CN106495822A - A kind of medicine fertilizer composition containing MTI-446 and gamma cyhalothrin - Google Patents
A kind of medicine fertilizer composition containing MTI-446 and gamma cyhalothrin Download PDFInfo
- Publication number
- CN106495822A CN106495822A CN201610810852.6A CN201610810852A CN106495822A CN 106495822 A CN106495822 A CN 106495822A CN 201610810852 A CN201610810852 A CN 201610810852A CN 106495822 A CN106495822 A CN 106495822A
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- Prior art keywords
- fertilizer
- mti
- medicine fertilizer
- fertilizer composition
- medicine
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
- C05G5/23—Solutions
Abstract
The present invention relates to pesticide new product field, particularly relate to a kind of medicine fertilizer composition containing MTI-446 and gamma cyhalothrin and preparation method thereof, the medicine fertilizer composition not only can kill insect supplemented with nutrition necessary to crop, and compare with pesticide than fertilizer is used alone after both compoundings, all increase significantly in insecticidal effect and in terms of increasing yield, fertilizer and pesticide can be saved, reduce the cost of labor of dispenser fertilising, high to crop safety, meet the guiding theory of agrochemical fertilizer " effects enhancing and dose reducing ".
Description
Technical field
The present invention relates to pesticide new product field, and in particular to be a kind of medicine containing MTI-446 and gamma cyhalothrin
Fertilizer composition, contains a great number of elements in the compositionss, has the dual-use function of parasite killing and Fertilizer nutrient concurrently.
Background technology
MTI-446 is the anabasine insecticide of Mitsui company research and development, and which has a very wide insecticidal spectrum, and to crop,
People and animals and environment are again fool proof.Its model of action is novel, select strong toxicity, efficiently, wide spectrum and good to Environmental compatibility.Which is made
Insect nerve system nicotinic acetylcholine esterase receptor is controlled by selectivity mainly with mechanism, insecticide nervus centraliss are blocked
, there is paralysis and then death so as to cause insect in the normal conduction of system.As the insecticide has unique mechanism of action, with
Common insecticides do not have cross resistance, and which not only has efficient, wide spectrum and good root absorbability, tags and stomach poison function,
And low to mammalian toxicity, the insects such as Homoptera, coleoptera, Diptera and Lepidoptera can be effectively prevented and treated, to being killed with tradition
The insect that worm agent preventing and treating is developed immunity to drugs also has good activity.Anabasine insecticide can be not only used for cauline leaf process, also can use
In soil, seed treatment.
Gamma cyhalothrin is called trifluoro lambda-cyhalothrin, cyhalothrin.It can suppress insecticide neural axon position
Conduction, has the effect that walks quickly and keeps away, knock down and kill to insecticide, and insecticidal spectrum is wide, and activity is higher, and drug effect is rapid, resistance to rainwater after sprinkling
Wash away.
Medicine fertilizer is a new technique adopting in agricultural in recent years, refers to parasite killing, weeding, bactericidal action and effect life
Two or more function in long regulation, and nutrition can be provided for crops or while there is offer nutrition and improve fertilizer and agriculture
The multi-Functional Fertilizers of medicine utilization rate, the features such as operating with simplification, save labour force.Therefore, develop new have concurrently pesticide and
The medicine fertilizer of fertilizer is significant.
Present inventor, will be containing MTI-446 and high-performance cyhalothrin pesticide active component through substantial amounts of test discovery
Liquid medicine fertilizer is prepared with a great number of elements, the double effects of pesticide and fertilizer are had concurrently, applied once can meet crop pair
The needs of N,P,K fertilizers, can both increase crop yield, while can kill the insect of harm plant again, can reduce peasant household's weight
Multiple work, not only liberates labour force, and reduces the consumption of time and the energy.
Content of the invention
It is an object of the invention to provide a kind of containing MTI-446 and gamma cyhalothrin aqueous liquid medicine fertilizer and its
Preparation method, unexpected, mutually cooperate between the active insecticidal components and fertilizer, be mutually improved.
For solving above-mentioned technical problem, the present invention is adopted the following technical scheme that:
A kind of medicine fertilizer composition, it is characterised in that the medicine fertilizer composition includes MTI-446 and gamma cyhalothrin, great Liang Yuan
Plain Water soluble fertilizer and medicine fertilizer preparation auxiliary element;Wherein, a great number of elements Water soluble fertilizer is made up of nitrogen, phosphorus, potassium;
In the medicine fertilizer composition, the weight percentage composition of each component is as follows:
MTI-446:0.5-25%
Betacyfluthrin:0.5-25%
A great number of elements Water soluble fertilizer:18.5-34.5%
Medicine fertilizer preparation auxiliary element:Surplus;
Further, medicine fertilizer composition of the invention can also include other fertilizer, such as moderate-element fertilizer, marsh gas dregs fertilizer, alga fertilizer,
One or more in amino acid fertilizer, humic acid fertilizer, chitin, carbamide etc..
Further, in the medicine fertilizer composition, the weight ratio of MTI-446 and betacyfluthrin is 1:50-50:1.
Further, a great number of elements Water soluble fertilizer is made up of the nutrient of following weight percentage:
Nitrogen 3-7%
Phosphorus 8-13.5%
Potassium 7.5-14%.
Further, medicine fertilizer composition of the invention can be processed into granule, suspending agent, suspension emulsion.
Compared with prior art, of the invention medicine fertilizer composition has the beneficial effect that:
The invention provides a kind of supplementary plant nutrient, killing the water-soluble medicine fertilizer of the novel multi-effect a great number of elements that is integrated of insect, remove
Containing outside nutrient nitrogen, phosphorus, potassium necessary to healthy growth of crops, but also with the effect for killing insect.With traditional water
Soluble fertilizers compare, and the present invention has advantages below and feature:(1) safety and environmental protection.Soil is applied to, and spraying pesticide is compared to making
Thing and people are safer, few using rear residual, few to air, crop, soil, water body and ambient contamination;(2) time and labour saving,
Application with irrigation water, using water wisely.(3) active insecticidal components mutually cooperate with mutual potentiation, lasting medicine, Protect natural enemies with fertilizer.
Medicine fertilizer can keep drug effect for a long time, and be avoided that pest natural enemy and beneficial microbe from harm;(4) musted containing plant growth
The a great number of elements for needing, can reach increase yield, improving quality, and then increase the purpose of income.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, the present invention is carried out with specific examples below
Illustrate, but the present invention is limited to absolutely not these examples.Described below is only the present invention preferably embodiment, is used only for explaining this
Bright, but can not be therefore understands that being the restriction to the scope of the claims of the present invention.It should be pointed out that all in the spirit and principles in the present invention
Within any modification, equivalent or the improvement made etc., should be included within the scope of the present invention, therefore, this
The protection domain of bright patent should be defined by claims.
First, example of formulations
1st, embodiment 1
MTI-446 25%
Gamma cyhalothrin 0.5%
Carbamide 6.5%
Phosphatase 11 .5%
Tripotassium phosphate 21%
Polyoxyethylene polyoxypropylene block copolymer 2%
Aliphatic alcohol polyoxyvinethene phosphate 4.5%
Glycerol 3.0%
Aluminium-magnesium silicate 0.1%
Xanthan gum 0.1%
Sodium benzoate 0.2%
Water surplus
The concrete procedure of processing of the medicine fertilizer composition is:Phosphoric acid, carbamide and tripotassium phosphate is initially charged in water by above-mentioned formula
Dissolving.After stirring and dissolving is transparent, polyoxyethylene polyoxypropylene block copolymer, poly alkyl alcohol is sequentially added under stirring
Oxygen ethylene ether phosphate, glycerol, aluminium-magnesium silicate, xanthan gum and sodium benzoate, shearing are uniform, add MTI-446 and efficient chlorine
Flucythrinate, continues shearing and mixes, grind subsequently in horizontal sand mill, make material particular diameter all in below 5UM, this is obtained
25.5% described MTI-446 gamma cyhalothrin medicinal fertilizer suspending agent containing a great number of elements of invention.
2nd, embodiment 2
MTI-446 0.5%
Gamma cyhalothrin 25%
Carbamide 6.5%
Phosphatase 11 .5%
Tripotassium phosphate 21%
Polyoxyethylene polyoxypropylene block copolymer 1.8%
Aliphatic alcohol polyoxyvinethene phosphate 4.7%
Glycerol 3.0%
Aluminium-magnesium silicate 0.1%
Xanthan gum 0.1%
Sodium benzoate 0.2%
Water surplus
The preparation method of the medicine fertilizer composition is:The dissolving of phosphoric acid, carbamide and tripotassium phosphate is initially charged in water by above-mentioned formula.
After stirring and dissolving is transparent, polyoxyethylene polyoxypropylene block copolymer, fatty alcohol polyoxy second is sequentially added under stirring
Alkene ether phosphate, glycerol, aluminium-magnesium silicate, xanthan gum and sodium benzoate, shearing are uniform, add MTI-446 and efficient chlorine fluorine cyanogen
Chrysanthemum ester, continues shearing and mixes, grind subsequently in horizontal sand mill, make material particular diameter all in below 5UM, the present invention is obtained
25.5% described MTI-446 gamma cyhalothrin medicinal fertilizer suspending agent containing a great number of elements.
3rd, embodiment 3
MTI-446 12.5%
Gamma cyhalothrin 12.5%
Carbamide 6.5%
Phosphatase 11 .5%
Tripotassium phosphate 21%
Polyoxyethylene polyoxypropylene block copolymer 2.2%
Aliphatic alcohol polyoxyvinethene phosphate 4.3%
Glycerol 3.0%
Aluminium-magnesium silicate 0.1%
Xanthan gum 0.1%
Sodium benzoate 0.2%
Water surplus
The concrete procedure of processing of the medicine fertilizer composition is:Phosphoric acid, carbamide and tripotassium phosphate is initially charged in water by above-mentioned formula
Dissolving.After stirring and dissolving is transparent, polyoxyethylene polyoxypropylene block copolymer, poly alkyl alcohol is sequentially added under stirring
Oxygen ethylene ether phosphate, glycerol, aluminium-magnesium silicate, xanthan gum and sodium benzoate, shearing are uniform, add MTI-446 and efficient chlorine
Flucythrinate, continues shearing and mixes, grind subsequently in horizontal sand mill, make material particular diameter all in below 5UM, this is obtained
25.0% described MTI-446 gamma cyhalothrin medicinal fertilizer suspending agent containing a great number of elements of invention.
4th, embodiment 4
MTI-446 25%
Gamma cyhalothrin 0.5%
Diammonium phosphate (DAP) 18.5%
Tripotassium phosphate 11%
Polyoxyethylene polyoxypropylene block copolymer 2%
Aliphatic alcohol polyoxyvinethene phosphate 4.5%
Glycerol 3.0%
Aluminium-magnesium silicate 1.5%
Xanthan gum 0.1%
Sodium benzoate 0.2%
Water surplus
The preparation method of the medicine fertilizer composition is:Diammonium phosphate (DAP) and tripotassium phosphate dissolving is initially charged in water by above-mentioned formula.
After stirring and dissolving is transparent, polyoxyethylene polyoxypropylene block copolymer, fatty alcohol polyoxy second is sequentially added under stirring
Alkene ether phosphate, glycerol, aluminium-magnesium silicate, xanthan gum and sodium benzoate, shearing are uniform, add MTI-446 and efficient chlorine fluorine cyanogen
Chrysanthemum ester, continues shearing and mixes, grind subsequently in horizontal sand mill, make material particular diameter all in below 5UM, the present invention is obtained
25.5% described MTI-446 gamma cyhalothrin medicinal fertilizer suspending agent containing a great number of elements.
5th, embodiment 5
MTI-446 0.5%
Gamma cyhalothrin 25%
Diammonium phosphate (DAP) 18.5%
Tripotassium phosphate 11%
Polyoxyethylene polyoxypropylene block copolymer 1.8%
Aliphatic alcohol polyoxyvinethene phosphate 4.7%
Glycerol 3.0%
Aluminium-magnesium silicate 1.5%
Xanthan gum 0.1%
Sodium benzoate 0.2%
Water surplus
The preparation method of the medicine fertilizer composition is:Diammonium phosphate (DAP) and tripotassium phosphate dissolving is initially charged in water by above-mentioned formula.
After stirring and dissolving is transparent, polyoxyethylene polyoxypropylene block copolymer, fatty alcohol polyoxy second is sequentially added under stirring
Alkene ether phosphate, glycerol, aluminium-magnesium silicate, xanthan gum and sodium benzoate, shearing are uniform, add MTI-446 and efficient chlorine fluorine cyanogen
Chrysanthemum ester, continues shearing and mixes, grind subsequently in horizontal sand mill, make material particular diameter all in below 5UM, the present invention is obtained
25.5% described MTI-446 gamma cyhalothrin medicinal fertilizer suspending agent containing a great number of elements.
6th, embodiment 6
MTI-446 12.5%
Gamma cyhalothrin 12.5%
Diammonium phosphate (DAP) 18.5%
Tripotassium phosphate 11%
Polyoxyethylene polyoxypropylene block copolymer 2.2%
Aliphatic alcohol polyoxyvinethene phosphate 4.3%
Glycerol 3.0%
Aluminium-magnesium silicate 1.5%
Xanthan gum 0.1%
Sodium benzoate 0.2%
Water surplus
The preparation method of the medicine fertilizer composition is:Diammonium phosphate (DAP) and tripotassium phosphate dissolving is initially charged in water by above-mentioned formula.
After stirring and dissolving is transparent, polyoxyethylene polyoxypropylene block copolymer, fatty alcohol polyoxy second is sequentially added under stirring
Alkene ether phosphate, glycerol, aluminium-magnesium silicate, xanthan gum and sodium benzoate, shearing are uniform, add MTI-446 and efficient chlorine fluorine cyanogen
Chrysanthemum ester, continues shearing and mixes, grind subsequently in horizontal sand mill, make material particular diameter all in below 5UM, the present invention is obtained
25.0% described MTI-446 gamma cyhalothrin medicinal fertilizer suspending agent containing a great number of elements.
7th, embodiment 7
MTI-446 25%
Gamma cyhalothrin 0.5%
Carbamide 13%
Phosphoric acid 2.5%
Diammonium phosphate (DAP) 4.5%
Tripotassium phosphate 12%
Polyoxyethylene polyoxypropylene block copolymer 2.1%
Aliphatic alcohol polyoxyvinethene phosphate 4.7%
Glycerol 3.0%
Aluminium-magnesium silicate 1.5%
Xanthan gum 0.1%
Sodium benzoate 0.2%
Water surplus
The preparation method of the medicine fertilizer composition is:Phosphoric acid, carbamide, Diammonium phosphate (DAP) and phosphoric acid is initially charged in water by above-mentioned formula
Tripotassium dissolves.After stirring and dissolving is transparent, polyoxyethylene polyoxypropylene block copolymer, fat is sequentially added under stirring
Polyoxyethylenated alcohol phosphate ester, glycerol, aluminium-magnesium silicate, xanthan gum and sodium benzoate, shearing are uniform, add MTI-446 and height
Effect lambda-cyhalothrin, continues shearing and mixes, grind subsequently in horizontal sand mill, makes material particular diameter all in below 5UM, system
Obtain 25.5% MTI-446 gamma cyhalothrin medicinal fertilizer suspending agent containing a great number of elements of the present invention.
8th, embodiment 8
MTI-446 0.5%
Gamma cyhalothrin 25%
Carbamide 13%
Phosphoric acid 2.5%
Diammonium phosphate (DAP) 4.5%
Tripotassium phosphate 12%
Polyoxyethylene polyoxypropylene block copolymer 1.9%
Aliphatic alcohol polyoxyvinethene phosphate 4.9%
Glycerol 3.0%
Aluminium-magnesium silicate 1.5%
Xanthan gum 0.1%
Sodium benzoate 0.2%
Water surplus
The preparation method of the medicine fertilizer composition is:Phosphoric acid, carbamide, Diammonium phosphate (DAP) and phosphoric acid is initially charged in water by above-mentioned formula
Tripotassium dissolves.After stirring and dissolving is transparent, polyoxyethylene polyoxypropylene block copolymer, fat is sequentially added under stirring
Polyoxyethylenated alcohol phosphate ester, glycerol, aluminium-magnesium silicate, xanthan gum and sodium benzoate, shearing are uniform, add MTI-446 and height
Effect lambda-cyhalothrin, continues shearing and mixes, grind subsequently in horizontal sand mill, makes material particular diameter all in below 5UM, system
Obtain 25.5% MTI-446 gamma cyhalothrin medicinal fertilizer suspending agent containing a great number of elements of the present invention.
9th, embodiment 9
MTI-446 12.5%
Gamma cyhalothrin 12.5%
Carbamide 13%
Phosphoric acid 2.5%
Diammonium phosphate (DAP) 4.5%
Tripotassium phosphate 12%
Polyoxyethylene polyoxypropylene block copolymer 2.0%
Aliphatic alcohol polyoxyvinethene phosphate 5.0%
Glycerol 3.0%
Aluminium-magnesium silicate 1.5%
Xanthan gum 0.1%
Sodium benzoate 0.2%
Water surplus
The concrete preparation method of the medicine fertilizer composition is:By above-mentioned formula be initially charged in water phosphoric acid, carbamide, Diammonium phosphate (DAP) and
Tripotassium phosphate dissolves.After stirring and dissolving is transparent, sequentially add under stirring polyoxyethylene polyoxypropylene block copolymer,
Aliphatic alcohol polyoxyvinethene phosphate, glycerol, aluminium-magnesium silicate, xanthan gum and sodium benzoate, shearing are uniform, add MTI-446
And gamma cyhalothrin, continue shearing mix, subsequently in horizontal sand mill grind, make material particular diameter all 5UM with
Under, 25.0% MTI-446 gamma cyhalothrin medicinal fertilizer suspending agent containing a great number of elements of the present invention is obtained.
2nd, raw survey embodiment
The preparations embodiment of application embodiment of the present invention 1-9 carries out Fructus Cucumidis sativi pest control and volume increase field control effectiveness test, examination
Test according to unified cost budgeting, following process is set:
Process 1-9:The medicine fertilizer composition of embodiment 1-9;
Process 10:25% gamma cyhalothrin suspending agent;
Process 11:25% MTI-446 suspending agent;
Process 12:25% MTI-446 gamma cyhalothrin suspending agent(1:1);
Process 13:According to the formula of embodiment 9, without pesticide activity component.
In addition to the processing described above, this test is also provided with space management.1- will be processed 13 are processed according to unified cost budgeting
Consumption, transplants backlash of turning green in Fructus Cucumidis sativi and applies, and each process sets 3 repetitions, each experimental plot 67m2, cell random alignment.In
After dispenser after 5 days, the Harm of Fructus Cucumidis sativi insect after 7 days, after 10 days, is investigated after 20 days respectively, and when harvesting, investigation Fructus Cucumidis sativi increases
Product situation.Referring to table 1, result of the test is shown in Table 2 to each using method for processing
Shown according to result of the test:Fructus Cucumidis sativi is applied to using the present invention, compared with alone gamma cyhalothrin or MTI-446, right
The prevention effect of Fructus Cucumidis sativi insect is good, and the lasting period is longer, and compounds with synergistic function;With alone gamma cyhalothrin
Or MTI-446, MTI-446 are compared without fertile, alone a great number of elements Water soluble fertilizer with high-efficient lambda-cyhalothrin compound, the present invention is to Fructus Cucumidis sativi
Production-increasing function become apparent from.
Claims (6)
1. a kind of medicine fertilizer composition, it is characterised in that comprising following component, pesticide activity component is MTI-446 and efficient chlorine fluorine cyanogen
Chrysanthemum ester, fertilizer are a great number of elements Water soluble fertilizer.
2. medicine fertilizer composition according to claim 1, it is characterised in that the weight hundred of MTI-446 and gamma cyhalothrin
Point content is 1-50%, and the content of a great number of elements Water soluble fertilizer is 18.5-34.5%, remaining be auxiliary in medicine fertilizer preparation processing into
Point.
3. medicine fertilizer composition according to claim 2, it is characterised in that a great number of elements Water soluble fertilizer is nitrogen, phosphorus, potassium.
4. the medicine fertilizer composition according to any one of claim 1-3 claim, it is characterised in that the medicine fertilizer combination
Thing is prepared into granule, suspending agent, suspension emulsion or microcapsule suspending agent.
5. the medicine fertilizer composition according to any one of claim 1-4 claim is used for the use for preventing and kill off crop pests
On the way.
6. the medicine fertilizer composition according to any one of claim 1-4 claim is used for the purposes for increasing crop yield.
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CN201610810852.6A CN106495822A (en) | 2016-09-09 | 2016-09-09 | A kind of medicine fertilizer composition containing MTI-446 and gamma cyhalothrin |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113004096A (en) * | 2021-02-20 | 2021-06-22 | 贵州省植物保护研究所 | Sustained-release pesticide-fertilizer granules for controlling underground pests and preparation method and application thereof |
Citations (3)
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CN102805080A (en) * | 2012-08-24 | 2012-12-05 | 广西田园生化股份有限公司 | Soluble granule capable of being used for preventing and treating agricultural pest |
CN104542079A (en) * | 2013-10-16 | 2015-04-29 | 中国农业科学院蔬菜花卉研究所 | Method for processing drug-containing slow-release material and preventing and treating vegetable diseases and insect pests |
CN105061084A (en) * | 2015-08-21 | 2015-11-18 | 西安炬光生物科技有限公司 | Controlled-release pesticide fertilizer and preparing method thereof |
-
2016
- 2016-09-09 CN CN201610810852.6A patent/CN106495822A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102805080A (en) * | 2012-08-24 | 2012-12-05 | 广西田园生化股份有限公司 | Soluble granule capable of being used for preventing and treating agricultural pest |
CN104542079A (en) * | 2013-10-16 | 2015-04-29 | 中国农业科学院蔬菜花卉研究所 | Method for processing drug-containing slow-release material and preventing and treating vegetable diseases and insect pests |
CN105061084A (en) * | 2015-08-21 | 2015-11-18 | 西安炬光生物科技有限公司 | Controlled-release pesticide fertilizer and preparing method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN113004096A (en) * | 2021-02-20 | 2021-06-22 | 贵州省植物保护研究所 | Sustained-release pesticide-fertilizer granules for controlling underground pests and preparation method and application thereof |
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Application publication date: 20170315 |