photocatalysis performance, which is characterized in that raw material further includes hydrolysis Inhibitor, hydrolysis inhibitor are hydrochloric acid or acetic acid.
4. a kind of as described in claim 1 with the Environment-friendlywallpaper wallpaper of photocatalysis performance, which is characterized in that the thickness of wallpaper is less than 1mm。
5. a kind of preparation method of the Environment-friendlywallpaper wallpaper according to any one of claims 1-4 with photocatalysis performance, feature It is, comprising the following steps: (1) wood pulp cellulose, polyester fiber are added to the water, are beaten with beater, mixing is made Slurry;(2) butyl titanate is added to preparation butyl titanate ethanol solution in ethanol solution;(3) by mixing slurry by copying Paper, squeezing, preliminary drying, the butyl titanate ethanol solution for passing through step (2), drying, coiling process make wallpaper, obtain a kind of tool There is the Environment-friendlywallpaper wallpaper of photocatalysis performance.
6. a kind of preparation method of the Environment-friendlywallpaper wallpaper with photocatalysis performance as claimed in claim 5, which is characterized in that step (3) pre-baked wallpaper is 30-60 DEG C by the temperature of butyl titanate ethanol solution.
7. a kind of preparation method of the Environment-friendlywallpaper wallpaper with photocatalysis performance as claimed in claim 5, which is characterized in that step (3) beating time 0.5-1.5 hours, the beating degree of slurry was controlled in 50~60 ° of SR.
8. a kind of preparation method of the Environment-friendlywallpaper wallpaper with photocatalysis performance as claimed in claim 5, which is characterized in that step (3) one of fire retardant, softening agent, water repellent or a variety of can also be added into slurry when being beaten.
9. a kind of preparation method of the Environment-friendlywallpaper wallpaper with photocatalysis performance as claimed in claim 5, which is characterized in that step (3) preliminary drying temperature is 80-95 DEG C, preliminary drying time 2-10min.
CN201810837442.XA 2018-07-26 2018-07-26 A kind of Environment-friendlywallpaper wallpaper with photocatalysis performance Pending CN108951300A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113201960A (en) * 2021-04-30 2021-08-03 北京依依星科技有限公司 Photocatalytic paper and preparation method thereof
CN113529491A (en) * 2021-07-02 2021-10-22 武汉梓强生态科技有限公司 Modified diatomite adsorption wallpaper and preparation method thereof

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WO2014208934A1 (en) * 2013-06-24 2014-12-31 Lg Hausys, Ltd. Absorption and desorption wallpaper and method of manufacturing the same
CN107178007A (en) * 2017-03-30 2017-09-19 天长市天达纸箱纸品厂 A kind of preparation method of antimicrobial form hanging raw stock
CN107366195A (en) * 2017-09-20 2017-11-21 武汉菡美洛建筑材料有限公司 A kind of light soft sound insulation high-adhesiveness wallpaper and its manufacture method
CN107476137A (en) * 2017-09-13 2017-12-15 武汉菡美洛建筑材料有限公司 A kind of antibacterial environment protection wallpaper

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102268835B (en) * 2010-06-03 2013-01-02 中国制浆造纸研究院 Preparation method for tile stock
WO2014208934A1 (en) * 2013-06-24 2014-12-31 Lg Hausys, Ltd. Absorption and desorption wallpaper and method of manufacturing the same
CN107178007A (en) * 2017-03-30 2017-09-19 天长市天达纸箱纸品厂 A kind of preparation method of antimicrobial form hanging raw stock
CN107476137A (en) * 2017-09-13 2017-12-15 武汉菡美洛建筑材料有限公司 A kind of antibacterial environment protection wallpaper
CN107366195A (en) * 2017-09-20 2017-11-21 武汉菡美洛建筑材料有限公司 A kind of light soft sound insulation high-adhesiveness wallpaper and its manufacture method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113201960A (en) * 2021-04-30 2021-08-03 北京依依星科技有限公司 Photocatalytic paper and preparation method thereof
CN113529491A (en) * 2021-07-02 2021-10-22 武汉梓强生态科技有限公司 Modified diatomite adsorption wallpaper and preparation method thereof

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Application publication date: 20181207