CN107033610A - A kind of fiber reinforcement type modified pitch roofing healant and preparation method thereof - Google Patents
A kind of fiber reinforcement type modified pitch roofing healant and preparation method thereof Download PDFInfo
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- CN107033610A CN107033610A CN201611044226.7A CN201611044226A CN107033610A CN 107033610 A CN107033610 A CN 107033610A CN 201611044226 A CN201611044226 A CN 201611044226A CN 107033610 A CN107033610 A CN 107033610A
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- China
- Prior art keywords
- healant
- fiber reinforcement
- modified pitch
- reinforcement type
- roofing
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
A kind of fiber reinforcement type modified pitch roofing healant and preparation method thereof, the roofing healant is made up of the raw material of following mass fraction, wherein, pitch is 20~50%, tackifying resin is 5~20%, polymer modifiers is 0.2~10%, solubilizer is 0.5~5%, inorganic reinforcing filler is 20~80%, auxiliary rheological agents are 0.5~2%, and reinforcing fiber is 1~10%, and antioxidant is 0.1~1.0%, organic solvent is 20~30%, and the mass percent sum of all raw material components is 100%.Present invention additionally comprises the preparation method of fiber reinforcement type modified pitch roofing healant.Product of the present invention has prominent adhesiveness, broad Acclimation temperature scope, good thixotropy, good ageing-resistant performance and extensive basic unit's adaptability.
Description
Technical field
A kind of roofing healant of the present invention and preparation method thereof, and in particular to a kind of fiber reinforcement type modified pitch roofing is repaiied
Tonic and preparation method thereof.
Background technology
Buildings waterproof concerns building safety, building energy conservation and common people's people's livelihood, and the quality of waterproofing quality is directly influenced
The service life of building and living and working in peace and contentment for the people, while influenceing the normal operation of production.However, architectural engineering seepage is asked
Topic, especially roof leakaging problem remains high always for a long time, to national wealth and people's lives cause very big loss and
Unnecessary worry.Investigated according to building waterproofing industry association of China, the new house one of the current country 65% to occurring in two years
Different degrees of seepage, 65% construction waterproofing engineering needs renovation after 6~8 years.Leakage of building has become outside structure
Two big building problems, the numerous developers of long-standing problem and the people.
At present, roofworks treating seepage mainly includes two schemes, including overall overhaul is administered with local.For entirety
Overhaul, it is similar with new roofing of repairing, various waterproof rolls and water-repellent paint can be selected, is substantially more expensive, the cycle is longer, and
It is difficult to be applicable in many cases.Therefore, local improvement is carried out to roof leakage, as the first choice side for solving Leakage Problems in Buildings
Case, the selection of its waterproof material typically should specifically be selected according to roof leakage scope, leak magnitude, leakage cause and environmental quality etc.
Select.However, so far in the market also not dedicated for roofing repair waterproof material, more with various water-repellent paints, sealing or
Grouting material is substituted, and some are even directly with hot-melt asphalt as patching material, and these materials are either in workability, application
All it is difficult to the requirement for meeting roofing healant in terms of performance and ageing-resistant performance.Therefore, for the leakage problems of building roof, urgently
A permeability to be developed is strong, good to basic unit's caking property, and application property and basic unit adapt to, and both can be applied to most basic units
(cement, concrete, macromolecule, metal etc.), can also construct in wet base, and the fiber with good ageing-resistant performance
Enhanced modified pitch roofing healant.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of with prominent adhesiveness, broad Acclimation temperature model
Enclose, good thixotropy, good ageing-resistant performance and the sticky clay shape roofing repairing of the one-component of extensive basic unit's adaptability
Agent.
The technical scheme that the present invention solves the use of its technical problem is that a kind of fiber reinforcement type modified pitch roofing is repaired
Agent, is made up of the raw material of following mass fraction, wherein, pitch is 20~50%, and tackifying resin is 5~20%, polymer modification
Agent is 0.2~10%, and solubilizer is 0.5~5%, and inorganic reinforcing filler is 20~80%, and auxiliary rheological agents are 0.5~2%, enhancing
Fiber is 1~10%, and antioxidant is 0.1~1.0%, and organic solvent is 20~30%, and the quality hundred of all raw material components
It is 100% to divide than sum.
Further, the pitch is 90# asphalt.
Further, the tackifying resin be coumarone indene resin, terpene resin, rosin resin, Petropols, phenolic resin,
Mixture more than one or both of epoxy resin and xylene formaldehyde resin.
Further, the polymer modifiers is nitrile rubber, butadiene-styrene rubber, natural rubber, butadiene rubber, neoprene rubber
Glue, styrene-butadiene-styrene (SBS), SIS (SIS), benzene second
Alkene-ethylene-butylene, Styrene block copolymer (SEBS) and styrene ethylene-propylene-styrene type block copolymer
One or both of (SEPS) mixture more than.
Further, the solubilizer is to subtract third fractional oil and/or aromatic naphtha.
Further, the inorganic reinforcing filler is powdered whiting and/or talcum powder.
Further, the reinforcing fiber is one in cellulose fibre, polyester fiber, polypropylene fibre and lignin fibre
Plant or two or more mixtures.
Further, the auxiliary rheological agents be organobentonite, polyamide, aerosil and castor oil in one kind or
Two or more mixtures.
Further, organic solvent is gasoline, 120# solvent naphthas, 140# solvent naphthas, dimethylbenzene, trimethylbenzene and Stoddard
Mixture more than one or both of solvent.
The present invention further solve its technical problem use technical scheme be, a kind of fiber reinforcement type modified pitch roofing
The preparation method of healant, by pitch, tackifying resin, polymer modifiers, solubilizer, in 160~190 DEG C of high speed shears, system
The modified pitch obtained, is then cooled to 100~120 DEG C of addition organic solvents, continues to be cooled to room temperature, adds inorganic enhancing and fills out
Material, reinforcing fiber, auxiliary rheological agents, antioxidant, are stirred under high speed agitator,.
Compared with the repairing of existing roofing various water-repellent paints, encapsulant used, the present invention has advantages below：
(1) extensive basic unit adaptability：It is each for cement concrete, cement fibrolite plate, high polymer material, asphalt material etc.
Planting material all has good adhesiveness, can not only dry basal plane construction, and can be constructed in wet base.
(2) prominent adhesiveness：Adhesion strength for cement concrete basic unit reaches more than 0.6Mpa.
(3) broad Acclimation temperature scope：Modified pitch roofing healant product heat resistance of the present invention reach 170 DEG C with
On, the low temperature flexibility limit is below -15 DEG C, with broad temperature application range.
(4) good workability：Modified pitch roofing healant product of the present invention had both been suitable for plane construction, also was adapted for
It is once thick to apply 3mm not saggings in elevation construction, with good thixotropy.
The present invention is applied in crack repairing, joint seals such as roofworks, reservoir dam, drainage pipelines (undrinkable water)
Deng.
Embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1
By 45 parts of 90# pitches, 15 parts of coumarone indene resins, 6 parts of SEBS, 2 parts of aromatic naphtha, in 170 DEG C of high speed shear 3h, system
The modified pitch obtained, is then cooled to 100~120 DEG C of additions, 25 parts of xylene solvents, continues to be cooled to room temperature, add 50 parts of carbon
Sour calcium, 6 parts of lignin fibres, 2 parts of organobentonites and 0.5 part of antioxidant 1010,20min is stirred under high speed agitator,
Produce fiber reinforcement type modified pitch roofing healant.
Embodiment 2
It is obtained in 180 DEG C of high speed shear 3h by 40 parts of 90# pitches, 10 parts of Petropols, 6 parts of SBS, 1 part of aromatic naphtha
Modified pitch, is then cooled to 100~120 DEG C of additions, 23 parts of xylene solvents, continues to be cooled to room temperature, add 45 parts of carbonic acid
Calcium, 4 parts of polyester fibers, 2 parts of polyamide and 0.5 part of antioxidant 1010, stir 20min under high speed agitator, produce fiber
Enhanced modified pitch roofing healant.
Embodiment 3
By 50 parts of 90# pitches, 10 parts of rosin resins, 6 parts of SEBS, 2 parts of aromatic naphtha, in 180 DEG C of high speed shear 3h, it is made
Modified pitch, be then cooled to 100~120 DEG C of additions, 25 parts of xylene solvents, continue to be cooled to room temperature, add 50 parts of carbonic acid
Calcium, 6 parts of PP fibers, 2 parts of organobentonites, 1 part of aerosil and 0.5 part of antioxidant 1010, under high speed agitator
20min is stirred, fiber reinforcement type modified pitch roofing healant is produced.
Embodiment 4
By the oil that subtracts three of 40 parts of 90# pitches, 10 parts of novolac epoxy resin resins, 6 parts of SBS, 2 parts, in 175 DEG C of high speed shears
Then 3h, obtained modified pitch is cooled to 100~120 DEG C of additions, 25 parts of xylene solvents, continues to be cooled to room temperature, add
50 parts of calcium carbonate, 6 parts of polyester fibers, 2 parts of organobentonites, 1 part of polyamide and 0.5 part of antioxidant 1010, in high-speed stirred
20min is stirred under device, fiber reinforcement type modified pitch roofing healant is produced.
According to GB/T 16777-2008《Test methods for building waterproof coatings》Test, the physical force of the product of embodiment 1~4
Learn performance as shown in table 1：
The physical and mechanical property test result of the product of table 1- embodiments 1~4
Claims (10)
1. a kind of fiber reinforcement type modified pitch roofing healant, it is characterised in that be made up of the raw material of following mass fraction, its
In, pitch is 20~50%, and tackifying resin is 5~20%, and polymer modifiers is 0.2~10%, and solubilizer is 0.5~5%,
Inorganic reinforcing filler be 20~80%, auxiliary rheological agents be 0.5~2%, reinforcing fiber be 1~10%, antioxidant be 0.1~
1.0%, organic solvent is 20~30%, and the mass percent sum of all raw material components is 100%.
2. fiber reinforcement type modified pitch roofing healant according to claim 1, it is characterised in that the pitch is
90# asphalt.
3. fiber reinforcement type modified pitch roofing healant according to claim 1, it is characterised in that the tackifying resin
For in coumarone indene resin, terpene resin, rosin resin, Petropols, phenolic resin, epoxy resin and xylene formaldehyde resin
One or more kinds of mixtures.
4. fiber reinforcement type modified pitch roofing healant according to claim 1, it is characterised in that the polymer changes
Property agent be nitrile rubber, butadiene-styrene rubber, natural rubber, butadiene rubber, neoprene, s-B-S copolymerization
Thing, SIS, styrene-ethylene-butylene-styrene block copolymer and benzene second
Mixture more than one or both of alkene-ethylene-propylene, Styrene type block copolymer.
5. fiber reinforcement type modified pitch roofing healant according to claim 1, it is characterised in that the solubilizer is
Subtract third fractional oil and/or aromatic naphtha.
6. fiber reinforcement type modified pitch roofing healant according to claim 1, it is characterised in that the inorganic enhancing
Filler is powdered whiting and/or talcum powder.
7. fiber reinforcement type modified pitch roofing healant according to claim 1, it is characterised in that the reinforcing fiber
For mixture more than one or both of cellulose fibre, polyester fiber, polypropylene fibre and lignin fibre.
8. fiber reinforcement type modified pitch roofing healant according to claim 1, it is characterised in that the auxiliary rheological agents
For mixture more than one or both of organobentonite, polyamide, aerosil and castor oil.
9. fiber reinforcement type modified pitch roofing healant according to claim 1, it is characterised in that organic solvent is vapour
Mixing more than one or both of oil, 120# solvent naphthas, 140# solvent naphthas, dimethylbenzene, trimethylbenzene and stoddard solvent
Thing.
10. a kind of preparation method of fiber reinforcement type modified pitch roofing healant as described in one of claim 1~9, its
It is characterised by, by pitch, tackifying resin, polymer modifiers, solubilizer, in 160~190 DEG C of high speed shears, obtained modification
Pitch, is then cooled to 100~120 DEG C of addition organic solvents, continues to be cooled to room temperature, adds inorganic reinforcing filler, enhancing fibre
Dimension, auxiliary rheological agents, antioxidant, are stirred under high speed agitator,.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611044226.7A CN107033610B (en) | 2016-11-23 | 2016-11-23 | Fiber-reinforced modified asphalt roof repairing agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611044226.7A CN107033610B (en) | 2016-11-23 | 2016-11-23 | Fiber-reinforced modified asphalt roof repairing agent and preparation method thereof |
Publications (2)
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| CN107033610A true CN107033610A (en) | 2017-08-11 |
| CN107033610B CN107033610B (en) | 2020-01-14 |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107841925A (en) * | 2017-10-26 | 2018-03-27 | 蓝婷 | Road surface prosthetic device and technology |
| CN108467700A (en) * | 2018-03-29 | 2018-08-31 | 宁夏睿泰天成新材料科技有限公司 | A kind of SMC pitches cold-patch agent and preparation method thereof |
| CN108864719A (en) * | 2018-07-26 | 2018-11-23 | 江苏增光复合材料科技有限公司 | The ground surface material of stretch-proof Resisting fractre |
| CN109109886A (en) * | 2018-08-22 | 2019-01-01 | 佛山豆萁科技有限公司 | A kind of city rail compartment electric heater |
| CN109181329A (en) * | 2018-09-29 | 2019-01-11 | 杨林 | Stable anti-cracking modified asphalt and preparation method thereof |
| CN109181323A (en) * | 2018-07-20 | 2019-01-11 | 鞍山科顺建筑材料有限公司 | A kind of waterproof roll age-resistant modified asphalt and preparation method thereof |
| CN109422483A (en) * | 2017-08-25 | 2019-03-05 | 山东路联交通材料有限公司 | A kind of road cracking repair materials and construction method |
| CN109762468A (en) * | 2019-03-25 | 2019-05-17 | 河北建设集团股份有限公司 | A kind of asphalt concrete pavement protective agent and its preparation method and application |
| CN110527310A (en) * | 2019-08-19 | 2019-12-03 | 江苏增光复合材料科技有限公司 | A kind of waterproof antiskid asphalt pavement conserving material |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109422483A (en) * | 2017-08-25 | 2019-03-05 | 山东路联交通材料有限公司 | A kind of road cracking repair materials and construction method |
| CN107841925A (en) * | 2017-10-26 | 2018-03-27 | 蓝婷 | Road surface prosthetic device and technology |
| CN108467700A (en) * | 2018-03-29 | 2018-08-31 | 宁夏睿泰天成新材料科技有限公司 | A kind of SMC pitches cold-patch agent and preparation method thereof |
| CN109181323A (en) * | 2018-07-20 | 2019-01-11 | 鞍山科顺建筑材料有限公司 | A kind of waterproof roll age-resistant modified asphalt and preparation method thereof |
| CN108864719A (en) * | 2018-07-26 | 2018-11-23 | 江苏增光复合材料科技有限公司 | The ground surface material of stretch-proof Resisting fractre |
| CN109109886A (en) * | 2018-08-22 | 2019-01-01 | 佛山豆萁科技有限公司 | A kind of city rail compartment electric heater |
| CN109181329A (en) * | 2018-09-29 | 2019-01-11 | 杨林 | Stable anti-cracking modified asphalt and preparation method thereof |
| CN109762468A (en) * | 2019-03-25 | 2019-05-17 | 河北建设集团股份有限公司 | A kind of asphalt concrete pavement protective agent and its preparation method and application |
| CN110527310A (en) * | 2019-08-19 | 2019-12-03 | 江苏增光复合材料科技有限公司 | A kind of waterproof antiskid asphalt pavement conserving material |
| CN110527310B (en) * | 2019-08-19 | 2021-09-03 | 江苏增光新材料科技股份有限公司 | Waterproof and anti-skid asphalt pavement maintenance material |
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| CN107033610B (en) | 2020-01-14 |
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Effective date of registration: 20200925 Address after: 101300 Shunyi District Shunping road section of Beijing City Area No. 2 Patentee after: Beijing Oriental Yuhong Waterproof Technologies Co.,Ltd. Patentee after: SHANGHAI ORIENTAL YUHONG WATERPROOF TECHNOLOGY Co.,Ltd. Address before: 101309 Shunyi District Shunping road section of Beijing City Area No. 2 Patentee before: Beijing Oriental Yuhong Waterproof Technologies Co.,Ltd. |
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Effective date of registration: 20210714 Address after: 101309 Sha Ling section 2, Shunping Road, Shunyi District, Beijing Patentee after: Beijing Oriental Yuhong Waterproof Technologies Co.,Ltd. Address before: 101300 a 2, Shaling section, Shunping Road, Shunyi District, Beijing Patentee before: Beijing Oriental Yuhong Waterproof Technologies Co.,Ltd. Patentee before: SHANGHAI ORIENTAL YUHONG WATERPROOF TECHNOLOGY Co.,Ltd. |