CN105358767B - Adsorption and desorption wallpaper and preparation method thereof - Google Patents
Adsorption and desorption wallpaper and preparation method thereof Download PDFInfo
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- CN105358767B CN105358767B CN201480035907.XA CN201480035907A CN105358767B CN 105358767 B CN105358767 B CN 105358767B CN 201480035907 A CN201480035907 A CN 201480035907A CN 105358767 B CN105358767 B CN 105358767B
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/30—Multi-ply
Abstract
The invention discloses the inorganic substances adsorption and desorption wallpaper for the bio-resin for preventing various diseases (such as building syndrome of causing a disease) using that can control humidity by using environment-friendly materials, and the method for preparing the wallpaper.Preparing the method for adsorption and desorption wallpaper may include：Form basalis；Coat and stack on the base layer bio-resin layer；Inorganic bond oxidant layer is formed by spraying inorganic bond on bio-resin layer；Inorganic powder last layer is formed by scattering inorganic substances in inorganic bond oxidant layer；And form sealer in inorganic powder last layer using wipe method.
Description
Technical field
The present invention relates to adsorption and desorption wallpaper and preparation method thereof, more particularly, to using can be by using
Environment-friendly materials control humidity come the inorganic substances absorption for the bio-resin for preventing various diseases (such as cause a disease building syndrome) and
Desorption wallpaper.
Background technology
With the concern increase of recent harmless product, to environmental protection, organic agriculture and pollution-free product category
Concern is also in increase.Especially, because the infringement of noxious material for being attributable to be produced by construction material is in increase, thus to
Become higher in the concern for the construction material for preventing so-called pathogenic building syndrome.
Wallpaper, i.e., a kind of construction material, be marked as providing cause a disease building syndrome the cause of disease product category it
One.Which increase the concern to Environment-friendlywallpaper wallpaper.
Additionally, proper it is to create one of most basic demand of comfortable internal environment to maintain internal temperature and humidity, and
And increase the need for quality of life of its importance with modern to pursuing improvement.
However, only controlling humidity to maintain comfortable environment to be limited by inner ventilation.Therefore, by house or
The inner wall surface of building sticks ceramic tile or wallpaper with moisture control function to control interior humidity.
Fig. 1 is the side cross-sectional view for the stacked structure for showing the conventional wallpaper with moisture control function.
With reference to Fig. 1, conventional wallpaper 1 has a structure in which：Bottom non-woven fabric layer 10 is stacked wherein from bottom, is glued
Mixture layer 20, top non-woven fabric layer 30, printing layer 40, acrylate resin layer 50 and silicon dioxide layer 60.
That is, manufacture has the conventional wallpaper of the structure by the following method：A pair of supatex fabric are connected wherein
Printing layer is formed on non-woven fabric layer；Carry out stamp；Using wipe method acrylic resin is coated on the product after stamp；It is logical
Cross and silica is scattered on acrylate resin layer so that with repetition adsorption and desorption (i.e. moisture control function) characteristic
Silica be attached on acrylate resin layer so that by moisture control function be applied to common wallpaper extraneous adornment effect.
However, the manufacture method of such conventional wallpaper is very complicated, and this method is costly.In addition, the wallpaper
Problem is because wallpaper is made up of chemical substance, therefore presence can produce various noxious materials --- i.e., building of causing a disease is integrated
The cause of disease levied --- possibility, and be difficult to maintain interior humidity.
The content of the invention
Technical problem
Therefore, the present invention is made in view of the above problems, and it is an object of the invention to provide can be by using environmental protection
Control of material humidity come realize comfortable internal environment and prevent various diseases (as cause a disease building syndrome) absorption and desorption
Attached wallpaper, the environment-friendly materials are the humidity control material being for example made up of bio-resin and mineral matter, and it is described to provide preparation
The method of wallpaper.
Technical scheme
According to an aspect of the present invention, adsorption and desorption wallpaper is configurable to include basalis, is stacked on basalis
On bio-resin layer, be stacked on bio-resin layer on the first inorganic bond oxidant layer, be stacked in the first inorganic bond oxidant layer
The first inorganic powder last layer, and the sealer being stacked in the first inorganic powder last layer.
According to another aspect of the present invention, adsorption and desorption wallpaper is configurable to include basalis, is stacked on substrate
On layer bio-resin layer, be stacked on bio-resin layer on the first inorganic bond oxidant layer, be stacked on the first inorganic bond oxidant layer
On the first inorganic powder last layer, be stacked in the first inorganic powder last layer the second inorganic bond oxidant layer, to be stacked on second inorganic viscous
The second inorganic powder last layer in mixture layer, and the sealer being stacked in the second inorganic powder last layer.
In addition, basalis is made up of supatex fabric, the supatex fabric is by paper pulp and polyester, ceramic paper or glassine paper
It is made.
In addition, the per unit area quality that basalis has is 60-80g/m2。
In addition, bio-resin layer is formed from a resin, the resin, which is included, is selected from following one or more：It is cellulose, several
Ding Zhi, starch, PLA (PLA), polyhydroxyalkanoatefrom (PHA), hydroxybutyric acid valerate (PHBV), polyvinyl alcohol (PVA),
Polyglycolic acid (PGA), polybutylene succinate (PBS), poly adipate succinic acid ester-copolymerization-butylene succinate
(PBSA), polyadipate mutual-phenenyl two acid bromide two alcohol ester (PBAT), polycaprolactone (PCL), poly- (ester-acid amide) and poly- (ester-amino
Formic acid esters).
In addition, forming bio-resin layer by the following method：By the 10-50 parts by weight for the PLA resin of 100 parts by weight
Citric acid, the CaCO of 10-150 parts by weight3, 1-10 parts by weight acrylic copolymer and 1-5 parts by weight stearic acid carry out
Mixing；Grinder milled mixtures are used at a temperature of 90-200 DEG C；And rolled or extruded.
In addition, inorganic bond oxidant layer includes mineral grain, the mineral grain includes being selected from following one or more：It is sliding
Stone, mica, clay, Woelm Alumina, sodium metasilicate and calcium silicates, and the inorganic bond oxidant layer is by spraying formation.
In addition, inorganic powder last layer includes mineral grain, the mineral grain includes being selected from following one or more：It is sliding
Stone, mica, clay, Woelm Alumina, sodium metasilicate and calcium silicates, and the inorganic powder last layer is by scattering formation.
In addition, the use of part by weight being 2:8 acrylic resin and methyl ethyl ketone formation sealer.
According to an aspect of the present invention, preparing the method for adsorption and desorption wallpaper includes：Form basalis；In substrate
Bio-resin layer is coated and stacked on layer；Inorganic bond oxidant layer is formed by spraying inorganic bond on bio-resin layer；
Inorganic powder last layer is formed by scattering inorganic substances in inorganic bond oxidant layer；And using wipe method in inorganic powder last layer
Form sealer.
According to another aspect of the present invention, preparing the method for adsorption and desorption wallpaper includes：Form basalis；In base
Bio-resin layer is coated and stacked on bottom；The first inorganic bond is formed by spraying inorganic bond on bio-resin layer
Oxidant layer；The first inorganic powder last layer is formed by scattering inorganic substances in the first inorganic bond oxidant layer；By inorganic first
Inorganic bond is sprayed on powder bed to form the second inorganic bond oxidant layer；It is inorganic by being scattered in the second inorganic bond oxidant layer
Material forms the second inorganic powder last layer；And form sealer in the second inorganic powder last layer using wipe method.
Beneficial effects of the present invention
According to the present invention because using environment-friendly materials such as by humidity control material that bio-resin and mineral matter are made and
Have the advantage that：Humidity can be controlled, comfortable internal environment can be realized, and thus can prevent various diseases as caused a disease
Build syndrome.
Brief description of the drawings
Fig. 1 is the side cross-sectional view for the stacked structure for showing the conventional wallpaper with moisture control function；
Fig. 2 shows the stacked structure of the adsorption and desorption wallpaper of one embodiment of the invention；
Fig. 3 is the flow chart of the method for the preparation adsorption and desorption wallpaper for showing one embodiment of the invention；With
And
Fig. 4 shows the stacked structure of the adsorption and desorption wallpaper of another embodiment of the invention.
<The explanation of the reference numeral of essential element in accompanying drawing>
100：Wallpaper
110：Basalis
120：Bio-resin layer
130：Inorganic bond oxidant layer
140：Inorganic powder last layer
150：Sealer
Embodiment
Hereinafter, according to some embodiments, construction and the operation of the present invention is described in detail below with reference to the accompanying drawings.
It should be noted that in the element assignment reference numeral in for accompanying drawing, in whole accompanying drawings, identical reference numeral is represented
Identical element, in the case that element is shown in different accompanying drawings.
Fig. 2 shows the stacked structure of the adsorption and desorption wallpaper of one embodiment of the invention, and Fig. 3 is to show
The flow chart of the method for the preparation adsorption and desorption wallpaper of one embodiment of the invention.
With reference to Fig. 2, the adsorption and desorption wallpaper 100 of one embodiment of the invention is configurable to include：Basalis
110th, be stacked on basalis 110 bio-resin layer 120, be stacked on bio-resin layer 120 on inorganic bond oxidant layer 130,
It is stacked on the inorganic powder last layer 140 in inorganic bond oxidant layer 130, and the sealer being stacked in inorganic powder last layer 140
150。
The structure of adsorption and desorption wallpaper 100 is described in detail below.
Basalis 110 is the most basic layer for making the upper and lower part of wallpaper keep overall crimp balance.Basalis 110 can
It is made up of supatex fabric or cotton goods, the supatex fabric or cotton goods are made up of brown paper, paper pulp and polyester.Or,
Basalis 110 can be made up of the ceramic paper or glassine paper of the adsorption and desorption effect that can improve wallpaper.
In the case, the per unit area quality that basalis 110 can have is 60-80g/m2.That is, if basalis
The 110 per unit area quality having are less than 60g/m2, then the intensity of wallpaper will not be sufficiently ensured.If basalis
The 110 per unit area quality having are more than 80g/m2, then have problems in that for preparing the per unit face needed for wallpaper
The cost of product raw material unnecessarily increases without the change of physical characteristic.
Bio-resin layer 120 is stacked on basalis 110.Bio-resin layer 120 can be formed from a resin, and the resin includes
Selected from following one or more：Cellulose, chitin, starch, PLA (PLA), polyhydroxyalkanoatefrom (PHA), hydroxyl
Butyric acid valerate (PHBV), polyvinyl alcohol (PVA), polyglycolic acid (PGA), polybutylene succinate (PBS), polyadipate fourth
Diol ester-copolymerization-butylene succinate (PBSA), polyadipate mutual-phenenyl two acid bromide two alcohol ester (PBAT), polycaprolactone
(PCL) it is, poly- (ester-acid amide) and poly- (ester-carbamate).
In addition, bio-resin layer 120 can also include the nanometer ore deposit of the above-mentioned resin for 100 parts by weight of 5-20 parts by weight
Material, so as to improve the compatibility between the heat resistance of wallpaper and resistance to net (web-proof property) and resin.
In this case, the nanometer mineral matters may include mica, talcum or nanoclay, but the invention is not restricted to this.
Such nanometer mineral matters can have 1-100nm average-size.That is, if the size of nanometer mineral matters is less than
1nm, then dispersibility can deteriorate, for example bio-resin layer 120 in occur undesirable clustering phenomena.If nanometer mineral matters
Size more than 100nm, then the performance of nanometer mineral matters can decline.
Inorganic bond oxidant layer 130 make use of following principle：When water is mixed with inorganic substances, nothing is made due to chemical reaction
Machine material has the property of adhesive.Such inorganic bond oxidant layer 130 is used as adhesive to be made up of mineral grain
Inorganic powder last layer 140 adhere to bio-resin layer 120 upper surface.In the case, inorganic bond oxidant layer 130 can be by one kind
More than be made selected from following mineral grain, the mineral grain is, for example, talcum, mica, clay, Woelm Alumina, silicic acid
Sodium and calcium silicates.
Inorganic powder last layer 140 is typically stacked on bio-resin layer 120, and inorganic bond oxidant layer 130 is inserted therebetween to reduce
Indoor noxious material and smell in life simultaneously improve the humid control effect of wallpaper.In the case, inorganic powder last layer 140 can
Be selected from following mineral grain including more than one, the mineral grain is such as talcum, mica, clay, Woelm Alumina,
Sodium metasilicate and calcium silicates.Such inorganic powder last layer 140 is formed using scattering method, and can be realized as setting with property close friend
Meter.
Sealer 150 is stacked in inorganic powder last layer 140 and with penetrability.Sealer 150, which can be used, to be wiped
Method is wiped to be formed by coating.In the case, sealer 150 can by by acrylic resin and methyl ethyl ketone with 2:8
Part by weight mixed and formed.Such sealer 150 is formed at by adsorbing and desorbing using coating processes method
The upper surface for the inorganic powder last layer 140 that addendum matter is made, so as to improve the scratch resistance, wearability and durability of wallpaper.
Fig. 4 shows the stacked structure of the adsorption and desorption wallpaper of another embodiment of the invention.
With reference to Fig. 4, the adsorption and desorption wallpaper 100 of another embodiment of the invention includes repeatedly stacking in biology
Inorganic bond oxidant layer 130 and inorganic powder last layer 140 on resin bed 120, so as to increase the amount of humid control material and improve suction
Echo desorption function.
The adsorption and desorption wallpaper 100 (100 ') of embodiment of the present invention because using environment-friendly materials (such as bio-resin and
Mineral matter) and humidity can be controlled and comfortable internal environment is realized, and thus various diseases can be prevented as comprehensive such as building of causing a disease
Simulator sickness.
<Embodiment>
1. basalis
Basalis is prepared using the supatex fabric being made up of 70% paper pulp and 30% polyester.
2. form inorganic bond oxidant layer
Inorganic bond oxidant layer, the mineral are formed on the base layer selected from following mineral grain using more than one
Grain is such as talcum, mica, clay, Woelm Alumina, sodium metasilicate and calcium silicates.
3. form bio-resin layer
By the CaCO for the citric acid of the 10-50 parts by weight of the PLA resin of 100 parts by weight, 10-150 parts by weight3、1-
The acrylic copolymer of 10 parts by weight and the stearic acid of 1-5 parts by weight are mixed and formed over the binder layer.In 90-200
The mixture is ground using grinder at a temperature of DEG C, and the biology that thickness is about 0.15mm is prepared using rolling process or extrusion molding
Resin bed.
4. form sealer
Prepared by the way that the methyl ethyl ketone of 20 weight % acrylic resin and 80 weight % is mixed for table
The coating solution of face processing.Then, using wipe method bio-resin layer surface coating surface protective layer.
Claims (10)
1. adsorption and desorption wallpaper, including：
Basalis；
It is stacked on the bio-resin layer on the basalis；
It is stacked on the first inorganic bond oxidant layer on the bio-resin layer；
It is stacked on the first inorganic powder last layer in the first inorganic bond oxidant layer；With
The sealer in the first inorganic powder last layer is stacked on,
Wherein described bio-resin layer includes citric acid, the 10- of the 10-50 parts by weight of the PLA resin relative to 100 parts by weight
The CaCO of 150 parts by weight3, the acrylic copolymers of 1-10 parts by weight, the stearic acid of 1-5 parts by weight and 5-20 parts by weight include
The nanometer mineral matters of mica, talcum or nanoclay,
Wherein described sealer is 2 using part by weight:8 acrylic resin and methyl ethyl ketone is formed,
The first inorganic bond oxidant layer includes mineral grain, and the mineral grain includes being selected from following one or more：It is sliding
Stone, mica, clay, Woelm Alumina, sodium metasilicate and calcium silicates, and the inorganic bond oxidant layer is by spraying formation.
2. the adsorption and desorption wallpaper of claim 1, wherein adsorption and desorption wallpaper, further comprise：
It is stacked on the second inorganic bond oxidant layer in the first inorganic powder last layer；
The second inorganic powder last layer in the second inorganic bond oxidant layer is stacked on,
Therefore, the sealer is stacked in the second inorganic powder last layer.
3. the adsorption and desorption wallpaper of claim 1, wherein the basalis is made up of supatex fabric, the nonwoven
Thing is made up of paper pulp and polyester, ceramic paper or glassine paper.
4. the adsorption and desorption wallpaper of claim 3, wherein the per unit area quality that the basalis has is 60-80g/
m2。
5. the adsorption and desorption wallpaper of claim 1, wherein bio-resin layer is formed from a resin, the resin includes choosing
From following one or more：Cellulose, chitin, starch, PLA (PLA), polyhydroxyalkanoatefrom (PHA), hydroxyl fourth
Sour valerate (PHBV), polyvinyl alcohol (PVA), polyglycolic acid (PGA), polybutylene succinate (PBS), polyadipate fourth two
Alcohol ester-copolymerization-butylene succinate (PBSA), polyadipate mutual-phenenyl two acid bromide two alcohol ester (PBAT), polycaprolactone
(PCL) it is, poly- (ester-acid amide) and poly- (ester-carbamate).
6. the adsorption and desorption wallpaper of claim 1, wherein bio-resin layer is formed by the following method：It will be used for
Citric acid, the CaCO of 10-150 parts by weight of the 10-50 parts by weight of the PLA resin of 100 parts by weight3, 1-10 parts by weight propylene
Acid copolymer and the stearic acid of 1-5 parts by weight are mixed；At a temperature of 90-200 DEG C the mixture is ground using grinder；
And rolled or extruded.
7. the adsorption and desorption wallpaper of claim 2, wherein：
The first inorganic powder last layer and the second inorganic powder last layer include mineral grain, and the mineral grain is included selected from following
It is one or more：Talcum, mica, clay, Woelm Alumina, sodium metasilicate and calcium silicates, and
The inorganic powder last layer is formed by scattering.
8. the adsorption and desorption wallpaper of claim 1, wherein the sealer has penetrability and uses wipe method
Formed by coating.
9. the method for adsorption and desorption wallpaper is prepared, including：
Form basalis；
Coated on the basalis and stack bio-resin layer；
Wherein described bio-resin layer includes citric acid, the 10- of the 10-50 parts by weight of the PLA resin relative to 100 parts by weight
The CaCO of 150 parts by weight3, 1-10 parts by weight acrylic copolymer and the stearic acid of 1-5 parts by weight；
Inorganic bond oxidant layer is formed by spraying inorganic bond on bio-resin layer；
Inorganic powder last layer is formed by scattering inorganic substances in the inorganic bond oxidant layer；And
Sealer is formed in the inorganic powder last layer using wipe method,
Wherein described sealer is 2 using part by weight:8 acrylic resin and methyl ethyl ketone is formed.
10. the method for adsorption and desorption wallpaper is prepared, including：
Form basalis；
Bio-resin layer is coated and stacked on the basalis；
Wherein described bio-resin layer includes citric acid, the 10- of the 10-50 parts by weight of the PLA resin relative to 100 parts by weight
The CaCO of 150 parts by weight3, 1-10 parts by weight acrylic copolymer and the stearic acid of 1-5 parts by weight；
The first inorganic bond oxidant layer is formed by spraying inorganic bond on bio-resin layer；
The first inorganic powder last layer is formed by scattering inorganic substances in the first inorganic bond oxidant layer；
The second inorganic bond oxidant layer is formed by spraying inorganic bond in the first inorganic powder last layer；
The second inorganic powder last layer is formed by scattering inorganic substances in the second inorganic bond oxidant layer；
Sealer is formed in the second inorganic powder last layer using wipe method,
Wherein described sealer is 2 using part by weight:8 acrylic resin and methyl ethyl ketone is formed.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020130072131A KR101848949B1 (en) | 2013-06-24 | 2013-06-24 | Absorption-desorption wallpaper |
| KR10-2013-0072131 | 2013-06-24 | ||
| PCT/KR2014/005463 WO2014208934A1 (en) | 2013-06-24 | 2014-06-20 | Absorption and desorption wallpaper and method of manufacturing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105358767A CN105358767A (en) | 2016-02-24 |
| CN105358767B true CN105358767B (en) | 2017-10-17 |
Family
ID=52142212
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480035907.XA Active CN105358767B (en) | 2013-06-24 | 2014-06-20 | Adsorption and desorption wallpaper and preparation method thereof |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP2976461B1 (en) |
| JP (1) | JP6168437B2 (en) |
| KR (1) | KR101848949B1 (en) |
| CN (1) | CN105358767B (en) |
| WO (1) | WO2014208934A1 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105586809A (en) * | 2016-01-29 | 2016-05-18 | 太仓卡斯特姆新材料有限公司 | Environment-friendly adsorption type moisture-proof wallpaper |
| CN107556536B (en) * | 2017-09-12 | 2021-02-12 | 江苏金聚合金材料有限公司 | Low-cost bio-based fully-degradable film and preparation method thereof |
| CN108914706B (en) * | 2018-07-26 | 2020-06-16 | 山东汇高智慧纺织科技有限公司 | Environment-friendly wallpaper capable of adsorbing formaldehyde |
| CN108951300A (en) * | 2018-07-26 | 2018-12-07 | 武汉菡美洛建筑材料有限公司 | A kind of Environment-friendlywallpaper wallpaper with photocatalysis performance |
| CN108914707B (en) * | 2018-07-26 | 2020-08-18 | 罗仙花 | Environment-friendly wallpaper capable of adsorbing photocatalytic degradation organic matters and preparation method thereof |
| CN108951299B (en) * | 2018-07-26 | 2020-08-18 | 罗仙花 | Brown-black environment-friendly wallpaper and preparation method thereof |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60164502U (en) * | 1984-04-11 | 1985-11-01 | 菊水化学工業株式会社 | wall covering sheet |
| CN2158886Y (en) * | 1993-07-03 | 1994-03-16 | 沈志坚 | Holographic art wall paper |
| DE19515517C2 (en) * | 1995-04-27 | 1997-08-14 | Johnson & Johnson Gmbh | Method and device for the continuous production of lengths from a strand of liquid-absorbent material and its use |
| KR100280334B1 (en) * | 1998-03-30 | 2001-05-02 | 박미애 | Biodegradable Wallpaper |
| JP2000320026A (en) * | 1999-05-07 | 2000-11-21 | Ykk Architectural Products Inc | Gas adsorption panel for construction |
| JP4863180B2 (en) * | 2000-12-27 | 2012-01-25 | 大塚化学株式会社 | Water-based paint and wallpaper for wallpaper |
| WO2007102647A1 (en) * | 2006-03-06 | 2007-09-13 | Lg Chem, Ltd. | Breathable wall covering including olefin material and production method thereof |
| JP4895843B2 (en) * | 2007-02-01 | 2012-03-14 | アキレス株式会社 | Anti-stain hygroscopic wallpaper |
| US20090286090A1 (en) * | 2008-05-19 | 2009-11-19 | Ting Yuan-Ping R | Enhance performance on current renewable film using functional polymer coatings |
| KR101342218B1 (en) * | 2008-10-30 | 2013-12-16 | (주)엘지하우시스 | Bio-wallpapers and preparation methods thereof |
| JP5074462B2 (en) * | 2009-06-30 | 2012-11-14 | 山天東リ株式会社 | Paper wallpaper |
| KR101233995B1 (en) * | 2009-12-23 | 2013-02-18 | (주)엘지하우시스 | Humidity controlling wallpaper with fire resistance |
| CN102345249B (en) * | 2010-08-06 | 2015-06-03 | 范晓星 | Photocatalytic wallpaper for indoor air purification |
| KR101643001B1 (en) * | 2010-10-07 | 2016-08-11 | 금호석유화학 주식회사 | The environmental-friendly wallpaper compositions which resolve the indoor polluted air environment and manufacturing method thereof |
-
2013
- 2013-06-24 KR KR1020130072131A patent/KR101848949B1/en active IP Right Grant
-
2014
- 2014-06-20 WO PCT/KR2014/005463 patent/WO2014208934A1/en active Application Filing
- 2014-06-20 JP JP2016513885A patent/JP6168437B2/en active Active
- 2014-06-20 EP EP14817141.6A patent/EP2976461B1/en active Active
- 2014-06-20 CN CN201480035907.XA patent/CN105358767B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP2976461B1 (en) | 2018-10-24 |
| EP2976461A4 (en) | 2016-12-21 |
| JP6168437B2 (en) | 2017-07-26 |
| CN105358767A (en) | 2016-02-24 |
| EP2976461A1 (en) | 2016-01-27 |
| WO2014208934A1 (en) | 2014-12-31 |
| KR20150000127A (en) | 2015-01-02 |
| JP2016525960A (en) | 2016-09-01 |
| KR101848949B1 (en) | 2018-05-28 |
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