CN105342932B - A kind of all natural multifunctional liquid soap and its production method containing carboxymethyl chitosan - Google Patents
A kind of all natural multifunctional liquid soap and its production method containing carboxymethyl chitosan Download PDFInfo
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- CN105342932B CN105342932B CN201510912095.9A CN201510912095A CN105342932B CN 105342932 B CN105342932 B CN 105342932B CN 201510912095 A CN201510912095 A CN 201510912095A CN 105342932 B CN105342932 B CN 105342932B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/63—Steroids; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/736—Chitin; Chitosan; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/005—Antimicrobial preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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Abstract
A kind of all natural multifunctional liquid soap and its production method containing carboxymethyl chitosan, it is related to articles for washing technical field, first carboxymethyl chitosan is dissolved completely in deionized water, then saponin is added and tea polyphenols stirs evenly, system to be mixed is cooled to room temperature, viscosity, then homogeneous, degassing, packing are adjusted with lemon juice solution adjustment pH to 6.0~6.5, with natural pigment toning, with sodium chloride solution.The requirement of the method for the present invention technique is low, and preparation process is simple and environmentally-friendly, and product stability is good, existing cleaning decontamination, and has antibiotic and sterilizing, moistens nursing skin.
Description
Technical field
The present invention relates to articles for washing technical field more particularly to the production technical fields of hand cleanser.
Technical background
Hand cleanser is a kind of daily articles for washing, many kinds of, but hand cleanser all contains a certain amount of chemistry conjunction at present
At ingredient.The substances such as excessive synthetic surfactant, preservative, organic solvent are contacted, stimulation skin is easy, causes skin
The problems such as skin allergy, contact dermatitis, will cause injury to skin, and can also generate to human health certain direct or indirect
Influence, then can cause environmental pollution, so existing hand cleanser is no longer satisfied people for health, antibacterial, strong
Various demands such as health, beauty, environmental protection need to develop towards green, environmental protection, renewable direction.
Chitosan is that unique a large amount of existing basic amine group polysaccharide, carboxymethyl chitosan are that a kind of both sexes are poly- in natural polysaccharide
The chitosan derivatives of electrolyte.Carboxymethyl chitosan not only has the advantageous property of chitosan, also has good water solubility,
Application range is more extensive.It has excellent antibiotic property, thickening property, dispersibility, emulsibility, moisture retention, film forming, gelation etc.
Performance；With many good characteristics such as itself zero toxicity, good biocompatibility and degradabilities；In addition chitosan and its derivative
Object can also inhibit the growth and breeding of fungi, bacterium and virus, have good broad-spectrum sterilization.Its carboxyl of carboxymethyl chitosan and ammonia
Base is hydrophilic radical, stronger water imbibition, and 0.25% aqueous solution wettability is suitable with 20% propylene glycol, has good moisturizing
Property, and it and hyaluronic acid have quite similar molecular structure, and performance is suitable with hyaluronic acid, is expected to substitution hyalomitome
Acid.
Chinese honey locust also known as honey locust are one of distinctive Caesalpiniaceae Gleditsia tree species in China, and Qin Han dynasty people begin to use
Gleditsia sinensis carrys out washed and hair, has formed convention to Tang, Sui.Gleditisia sinensis Saponin is the triterpenoid saponin for being widely present in Gleditsia, is one
The excellent natural nonionic surfactant of class, is optimal natural cleaning agent.Chinese honey locust is resourceful in China, and southwest is only
Wild Chinese honey locust annual output contains 15%~32% saponin with regard to tons up to ten thousand in Chinese honey locust fruit, so Gleditisia sinensis Saponin has as raw material
Wide, resourceful, the cheap feature in source.In addition, Gleditisia sinensis Saponin is in neutrality, the strong foaming abundancy of surface-active, nontoxic
Secondary pollution is not generated to environment using safe, non-stimulated to skin, degradable, in addition to washing function, there are also health care and
Sterilizing function.It also has the performances such as emulsibility, dispersibility, solubility, impregnability as plant surface activating agent, is better than appointing
What chemical, thus have very high Development volue.
Tea polyphenols are the general names of Polyphenols of Tea, have the formation for stopping ultraviolet light, inhibiting melanin；It removes certainly
By base, anti-skin oxidative；Greasy, convergence pore and other effects is removed, experiment shows tea polyphenols to the clearance rate of active oxygen radical
Up to 98% or more, in addition to hay bacillus, staphylococcus aureus, Escherichia coli, the routed sore of tomato, S.mutans and Mucor
Bacterium, Penicillium notatum, gibberella, anthrax bacteria, saccharomyces cerevisiae etc. have inhibits bactericidal property well, and there is good anti-corrosion to make
With, and free from extraneous odour, the features such as having no toxic side effect.
Plants essential oil is a kind of plant source secondary metabolites, is a kind of biologically active chemical substance.Botany
Upper to be known as essential oil, commercial title aromatic oil and pharmaceutically claims volatile oil at chemistry.By aldehyde, alcohol, ketone, phenol, alkene, monoterpene, diterpene and
The chemical moleculars such as sequiterpene composition, chemical component are considerably complicated.With inside and outside promotion Lymphatic Circulation, removing toxin, adjusting points
Secrete gland, promote histocyte regeneration and other effects.The annual essential oil total output in China reaches 20000 tons of 15000-, for a long time natural essence
Oil is exactly one of raw material of daily chemical products, commonly used to prepare essence, perfume, but with research go deep into and people are raw
The raising of bioplasm amount and the reinforcement of environmental consciousness, plants essential oil desinsection, antibacterial and in terms of function, be also increasingly subject to
The concern and attention of people, therefore the application of plants essential oil is also gradually expanded.
Summary of the invention
The purpose of the present invention is mention for defect and the deficiencies in the prior art present in current hand cleanser recited above
It is a kind of without any chemical synthesis ingredient out, existing cleaning decontamination, and it is multi-functional with antibiotic and sterilizing, moist nursing skin etc.
Health, environmental protection all natural hand cleanser.
The present invention includes carboxymethyl chitosan, saponin, tea polyphenols, natural pigment, sodium chloride, lemon juice and deionized water,
The carboxymethyl chitosan accounts for the 0.5~2.0% of hand cleanser gross mass, saponin, and to account for the 6.0~12.0% of hand cleanser gross mass, tea more
Phenol, which accounts for the 0.2~1.0% of hand cleanser gross mass, natural pigment and accounts for the 0.05~0.2% of hand cleanser gross mass, sodium chloride, accounts for hand cleanser
The 0.1~1.0% of gross mass.
Superiority of the invention:
1. the present invention utilizes the functions such as the strong surface-active, antibacterial, emulsification of natural saponin；Carboxymethyl chitosan thickening resists
The functions such as bacterium, moisturizing；Tea polyphenols are anti-oxidant, restrain the functions such as pore, antibacterial；Toning effect of natural plant pigment etc., it is pure
Natural manufacture, without any chemical synthesis ingredients such as artificial essence, pigment, synthetic preservative, organic solvents.
2. the present invention have adequately cleaning dirt-removing power, foaming abundancy and stablize, Yi Chongxi, can be in hard water and room temperature item
The washing effect having had under part, product have certain viscosity, can stop on hand, the simple and elegant fragrance of smell.
3. product of the present invention subacidity, non-stimulated to skin, safe without toxic side effect；Product antibiotic and sterilizing also has taste concurrently
Profit nursing and improvement skin metabolism mitigate and prevent the functions such as chap, and various personages is suitble to use.
4. product of the present invention good biocompatibility, environmentally protective；Raw material resources are abundant, and price is less expensive.
Further, the invention also includes add natural refined plant oil, natural plant essential oils or hydrosol.The addition day
Right refined plant oil accounts for the 0.5~2.0% of hand cleanser gross mass.
Refined plant oil has to skin care, soft and smooth and moist etc. excellent results；And plants essential oil has to cytothesis, resists
The multiple efficacies such as bacterium and anti-corrosion, light pleasant adjustment odor type.
The present invention is another object is that propose the production method of all natural multifunctional liquid soap.
The method of the present invention is: under 40~65 DEG C of stirrings, carboxymethyl chitosan being first dissolved completely in deionized water
In, saponin then is added and tea polyphenols stir evenly, system to be mixed is cooled to room temperature, and adjusts pH to 6.0 with lemon juice solution
~6.5, viscosity, then homogeneous, degassing, packing are adjusted with natural pigment toning, with sodium chloride solution.It is total that the saponin accounts for hand cleanser
The quality that feeds intake 6.0~12.0%, carboxymethyl chitosan accounts for hand cleanser the 0.5~2.0% of the quality, tea polyphenols that always feed intake and accounts for hand cleanser
The quality that always feeds intake 0.2~1.0%, natural pigment account for hand cleanser always feed intake quality 0.05~0.2%, that sodium chloride accounts for hand cleanser is total
The 0.1~1.0% of the quality that feeds intake.
The requirement of the method for the present invention technique is low, and preparation process is simple and environmentally-friendly, and product stability is good.
In addition, being additionally added natural refined plant oil, the natural refined plant oil of addition when saponin and tea polyphenols are added
It accounts for hand cleanser and always feeds intake the 0.5~2.0% of quality.
Essential oil is made of chemical moleculars such as terpenes, aldehydes, esters, alcohols, because of high fluidity, is known as " oil "；
Vegetable oil main component is triglyceride and fatty acid composition, and the two has difference substantially.
Vegetable oil also has part from the leaf of plant, stem, root and spends mainly from the fruit and seed of plant.It
Right enriched vegetable oil is suitable in various formulas, as people increasingly tend to " back to nature advocates green ", Yi Jizhi
Object extracts and the raising of purification technique, and the application of crude vegetal gradually becomes hot spot.Addition vegetable oil is main in this recipe
Rise skin care, it is soft and smooth and moist the effects of, do not dried after washing.
Natural plant essential oils have the characteristics that low boiling point and volatile.Some of chemical components have thermal sensitivity, especially
It is that some lipoid substance heat resistances are poor.The present invention is used is added natural plant essential oils or hydrosol before adjusting viscosity.
Illustrate the difference of natural plant essential oils and natural plants hydrosol:
Hydrosol, also known as crystal oil are the distillation stoste that the one kind 100% separated when refining essential oil is saturated, are essential oils
A kind of byproduct.The ingredient of a variety of preciousnesses in plant is incorporated in hydrosol water, and water-soluble containing about 0.3~0.5% essential oil
Ingredient, so still possessing the fragrance of essential oil, part curative effect and slight antibiotic property, and the unexistent plant essence containing essential oil
(such as tannic acid and flavonoids).Hydrosol, which has, to be adjusted, purifies, anti-inflammatory, astriction, is controlled fat secretion, is added dark sore wound
Fast healing, oiliness, dark sore skin are especially suitable.It plays the role of similar and effect with plants essential oil itself, and composition is natural
Pure, fragrance is light pleasant.There is certain complementary effect between hydrosol and corresponding essential oil, collocation is using can allow effect more preferable.
The present invention such as uses hydrosol, then price is cheap compared with essential oil, and production cost is more advantageous.
Saponin of the present invention is Gleditisia sinensis Saponin or Tea Saponin；The natural pigment is that S. haematocheir Huang, safflower yellow, purple are red
In potato, turmeric, cochineal or monascorubin at least any one.
The lemon juice is that deionized water dilutes after Fresh Lemon is squeezed, takes juice, is clarified with carboxymethyl chitosan solution
The supernatant obtained.
The natural refined plant oil is grape seed oil, evening primrose oil, rose hip oil, Sweet Almond Oil, hippophae rhamnoides fruit oil or lotus
In lotus bar oil at least any one, the natural plant essential oils or hydrosol are tea tree, peppermint, folium eucalypti, camphor tree, fish pelargonium, silk
In cypress, ginger essential oil or Jiang Chunlu at least any one.
Specific embodiment
Further illustrate that technical solution of the invention, embodiment are not to be construed as With reference to embodiment
Limitation to technical solution.
One, preparation process:
Embodiment 1: weighing 1kg deionized water and be added in flask, be heated to 40~65 DEG C (this example use 55 DEG C), first plus
Enter the stirring of 10g carboxymethyl chitosan to make it completely dissolved, adds 60.0g saponin, 4.0g tea polyphenols stir evenly, drop to room temperature
Pink is adjusted to lemon juice adjustment solution ph to 6.0, with natural lanigerin afterwards, 1mL tea tree ethereal oil adjustment odor type, is delayed
The sodium chloride solution of slow addition 5% is adjusted to moderate viscosity, then homogeneous, degassing, packing.
Embodiment 2: weighing 8kg deionized water and be added in reaction kettle, is heated to 40~65 DEG C (this example uses 45 DEG C), first
The stirring of 0.1kg carboxymethyl chitosan is added to make it completely dissolved, adds 0.9kg saponin, 0.05kg tea polyphenols, 60mL grape pip
Oil stirs evenly, drop to after room temperature with lemon juice adjust solution ph to 6.5, with neutral red Gardenia Yellow be adjusted to it is amber,
10mL natural Peppermint essential oil adjustment odor type is slowly added to 5% sodium chloride solution and adjusts to moderate viscosity, is supplied with deionized water
To 10Kg, then homogeneous, degassing, packing.
Embodiment 3,4,5,6:
Other conditions only adjust each raw material dosage referring to embodiment 2.
Product of the present invention main component additive amount (finished product is in terms of 1 kg)
In addition, Gleditisia sinensis Saponin or Tea Saponin can be used in the saponin in above each example.
Natural pigment can be used in S. haematocheir Huang, safflower yellow, purple sweet potato, turmeric, cochineal or monascorubin extremely
Lack any one.
Lemon juice is that deionized water dilutes after Fresh Lemon is squeezed, takes juice, is clarified with carboxymethyl chitosan solution
Supernatant.
Natural refined plant oil is grape seed oil, evening primrose oil, rose hip oil, Sweet Almond Oil, hippophae rhamnoides fruit oil or Jojoba
In oil at least any one.
Natural plant essential oils or hydrosol are in tea tree, peppermint, folium eucalypti, camphor tree, fish pelargonium, cypress, ginger essential oil or Jiang Chunlu
At least any one.
Two, product testing result:
Following table is the main indicators testing results such as sense organ, physicochemical property, the microorganism of 2 product of embodiment.
After testing, this product indices meet QB 2654-2004 relevant national standard.
Indices detection is carried out to implement 1,3,4,5,6, it is as a result similar.
Claims (9)
1. a kind of all natural hand cleanser containing carboxymethyl chitosan, it is characterised in that more including carboxymethyl chitosan, saponin, tea
Phenol, natural pigment, sodium chloride, lemon juice and deionized water, the carboxymethyl chitosan account for hand cleanser gross mass 0.5~
2.0%, saponin accounts for the 6.0~12.0% of hand cleanser gross mass, tea polyphenols and accounts for the 0.2~1.0% of hand cleanser gross mass, natural pigment
It accounts for the 0.05~0.2% of hand cleanser gross mass, sodium chloride and accounts for the 0.1~1.0% of hand cleanser gross mass；The saponin is Gleditisia sinensis Saponin
Or Tea Saponin.
2. hand cleanser according to claim 1, it is characterised in that further include natural refined plant oil, the natural refined plant
Oil accounts for the 0.5~2.0% of hand cleanser gross mass.
3. hand cleanser according to claim 1 or claim 2, it is characterised in that further include natural plant essential oils or hydrosol.
4. the production method of all natural hand cleanser as described in claim 1, it is characterised in that under 40~65 DEG C of stirrings, first
Carboxymethyl chitosan is dissolved completely in deionized water, saponin then is added and tea polyphenols stir evenly；System drop to be mixed
To room temperature, viscosity is adjusted with lemon juice solution adjustment pH to 6.0~6.5, with natural pigment toning, with sodium chloride solution, then
Homogeneous, degassing, packing；The carboxymethyl chitosan accounts for hand cleanser the 0.5~2.0% of the quality, saponin that always feeds intake and accounts for hand cleanser and always throw
Material quality 6.0~12.0%, tea polyphenols account for hand cleanser the 0.2~1.0% of the quality, natural pigment that always feeds intake and account for hand cleanser and always feed intake
Quality 0.05~0.2%, sodium chloride accounts for hand cleanser and always feeds intake the 0.1~1.0% of quality.
5. the production method of all natural hand cleanser according to claim 4, it is characterised in that when saponin and tea polyphenols are added,
It is additionally added natural refined plant oil, the natural refined plant oil accounts for hand cleanser and always feeds intake the 0.5~2.0% of quality.
6. the production method of all natural hand cleanser according to claim 5, it is characterised in that before adjusting viscosity, natural plant is added
Object essential oil or hydrosol.
7. the production method of all natural hand cleanser according to claim 4, it is characterised in that the natural pigment is S. haematocheir
In Huang, safflower yellow, purple sweet potato, turmeric, cochineal or monascorubin at least any one.
8. the production method of all natural hand cleanser according to claim 4, it is characterised in that the lemon juice is Fresh Lemon
It is diluted after being squeezed, taking juice with deionized water, the supernatant clarified with carboxymethyl chitosan solution.
9. the production method of all natural hand cleanser according to claim 6, it is characterised in that the natural refined plant oil is
In grape seed oil, evening primrose oil, rose hip oil, Sweet Almond Oil, hippophae rhamnoides fruit oil or SIMMONDSIA CHINENSIS SEED OIL at least any one, the day
Right plants essential oil or hydrosol are at least any in tea tree, peppermint, folium eucalypti, camphor tree, fish pelargonium, cypress, ginger essential oil or Jiang Chunlu
It is a kind of.
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107496206A (en) * | 2016-06-14 | 2017-12-22 | 中国科学院理化技术研究所 | A kind of chitosan derivatives base children special-purpose non-water hand cleanser and preparation method thereof |
| CN105997826A (en) * | 2016-07-18 | 2016-10-12 | 鄢海军 | Nano-silver-containing traditional Chinese medicine liquid soap for infants and children |
| CN106265380A (en) * | 2016-10-14 | 2017-01-04 | 柳州立洁科技有限公司 | A kind of handwashing liquid |
| CN106726956A (en) * | 2016-12-23 | 2017-05-31 | 严志海 | A kind of antibacterial skin moistening liquid soap and preparation method thereof |
| CN108165378A (en) * | 2017-11-23 | 2018-06-15 | 汪锦川 | A kind of manufacture of pure natural liquid detergent and processing technology |
| CN112391242A (en) * | 2020-11-16 | 2021-02-23 | 四川宸煜林业开发有限责任公司 | Laundry detergent containing camphor oil component and preparation method thereof |
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| CN1696145A (en) * | 2005-04-29 | 2005-11-16 | 北京林业大学 | Technique for preparing saponin of gleditschia horrida and application |
| CN103006459A (en) * | 2012-12-20 | 2013-04-03 | 青岛海芬海洋生物科技有限公司 | Washing-free degerming liquid for hands and preparation method of degerming liquid |
| CN103816058A (en) * | 2012-11-18 | 2014-05-28 | 镇江新区雨泰香茗园艺专业合作社 | Facial cleanser containing tea polyphenol and tea saponin and preparation method of facial cleanser |
| CN104288026A (en) * | 2014-09-27 | 2015-01-21 | 张乔木 | Hand sanitizer and preparation method thereof |
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| CN1696145A (en) * | 2005-04-29 | 2005-11-16 | 北京林业大学 | Technique for preparing saponin of gleditschia horrida and application |
| CN103816058A (en) * | 2012-11-18 | 2014-05-28 | 镇江新区雨泰香茗园艺专业合作社 | Facial cleanser containing tea polyphenol and tea saponin and preparation method of facial cleanser |
| CN103006459A (en) * | 2012-12-20 | 2013-04-03 | 青岛海芬海洋生物科技有限公司 | Washing-free degerming liquid for hands and preparation method of degerming liquid |
| CN104288026A (en) * | 2014-09-27 | 2015-01-21 | 张乔木 | Hand sanitizer and preparation method thereof |
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