CN108467700A - A kind of SMC pitches cold-patch agent and preparation method thereof - Google Patents

A kind of SMC pitches cold-patch agent and preparation method thereof Download PDF

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Publication number
CN108467700A
CN108467700A CN201810282221.0A CN201810282221A CN108467700A CN 108467700 A CN108467700 A CN 108467700A CN 201810282221 A CN201810282221 A CN 201810282221A CN 108467700 A CN108467700 A CN 108467700A
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CN
China
Prior art keywords
parts
resin
surfactant
agent
cold
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810282221.0A
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Chinese (zh)
Inventor
何鹏
马成
郭朝阳
王天军
马海洋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ningxia Rui Tai Tiancheng New Mstar Technology Ltd
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Ningxia Rui Tai Tiancheng New Mstar Technology Ltd
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Application filed by Ningxia Rui Tai Tiancheng New Mstar Technology Ltd filed Critical Ningxia Rui Tai Tiancheng New Mstar Technology Ltd
Priority to CN201810282221.0A priority Critical patent/CN108467700A/en
Publication of CN108467700A publication Critical patent/CN108467700A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention belongs to asphalt additive production fields, and in particular to a kind of SMC pitches cold-patch agent and preparation method thereof;Composition of raw materials includes methyl styrene based block copolymer, reinforcing agent, surfactant and resin, wherein the mass fraction of various raw materials is 15 20 parts of 75 82 parts of methyl styrene based block copolymer, 23 parts of reinforcing agent, 12 parts of surfactant and resin;Wherein reinforcing agent is the mixture of lignin, polyester, one kind in polyacrylonitrile three, two kinds or three kinds, surfactant is one or both of both ethylene oxide polymerization surfactant and AB type block macromolecular surfactants mixture, and resin is epoxy resin, phenolic resin, one kind in polyamide three, two kinds or three kinds of mixtures;Simple production process is not necessarily to special process and equipment, and storage period is long, on-demand, and the hole after repairing is not likely to produce the bad phenomenons such as fall off, be cracked, and is not required to repeat to repair.

Description

A kind of SMC pitches cold-patch agent and preparation method thereof
Technical field:
The invention belongs to asphalt additive production fields, and in particular to a kind of SMC pitches cold-patch agent and preparation method thereof.
Background technology:
SMC pitch cold-patch agent is the methyl styrene based block copolymer to be extracted from waste plastic, rubber etc. (Styrenic Methyl Copolymers abbreviation SMC) be primary raw material, add certain type and quantity surfactant, Resin etc., miscible manufactured organic solution, as asphalt cold repairing modifying agent.Asphalt modifier when cold-repairing material production can be regarded It uses, is suitable for the pit repairing of each standard highway bituminous paving.The pavement performance of SMC cold-repairing materials is suitable with traditional hot-patch material, The repairing and maintenance on the various road surfaces such as highway, ordinary highway, town road, airport, bridge and tunnel are can be widely used for, it is real Border service life is durable, can make up the previous undesirable technological deficiency of cold mixing material pavement performance.
About 100 DEG C lower than hot-mix asphalt mixture or so of mixture temperature when cold repairing asphalt mixture produces, not only Producing cost is low, it is important that reduces the aging of pitch, can extend the service life of cold-repairing material.It is said from work progress, heat drip Green mixture construction is by temperature limiting, it is desirable that temperature is not less than 5 DEG C, and otherwise asphalt Forming Quality will reduce, and cold The construction of feed supplement then is not influenced to construct under subzero 15 DEG C of temperature by temperature, and quality can still ensure that cold-repairing material has simultaneously Standby good water resistance, in rain and snow with can construct under the conditions of the ponding hole punished, when bottom condition is good Even without spread adhesion coating pitch, thus bring great convenience to the maintenance on road surface, in addition, cold-patch agent be it is a kind of at Product can be stored, on-demand.There is the cold asphalt mixture for meeting high-quality raw material requirement good adhesion property, material to match System can be adjusted according to various regions varying environment condition and purposes, be bituminous concrete, coagulating cement for repaired object Without apparent selectivity when soil, bridge floor material, all kinds of base materials.
When repairing bituminous paving pit-hole using cold asphalt mixture, without large-scale mixture laying and compacting equipment, only rely on small The simple construction equipment of type, when unconditional even available artificial process pave molding by Construction traffic and road by vehicle Can complete compacting link, stock with take with, it is not high to working space and personnel requirement, work progress have greatly flexibly Property.
Invention content:
The present invention provides a kind of SMC pitches cold-patch agent and preparation method thereof, and preparation method is simple, superior performance, bond Property it is good, intensity is high.
A kind of composition of raw materials of SMC pitches cold-patch agent, including methyl styrene based block copolymer, reinforcing agent, surface work Property agent and resin, wherein the mass fraction of various raw materials be 75-82 parts of methyl styrene based block copolymer, 2-3 parts of reinforcing agent, 15-20 parts of 1-2 parts of surfactant and resin;Wherein reinforcing agent is lignin, polyester, one kind in polyacrylonitrile three, two Kind or three kinds of mixture, surfactant are ethylene oxide polymerization surfactant and AB type block macromolecular surface-actives One or both of both agent mixture, resin are epoxy resin, phenolic resin, one kind in polyamide three, two Kind or three kinds of mixtures.
Preferably, the mass fraction of various raw materials is methyl styrene class in a kind of composition of raw materials of SMC pitches cold-patch agent 17 parts of 79 parts of block copolymer, 2.5 parts of reinforcing agent, 1.5 parts of surfactant and resin.
A kind of production technology of SMC pitches cold-patch agent, it is characterised in that:
The first step:It weighs, methyl styrene based block copolymer 75-82 is weighed according to the raw material proportioning in claim 1 Part, 2-3 parts of reinforcing agent, 1-2 parts of surfactant and 15-20 parts of resin;
Second step:Stirring, by after above-mentioned weigh methyl styrene based block copolymer, reinforcing agent, surfactant and Resin pours into same blender, stirs 1-5 minutes at normal temperatures.
Simple production process of the present invention is not necessarily to special process and equipment, can be complete using the original equipment of cold and hot feed supplement At production, and production process is easy, quick.SMC cold-repairing material storage periods, are long, on-demand, not by weather and hole size Limitation, surplus material can be continuing in repairing next time, not cause the waste of mixture.SMC cold-repairing material adhesion strengths are strong, with drip Green concrete, cement concrete, metal, wooden road surface is combined preferable cohesive force, and the hole after repairing is not likely to produce The bad phenomenons such as fall off, be cracked, and is not required to repeat to repair.SMC cold-repairing materials are improving pavement performance and are making compared with traditional cold-repairing material With suitable with traditional cold mixing feed supplement price in the case of the service life, compared with traditional hot-patch material and temperature compensation material, the energy of consumption is released The pernicious gas put is less.
Specific embodiment:
Embodiment one:
A kind of composition of raw materials of SMC pitches cold-patch agent, including methyl styrene based block copolymer, reinforcing agent, surface work Property agent and resin, wherein the mass fraction of various raw materials is 75 parts of methyl styrene based block copolymer, 3 parts of reinforcing agent, surface 20 parts of 2 parts of activating agent and resin;Wherein reinforcing agent is lignin and polyester, and surfactant is ethylene oxide polymerization surface-active Agent and AB type block macromoleculars two kinds of mixtures of surfactant, resin are epoxy resin and phenolic resin.
A kind of production technology of SMC pitches cold-patch agent, it is characterised in that:
The first step:Weigh, according to the raw material proportioning in claim 1 weigh 75 parts of methyl styrene based block copolymer, 20 parts of 3 parts of reinforcing agent, 2 parts of surfactant and resin;Wherein, reinforcing agent is lignin and polyester, and surfactant is epoxy Ethane polymeric surfactant and AB type block macromoleculars two kinds of mixtures of surfactant, resin are epoxy resin and phenolic aldehyde tree Fat.
Second step:Stirring, by after above-mentioned weigh methyl styrene based block copolymer, reinforcing agent, surfactant and Resin pours into same blender, stirs 1-5 minutes at normal temperatures.
Embodiment two:
A kind of composition of raw materials of SMC pitches cold-patch agent, including methyl styrene based block copolymer, reinforcing agent, surface work Property agent and resin, wherein the mass fraction of various raw materials is 79 parts of methyl styrene based block copolymer, 2.5 parts of reinforcing agent, table 17 parts of 1.5 parts of face activating agent and resin;Wherein reinforcing agent is polyester and polyacrylonitrile, and surfactant is ethylene oxide polymerization table Face activating agent, resin are phenolic resin and polyamide.
A kind of production technology of SMC pitches cold-patch agent, it is characterised in that:
The first step:Weigh, according to the raw material proportioning in claim 1 weigh 79 parts of methyl styrene based block copolymer, 17 parts of 2.5 parts of reinforcing agent, 1.5 parts of surfactant and resin;Wherein reinforcing agent is polyester and polyacrylonitrile, and surfactant is Ethylene oxide polymerization surfactant, resin are phenolic resin and polyamide;
Second step:Stirring, by after above-mentioned weigh methyl styrene based block copolymer, reinforcing agent, surfactant and Resin pours into same blender, stirs 1-5 minutes at normal temperatures.
Embodiment three:
A kind of composition of raw materials of SMC pitches cold-patch agent, including methyl styrene based block copolymer, reinforcing agent, surface work Property agent and resin, wherein the mass fraction of various raw materials is 82 parts of methyl styrene based block copolymer, 2 parts of reinforcing agent, surface 15 parts of 1 part of activating agent and resin;Wherein reinforcing agent is lignin, polyester and polyacrylonitrile, and surfactant is that AB types block is high Molecular surface active agent, resin are three kinds of epoxy resin, phenolic resin, polyamide mixtures.
A kind of production technology of SMC pitches cold-patch agent, it is characterised in that:
The first step:Weigh, according to the raw material proportioning in claim 1 weigh 82 parts of methyl styrene based block copolymer, 15 parts of 2 parts of reinforcing agent, 1 part of surfactant and resin;Wherein reinforcing agent is lignin, polyester and polyacrylonitrile, surface-active Agent is AB type block macromolecular surfactants, and resin is three kinds of epoxy resin, phenolic resin, polyamide mixtures;
Second step:Stirring, by after above-mentioned weigh methyl styrene based block copolymer, reinforcing agent, surfactant and Resin pours into same blender, stirs 1-5 minutes at normal temperatures.

Claims (3)

1. a kind of composition of raw materials of SMC pitches cold-patch agent, it is characterised in that:Including methyl styrene based block copolymer, enhancing Agent, surfactant and resin, wherein the mass fraction of various raw materials is 75-82 parts of methyl styrene based block copolymer, increases 15-20 parts of strong 2-3 parts of agent, 1-2 parts of surfactant and resin;Wherein reinforcing agent is in lignin, polyester, polyacrylonitrile three One kind, two kinds or three kinds mixture, surfactant is ethylene oxide polymerization surfactant and AB type block high scores One or both of both sub- surfactants mixture, resin are in epoxy resin, phenolic resin, polyamide three One kind, two kinds or three kinds of mixtures.
2. a kind of raw materials for production of SMC pitches cold-patch agent according to claim 1, it is characterised in that:A kind of SMC pitches are cold The mass fraction of various raw materials is 79 parts of methyl styrene based block copolymer, 2.5 parts of reinforcing agent, table in the composition of raw materials of tonic 17 parts of 1.5 parts of face activating agent and resin.
3. a kind of production technology of SMC pitches cold-patch agent, it is characterised in that:
The first step:It weighs, weighs 75-82 parts of methyl styrene based block copolymer according to the raw material proportioning in claim 1, increases 15-20 parts of strong 2-3 parts of agent, 1-2 parts of surfactant and resin;
Second step:Stirring, by methyl styrene based block copolymer, reinforcing agent, surfactant and the resin after above-mentioned weigh It pours into same blender, stirs 1-5 minutes at normal temperatures.
CN201810282221.0A 2018-03-29 2018-03-29 A kind of SMC pitches cold-patch agent and preparation method thereof Pending CN108467700A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109852082A (en) * 2018-12-29 2019-06-07 湖南鑫长胜材料科技有限公司 A kind of modified SMC room temperature pitch and preparation method thereof
CN110387132A (en) * 2019-08-22 2019-10-29 河南万里交通科技集团股份有限公司 A kind of nano modified alphalt cold-repairing material and preparation method thereof
CN115746546A (en) * 2022-11-15 2023-03-07 大连海事大学 Resin-based asphalt pavement shallow groove repairing material and preparation method and construction method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102190459A (en) * 2010-03-10 2011-09-21 中国石油天然气股份有限公司 Storable emulsified asphalt cold-patch mixture and preparation method and application thereof
CN102826792A (en) * 2012-09-13 2012-12-19 安徽路达泰克沥青新材料有限公司 Preparation method of LB cold patch material
WO2017088892A1 (en) * 2015-11-24 2017-06-01 Inbicon A/S Bitumen compositions comprising lignin
CN107033610A (en) * 2016-11-23 2017-08-11 北京东方雨虹防水技术股份有限公司 A kind of fiber reinforcement type modified pitch roofing healant and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102190459A (en) * 2010-03-10 2011-09-21 中国石油天然气股份有限公司 Storable emulsified asphalt cold-patch mixture and preparation method and application thereof
CN102826792A (en) * 2012-09-13 2012-12-19 安徽路达泰克沥青新材料有限公司 Preparation method of LB cold patch material
WO2017088892A1 (en) * 2015-11-24 2017-06-01 Inbicon A/S Bitumen compositions comprising lignin
CN107033610A (en) * 2016-11-23 2017-08-11 北京东方雨虹防水技术股份有限公司 A kind of fiber reinforcement type modified pitch roofing healant and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109852082A (en) * 2018-12-29 2019-06-07 湖南鑫长胜材料科技有限公司 A kind of modified SMC room temperature pitch and preparation method thereof
CN110387132A (en) * 2019-08-22 2019-10-29 河南万里交通科技集团股份有限公司 A kind of nano modified alphalt cold-repairing material and preparation method thereof
CN115746546A (en) * 2022-11-15 2023-03-07 大连海事大学 Resin-based asphalt pavement shallow groove repairing material and preparation method and construction method thereof
CN115746546B (en) * 2022-11-15 2024-02-20 大连海事大学 Resin-based asphalt pavement shallow groove repair material and preparation method and construction method thereof

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Application publication date: 20180831