CN105199665B - A kind of high tack adhesive waterproof coil and preparation method thereof - Google Patents

A kind of high tack adhesive waterproof coil and preparation method thereof Download PDF

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Publication number
CN105199665B
CN105199665B CN201510733712.9A CN201510733712A CN105199665B CN 105199665 B CN105199665 B CN 105199665B CN 201510733712 A CN201510733712 A CN 201510733712A CN 105199665 B CN105199665 B CN 105199665B
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agent
styrene
asphalt
tackifier
waterproof coil
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CN105199665A (en
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宗建华
李文志
刘金景
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Henan Oriental Rainbow Building Materials Co., Ltd.
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Beijing Oriental Yuhong Waterproof Technology Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J195/00—Adhesives based on bituminous materials, e.g. asphalt, tar, pitch
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a kind of high tack adhesive waterproof coil, comprising following component, by percentage to the quality：Asphalt 35%~55%, softening agent 5%~25%, modifying agent 5%~25%, tackifier 2%~8%, interfacial agents 0.1%~2%, antioxidant 0.1%~3%, filler 5%~20%；Wherein, softening agent is naphthenic oil, modifying agent is the mixture of hydrogenated styrene butadiene block copolymer, styrene-isoprene-styrene block copolymer, butadiene-styrene rubber and devulcanized re-cycled rubber powder, and tackifier are C5 Petropols, the mixture of C9 Petropols and hydrogenated rosin glyceride.The adhesive waterproof coil of the present invention has good tack, there is a little dust even in substrate surface, it can also be carried out with basic unit in the case that wet base and temperature are relatively low good bonding, and it is not easily stripped after being bonded, it can ensure to leave complete modified pitch material in basic unit after stripping, it is ensured that higher water resistance.

Description

A kind of high tack adhesive waterproof coil and preparation method thereof
Present patent application is application number CN201310306329.6, July 19 2013 applying date, entitled A kind of divisional application of the patent of invention of high tack adhesive waterproof coil and preparation method thereof.
Technical field
The present invention relates to a kind of self-adhesive asphalt waterproof coiled material of high tack, belong to architectural waterproof material field.
Background technology
Self-adhesive asphalt waterproof coiled material is the waterproof material to grow up in recent years, suitable for industry and civil building Roofing, basement, interior, municipal works and cistern, swimming pool and subway tunnel waterproof, apply also for timber structure and gold Belong to the waterproofing work of structure roofing, the military installations for being particularly suitable for needing cold construction and the oil depot that should not employ naked light, change The waterproofing works such as factory, textile mills, grain depot.
Adhesive waterproof coil throws off surface isolation film under the conditions of normal construction, exposes self-adhesion sizing material, then again with basic unit It is bonded, forms one layer of waterproof layer.But there are floating ash, the situation that basic unit is moist or temperature is relatively low on basic unit's out-of-flatness, surface Under, it may appear that adhesive waterproof coil loosely, easily forms hollowing phenomenon, and can form a tunic not at basic unit interface with base adhesive Can be perfect Nian Jie with basic unit, it that is to say that after coiled material is stripped down from basic unit after constructing be interface unbound, it is impossible to stayed in basic unit Lower modified pitch material, so as to influence waterproof effect.
The content of the invention
The defects of for existing adhesive waterproof coil, present inventor roll up self-adhesion waterproof by a large amount of creative researches The composition of material is improved, so that a kind of adhesive waterproof coil with high tack has been invented, adhesive waterproof coil tool Have good tack, have a little dust in substrate surface, wet base and temperature it is relatively low in the case of can be carried out with basic unit Good bonding, and be not easily stripped after being bonded, it can ensure to leave complete modified pitch material in basic unit after stripping, it is ensured that Still there is higher water resistance.
Based on foregoing invention, applicant completes the present invention, and the present invention is achieved through the following technical solutions：
A kind of high tack adhesive waterproof coil, comprising following component, by percentage to the quality：Asphalt 35%~ 55%, softening agent 5%~25%, modifying agent 5%~25%, tackifier 2%~8%, interfacial agents 0.1%~2%, antioxidant 0.1%~3%, filler 5%~20%.
Preferably, the dosage of each component is, by percentage to the quality：Asphalt 40%~55%, softening agent 10%~ 17%, modifying agent 10%~20%, tackifier 3%~6%, interfacial agents 0.5%~1%, antioxidant 1%~2%, filler 10%~20%.
It is further preferred that the dosage of each component is, by percentage to the quality：Asphalt 50%, softening agent 15%, modifying agent 13%, tackifier 5%, interfacial agents 0.8%, antioxidant 1.2%, filler 15%.
In the further detailed description of the present invention and specific implementation, the preferred type of various composition used is disclosed, with Just more preferable, the clearer description present invention, but this detailed description does not form the special limitation to the present invention, not against this A little detailed information and use other general chemical materials of technical field, as long as to meet the present invention above-mentioned to each composition for it The restriction that Components Name is done, still belongs to protection scope of the present invention.
In the present invention, the asphalt is naphthene crude oils bitumen A level, and needle penetration is 70~200, in terms of 0.1mm.
In the present invention, the use of various auxiliary materials is not particularly restricted, every to meet chemically defined title Respective material be used equally for the present invention adhesive waterproof coil.
Wherein, softening agent is selected from maleic acid, 2-ethyl hexyl acrylate, second line of distillation machine oil, the line machine oil that subtracts three, furfural oil, ring One or more kinds of mixtures in alkane oil, aromatic naphtha, the cosolvent containing low-molecular-weight aromatic, are primarily to facilitate modification Agent and the swelling of additive.
Wherein, modifying agent is selected from styrene-butadiene block copolymer, hydrogenated styrene-butadiene block copolymer, benzene Ethene-isoprene-styrene block copolymer, butadiene-styrene rubber, neoprene, polyethylene, polypropylene, thermoplastic elastomer (TPE) One or more kinds of mixtures in POE, devulcanized re-cycled rubber powder, butyl reclaimed rubber, butyronitrile reclaimed rubber, are mainly used for carrying The various physical properties of high self-adhesive modified asphalt coiled material.
Wherein, tackifier are selected from alkyl phenol resin, C5 Petropols, C9 Petropols, terpene resin, liquid rosin tree It is one or more kinds of mixed in fat, hydrogenated rosin glyceride, phenolic resin, polyisobutene, epoxy resin, liquid C5 resins Compound, for improving the tack and bonding persistence of self-adhesion asphalt felt.
Wherein, interfacial agents are selected from polyvinyl acetate, polyacrylate, lignin sulfonic acid sodium salt water-reducing agent, naphthalene series high-efficiency Water-reducing agent, aliphatic high-efficiency water reducing agent, aminosulfonate-based superplasticizer are one or more kinds of in high performance water reducing agent of polyocarboxy acid Mixture, for reducing self-adhesion asphalt felt surface tension, improves " wetting " performance between self-adhesion asphalt felt and basic unit, from And interface cohesive force is improved, improve tack and the fastness being bonded in basic unit.
Wherein, antioxidant is selected from phenyl salicylate, Ultraviolet Absorber UV-P, UV-O, UV-531, light stabilizer GW- 540th, one or more kinds of mixtures in sulphur, sulfurous organic compound or organic peroxide, for improving from viscous bitumen The anti-aging property of coiled material.
Wherein, filler is in precipitated calcium carbonate, powdered whiting, mountain flour, pulverized limestone, flyash, talcum powder, carbon black One or more kinds of mixtures, for cause coiled material cure after bonding it is strong.
Correspondingly, high tack adhesive waterproof coil disclosed in this invention, can use conventional self-adhesion asphalt felt production Line produces, the production adhesive waterproof coil that can efficiently, inexpensive using existing production line, easy to large-scale industrial production Using.
Specifically, the preparation method of adhesive waterproof coil of the present invention, comprises the following steps：Asphalt is heated to 140 ~160 DEG C, softening agent, modifying agent and tackifier are then added, stirs evenly, is continuously heating to 160~180 DEG C, in this temperature Lower development 30~45 minutes, opens colloid mill and accelerates swelling process, and makes modifying agent homogenizing more complete, and interface is added after one hour Agent, antioxidant, stops colloid mill, at the uniform velocity stirs two hours, adds filler, continues development 45~90 minutes, the height is made Tack self-adhesive coiled material asphalt size.
Brief description of the drawings
Fig. 1 is the tack analyzer for detecting adhesive waterproof coil performance.
Embodiment
In following specific embodiments, The present invention gives the specific implementation of technical solution, and being only used for the present invention can How to realize, not the present invention is formed and is limited.On the basis of technical solution of the present invention is understood, the material of embodiment is replaced Change, dosage increase and decrease etc. still belong to protection scope of the present invention.
Embodiment 1
The high tack self-adhesive coiled material asphalt size 100kg of the production present invention, raw material used and its proportioning are as follows：
Wherein, asphalt hands over asphalt again for Qinhuangdao 90#；To subtract third fractional oil, propylene misery for Qinhuangdao for softening agent Ester and aromatic hydrocarbons cosolvent (mass ratio 7:2:1)；Modifying agent for styrene-butadiene block copolymer (SBS), styrene- Isoprene-styrene block copolymer (SIS), butadiene-styrene rubber (SBR) and butyl reclaimed rubber (mass ratio 3.5:2.2: 2.3:2)；Tackifier are C5 Petropols and terpene resin (mass ratio 6:4)；Interfacial agents are polyvinyl acetate；Antioxidant For UV-531 and light stabilizer GW-540 (mass ratioes 1:1)；Filler is precipitated calcium carbonate.
Embodiment 2
The high tack self-adhesive coiled material asphalt size 100kg of the production present invention, raw material used and its proportioning are as follows：
Wherein, asphalt hands over asphalt again for 70#；Softening agent is naphthenic oil and (mass ratio is aromatic hydrocarbons cosolvent 9:1)；Modifying agent is styrene-isoprene-styrene block copolymer (SIS), thermoplastic elastomer (TPE) POE, butadiene-styrene rubber (SBR) and butyronitrile reclaimed rubber (mass ratio 4:2:3:1)；Tackifier are C5 Petropols and liquid rosin resin (mass ratio For 7:3)；Interfacial agents are naphthalene series high-efficiency water-reducing agent；Antioxidant is UV-531 and sulphur (mass ratio 9:1)；Filler is lightweight Calcium carbonate.
Embodiment 3
The high tack self-adhesive coiled material asphalt size 100kg of the production present invention, raw material used and its proportioning are as follows：
Wherein, asphalt is 120# asphalt；Softening agent is naphthenic oil；Modifying agent is hydrogenated styrene-butadiene Block copolymer (SEBS), styrene-isoprene-styrene block copolymer (SIS), butadiene-styrene rubber (SBR) and desulfurization Regnerated rubber powder (mass ratio 2:3:3:2)；Tackifier are C5 Petropols, C9 Petropols and hydrogenated rosin glyceride (matter Amount is than being 4:4:2)；Interfacial agents are aliphatic high-efficiency water reducing agent；Antioxidant is sulphur；Filler is mountain flour.
Embodiment 4
The high tack self-adhesive coiled material asphalt size 100kg of the production present invention, raw material used and its proportioning are as follows：
Wherein, asphalt is 90# asphalt；Softening agent is aromatic naphtha and maleic acid (mass ratio 7:3)；It is modified Agent is styrene-butadiene block copolymer (SBS), polypropylene, butadiene-styrene rubber (SBR) and devulcanized re-cycled rubber powder (quality Than for 4:2:3:1)；Tackifier are C9 Petropols and epoxy resin (mass ratio 6:4)；Interfacial agents are polyacrylate；It is anti- Old agent is UV-P and sulphur (mass ratio 6:4)；Filler is powdered whiting.
In order to embody " high tack " defined in the present invention, the present invention is issued using State Administration for Quality Supervision and Inspection and Quarantine Standard GBT 4852-2002《Pressure-sensitive adhesive band tack test method (rolling ball method)》Carry out, test method is as follows：
Before preparing sample, self-adhesive asphalt waterproof coiled material should remove packaging material, non-overlapping copies in sample room temperature humidity bar More than when (21 DEG C~25 DEG C of temperature, humidity 60%~70%) placement 2 is small under part.
Sample：Specimen width is 10~80mm, and length about 250mm, its separation layer is thrown off with the speed of about 300mm/min, A sample is intercepted every 200mm or so, takes more than 4.When sample stretcher strain is larger, it is allowed to have parking no more than 3min Time, makes its recovery.Hand or other objects are not allowed to contact sample testing section during sampling.
Inclined-plane grounder device is by that can tilt 20 °, and 30 °, 40 ° of hang plate and its draw bail form, as shown in Figure 1, respectively Part is as follows:Hang plate 2 is installed on the stent 10 of base 1, and hang plate uses smooth rigid planar plate (glass plate, metal Plate, plank, plastic plate etc.), opposite with hang plate is box 3 of receiving.In order to adjust the inclination angle of hang plate, angle is equipped with stent Spend adjusting knob 11；In order to adjust position of the steel ball on hang plate, 20 position of ball device is put equipped with before and after steel ball in hang plate upper end Position adjusting knob 21, steel ball right position adjusting knob 22.Be also equipped with base air level 12 be used for calibrate to straight.
Wherein, rolling more than Duan Youchang 100mm are helped, transparent polyester film about 25 μm thick, is pasted on certainly in defined position Formed on viscous coiled material.Help rolling segment length 100mm.
Measure Duan Weicong helps rolling section lower end to start to count, and length is the gluing surface in the range of 100mm.
For spin material with GCr15 bearing steel makings, the precision grade of steel ball form tolerance and surface roughness should reach GB/ Class 4 more than 0 as defined in T 308.The ball number of spin is shown in Table 1 with corresponding nominal diameter.
The ball number of 1 spin of table and corresponding nominal diameter
Test method：
Grounder device is horizontally fixed on testboard with level meter, inclined plane takes 30 ° of standard angle.Also may be used when needing To take 20 ° or 40 °.
In the lower end of self-adhesive coiled material sample respectively with adhesive tape or counterweight (quality about 500g) is positioned, by sample with gluing surface Upward mode is fixed on defined position.Helping rolling section to be sticked on poly-vinegar film on the assigned position of sample gluing surface, It bubble is mingled with or is wrinkled when sticking poly-vinegar film, also not add big pressure.In fixed sample, it is careful not to It is allowed to that warpage occurs or heaves.If being heaved in marginal portion, this part is fixed on inclined plane using other adhesive tape On.
It is 100mm to make to help the consistent length of rolling section, according to the size of ball, as shown in Figure 1, ball center is adjusted in ball On initial position.
The ball that will be stored in antirust agent, is taken out with tweezers, is dipped in alcohol washes steel ball with gauze, after cleaning, has been placed on On beginning position, with different size of ball, the sequence of operations such as cleaning, the rolling of ball are repeated, it is (stone-dead in measure section from stopping at Up to more than 5s) each bulb in choose maximum.Take out the biggest ball that is found in same test piece and the ball number is adjacent thereto Two balls of size, are respectively once tested in same sample, to confirm the steel ball of biggest ball number.
In order to verify the beneficial effect of the high tack self-adhesive asphalt waterproof coiled material of the present invention, based on above-mentioned detection method to reality The tack for applying the self-adhesive asphalt waterproof coiled material of the preparation of example 1~4 is tested.Result of the test is shown in Table 2.
Table 2：The tack testing result of adhesive waterproof coil prepared by embodiment
Pilot project Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Tack 33 29 28 29
To the test of the current self-adhesive asphalt waterproof coiled material tack in market generally between 7-20# balls, and this test bit is remote Higher than this kind of product numerical value, show a kind of high tack self-adhesion asphalt waterproofing volume produced using inventive formulation and preparation method The tack of material reaches GBT 4852-2002《Pressure-sensitive adhesive band tack test method (rolling ball method)》Technical requirements, tool There is good tack, can be carried out with basic unit good bonding.

Claims (6)

1. a kind of high tack adhesive waterproof coil, it is characterised in that comprising following component, by percentage to the quality：Asphalt 35%~55%, softening agent 5%~25%, modifying agent 5%~25%, tackifier 2%~8%, interfacial agents 0.1%~2%, prevent Old agent 0.1%~3%, filler 5%~20%；Wherein,
The softening agent is naphthenic oil；
The modifying agent for hydrogenated styrene-butadiene block copolymer, styrene-isoprene-styrene block copolymer, The mixture of butadiene-styrene rubber and devulcanized re-cycled rubber powder；
The tackifier are C5 Petropols, the mixture of C9 Petropols and hydrogenated rosin glyceride；
The asphalt is naphthene crude oils bitumen A level, and needle penetration is 70~200, in terms of 0.1mm；
The interfacial agents are selected from polyvinyl acetate, polyacrylate, lignin sulfonic acid sodium salt water-reducing agent, naphthalene series high-efficiency diminishing It is one or more kinds of mixed in agent, aliphatic high-efficiency water reducing agent, aminosulfonate-based superplasticizer and high performance water reducing agent of polyocarboxy acid Compound.
2. high tack adhesive waterproof coil according to claim 1, it is characterised in that comprising following component, with quality hundred Divide than meter：Asphalt 40%~55%, softening agent 10%~17%, modifying agent 10%~20%, tackifier 3%~6%, boundary Face agent 0.5%~1%, antioxidant 1%~2%, filler 10%~20%.
3. high tack adhesive waterproof coil according to claim 1, it is characterised in that comprising following component, with quality hundred Divide than meter：Asphalt 50%, softening agent 15%, modifying agent 13%, tackifier 5%, interfacial agents 0.8%, antioxidant 1.2%, Filler 15%.
4. high tack adhesive waterproof coil according to claim 1, it is characterised in that in the modifying agent, hydrogenation of benzene Ethylene-butadiene block copolymer, styrene-isoprene-styrene block copolymer, butadiene-styrene rubber and desulfurization regeneration rubber The mass ratio of rubber powder is 2:3:3:2.
5. high tack adhesive waterproof coil according to claim 1, it is characterised in that in the tackifier, C5 oil The mass ratio of resin, C9 Petropols and hydrogenated rosin glyceride is 4:4:2.
6. the preparation method of high tack adhesive waterproof coil described in claim 1, it is characterised in that comprise the following steps：By stone Oil asphalt is heated to 140~160 DEG C, then adds softening agent, modifying agent and tackifier, stirs evenly, it is continuously heating to 160~ 180 DEG C, react 30~45 minutes at this temperature, open colloid mill and accelerate swelling process, and make modifying agent homogenizing more complete, one Add interfacial agents after hour, antioxidant, stops colloid mill, at the uniform velocity stirs two hours, adds filler, the reaction was continued 45~90 points Clock, is made the high tack self-adhesive coiled material asphalt size.
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