CN106467432A - A kind of medicine fertilizer composition of clothianidin-containing and Biphenthrin - Google Patents

A kind of medicine fertilizer composition of clothianidin-containing and Biphenthrin Download PDF

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Publication number
CN106467432A
CN106467432A CN201610755749.6A CN201610755749A CN106467432A CN 106467432 A CN106467432 A CN 106467432A CN 201610755749 A CN201610755749 A CN 201610755749A CN 106467432 A CN106467432 A CN 106467432A
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CN
China
Prior art keywords
fertilizer
biphenthrin
clothianidin
medicine
medicine fertilizer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610755749.6A
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Chinese (zh)
Inventor
贺星贵
王平勇
李次平
叶宇平
杨建江
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Foshan Yinghui Crop Science Co Ltd
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Foshan Yinghui Crop Science Co Ltd
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Priority to CN201610755749.6A priority Critical patent/CN106467432A/en
Publication of CN106467432A publication Critical patent/CN106467432A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F1/00Fertilisers made from animal corpses, or parts thereof
    • C05F1/005Fertilisers made from animal corpses, or parts thereof from meat-wastes or from other wastes of animal origin, e.g. skins, hair, hoofs, feathers, blood
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/70Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting wettability, e.g. drying agents

Abstract

The present invention relates to pesticide new product field, particularly relate to a kind of medicine fertilizer composition containing clothianidin and Biphenthrin and preparation method thereof, described medicine fertilizer composition can not only play the double effects of parasite killing and fertilizer, and both compounding after compare with pesticide than being used alone chemical fertilizer, all increase significantly in terms of insecticidal effect, crop yield, use cost, section fertile section medicine can be reduced, high to crop safety, meet the requirement of " pesticide zero growth rate ".

Description

A kind of medicine fertilizer composition of clothianidin-containing and Biphenthrin
Technical field
The invention belongs to medicament-fertilizer mixture field and in particular to be a kind of fertile combination of medicine comprising clothianidin and Biphenthrin Thing.
Background technology
China is a large agricultural country, and per capita cultivated land is few, and the yield therefore improving crops rises to the development of social economy Highly important effect.But it is presently mainly to promote crops to increase product by applying a large amount of chemical pesticides and chemical fertilizer Measure, guarantee quality.Applying chemical fertilizer for a long time in a large number makes soil inorganic salt content increase, and causes soil compaction, simultaneously using change Learn to farm during medicine prevention and elimination of disease and pests, a lot of noxious substances remain in plant and soil surface, have a strong impact on the quality of crop. Highly efficient farming to provide greater and better yields is the inexorable trend of modern agricultural development, and therefore in agricultural production, chemical fertilizer to be reduced makes With greatly developing fertilizer, the use of pesticide is rationally efficient, reduces medicament loss.
Clothianidin is one of anabasine insecticide, is mainly used on Oryza sativa L., fruit tree, vegetable and other crops preventing and treating aphid The Semipteras such as worm, leafhopper, thrips, plant hopper, coleoptera and some lepidoptera pests, the ground such as cutworm, Gryllotalpa, Holotrichia diomphalia Batess, wireworm Lower insect.Biphenthrin is that one kind efficiently synthesizes pyrethrin Insecticidal and acaricidal agent.Have tag, stomach poison function, no interior suction, smoked Steaming acts on.Insecticidal spectrum is wide, also has favorable effect to demodicid mite.Soil does not move, safer to environment, the longevity of residure is long.
Medicine fertilizer is by pesticide and fertilizer mixing, and by processing, fertilizer and pesticide is stable in specific compound system The mixture being formed, has and kills the function that suppression diseases and pests of agronomic crop and plant growth are adjusted, and can provide nutrition for crops, has When also have and nutrient be provided, improve the function of fertilizer efficiency and pesticide utilization rate to crops.Medicine fertilizer has agreed with existing to a certain extent The new demand of generation agricultural.Medicine and fertilizer unite two into one, and fertilising and laxative work twice are integrated into and once work, is conducive to improving labor Efficiency of movement, liberating rural labour force, reduces the constantly surging pressure of agriculture production cost.Additionally, medicine fertile as a class with chemical fertilizer For the pesticidal preparations of filler, it is estimated that about 500,000 tons of insecticides adjuvants, uses of solvent can be saved, and reduce a large amount of packaging The waste of thing, has adapted to current environment new situations that are friendly and developing low-carbon agriculture.
Present inventor, through substantial amounts of lab screening and field control effectiveness test, finds clothianidin and Biphenthrin Pesticidal combination and fertilizer mixture after, the double effects of parasite killing and fertilizer can not only be played, and both compounding after than individually Compared with pesticide using chemical fertilizer, all increase significantly in terms of insecticidal effect, crop yield, it is possible to decrease use cost, Section fertile section medicine, high to crop safety, meet the requirement of " pesticide zero growth rate ".
Content of the invention
It is an object of the invention to provide medicine fertilizer composition of a kind of clothianidin-containing and Biphenthrin and preparation method thereof, institute State the dual-use function that medicine fertilizer composition has pesticide and fertilizer, and pesticide and fertilizer compound after there is Synergistic each other make With.
For reaching above-mentioned purpose, the present invention adopts the following technical scheme that:
A kind of medicine fertilizer composition is it is characterised in that described medicine fertilizer composition includes Biphenthrin, clothianidin and organic water-soluble fertilizer Material, wherein, organic water-soluble fertilizer is selected from shrimp and crab shells, yellow tang or both combinations.
Further, in described medicine fertilizer composition, the percentage by weight of Biphenthrin and clothianidin is 1:50-50:1.
Further, the weight percentage of medicine fertilizer composition shared by described medicine fertilizer composition Pesticides active component is 1- 50%, preferably 1-30%.
Further, in described medicine fertilizer composition, the weight percentage of medicine fertilizer composition shared by organic water-soluble fertilizer is 1- 90%, preferably 5-20%.
Beat all, the pesticide activity component of the present invention and described organic water-soluble fertilizer can in above-mentioned content range Reach synergistic function.
Further, the medicine fertilizer composition of the present invention can be prepared into agriculturally allow any by customary preparation methods A kind of dosage form, such as granule, suspending agent, suspension emulsion, microcapsule suspending agent.
Further, the medicine fertilizer composition of the present invention also can comprise other agricultural active compositions, for example other insecticides, removes Careless agent, antibacterial, herbicide-safener, fertilizer.
Compared with prior art, beneficial effects of the present invention are:
1st, the medicine fertilizer composition of the present invention had both contained nutrient necessary to crops healthy growth, but also with the effect of parasite killing Really;
2nd, safe.Injury to crop and people during minimizing spraying pesticide is few using rear residual, to crop, soil, water Body and ambient contamination are few;
3rd, lasting medicine, Protect natural enemies.Medicine fertilizer can keep drug effect for a long time, makes pest natural enemy and beneficial microbe from danger Evil, organic matter is conducive to rehabilitating soil;
4th, increasing both production and income, improving quality.Using medicine fertilizer while improving crop yield, increase farmers' income, quality of agricultural product Also the standard of national pollution-free food can be reached;
5th, mutually collaborative.Described active insecticidal components are mutually collaborative with fertilizer, and described fertilizer and described insecticide use cooperatively, Insecticidal effect is significantly improved.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, present invention specific examples below Illustrate, but the present invention is limited to absolutely not these examples.Described below is only the preferable embodiment of the present invention, is used only for explaining The present invention, but can not be therefore understands that being the restriction to the scope of the claims of the present invention.It should be understood that when, all spirit in the present invention and Any modification, equivalent or improvement of being made within principle etc., should be included within the scope of the present invention, therefore, The protection domain of patent of the present invention should be defined by claims.
First, example of formulations
1st, embodiment 1:18% Biphenthrin clothianidin shrimp and crab shells medicinal fertilizer suspending agent
Biphenthrin 0.5%
Clothianidin 0.5%
Shrimp and crab shells 17%
Polycarboxylate 2%
Alkyl naphthalene formaldehyde condensate sulfonates 1.5%
White carbon 1.5%
Xanthan gum 0.4%
Aluminium-magnesium silicate 0.4%
Preservative 0.4%
Propylene glycol 4%
Defoamer 0.5%
Water polishing is to 100%
The concrete procedure of processing of described suspending agent is:By in above-mentioned formula by water and wetting agent, dispersant, thickening agent, antibacterial, Antifreeze and defoamer mixing, through high speed shear mix homogeneously, add Biphenthrin, clothianidin, shrimp and crab shells, continue shearing mixed Even, grind subsequently in horizontal sand mill, make preparation particle diameter all in below 5UM, of the present invention clothianidin-containing is obtained Organic water-soluble fertilizer with Biphenthrin(Source Organic Matter shrimp and crab shells)Suspending agent.
2nd, embodiment 2:12.5% Biphenthrin clothianidin shrimp and crab shells medicinal fertilizer suspending agent
Biphenthrin 0.5%
Clothianidin 5%
Shrimp and crab shells 7%
Polycarboxylate 3%
Alkyl naphthalene formaldehyde condensate sulfonates 2%
White carbon 1.5%
Xanthan gum 0.2%
Aluminium-magnesium silicate 0.4%
Preservative 0.2%
Propylene glycol 4%
Defoamer 0.5%
Water polishing is to 100%
Preparation method is with embodiment 1.
2nd, embodiment 3:40% Biphenthrin clothianidin shrimp and crab shells medicinal fertilizer suspending agent
Biphenthrin 1%
Clothianidin 30%
Shrimp and crab shells 9%
Polycarboxylate 3%
Alkyl naphthalene formaldehyde condensate sulfonates 3%
White carbon 1%
Xanthan gum 0.2%
Aluminium-magnesium silicate 0.4%
Preservative 0.2%
Propylene glycol 4%
Defoamer 0.5%
Water polishing is to 100%
Preparation method is with embodiment 3.
4th, embodiment 4:30.5% Biphenthrin clothianidin shrimp and crab shells medicinal fertilizer suspending agent
Biphenthrin 0.5%
Clothianidin 25%
Shrimp and crab shells 5%
Polycarboxylate 3%
Alkyl naphthalene formaldehyde condensate sulfonates 3%
White carbon 1%
Xanthan gum 0.2%
Aluminium-magnesium silicate 0.4%
Preservative 0.2%
Propylene glycol 4%
Defoamer 0.5%
Water polishing is to 100%
Preparation method is with embodiment 1.
5th, embodiment 5:21% Biphenthrin clothianidin yellow tang medicinal fertilizer suspending agent
Biphenthrin 0.5%
Clothianidin 0.5%
Yellow tang 20%
Polycarboxylate 3%
Alkyl naphthalene formaldehyde condensate sulfonates 2%
White carbon 1.5%
Xanthan gum 0.4%
Aluminium-magnesium silicate 0.8%
Preservative 0.4%
Propylene glycol 4%
Defoamer 0.5%
Water polishing is to 100%
Preparation method is with embodiment 1.
6th, embodiment 6:20.5% Biphenthrin clothianidin yellow tang medicinal fertilizer suspending agent
Biphenthrin 0.5%
Clothianidin 5%
Yellow tang 15%
Polycarboxylate 4%
Alkyl naphthalene formaldehyde condensate sulfonates 2%
White carbon 1.5%
Xanthan gum 0.3%
Aluminium-magnesium silicate 0.6%
Preservative 0.3%
Propylene glycol 4%
Defoamer 0.5%
Water polishing is to 100%
Preparation method is with embodiment 1.
7th, embodiment 7:34% Biphenthrin clothianidin yellow tang medicinal fertilizer suspending agent
Biphenthrin 1%
Clothianidin 30%
Yellow tang 3%
Polycarboxylate 4%
Alkyl naphthalene formaldehyde condensate sulfonates 2%
Alkyl polyoxyethylene ether sulfate ester 1%
White carbon 1%
Xanthan gum 0.2%
Aluminium-magnesium silicate 0.4%
Preservative 0.2%
Propylene glycol 4%
Defoamer 0.5%
Water polishing is to 100%
Preparation method is with embodiment 1.
8th, embodiment 8:31.5% Biphenthrin clothianidin yellow tang medicinal fertilizer suspending agent
Biphenthrin 0.5%
Clothianidin 25%
Yellow tang 6%
Polycarboxylate 4%
Alkyl naphthalene formaldehyde condensate sulfonates 2%
Alkyl polyoxyethylene ether sulfate ester 2%
White carbon 0.5%
Xanthan gum 0.2%
Aluminium-magnesium silicate 0.4%
Preservative 0.2%
Propylene glycol 4%
Defoamer 0.5%
Water polishing is to 100%
Preparation method is with embodiment 1.
2nd, raw survey embodiment
Carry out preventing and treating the preventing and treating of Brassica campestris L. ssp.chinensis striped flea-beetle and volume increase field test in Guangzhou, Guangdong suburb dish leaf.Test is according to system One cost budgeting, setting is following to be processed:
Process 1-8:It is respectively the medicine fertilizer composition of above-mentioned example of formulations 1-8 gained;
Process 9:2.5% Biphenthrin cream;
Process 10:30% clothianidin suspending agent;
Process 11:1% Biphenthrin clothianidin suspending agent(Biphenthrin:Clothianidin=1:1);
Process 12:17% shrimp and crab shells fertilizer suspending agent;
Process 13:20% yellow tang fertilizer suspending agent.
In addition to the processing described above, this test is also provided with space management.Process 13 by processing 1- according to unified cost budgeting Consumption, is watered punching and applies process of irrigating the fields when Brassica campestris L. ssp.chinensis are sowed, and each process sets 3 repetitions, each experimental plot 67m2, cell is random Arrangement.5 days after dispenser, 10 days, 15 days, the Harm of 20 days investigation Brassica campestris L. ssp.chinensis yellow song flea beetle, aphid and cutworms respectively, in Investigation Brassica campestris L. ssp.chinensis volume increase situation during results.Referring to table 1, result of the test is shown in Table 2 to each using method processing
Shown according to result of the test:It is applied to vegetable Brassica campestris L. ssp.chinensis crop using the present invention, with alone Biphenthrin or clothianidin or two Person compounds and compares, and good to the prevention effect of Sugarcane Pests, the lasting period is longer, and compounding has synergistic function;With alone Pesticide, compounding compare without fertile, alone fertilizer, the present invention becomes apparent to the production-increasing function of Caulis Sacchari sinensis.

Claims (6)

1. it is characterised in that comprising following component, pesticide activity component is clothianidin and Biphenthrin to a kind of medicine fertilizer composition, Fertilizer is organic fertilizer.
2. medicine fertilizer composition according to claim 1 is it is characterised in that the weight percentage of clothianidin and Biphenthrin For 1-50%, the content of organic fertilizer is 1-90%, and remaining is the auxiliary element in medicine fertilizer preparation processing.
3. medicine fertilizer composition according to claim 2 it is characterised in that organic fertilizer be shrimp and crab shells or yellow tang or both Compositionss.
4. the medicine fertilizer composition according to any one of claim 1-3 claim is it is characterised in that described medicine fertilizer combines Thing is prepared into granule, suspending agent, suspension emulsion or microcapsule suspending agent.
5. the medicine fertilizer composition according to any one of claim 1-4 claim is used for preventing and kill off the use of crop pests On the way.
6. the medicine fertilizer composition according to any one of claim 1-4 claim is used for increasing the purposes of crop yield.
CN201610755749.6A 2016-08-30 2016-08-30 A kind of medicine fertilizer composition of clothianidin-containing and Biphenthrin Pending CN106467432A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112500238A (en) * 2021-01-08 2021-03-16 中诚国联(河南)生物科技有限公司 High tower pesticide-fertilizer containing imidacloprid and cyfluthrin and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101179938A (en) * 2005-05-19 2008-05-14 Fmc有限公司 Insecticidal compositions suitable for use in preparation of insecticidal liquid fertilizers
CN105061084A (en) * 2015-08-21 2015-11-18 西安炬光生物科技有限公司 Controlled-release pesticide fertilizer and preparing method thereof
CN105622178A (en) * 2014-10-13 2016-06-01 郑州正合化学制品有限公司 Organic water-soluble fertilizer

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101179938A (en) * 2005-05-19 2008-05-14 Fmc有限公司 Insecticidal compositions suitable for use in preparation of insecticidal liquid fertilizers
CN105622178A (en) * 2014-10-13 2016-06-01 郑州正合化学制品有限公司 Organic water-soluble fertilizer
CN105061084A (en) * 2015-08-21 2015-11-18 西安炬光生物科技有限公司 Controlled-release pesticide fertilizer and preparing method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112500238A (en) * 2021-01-08 2021-03-16 中诚国联(河南)生物科技有限公司 High tower pesticide-fertilizer containing imidacloprid and cyfluthrin and preparation method thereof

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Application publication date: 20170301

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