CN105237203B - A kind of long-acting peanut biological medicine fertilizer and preparation method thereof - Google Patents
A kind of long-acting peanut biological medicine fertilizer and preparation method thereof Download PDFInfo
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- CN105237203B CN105237203B CN201510673259.7A CN201510673259A CN105237203B CN 105237203 B CN105237203 B CN 105237203B CN 201510673259 A CN201510673259 A CN 201510673259A CN 105237203 B CN105237203 B CN 105237203B
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Abstract
The invention discloses a kind of long-acting peanut biological medicine fertilizers and preparation method thereof, are grouped as by the group of following parts by weight：0.5 ~ 1 part of Paenibacillus polymyxa, 1 ~ 10 part of chlopyrifos carbosulfan suspension microcapsules, 25 ~ 35 parts of urea, 30 ~ 40 parts of monoammonium phosphate, 30 ~ 40 parts of potassium sulfate, wherein the number of viable of the Paenibacillus polymyxa is 9 ~ 1,100,000,000 cfu/g.The medicine fertilizer of the present invention can keep drug effect to cover peanut from soil-borne diseases such as the insect prevention for the whole process being hardened to peanut shell of sowing, anti-bacterial wilt, droop, root rot, clubroots all, and to improving yield, pre- diseases prevention, insect pest play whole control.
Description
Technical field
The invention belongs to agrochemical fields, and in particular to a kind of long-acting peanut biological medicine fertilizer and preparation method thereof.
Background technology
Medicine fertilizer be pesticide and fertilizer are formulated according to a certain percentage to mix, and by certain technology by fertilizer and
Pesticide is stable in specific compound system and the novel ecological compound fertilizer of formation, generally makees the carrier of pesticide with fertilizer.For
The sustainable development of Modern Agricultural, medicine fertilizer is for come the modern agriculture for supporting and driving being a kind of new with powerful technology
It attempts.Medicine fertilizer can be such that two operating procedures in field are combined into one, this not only saves labour, and reduces time and energy
The consumption in source.
Currently, there are many peanut medicine fertilizer on the market, but many shortcomings are still had, there is preparations for medicine fertilizer composition
Complexity, dispensing is complicated, and efficacy time is short, can achieve the purpose that fertilizer, but the effect is unsatisfactory in terms of desinsection, sterilization,
And desinsection, sterilization and volume increase are difficult to reach effective synergistic effect.
Invention content
The goal of the invention of the present invention is to provide a kind of long-acting peanut biological medicine fertilizer and preparation method thereof, which can not only
Achieve the purpose that fertilizer, it is ideal in terms of desinsection, bactericidal effect, and also desinsection, sterilization and volume increase reach effective synergistic effect.
The technical solution adopted by the present invention is as follows：
A kind of long-acting peanut biological medicine fertilizer, is grouped as by the group of following parts by weight：0.5~1 part of Paenibacillus polymyxa,
1~10 part of chlopyrifos-carbosulfan microcapsule suspending agent, 25~35 parts of urea, 30~40 parts of monoammonium phosphate, potassium sulfate 30~
40 parts, wherein the number of viable of the Paenibacillus polymyxa is 9~1,100,000,000 cfu/g.
Preferably, the long-acting peanut biological medicine fertilizer, is grouped as by the group of following parts by weight：Paenibacillus polymyxa
0.5~0.8 part, chlopyrifos -5~8 parts of carbosulfan suspension microcapsules, 25~28 parts of urea, 32~35 parts of monoammonium phosphate, sulphur
33~35 parts of sour potassium, wherein the number of viable of the Paenibacillus polymyxa is 10~1,100,000,000 cfu/g.
By experimental results demonstrate and verification, not only the drug effect phase is long for the long-acting peanut biological medicine fertilizer of said ratio, but also kills
Bacterium, desinsection and effect of increasing production are preferable.
It is further preferred that the long-acting peanut biological medicine fertilizer, is grouped as by the group of following parts by weight：Mostly viscous class gemma
0.5 part of bacillus, chlopyrifos -8 parts of carbosulfan suspension microcapsules, 28 parts of urea, 35 parts of monoammonium phosphate, 33 parts of potassium sulfate,
Described in Paenibacillus polymyxa number of viable be 1,000,000,000 cfu/g.
By experimental results demonstrate and verification, the long-acting peanut biological medicine fertilizer of said ratio not only drug effect phase longest, but also
Sterilization, desinsection and effect of increasing production are best.
The addition manner of the Paenibacillus polymyxa is water dispersible powder of Paemobacillus polymyxa, Paenibacillus polymyxa
Wettable powder does not use solvent and emulsifier, safer to plant, is not likely to produce poisoning, environmentally safe.
Chlopyrifos-carbosulfan microcapsule suspending agent is to be composed of the following raw materials by weight：Chlopyrifos active compound 3~5
Part, 3~10 parts of carbosulfan active compound, 1~3 part of (R)-4-isopropenyl-1-methyl-1-cyclohexene, 1~3 part of beta-cyclodextrin, neopelex 0.1~
0.3 part, 0.5~1 part of polyvinyl alcohol, 1~5 part of water.
Preferably, chlopyrifos-carbosulfan microcapsule suspending agent is to be composed of the following raw materials by weight：95% poison
Dead 3 parts of tick active compound, 3 parts of 92% carbosulfan active compound, 1 part of (R)-4-isopropenyl-1-methyl-1-cyclohexene, 1 part of beta-cyclodextrin, neopelex
0.2 part, 0.8 part of polyvinyl alcohol, 2 parts of water.By experimental verification and analysis, each raw material formation of this specific proportion relation is poisoned with poison
Tick-carbosulfan suspension microcapsules effect is best.
Preparation method includes the following steps：
(1) chlopyrifos active compound and carbosulfan active compound are dissolved in (R)-4-isopropenyl-1-methyl-1-cyclohexene, obtain organic phase；
(2) organic phase in step (1) is added in beta-cyclodextrin and water, high speed shear forms oil-in-water emulsion；
(3) polyvinyl alcohol is added in oil-in-water emulsion into step (2), in normal temperature condition, cyst membrane polymerisation 1.5~
2.5h；
(4) after completion of the reaction, neopelex is added in the reaction system into step (3), is uniformly mixed and obtains
Chlopyrifos-carbosulfan microcapsule suspending agent.
In step (3), preferably cyst membrane polymerization reaction time 2h, the formation of chlopyrifos-carbosulfan suspension microcapsules
Effect is best.
Chlorpyrifos-carbosulfan microcapsule suspending agent of the present invention uses interfacial polymerization：Interfacial polymerization is cyst wall
Film formation reaction is happened on immiscible oil-water two-phase interfaces, and reaction can carry out at normal temperatures.The basic process of this method
It is, first by the oil-soluble high polymer monomer used in film formation reaction, to be dissolved in pesticide crude oil and constitute so-called organic phase (such as orchard worker
Medicine is not oily liquids but solid, then should first dissolve it in in the immiscible organic solvent of water).Then, this is organic
Emulsifier, water are added in high speed shear, forms oil-in-water emulsion.Again into this emulsion, water-soluble macromolecule is added
Monomer.Then, the polymerisation of cyst membrane, polymeric membrane can occur at the oil-water interface of emulsion particle in normal temperature condition
By farm chemical ingredients and water segregation.Reaction finishes, and appropriate amount of addition agent is added, after modulation, you can final preparation is made.
The chlopyrifos being prepared using above method-carbosulfan suspension microcapsules, compared with conventional pesticide dosage form,
Micro-capsule suspension has long lasting period, active constituent chlopyrifos and carbosulfan effective rate of utilization high, can be reduced or avoided
The characteristics of active constituent decomposes loss caused by external environment, mitigates toxicity and poisoning, reduction environmental pollution.
Active ingredient in the chlopyrifos-carbosulfan suspension microcapsules：The quality of chlopyrifos and carbosulfan
Than being 1:1~1:2.The chlopyrifos of specific proportion relation and carbosulfan act synergistically, and insecticidal spectrum is wide, absorbability is good,
Penetration is strong, effect is rapid, residual is low, has longer residual effect, safe to use etc., effective to adult and larva, is easy to soil
In organic matter combine, it is harmless to crop.
The preparation method of the long-acting peanut biological medicine fertilizer, includes the following steps：
Urea, monoammonium phosphate and potassium sulfate are added to blender according to weight proportion, after stirring evenly, are crushed,
The raw material being crushed is granulated, then dry, cooling, screening, coating, Paenibacillus polymyxa is then added and poisoned with poison
Tick-carbosulfan suspension microcapsules are uniformly mixed to get to long-acting peanut biological medicine fertilizer.
Specific preparation method includes the following steps：
(1) urea, monoammonium phosphate, potassium sulfate are added to blender according to weight proportion, stirred evenly, carry out broken place
Reason；
(2) it is 500~800 μm to be crushed to each raw material particle size, and the raw material be crushed is granulated, granulation grain size for 2000~
3500μm；
(3) raw material after being granulated is dried, and drying condition is：80~100 DEG C, it is up to being dried to particle water content
0.3% hereinafter, cooling, sieving, obtains the particle of qualified grain size after sieving, is eventually adding the Paenibacillus polymyxa of set amount
It is uniformly mixed to get to long-acting peanut biological medicine fertilizer with chlopyrifos-carbosulfan suspension microcapsules.
The beneficial effects of the invention are as follows：
1. raw material components proportioning science in the long-acting peanut medicine fertilizer of the present invention, rationally, wherein：Pesticide and fertilizer and plant
Mineral nutrition is in close relations, interaction.This interaction had both included (such as formulations of pesticide, fertilizer physical property physically
On), also there are (chemical reaction etc. between agrochemical fertilizer) chemically, the phase interaction also in bioactivity and biological effect
With Paenibacillus polymyxa is a kind of sporiferous gram-positive bacterium, has prophylaxis effect simultaneously to peanut non-pathogenic
And growth-promoting functions, it, which is acted on, can generate multiclass antibacterial material, predominantly peptides and protease in peanut soil, and can also
Generate steroids antibacterial material；In addition, Paenibacillus polymyxa can act as peanut by fixed nitrogen and Soluble phosphorus provides itself hardly possible
With the nitrogen source of absorption and phosphate fertilizer nutriment, promotes peanut plant growth, to play the effect for resisting various pathogenic microorganisms, can have
The bacillary and fungoid soil-borne diseases such as the prevention bacterial wilt of effect, droop, improve the resistance of crop, while can effectively promote
Into the about 5%-10% that is absorbed and utilized of insecticide (chlopyrifos-carbosulfan suspension microcapsules), drug effect and fertilizer efficiency are improved.
Chlopyrifos-carbosulfan microcapsule suspending agent is that chlopyrifos and carbosulfan compounding are prepared into microactuator suspension glue
Capsule, compared with conventional pesticide dosage form, micro-capsule suspension has long lasting period, active constituent chlopyrifos and carbosulfan effective
Utilization rate is high, and active constituent can be reduced or avoided and decompose loss caused by external environment, mitigate toxicity and poisoning, reduction to ring
The characteristics of border is polluted.
For urea as a kind of neutral fertilizer, especially suitable for peanut plant, it is not only easy to maintain, easy to use, and right
The destruction of soil is small.Since urea is organic nitrogen, with the compatible use of Paenibacillus polymyxa, pass through mostly viscous class gemma
Bacillus can nitrogen fixation the nitrogen source nutriment for itself being difficult to absorb is provided for peanut, promote plant growth.
Monoammonium phosphate is mainly that peanut provides water-soluble phosphorus pentoxide, moreover it is possible to provide certain nitrogen, be phosphate fertilizer
It is optimum to be applied during peanut growth, and peanut soil is in subacidity, and in acid soil, it is more excellent than other phosphate fertilizer
More.
Potassium sulfate is a kind of stronger electrolyte, readily soluble, and solubility is less than potassium chloride, and aqueous solution is in neutrality, chemical property
Stablize.After burying, because crop root is to K+And SO4 2The uneven ion exchange for absorbing or occurring with soil colloid it is anti-
It answers, easily remains SO4 2-, make medium that a degree of acidification occur, be a kind of physiological acidic fertilizer.Potassium sulfate and potassium chloride are most
Big difference is with K+Anion into soil is different, the former remains SO4 2-, sulfuric acid or the smaller sulfate of solubility are formed,
SO4 2-To most of crop, especially industrial crops without direct toxic action, the latter remains Cl-, form hydrochloric acid or solubility
Larger chloride, excess chlorine will produce certain side effect, influence the quality of product.
2, for the conversion of the nutriment needed for peanut growth, Paenibacillus polymyxa plays very important effect,
Paenibacillus polymyxa generates the substances such as vitamin, auxin, amino acid during its vital movement, can be direct by peanut
It is absorbed and utilized, promotes or stimulate peanut growth；It can act synergistically with chlopyrifos-carbosulfan suspension microcapsules, not only
Peanut plant can be promoted to grow, drug effect can also be kept to cover peanut from the insect prevention of the whole process being hardened to peanut shell of sowing, anti-
All, to improving yield, pre- diseases prevention, insect pest play whole control to the soil-borne diseases such as bacterial wilt, droop, root rot, clubroot
System.
3, there is the medicine fertilizer that chlopyrifos and carbosulfan etc. are common on the market, this common drug fertilizer drug effect phase is generally at one
Month or so, and the present invention is as a result of chlopyrifos-carbosulfan suspension microcapsules and Paenibacillus polymyxa, the drug effect phase is long
It it is the common drug fertilizer drug effect phase more than 3 times up to 100~120 days, the lasting period of medicine fertilizer is that common drug fertilizer is incomparable.
4, medicine fertilizer preparation method of the present invention and Easy dosing, can not only achieve the purpose that fertilizer, in terms of desinsection, sterilization
It is ideal in terms of effect, and desinsection, sterilization and volume increase reach effective synergistic effect.
5, long-acting biological medicine fertilizer of the invention, it is safe, in crop not interior suction, noresidue, to crop safety, to soil
Microbial safety, desinsection are sterilized while being acted on, and the lasting period is long, and strong adsorption not easily runs off slow release.
6, the saving of laborization demand of farming after the following land transformation has been adapted to, medicine fertilizer of the invention can make two of field to operate
Step is combined into one, and has accomplished saving of labor, time saving, laborsaving, economical purpose.
7, the present invention uses rational raw material proportioning and makes the growth for being more suitable for peanut according to the growth characteristics of peanut,
Suitable potassium sulfate promotes the development of peanut overground part substance accumulation and reproductive organs, coordinates urea and monoammonium phosphate chemical fertilizer
With the use of microbial pesticide and chemical pesticide, improve the economic character of peanut, has established good basis for the high yield of peanut, passed through
Character of helping refers to the characters such as single plant pod tree, fruit weight, kernel percent.
Specific implementation mode
Embodiment 1
A kind of long-acting peanut biological medicine fertilizer, is grouped as by the group of following parts by weight：Paenibacillus polymyxa wettable powder
0.5 part of agent, chlopyrifos -8 parts of carbosulfan suspension microcapsules, 28 parts of urea, 35 parts of monoammonium phosphate, 33 parts of potassium sulfate, wherein
The number of viable of the water dispersible powder of Paemobacillus polymyxa is 1,000,000,000 cfu/g.
Wherein, the chlopyrifos-carbosulfan microcapsule suspending agent, is to be composed of the following raw materials by weight：Quality point
Number is 95% 3 parts of chlopyrifos active compound, 3 parts of the carbosulfan active compound that mass fraction is 92%, 1 part of (R)-4-isopropenyl-1-methyl-1-cyclohexene, β-ring paste
1 part of essence, 0.2 part of neopelex, 0.8 part of polyvinyl alcohol, 2 parts of water.
Preparation method includes the following steps：
(1) chlopyrifos active compound and carbosulfan active compound are dissolved in (R)-4-isopropenyl-1-methyl-1-cyclohexene, obtain organic phase；
(2) organic phase in step (1) is added in beta-cyclodextrin and water, high speed shear forms oil-in-water emulsion；
(3) polyvinyl alcohol is added in the oil-in-water emulsion into step (2), in normal temperature condition, cyst membrane polymerisation 2h；
(4) after completion of the reaction, neopelex is added in the reaction system into step (3), is uniformly mixed and obtains
Chlopyrifos-carbosulfan microcapsule suspending agent.
A kind of long-acting specific preparation method of peanut biological medicine fertilizer includes the following steps：
(1) urea, monoammonium phosphate, potassium sulfate are added to blender according to weight proportion, stirred evenly, carry out broken place
Reason；
(2) it is 500 μm to be crushed to each raw material particle size, and the raw material being crushed is granulated, and it is 2000 μm to be granulated grain size；
(3) raw material after being granulated is dried, and drying condition is：80 DEG C, until it is 0.3% to be dried to particle water content
Hereinafter, cooling, sieving, obtains the particle of qualified grain size, the Paenibacillus polymyxa for being eventually adding set amount is wettable after sieving
Property pulvis and chlopyrifos-carbosulfan suspension microcapsules be uniformly mixed to get to long-acting peanut biological medicine fertilizer.
Embodiment 2
A kind of long-acting peanut biological medicine fertilizer, is grouped as by the group of following parts by weight：Paenibacillus polymyxa wettable powder
0.5 part of agent, chlopyrifos -1 part of carbosulfan suspension microcapsules, 25 parts of urea, 30 parts of monoammonium phosphate, 30 parts of potassium sulfate, wherein
The number of viable of the water dispersible powder of Paemobacillus polymyxa is 900,000,000 cfu/g.
Wherein, the chlopyrifos-carbosulfan microcapsule suspending agent, is to be composed of the following raw materials by weight：Quality point
Number is 95% 3 parts of chlopyrifos active compound, 5 parts of the carbosulfan active compound that mass fraction is 92%, 2 parts of (R)-4-isopropenyl-1-methyl-1-cyclohexene, β-ring paste
2 parts of essence, 0.1 part of neopelex, 0.5 part of polyvinyl alcohol, 4 parts of water.
Preparation method includes the following steps：
(1) chlopyrifos active compound and carbosulfan active compound are dissolved in (R)-4-isopropenyl-1-methyl-1-cyclohexene, obtain organic phase；
(2) organic phase in step (1) is added in beta-cyclodextrin and water, high speed shear forms oil-in-water emulsion；
(3) polyvinyl alcohol is added in the oil-in-water emulsion into step (2), in normal temperature condition, cyst membrane polymerisation 1.5h；
(4) after completion of the reaction, neopelex is added in the reaction system into step (3), is uniformly mixed and obtains
Chlopyrifos-carbosulfan microcapsule suspending agent.
A kind of long-acting specific preparation method of peanut biological medicine fertilizer includes the following steps：
(1) urea, monoammonium phosphate, potassium sulfate are added to blender according to weight proportion, stirred evenly, carry out broken place
Reason；
(2) it is 800 μm to be crushed to each raw material particle size, and the raw material being crushed is granulated, and it is 3500 μm to be granulated grain size；
(3) raw material after being granulated is dried, and drying condition is：90 DEG C, until it is 0.3% to be dried to particle water content
Hereinafter, cooling, sieving, obtains the particle of qualified grain size, the Paenibacillus polymyxa for being eventually adding set amount is wettable after sieving
Property pulvis and chlopyrifos-carbosulfan suspension microcapsules be uniformly mixed to get to long-acting peanut biological medicine fertilizer.
Embodiment 3
A kind of long-acting peanut biological medicine fertilizer, is grouped as by the group of following parts by weight：Paenibacillus polymyxa wettable powder
1 part of agent, chlopyrifos -10 parts of carbosulfan suspension microcapsules, 30 parts of urea, 35 parts of monoammonium phosphate, 40 parts of potassium sulfate, wherein institute
The number of viable for stating water dispersible powder of Paemobacillus polymyxa is 1,100,000,000 cfu/g.
Wherein, the chlopyrifos-carbosulfan microcapsule suspending agent, is to be composed of the following raw materials by weight：Quality point
Number is 95% 3 parts of chlopyrifos active compound, 7 parts of the carbosulfan active compound that mass fraction is 92%, 3 parts of (R)-4-isopropenyl-1-methyl-1-cyclohexene, β-ring paste
3 parts of essence, 0.3 part of neopelex, 1 part of polyvinyl alcohol, 5 parts of water.
Preparation method includes the following steps：
(1) chlopyrifos active compound and carbosulfan active compound are dissolved in (R)-4-isopropenyl-1-methyl-1-cyclohexene, obtain organic phase；
(2) organic phase in step (1) is added in beta-cyclodextrin and water, high speed shear forms oil-in-water emulsion；
(3) polyvinyl alcohol is added in the oil-in-water emulsion into step (2), in normal temperature condition, cyst membrane polymerisation 2.5h；
(4) after completion of the reaction, neopelex is added in the reaction system into step (3), is uniformly mixed and obtains
Chlopyrifos-carbosulfan microcapsule suspending agent.
A kind of long-acting specific preparation method of peanut biological medicine fertilizer includes the following steps：
(1) urea, monoammonium phosphate, potassium sulfate are added to blender according to weight proportion, stirred evenly, carry out broken place
Reason；
(2) it is 600 μm to be crushed to each raw material particle size, and the raw material being crushed is granulated, and it is 2500 μm to be granulated grain size；
(3) raw material after being granulated is dried, and drying condition is：100 DEG C, it is up to being dried to particle water content
0.3% hereinafter, cooling, sieving, obtains the particle of qualified grain size after sieving, is eventually adding the Paenibacillus polymyxa of set amount
Wettable powder and chlopyrifos-carbosulfan suspension microcapsules are uniformly mixed to get to long-acting peanut biological medicine fertilizer.
Embodiment 4
A kind of long-acting peanut biological medicine fertilizer, is grouped as by the group of following parts by weight：Paenibacillus polymyxa wettable powder
0.8 part of agent, chlopyrifos -5 parts of carbosulfan suspension microcapsules, 29 parts of urea, 32 parts of monoammonium phosphate, 35 parts of potassium sulfate, wherein
The number of viable of the water dispersible powder of Paemobacillus polymyxa is 10.5 hundred million cfu/g.
Wherein, the chlopyrifos-carbosulfan suspension microcapsules and preparation method are identical as in embodiment 1.
A kind of long-acting specific preparation method of peanut biological medicine fertilizer includes the following steps：
(1) urea, monoammonium phosphate, potassium sulfate are added to blender according to weight proportion, stirred evenly, carry out broken place
Reason；
(2) it is 700 μm to be crushed to each raw material particle size, and the raw material being crushed is granulated, and it is 3000 μm to be granulated grain size；
(3) raw material after being granulated is dried, and drying condition is：90 DEG C, until it is 0.3% to be dried to particle water content
Hereinafter, cooling, sieving, obtains the particle of qualified grain size, the Paenibacillus polymyxa for being eventually adding set amount is wettable after sieving
Property pulvis and chlopyrifos-carbosulfan suspension microcapsules be uniformly mixed to get to long-acting peanut biological medicine fertilizer.
Embodiment 5
A kind of long-acting peanut biological medicine fertilizer, is grouped as by the group of following parts by weight：Paenibacillus polymyxa wettable powder
0.9 part of agent, 2 parts of chlopyrifos-carbosulfan microcapsule suspending agent, 30 parts of urea, 31 parts of monoammonium phosphate, 32 parts of potassium sulfate,
Described in water dispersible powder of Paemobacillus polymyxa number of viable be 900,000,000 cfu/g.
Wherein, the chlopyrifos-carbosulfan suspension microcapsules and preparation method are identical as in embodiment 3.
The preparation method is the same as that of Example 1 for long-acting peanut biological medicine fertilizer.
Comparative example 1
One cultivate peanut medicine fertilizer, be to be grouped as by the group of following parts by weight：0.5 part of water dispersible powder of Paemobacillus polymyxa,
4 parts of chlopyrifos 4+ carbosulfans, 28 parts of urea, 35 parts of monoammonium phosphate, 33 parts of potassium sulfate, wherein the Paenibacillus polymyxa
The number of viable of wettable powder is 1,000,000,000 cfu/g.
Specific preparation method includes the following steps：
(1) chlopyrifos, carbosulfan, urea, monoammonium phosphate and potassium sulfate are added to blender according to weight proportion,
It stirs evenly, carries out break process；
(2) it is 500 μm to be crushed to each raw material particle size, and the raw material being crushed is granulated, and it is 2000 μm to be granulated grain size；
(3) raw material after being granulated is dried, and drying condition is：80 DEG C, until it is 0.3% to be dried to particle water content
Hereinafter, cooling, sieving, obtains the particle of qualified grain size, the Paenibacillus polymyxa for being eventually adding set amount is wettable after sieving
Property pulvis be uniformly mixed to get to long-acting peanut biological medicine fertilizer.
Comparative example 2
One cultivate peanut medicine fertilizer, be to be grouped as by the group of following parts by weight：0.5 part of waxy Bacillus, chlopyrifos-fourth sulphur gram
8 parts of Budweiser micro-capsule suspension, 28 parts of urea, 35 parts of monoammonium phosphate, 33 parts of potassium sulfate, wherein the waxy Bacillus is wettable
Property pulvis number of viable be 1,000,000,000 cfu/g.
Wherein, the chlopyrifos-carbosulfan suspension microcapsules and preparation method are identical as in embodiment 1.
Specific preparation method includes the following steps：
(1) urea, monoammonium phosphate, potassium sulfate are added to blender according to weight proportion, stirred evenly, carry out broken place
Reason；
(2) it is 500 μm to be crushed to each raw material particle size, and the raw material being crushed is granulated, and it is 2000 μm to be granulated grain size；
(3) raw material after being granulated is dried, and drying condition is：80 DEG C, until it is 0.3% to be dried to particle water content
Hereinafter, cooling, sieving, the particle of qualified grain size is obtained after sieving, it is eventually adding the waxy Bacillus of set amount and poisons with poison
Tick-carbosulfan suspension microcapsules are uniformly mixed to get to long-acting peanut biological medicine fertilizer.
Comparative example 3
One cultivate peanut medicine fertilizer, be to be grouped as by the group of following parts by weight：0.5 part of water dispersible powder of Paemobacillus polymyxa,
8 parts of chlopyrifos-carbosulfan, 28 parts of ammonium sulfate, 35 parts of Diammonium phosphate (DAP), 33 parts of potassium chloride, wherein more viscous class gemma bars
The number of viable of bacterium wettable powder is 1,000,000,000 cfu/g.
Wherein, the chlopyrifos-carbosulfan suspension microcapsules and preparation method are identical as in embodiment 1.
Specific preparation method includes the following steps：
(1) ammonium sulfate, Diammonium phosphate (DAP), potassium chloride are added to blender according to weight proportion, stirred evenly, is crushed
Processing；
(2) it is 500 μm to be crushed to each raw material particle size, and the raw material being crushed is granulated, and it is 2000 μm to be granulated grain size；
(3) raw material after being granulated is dried, and drying condition is：80 DEG C, until it is 0.3% to be dried to particle water content
Hereinafter, cooling, sieving, the particle of qualified grain size is obtained after sieving, it is eventually adding the waxy Bacillus of set amount and poisons with poison
Tick-carbosulfan suspension microcapsules are uniformly mixed to get to long-acting peanut biological medicine fertilizer.
Comparative example 4
One cultivate peanut medicine fertilizer, be to be grouped as by the group of following parts by weight：0.4 part of water dispersible powder of Paemobacillus polymyxa,
Chlopyrifos -11 parts of carbosulfan suspension microcapsules, 42 parts of urea, 25 parts of monoammonium phosphate, 25 parts of potassium sulfate, wherein described mostly viscous
The number of viable of series bacillus wettable powder is 900,000,000 cfu/g.
Wherein, the chlopyrifos-carbosulfan suspension microcapsules and preparation method are identical as in embodiment 1.
The preparation method is the same as that of Example 1.
Comparative example 5
One cultivate peanut medicine fertilizer, be to be grouped as by the group of following parts by weight：1.1 parts of water dispersible powder of Paemobacillus polymyxa,
Chlopyrifos -11 parts of carbosulfan suspension microcapsules, 22 parts of urea, 37 parts of monoammonium phosphate, 35 parts of potassium sulfate, wherein described mostly viscous
The number of viable of series bacillus wettable powder is 900,000,000 cfu/g.
Wherein, the chlopyrifos-carbosulfan suspension microcapsules and preparation method are identical as in embodiment 1.
The preparation method is the same as that of Example 1.
In order to preferably verify the practical application effect of the present invention, proved as following tests：
Field trial 1
Long-acting peanut biological medicine fertilizer in the embodiment of the present invention 1, embodiment 2 is with the medicine fertilizer of comparative example 1~5 in identical item
Peanut field is administered under part, volume increase comparing result see the table below 1：
Table 1
Test result：Test result is shown in Table 1.Test result shows the peanut yield of embodiment 1 and embodiment 2 than applying
It is high with the yield of the medicine fertilizer in comparative example.
Field trial 2
Long-acting peanut biological medicine fertilizer in the embodiment of the present invention 1, embodiment 2 is with the medicine fertilizer of comparative example 1~5 in identical item
Peanut field is administered under part, control of grubs, wireworm, cutworm and mole cricket comparing result see the table below 2：
Table 2
Test result：Test result is shown in Table 2.Test result shows embodiment 1 and embodiment 2 to peanut soil pest (Qi
Scarabaeiform, cutworm, wireworm, mole cricket) preventive effect 15 days after medicine, 30 days after medicine, 60 days after medicine, drug effect 90 days, drug effect 100 days and
120 days average preventive effects of drug effect are better than the medicine fertilizer in comparative example.
Field trial 3
Long-acting peanut biological medicine fertilizer in the embodiment of the present invention 1, embodiment 2 is with the medicine fertilizer of comparative example 1~5 in identical item
Peanut field is administered under part, prevention bacterial wilt, droop, root rot, clubroot comparing result see the table below 3：
Test result：Test result is shown in Table 3.Test result shows that embodiment 1 and embodiment 2 are preventing bacterial wilt, withering
It is superior to apply the medicine fertilizer in comparative example in terms of disease, root rot, clubroot.
Claims (10)
1. a kind of long-acting peanut biological medicine fertilizer, characterized in that be grouped as by the group of following parts by weight：Paenibacillus polymyxa
0.5~1 part, chlopyrifos -1~10 part of carbosulfan suspension microcapsules, 25~35 parts of urea, 30~40 parts of monoammonium phosphate, sulphur
30~40 parts of sour potassium, wherein the number of viable of the Paenibacillus polymyxa is 9~1,100,000,000 cfu/g.
2. long-acting peanut biological medicine fertilizer as described in claim 1, characterized in that be grouped as by the group of following parts by weight：It is more
Viscous 0.5~0.8 part of series bacillus, chlopyrifos -5~8 parts of carbosulfan suspension microcapsules, 25~28 parts of urea, phosphoric acid one
32~35 parts of ammonium, 33~35 parts of potassium sulfate, wherein the number of viable of the Paenibacillus polymyxa is 10~1,100,000,000 cfu/g.
3. long-acting peanut biological medicine fertilizer as claimed in claim 2, characterized in that be grouped as by the group of following parts by weight：It is more
Viscous 0.5 part of series bacillus, chlopyrifos -8 parts of carbosulfan suspension microcapsules, 28 parts of urea, 35 parts of monoammonium phosphate, potassium sulfate
33 parts, wherein the number of viable of the Paenibacillus polymyxa is 1,000,000,000 cfu/g.
4. the long-acting peanut biological medicine fertilizer as described in any in claims 1 to 3 item, characterized in that the chlopyrifos-fourth sulphur gram
Budweiser micro-capsule suspension is to be composed of the following raw materials by weight：3~5 parts of chlopyrifos active compound, carbosulfan active compound 3~10
Part, 1~3 part of (R)-4-isopropenyl-1-methyl-1-cyclohexene, 1~3 part of beta-cyclodextrin, 0.1~0.3 part of neopelex, 0.5~1 part of polyvinyl alcohol,
1~5 part of water.
5. long-acting peanut biological medicine fertilizer as claimed in claim 4, characterized in that the chlopyrifos-carbosulfan microcapsules
Suspending agent is to be composed of the following raw materials by weight：3 parts of the chlopyrifos active compound that mass fraction is 95%, mass fraction are 92%
3 parts of carbosulfan active compound, 1 part of (R)-4-isopropenyl-1-methyl-1-cyclohexene, 1 part of beta-cyclodextrin, 0.2 part of neopelex, polyvinyl alcohol 0.8
Part, 2 parts of water.
6. long-acting peanut biological medicine fertilizer as claimed in claim 4, characterized in that the chlopyrifos-carbosulfan microcapsules
The preparation method of suspending agent includes the following steps：
(1) chlopyrifos active compound and carbosulfan active compound are dissolved in (R)-4-isopropenyl-1-methyl-1-cyclohexene, obtain organic phase；
(2) organic phase in step (1) is added in beta-cyclodextrin and water, high speed shear forms oil-in-water emulsion；
(3) polyvinyl alcohol is added in oil-in-water emulsion into step (2), in normal temperature condition, cyst membrane polymerisation 1.5~
2.5h；
(4) after completion of the reaction, neopelex is added in the reaction system into step (3), is uniformly mixed and is poisoned with poison
Tick-carbosulfan microcapsule suspending agent.
7. the preparation method of the long-acting peanut biological medicine fertilizer as described in any in claims 1 to 3 item, characterized in that including with
Lower step：Urea, monoammonium phosphate and potassium sulfate are added to blender according to weight proportion, after stirring evenly, are crushed, it will
The raw material being crushed is granulated, then Paenibacillus polymyxa and chlopyrifos-is added in then dry, cooling, screening, coating
Carbosulfan suspension microcapsules are uniformly mixed to get to long-acting peanut biological medicine fertilizer.
8. the preparation method of long-acting peanut biological medicine fertilizer as claimed in claim 7, it is characterized in that：Broken grain size is 500
~800 μm.
9. the preparation method of long-acting peanut biological medicine fertilizer as claimed in claim 7, it is characterized in that：Be granulated grain size be 2000~
3500μm。
10. the preparation method of long-acting peanut biological medicine fertilizer as claimed in claim 7, characterized in that dry condition is：80~
100 DEG C, until it is 0.3% or less to be dried to particle water content.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3205208A1 (en) * | 2016-02-09 | 2017-08-16 | Basf Se | Mixtures and compositions comprising paenibacillus strains or fusaricidins and chemical pesticides |
| CN106818123B (en) * | 2016-12-25 | 2020-06-23 | 菏泽市农业科学院 | Simple and efficient peanut disease, insect and weed control method |
| CN107432151B (en) * | 2017-08-06 | 2020-05-19 | 菏泽市农业科学院 | Simple and efficient peanut machine pesticide application fertilizer application method |
| US20210204550A1 (en) * | 2018-05-17 | 2021-07-08 | Bayer Cropscience Lp | Stabilized fungicidal composition |
| CN108484282A (en) * | 2018-05-30 | 2018-09-04 | 青岛农业大学 | One group of novel peanut special medicated fertilizer |
| CN108484281A (en) * | 2018-05-30 | 2018-09-04 | 青岛农业大学 | One group of novel peanut special medicated fertilizer for containing phoxim and carbaryl |
| CN109287679A (en) * | 2018-11-23 | 2019-02-01 | 王变芝 | Biological agent and preparation method thereof for preventing and treating peanut root rot |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101712941A (en) * | 2009-11-30 | 2010-05-26 | 浙江大学 | Paenibacillus polymyxa and application thereof |
| CN101857511A (en) * | 2010-06-24 | 2010-10-13 | 安徽省农业科学院土壤肥料研究所 | Peanut pesticidal special fertilizer and production method thereof |
| CN101985410A (en) * | 2010-11-01 | 2011-03-16 | 邢志胜 | Insecticide disease-resistant fertilizer |
| CN102067863A (en) * | 2011-01-06 | 2011-05-25 | 北京燕化永乐农药有限公司 | Pesticide composition for preventing underground insects in peanut field |
| CN102531788A (en) * | 2012-01-17 | 2012-07-04 | 广东中迅农科股份有限公司 | Pesticide granule for controlling soil insects of peanut and preparation method thereof |
| CN103664416A (en) * | 2013-12-16 | 2014-03-26 | 辽宁南洋肥业有限公司 | Organic-inorganic ecological compound pesticide fertilizer and preparation method thereof |
| WO2014079730A1 (en) * | 2012-11-23 | 2014-05-30 | Basf Se | Pesticidal mixtures |
-
2015
- 2015-10-13 CN CN201510673259.7A patent/CN105237203B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101712941A (en) * | 2009-11-30 | 2010-05-26 | 浙江大学 | Paenibacillus polymyxa and application thereof |
| CN101857511A (en) * | 2010-06-24 | 2010-10-13 | 安徽省农业科学院土壤肥料研究所 | Peanut pesticidal special fertilizer and production method thereof |
| CN101985410A (en) * | 2010-11-01 | 2011-03-16 | 邢志胜 | Insecticide disease-resistant fertilizer |
| CN102067863A (en) * | 2011-01-06 | 2011-05-25 | 北京燕化永乐农药有限公司 | Pesticide composition for preventing underground insects in peanut field |
| CN102531788A (en) * | 2012-01-17 | 2012-07-04 | 广东中迅农科股份有限公司 | Pesticide granule for controlling soil insects of peanut and preparation method thereof |
| WO2014079730A1 (en) * | 2012-11-23 | 2014-05-30 | Basf Se | Pesticidal mixtures |
| CN103664416A (en) * | 2013-12-16 | 2014-03-26 | 辽宁南洋肥业有限公司 | Organic-inorganic ecological compound pesticide fertilizer and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 5%丁硫克百威﹒毒死蜱颗粒剂防治花生蛴螬药效试验;林笑丽 等;《福建农业科学》;20041231(第5期);第28页第3节 * |
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Denomination of invention: The invention relates to a long-acting peanut biological medicine fertilizer and a preparation method thereof Effective date of registration: 20210820 Granted publication date: 20180727 Pledgee: Linshang Bank Co.,Ltd. Yihe sub branch Pledgor: SHANDONG JINHONGYUAN ECOLOGICAL AGRICULTURE Co.,Ltd. Registration number: Y2021980008063 |
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