CN105325433A - Insecticidal composition containing cyhalodiamide and padan - Google Patents
Insecticidal composition containing cyhalodiamide and padan Download PDFInfo
- Publication number
- CN105325433A CN105325433A CN201410385018.8A CN201410385018A CN105325433A CN 105325433 A CN105325433 A CN 105325433A CN 201410385018 A CN201410385018 A CN 201410385018A CN 105325433 A CN105325433 A CN 105325433A
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- China
- Prior art keywords
- pesticidal combination
- cartap
- insect amide
- chlorine fluorine
- cyanogen insect
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- NNRSYETYEADPBW-UHFFFAOYSA-N cyhalodiamide Chemical compound CC1=CC(C(F)(C(F)(F)F)C(F)(F)F)=CC=C1NC(=O)C1=CC=CC(Cl)=C1C(=O)NC(C)(C)C#N NNRSYETYEADPBW-UHFFFAOYSA-N 0.000 title abstract description 7
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- NAMPHRGXOPFKSX-UHFFFAOYSA-L S(=O)(=O)(O)C(C(=O)[O-])CC(=O)[O-].[Na+].[Na+].C(CCCCC(C)C)O Chemical compound S(=O)(=O)(O)C(C(=O)[O-])CC(=O)[O-].[Na+].[Na+].C(CCCCC(C)C)O NAMPHRGXOPFKSX-UHFFFAOYSA-L 0.000 description 1
- 241000258242 Siphonaptera Species 0.000 description 1
- 241000180219 Sitobion avenae Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 241001414989 Thysanoptera Species 0.000 description 1
- 241000018137 Trialeurodes vaporariorum Species 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- RRTCFFFUTAGOSG-UHFFFAOYSA-N benzene;phenol Chemical compound C1=CC=CC=C1.OC1=CC=CC=C1 RRTCFFFUTAGOSG-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 230000003592 biomimetic effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000021329 brown rice Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 210000003169 central nervous system Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 150000001470 diamides Chemical class 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 229960000878 docusate sodium Drugs 0.000 description 1
- VICYBMUVWHJEFT-UHFFFAOYSA-N dodecyltrimethylammonium ion Chemical class CCCCCCCCCCCC[N+](C)(C)C VICYBMUVWHJEFT-UHFFFAOYSA-N 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 210000005069 ears Anatomy 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000001586 eradicative effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229960005082 etohexadiol Drugs 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000008141 laxative Substances 0.000 description 1
- 230000002475 laxative effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 235000011147 magnesium chloride Nutrition 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- PYLWMHQQBFSUBP-UHFFFAOYSA-N monofluorobenzene Chemical compound FC1=CC=CC=C1 PYLWMHQQBFSUBP-UHFFFAOYSA-N 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 230000004118 muscle contraction Effects 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000008177 pharmaceutical agent Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- NAYYNDKKHOIIOD-UHFFFAOYSA-N phthalamide Chemical class NC(=O)C1=CC=CC=C1C(N)=O NAYYNDKKHOIIOD-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 102000042094 ryanodine receptor (TC 1.A.3.1) family Human genes 0.000 description 1
- 108091052345 ryanodine receptor (TC 1.A.3.1) family Proteins 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 108700004121 sarkosyl Proteins 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to the field of agriculture, in particular to an insecticidal composition, especially relates to an insecticidal composition containing cyhalodiamide and padan and application thereof. The insecticidal composition containing cyhalodiamide and padan is characterized by comprising active components of cyhalodiamide and padan in the weight ratio of 100:1-1:100. The invention also relates to an insecticidal composition comprising the insecticidal components of cyhalodiamide and padan, agriculturally acceptable additives and / or a carrier, and a method and application of the composition in control of agricultural pests.
Description
Technical field
What the present invention relates to is agriculture field, is specifically related to a kind of Pesticidal combination, particularly a kind of Pesticidal combination and application thereof containing chlorine fluorine cyanogen insect amide and cartap.
Background technology
The resistance problem of pest is global problems.Along with the impact of the prolongation of pest chemical control medication history, the agricultural chemicals not factor such as scientifical use, in recent years, pest resistance is day by day serious, the pest species producing resistance is continuing to increase, particularly very easily produce resistance Lepidoptera class pest, resistance level is higher, and resistance development speed is relatively very fast.Agriculture chemical compounding or mixture have expansion insecticidal spectrum, delay the feature such as pest resistance and pesticide resistance, are to solve pest resistance problem comparatively one of effective method.Therefore, the Pesticidal combination of efficient, the low toxicity of research and development, environmental protection has positive effect to agricultural sustainable development.
Chlorine fluorine cyanogen insect amide (ZJ4042, Cas.NO:1262605-53-7) be the phthalic diamides insecticide that Zhejiang Provincial Chemical Engineering Research Inst is developed, it is the novel pesticide of a kind of efficient, low toxicity and mechanism of action uniqueness, it acts on insect ryanodine receptor, impel the endogenous calcium ion release of insect cell, affect contraction of muscle, and then cause insect death; To the larva of Lepidoptera, coleoptera, diptera and Homoptera, there is very high activity, but main effect model is based on stomach toxicity, has certain interior absorption, can be used for the primary pest control of paddy rice, vegetables, fruit tree, cotton.
Cartap (cartap, Cas.NO:15263-53-3) is the biomimetic insecticide of simulation neires toxin synthesis; There is stomach toxicity, tag and systemic action, also have certain ovicidal action; Speed knocked down to insect fast, there is the longer lasting period, after entering polypide, change nereistoxin into, central nervous system cynapse can be blocked and transmit impulsion, insect is slow in action, food refusal, polypide is softened, dead after 3 ~ 5 days.Insecticidal spectrum is wide, can be used for preventing and treating various pests and the nematodes such as Lepidoptera, coleoptera, Semiptera, diptera.Be mainly used in water prevention chilo suppressalis, paddy stem borer, paddy stem maggot etc., also for preventing and treating cabbage caterpillar, the diamond-back moth of vegetables, the heart-eating worm of fruit tree, leaf miner, the lepidoptera pest on tea tree and corn borer, potato tuberworm etc.
Paddy rice is mankind's staple food crops, and countries in the world have plantation and area is extensive.Rice-stem borer is one of important insect pest of paddy rice, and rice plant of tillering stage, booting stage and heading stage all can endanger, and causes withered heart seedling, withered sheath, withered booting or dead ears, and then causes the underproduction, even have no harvest.Because striped rice borer is a kind of borer pest, get a grip on Control stage extremely important, and peasant sees that the withered heart or withered fringe just start laxative, this needs medicament to have comparatively strong interior absorption.In recent years, the report all creating resistance to more and more medicament about striped rice borer is continuous.Chlorine worm benzene insect amide and the listing of fluorobenzene insect amide class medicament become the major pharmaceutical agent of water prevention chilo suppressalis after promoting.Phthalic diamides agent activity is high, killing action strong, have certain osmosis; But there is the shortcoming that dead worm speed slowly, easily develops immunity to drugs, so the pharmacy mix strong with good, the interior absorption of quick-acting is needed to strengthen effect and delaying drug resistance.
Summary of the invention
The present invention seeks to provide a kind of Pesticidal combination containing chlorine fluorine cyanogen insect amide and cartap for above-mentioned weak point.
The present inventor have passed through long-term research, and finds unexpectedly on the basis of great many of experiments, by chlorine fluorine cyanogen insect amide and cartap composite after, produce synergistic function, effectively can prevent and treat pest, and can effectively delay pest resistance development.
Therefore, technical problem to be solved by this invention is to provide a kind of Synergistic composition can effectively prevented and treated pest, delay can reduce the while that pest resistance to insecticide developing drug cost.
In order to solve the problem, the present invention adopts following technical scheme:
Contain a Pesticidal combination for chlorine fluorine cyanogen insect amide and cartap, it is characterized in that, described Pesticidal combination contains active component chlorine fluorine cyanogen insect amide and cartap.
In described Pesticidal combination, the weight ratio of active component chlorine fluorine cyanogen insect amide and cartap is 100:1 to 1:100.
Preferably, in described Pesticidal combination, the weight ratio of active component chlorine fluorine cyanogen insect amide and cartap is 50:1 to 1:50, preferably 25:1 to 1:25, more preferably 10:1 to 1:10, especially preferably 5:1 to 1:5.
Another object of the present invention is for providing a kind of Pesticidal combination comprising above-mentioned active component chlorine fluorine cyanogen insect amide and cartap and agriculturally acceptable auxiliary agent and/or carrier.
Wherein, in above-mentioned Pesticidal combination, the weight content that described active component chlorine fluorine cyanogen insect amide and cartap account for Pesticidal combination is 1wt.% to 90wt.%, preferably 10wt.% to 80wt.%, more preferably 12wt.% to 45wt.%, especially preferably 15wt.% to 40wt.%.
Above-mentioned Pesticidal combination can be prepared into agriculturally acceptable any formulation, preferred missible oil, granule, wetting powder, water dispersible granules, suspending agent, microcapsule suspending agent, aqueous emulsion, microemulsion.
Above-mentioned formulation is this area regular dosage form, its preparation method is well known to those skilled in the art, be prepared into agricultural agent used by above-mentioned various formulation and/or carrier and consumption thereof and be similarly well-known to those skilled in the art, these all can see such as " formulations of pesticide process technology " (Liu Bulin edits, the second edition).Auxiliary agent used and/or carrier such as include but not limited to solvent, cosolvent, emulsifier, dispersant, wetting agent, adhesive, disintegrant, thickener, antifreezing agent, stabilizing agent, pH adjusting agent, filler and/or carrier etc.Those skilled in the art can select one or more auxiliary agents wherein and/or carrier, such as:
Described solvent can be selected: one or more in benzene,toluene,xylene, acetone, dimethyl formamide, dimethyl sulfoxide (DMSO), chloroform, carrene, cyclohexane, cyclohexanone, 1-METHYLPYRROLIDONE, methyl alcohol, ethanol, propyl alcohol, isopropyl alcohol, butanols, isobutanol, cyclohexanol, Propylene Glycol ether, ethohexadiol ether, benzinum, acetonitrile, paraffin, tetrahydronaphthalene, isophorone, soybean oil, cottonseed wet goods;
Described cosolvent can be selected: one or more in methyl alcohol, ethanol, isopropyl alcohol, n-butanol etc.;
Described emulsifier can be selected: lauryl sodium sulfate, neopelex, calcium dodecyl benzene sulfonate, thermally coupled distillation columns amine salt, castor oil polyoxyethylene ether phosphate amine salt, triphen ethyl phenol polyoxy ether phosphate amine salt, Polyoxyethylene fatty acid amides, Fixanol, alkyl isoquinolinium salt, dialkylmorpholinum salts, oleamide sulfonate, diisopropyl naphthalene sulfonate, lignosulfonates, naphthalenesulfonate formaldehyde condensation compound, styryl phenyl APEO, phenethyl phenol polyoxyethylene poly-oxygen propylene aether, polyoxyethylene nonylphenol ether, fatty alcohol-polyoxyethylene ether, polyoxyethylene alkyl ether, polyoxyethylene polyoxypropylene block polymer, alkyl phenol formaldehyde resin polyoxyethylene ether, Polyoxyethylene Sorbitol Fatty Acid Esters, sorbitan monostearate, sorbitan monostearate APEO, one or more in polyoxypropylene glycol mono fatty acid ester etc.,
Described dispersant can be selected: lignosulfonates, to hydroxyphenyl sodium lignin sulfonate, fatty alcohol polyoxyethylene ether sulfate, alkylnaphthalene sulfonate, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, dodecyl trimethyl ammonium salt, alkyl dimethyl benzyl ammonium salt, two polyoxyethylene lauryl ether phosphate, styrene-maleic acid salt copolymer, aliphatic alcohol polyoxyvinethene phosphate, polyoxyethylene nonylphenol ether, glycerine fatty acid APEO, polyoxyethylene alkylaryl ether, polyoxyethylene lanolin alcohol, Polyoxyethylene Sorbitan acid esters, polyoxyethylene glyceryl mono fatty acid ester, one or more in alkylolamides and polyoxyethylene alkyl amine etc.,
Described wetting agent can be selected: lauryl sodium sulfate, calcium dodecyl benzene sulfonate, isooctanol Disodium sulfosuccinate, oleoyl methyl sodium taurocholate, polyoxyethylene lauryl ether carboxylic acid sodium, sodium N-lauroyl sarcosinate, N-sodium lauroyl glutamate, dioctyl sulfosuccinate, polyoxyethylene alkylaryl ether phosphate ester salt, trisiloxanes APEO, triphenoethyl benzene phenol polyethenoxy ether, castor oil polyoxyethylene ether, fatty alcohol-polyoxyethylene ether, alkylphenol-polyethenoxy gathers base ether formaldehyde condensation products, alkylphenol-polyethenoxy base ether phosphate, polyoxyethylene fatty acid ester, higher fatty acid ester, one or more in sorbitan aliphatic ester etc.,
Described adhesive can be selected: one or more in starch, polyvinylpyrrolidone, carboxymethyl cellulose, carboxyethyl cellulose, gelatin, gum Arabic, xanthans etc.;
Described disintegrant can be selected: one or more in urea, sodium sulphate, calcium sulphate, sodium bicarbonate, ammonium sulfate, magnesium chloride, sodium chloride etc.;
Described thickener can be selected: one or more in gum Arabic, xanthans, gelatin, polyvinyl alcohol, aluminium-magnesium silicate, sodium carboxymethylcellulose etc.;
Described defoamer can be selected: one or more in butylphosphoric acid ester, phosphoric acid isobutyl ester, n-octanol, silicone etc.;
Described antifreezing agent can be selected: be selected from ethylene glycol, propane diols, glycerine etc. one or more;
Described stabilizing agent can be selected: one or more in the soybean oil based trimethylene diamine of triphenyl phosphite, N-, dialkyl group succinate sulfonate, epoxychloropropane, butyl glycidyl ether etc.;
Described preservative can be selected: one or more in benzoic acid, Sodium Benzoate etc.;
Described pH adjusting agent can be selected: one or more in hydrochloric acid, calgon, sodium citrate, sodium bicarbonate, sodium hydroxide, hydrogen-oxygen agent, triethanolamine etc.;
Described filler and/or carrier can be selected: one or more in attapulgite, diatomite, kaolin, white carbon, bentonite, montmorillonite, calcium carbonate, zeolite, acid clay, carclazyte, pyrophyllite, talcum, calcite etc.
Another object of the present invention is for providing above-mentioned Pesticidal combination for preventing or control the purposes of pest.Such as can effectively prevent and treat the pest such as Lepidoptera, diptera, coleoptera, Homoptera, orthoptera, Hymenoptera, Isoptera, Siphonaptera, Blattaria, Thysanoptera.
Described Pesticidal combination is particularly effective to following insect: diamond-back moth, cabbage caterpillar, beet armyworm, tomato moth, tobacco budworm, black peach aphid, cotten aphid, apple aphid, English grain aphid, brown back rice plant hopper, small brown rice planthopper, Bemisia tabaci, Trialeurodes vaporariorum Westwood, leafhopper, rice leafhopper, rice leaf roller, cotton bollworm, striped rice borer, paddy stem borer etc.
Described Pesticidal combination is especially effective to diamond-back moth, beet armyworm, tomato moth, cotton bollworm, striped rice borer, paddy stem borer, cotten aphid etc., particularly effective to rice-stem borer, paddy stem maggot.
Another object of the present invention is for providing a kind of method of prevention or control pest, be specially, Pesticidal combination of the present invention is contacted with described pest, or Pesticidal combination of the present invention is applied to habitat or the living environment of described pest.Concrete application process can be foliar spray, seed treatment, soil treatment etc., preferred foliar spray; Its amount of application is that those skilled in the art can determine, such as 0.1-1000gai./ha, preferred 1-200gai./ha, more preferably 10-100gai./ha.
The various compound that the present invention is used and/or reagent are commercially available, can easily buy from the market.
Beneficial effect of the present invention shows:
A, synergy: both action compensatings, synergistic effect is obvious, can reduce the dosage of the two.
B, reduction chlorine fluorine cyanogen insect amide drug cost: when chlorine fluorine cyanogen insect amide is used alone, cost is higher, and limit it to a certain extent and apply, and cartap cost is low, both combinations can reduce chlorine fluorine cyanogen insect amide dosage, and then reduce costs.
C, improve the quick-acting of chlorine fluorine cyanogen insect amide: cartap has that the speed of knocking down is fast, systemic action strong and has ovicidal action, and chlorine fluorine cyanogen insect amide takes effect slowly, the lasting period is long, after the two combination, quick-acting is good, the lasting period is long, can play the effect of effectively control striped rice borer.
The generation of D, delaying drug resistance: single dose is used alone for a long time and easily causes pest resistance degree constantly to increase, and both mechanisms of action are completely different, after combination to low age, advanced age larvae and eggs kill activity, thus delay the generation of pest resistance.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, but does not limit the invention to these embodiments.One skilled in the art would recognize that all alternatives, improvement project and the equivalents that present invention encompasses and may comprise in Claims scope.
(1) example of formulations
embodiment 118% chlorine fluorine cyanogen insect amide+2% cartap aqueous emulsion
Chlorine fluorine cyanogen insect amide 18%
Cartap 2%
Isophorone 11%
Diisopropyl naphthalene sulfonate 4%
Aliphatic alcohol polyoxyvinethene phosphate 5%
Gum Arabic 2%
Silicone 2%
Propane diols 5%
The soybean oil based trimethylene diamine 1% of N-
Water supplies 100%
Take above-mentioned each component of formula ratio respectively, then pesticide activity component, solvent, surfactant are mixed with into oil phase, other components are added to the water and are prepared into aqueous phase, then in aqueous phase, add oil phase while stirring, obtained aqueous emulsion.
embodiment 26% chlorine fluorine cyanogen insect amide+9% cartap aqueous emulsion
Chlorine fluorine cyanogen insect amide 6%
Cartap 9%
Cyclohexanone 8%
Polyoxypropylene glycol mono fatty acid ester 5%
Sodium sulfate of polyethenoxy ether of fatty alcohol 4%
Sodium carboxymethylcellulose 3%
Butylphosphoric acid ester 3%
Glycerine 5%
Water supplies 100%
Take above-mentioned each component of formula ratio respectively, then pesticide activity component, solvent, surfactant are mixed with into oil phase, other components are added to the water and are prepared into aqueous phase, then in aqueous phase, add oil phase while stirring, obtained aqueous emulsion.
embodiment 32% chlorine fluorine cyanogen insect amide+24% cartap suspending agent
Chlorine fluorine cyanogen insect amide 2%
Cartap 24%
To hydroxyphenyl sodium lignin sulfonate 6%
Castor oil polyoxyethylene ether 5%
Gum Arabic 4%
Silicone 2%
Glycerine 3%
Water supplies 100%
Take above-mentioned each component of formula ratio respectively, by ultramicro grinding method, obtained suspending agent.
embodiment 418% chlorine fluorine cyanogen insect amide+6% cartap suspending agent
Chlorine fluorine cyanogen insect amide 18%
Cartap 6%
Glycerine fatty acid APEO 4%
Alkylphenol-polyethenoxy gathers base ether formaldehyde condensation products 5%
Gelatin 3%
Phosphoric acid isobutyl ester 3%
Glycerine 4%
Water supplies 100%
Take above-mentioned each component of formula ratio respectively, by ultramicro grinding method, obtained suspending agent.
embodiment 50.1% chlorine fluorine cyanogen insect amide+10% cartap microemulsion
Chlorine fluorine cyanogen insect amide 0.1%
Cartap 10%
Dimethyl formamide 8%
Isopropyl alcohol 4%
Sorbitan monostearate APEO 12%
Aliphatic alcohol polyoxyvinethene phosphate 7%
Polyvinyl alcohol 5%
N-octanol 2%
Ethylene glycol 4%
Water supplies 100%
Take above-mentioned each component of formula ratio respectively, then pesticide activity component, solvent, cosolvent, surfactant are mixed with into oil phase, other components are added to the water and are prepared into aqueous phase, then in aqueous phase, add oil phase while stirring, obtained microemulsion.
embodiment 62% chlorine fluorine cyanogen insect amide+18% cartap is micro-
Chlorine fluorine cyanogen insect amide 2%
Cartap 18%
Tetrahydronaphthalene 10%
Isopropyl alcohol 3%
Fatty alcohol-polyoxyethylene ether 11%
Polyoxyethylene lanolin alcohol 5%
Aluminium-magnesium silicate 4%
Silicone 3%
Glycerine 5%
Butyl glycidyl ether 2%
Water supplies 100%
Take above-mentioned each component of formula ratio respectively, then pesticide activity component, solvent, cosolvent, surfactant are mixed with into oil phase, other components are added to the water and are prepared into aqueous phase, then in aqueous phase, add oil phase while stirring, obtained microemulsion.
embodiment 710% chlorine fluorine cyanogen insect amide+0.1% cartap water dispersible granules
Chlorine fluorine cyanogen insect amide 10%
Cartap 0.1%
Alkylphenol-polyethenoxy base ether phosphate 6%
Sodium lignin sulfonate 9%
Carboxymethyl cellulose 5%
Urea 4%
Kaolin supplies 100%
Take above-mentioned each component of formula ratio respectively, and mixed, granulation, obtained water dispersible granules.
embodiment 84% chlorine fluorine cyanogen insect amide+40% cartap water dispersible granules
Chlorine fluorine cyanogen insect amide 4%
Cartap 40%
Fatty alcohol polyoxyethylene ether sulfate 12%
N-sodium lauroyl glutamate 4%
Carboxyethyl cellulose 5%
Calcium sulphate 4%
Attapulgite supplies 100%
Take above-mentioned each component of formula ratio respectively, and mixed, granulation, obtained water dispersible granules.
embodiment 91% chlorine fluorine cyanogen insect amide+25% cartap wetting powder
Chlorine fluorine cyanogen insect amide 1%
Cartap 25%
To hydroxyphenyl sodium lignin sulfonate 6%
Trisiloxanes APEO 8%
Kaolin supplies 100%
Take above-mentioned each component of formula ratio respectively, and mixed, grind, pulverize, obtained wetting powder.
embodiment 102% chlorine fluorine cyanogen insect amide+28% cartap wetting powder
Chlorine fluorine cyanogen insect amide 2%
Cartap 28%
Naphthalene sulfonic acid-formaldehyde condensation product sodium salt 9%
Sorbitan aliphatic ester 4%
Diatomite supplies 100%
Take above-mentioned each component of formula ratio respectively, and mixed, grind, pulverize, obtained wetting powder.
In above embodiment, proportioning is weight per distribution ratio.
(2) biological test
There will be three kinds of situations: antagonism, addition and synergistic effect after active compound, during effect summation usually when each reactive compound of effect of active compound combinations is used separately, can think that active compound exists synergistic function.The predictive role of reactive compound by Colby formulae discovery (CalculatingSynergisticandAntagonisticResponsesofHerbicid eCombination ", Colby, S.R.; Weeds15,20-22,1967):
X=is the killing rate when using active component A with the amount of application of mppm, is expressed as the percentage of untreated control group;
Y=is the killing rate when using active component B with the amount of application of nppm, is expressed as the percentage of untreated control group;
E=is the killing rate when using active component A and B with the amount of application of m and nppm, is expressed as the percentage of untreated control group.
If the killing rate of reality is higher than calculated value, then the eradicative rate of bond has superadditivity, namely there is synergy.In this case, the killing rate actually observed must exceed the expection killing rate (E) adopting above formula to calculate.Thus, if the activity observed is greater than the activity from the expection of Colby formula, then there is synergy.
biological test example 1 striped rice borer is tested
For examination material: rice-stem borer
Medicament is prepared: chlorine fluorine cyanogen insect amide, the former medicine of cartap are used dmso solution respectively, is made into mother liquor, for subsequent use.Used time, with 10% sodium dodecyl benzene sulfonate aqueous solution, above-mentioned mother liquor is diluted to working concentration.
Test method: the various medicaments preparing concentration described in table 1 by the deionized water containing 10% neopelex respectively.Being transplanted by the rice seedlings in all for 2-3 ages is respectively in the pallet of 100cm × 100cm × 20cm into length, width and height, cellar culture.When rice seedlings grows to 6-8 leaf period, inoculate 50 rice-stem borer larvas to each pallet, then spray the medicament of various concentration shown in table 1 respectively.Wherein, each concentration is a process, often processes 3 times and repeats.The each repetition spray amount of each process consistent (spray amount amounts to about per hectare 300 liters).In each process after 7 days, investigation death condition, finally calculates lethality (test repetition 3 times, averages), the results are shown in Table 1.Wherein " observation killing rate " actual killing rate for observing, " theoretical killing rate " is the killing rate using Colby formulae discovery to obtain.
the effect test of table 1 present composition
Be not difficult to find out by the data of table 1, in the present invention, by chlorine fluorine cyanogen insect amide and cartap composite, to rice-stem borer produce synergistic effect.
biological test example 2 paddy stem maggot is tested
For examination material: paddy stem maggot larva
Medicament is prepared: chlorine fluorine cyanogen insect amide, the former medicine of cartap are used dmso solution respectively, is made into mother liquor, for subsequent use.Used time, with 10% sodium dodecyl benzene sulfonate aqueous solution, above-mentioned mother liquor is diluted to working concentration.
Test method: the various medicaments preparing concentration described in table 2 by the deionized water containing 10% neopelex respectively.Being transplanted by the rice seedlings in all for 2-3 ages is respectively in the pallet of 100cm × 100cm × 20cm into length, width and height, cellar culture.When rice seedlings grows to 6-8 leaf period, inoculate 50 paddy stem maggot larvas to each pallet, then spray the medicament of various concentration shown in table 2 respectively.Wherein, each concentration is a process, often processes 3 times and repeats.The each repetition spray amount of each process consistent (spray amount amounts to about per hectare 300 liters).In each process after 7 days, investigation death condition, finally calculates lethality (test repetition 3 times, averages), the results are shown in Table 2.Wherein " observation killing rate " actual killing rate for observing, " theoretical killing rate " is the killing rate using Colby formulae discovery to obtain.
the effect test of table 2 present composition
Be not difficult to find out by the data of table 2, in the present invention, by chlorine fluorine cyanogen insect amide and cartap composite, to paddy stem maggot produce synergistic effect.
Pesticidal combination of the present invention is described by specific embodiment.But above-mentioned example is only to further explanation of the present invention, is not limitation of the invention, by the scheme simply adjusted by such scheme and then obtain, does not depart from spirit of the present invention, be all deemed to be included within scope of the present invention.
Claims (11)
1. contain a Pesticidal combination for chlorine fluorine cyanogen insect amide and cartap, it is characterized in that, described Pesticidal combination contains active component chlorine fluorine cyanogen insect amide and cartap.
2. Pesticidal combination according to claim 1, is characterized in that, the weight ratio of described active component chlorine fluorine cyanogen insect amide and cartap is 100:1 to 1:100.
3. Pesticidal combination according to claim 1, is characterized in that, the weight ratio of described active component chlorine fluorine cyanogen insect amide and cartap is 50:1 to 1:50.
4. Pesticidal combination according to claim 1, is characterized in that, the weight ratio of described active component chlorine fluorine cyanogen insect amide and cartap is 10:1 to 1:10.
5. Pesticidal combination according to claim 1, is characterized in that, described Pesticidal combination comprises active component chlorine fluorine cyanogen insect amide according to claim 1 and cartap, and agriculturally acceptable auxiliary agent and/or carrier.
6. Pesticidal combination according to claim 5, it is characterized in that, described active component chlorine fluorine cyanogen insect amide and the cartap weight content accounted in described Pesticidal combination are 1wt.% to 90wt.%, preferably 10wt.% to 80wt.%, more preferably 12wt.% to 45wt.%.
7. Pesticidal combination according to claim 5, it is characterized in that, described Pesticidal combination is prepared into agriculturally acceptable any formulation, preferred missible oil, granule, wetting powder, water dispersible granules, suspending agent, microcapsule suspending agent, aqueous emulsion, microemulsion.
8. Pesticidal combination according to claim 1 is for preventing or control the purposes of pest.
9. purposes according to claim 8, is characterized in that, the preferred lepidoptera pest of described pest.
10. a method for prevention or control pest, is characterized in that, contacted by Pesticidal combination according to claim 1 with pest.
The method of 11. 1 kinds of preventions or control pest, is characterized in that, Pesticidal combination according to claim 1 is applied to habitat or the living environment of pest.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107136078A (en) * | 2017-06-22 | 2017-09-08 | 江苏天容集团股份有限公司 | Pesticidal combination containing chlorine fluorine cyanogen insect amide and thiocyclam |
| CN107197867A (en) * | 2017-06-22 | 2017-09-26 | 江苏天容集团股份有限公司 | Pesticidal combination containing chlorine fluorine cyanogen insect amide |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101755776A (en) * | 2009-11-17 | 2010-06-30 | 陕西汤普森生物科技有限公司 | Pesticidal composition containing cartap and flubendiamide |
| CN101935291A (en) * | 2010-09-13 | 2011-01-05 | 中化蓝天集团有限公司 | Cyano phthalic diamide compounds, preparation method thereof and use thereof as agricultural chemical pesticide |
| CN102613183A (en) * | 2012-03-07 | 2012-08-01 | 中化蓝天集团有限公司 | Insecticide |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101755776A (en) * | 2009-11-17 | 2010-06-30 | 陕西汤普森生物科技有限公司 | Pesticidal composition containing cartap and flubendiamide |
| CN101935291A (en) * | 2010-09-13 | 2011-01-05 | 中化蓝天集团有限公司 | Cyano phthalic diamide compounds, preparation method thereof and use thereof as agricultural chemical pesticide |
| CN102613183A (en) * | 2012-03-07 | 2012-08-01 | 中化蓝天集团有限公司 | Insecticide |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107136078A (en) * | 2017-06-22 | 2017-09-08 | 江苏天容集团股份有限公司 | Pesticidal combination containing chlorine fluorine cyanogen insect amide and thiocyclam |
| CN107197867A (en) * | 2017-06-22 | 2017-09-26 | 江苏天容集团股份有限公司 | Pesticidal combination containing chlorine fluorine cyanogen insect amide |
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