CN105860925B - A kind of molecule adhesive for TPZ waterproof rolls and preparation method thereof - Google Patents
A kind of molecule adhesive for TPZ waterproof rolls and preparation method thereof Download PDFInfo
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- CN105860925B CN105860925B CN201610297514.7A CN201610297514A CN105860925B CN 105860925 B CN105860925 B CN 105860925B CN 201610297514 A CN201610297514 A CN 201610297514A CN 105860925 B CN105860925 B CN 105860925B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J195/00—Adhesives based on bituminous materials, e.g. asphalt, tar, pitch
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
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- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of molecule adhesive for TPZ waterproof rolls and preparation method thereof, the adhesive includes the component of following parts by weight：5 10 parts of 50 70 parts of asphalt, 8 15 parts of second line of distillation cycloalkanes base oil, 5 10 parts of SBS rubber, 38 parts of SBR rubber, 25 parts of neoprene, 13 parts of nitrile rubber, 38 parts of Petropols and calcium powder.The adhesive-layer that the adhesive is formed can low temperature fusion bonding, adhering and sealing is good, for TPZ waterproof rolls, effectively improves the performance of TPZ waterproof rolls.
Description
Technical field
The present invention relates to a kind of adhesive, and in particular to a kind of for the molecule adhesive of TPZ waterproof rolls and its preparation
Method.
Background technology
Adhesive is the nonmetallic media material for making object closely be connected as one with another object also known as adhesive.Two
Adhesive only accounts for one layer of very thin volume between individual adherend face, but completes to be glued after construction using adhesive, and gained is glued
Part can meet the requirements being actually needed in terms of mechanical performance and physical and chemical performance, and effectively materials from bonding can exist
Together.As expanding economy synthetic adhesive is increasingly being applied to every field.
The performance of the adhesive that building trade waterproof roll is used has important work for the waterproof effect of waterproof roll
With.
At present, the adhesive that building trade waterproof roll is used has the disadvantage that the waterproof of influence waterproof roll is imitated
Really.
(1) the viscous Wen Nengneng of glue-line is poor, and when environment temperature≤15 DEG C, glue-line cannot accomplish the bonding shape for combining together
State, the viscosity of material performance is only that table glues, and now adhesion between components do not possess water resistance.
(2) coiled material and basic unit's easy situation for seal bond failure occur of wet-laying construction, increase engineering large area channeling water seepage
Risk occur：
1. easily there is the situation of sealing failure in low temperature wet-laying, and common wet-laying coiled material is relatively low when environment temperature (≤5~10 DEG C)
When, glue-line viscosity is reduced rapidly, and the coiled material now constructed with the bonding of the cement mortar of solidification, and cannot occur wet-laying sealing failure.
2. easily there is the situation of sealing failure in high temperature wet-laying, and traditional wet-laying coiled material is situated between using the bonding that cement mortar does overlap edge
Coiled material in matter, construction 4 hours, because of ground cement mortar not first cure in overlap edge, therefore cannot carry out watering cooling measure, when applying
When work environment temperature is higher, high temperature makes moisture in cement slurry produce evaporation, the vapor that coiled material can be evaporated with basic unit every
From, cause waterproof layer wet-laying seal failure.
3. dashed forward in wet-laying work progress and meet the situation that sealing failure easily occurs in rainfall, traditional wet-laying coiled material is done using cement mortar
The bonding medium of overlap edge, as met rainfall because prominent in wet-laying work progress, rainwater can dilute coiled material overlap edge in 4 hours of constructing
Not first cure cement mortar, failure is sealed into waterproof layer wet-laying between coiled material and basic unit, is caused.
(3) when there is the sealing failure of wet-laying coiled material, it will usually the situation of engineering large area seepage occurs, reason is as follows：
1. the waterproof layer that wet-laying sealing fails, the guarantee of water resistance is mainly by overlap edge continuous sealing, common wet-laying
Coiled material uses cement mortar to be bonded for medium mostly, and rigid cement grout is easily crushed between two layers of flexible material, is caused and is taken
Edge fit seeps water, and causes engineering large area channeling water seepage.A small number of wet-laying coiled material lapping sides are bonded using glue-line, because of glue-line viscosity-temperature characteristics
Difference, directly bonding can not reach waterproof effect, and engineering can still occur channeling water seepage.
2. because wet-laying seals failure, coiled material layer has any breakage, at some positions of engineering, all can inevitably draw
The situation for sending out engineering large area channeling water seepage occurs.Such as the waterproof layer at underground engineering top board position, because its top layer of structure is multiple
It is miscellaneous, there are backfill, square brick, structure reversed beam etc. to exist, and the gradient is small or does not look for slope, causes top board impeded drainage, waterproof layer
Surface long term has bright hydropexis.If waterproof layer has damaged or defect, the bright water penetrated into inside waterproof layer will be along sand
Slurry screed-coat and the channeling water passage large area diffusion with structure interlayer, cause engineering leakage.
(4) common wet-laying coiled material construction quality is larger by inside even from weather, environment temperature it is too high, too low, constructed
May be happened suddenly in journey rainfall weather construction, cannot ensure wet-laying construction quality, easily trigger engineering leakage.
The content of the invention
Defect it is an object of the invention to be directed to prior art, there is provided the adhesive-layer that a kind of adhesive is formed can low temperature melt
Bonding is closed, adhering and sealing is good, can be used for molecule adhesive of TPZ waterproof rolls and preparation method thereof.
The technical scheme is that, a kind of molecule adhesive for TPZ waterproof rolls, including following parts by weight
Component：
Preferably, the asphalt is preferably No. 100 and hands over asphalt again.
The Petropols are preferably one or two in group aliphatic resin and aliphatic/aromatic copolymer resins.
Preferably, the weight of the SBS rubber, SBR rubber, neoprene and nitrile rubber accounts for total adhesive weight
15-20%.
Preferably, the Petropols are maleic anhydride modified Petropols, and it passes through initiator and adds at 165-180 DEG C
Enter maleic anhydride it is modified to be formed.
The calcium powder is preferably dicalcium powder, and the granularity of dicalcium powder is 500-600 mesh.
Preferably, the calcium powder is modified calcium powder, and it passes through silane coupler and lauryl sodium sulfate in 65-75 DEG C of bar
It is modified under part is obtained.
Preferably, a kind of molecule adhesive for TPZ waterproof rolls, including following parts by weight component：
A kind of preparation method of molecule adhesive for TPZ waterproof rolls, comprises the following steps：
(1) reactor heat conduction fuel tap is opened, asphalt, second line of distillation cycloalkanes base oil is squeezed into, with turns for 15-20 turns/min
Speed stirring；
(2) temperature adds SBR rubber, neoprene and nitrile rubber to mix to 130-150 DEG C, at 190-200 DEG C
1.0-1.5h is stirred in timing, complete to melting, and obtains mixture A；
(3) to SBS rubber is added in mixture A, keeping temperature is 180-200 DEG C, is stirred with the rotating speed of 40-50 turns/min
40min, crosses colloid mill one time, obtains mixture B；
(4) to Petropols are added in mixture B, keeping temperature is 170-190 DEG C, then is persistently stirred 0.5-1.0 hours,
Obtain mixture C；
(5) after after Petropols dissolving, to adding plastic after calcium powder, then insulated and stirred 0.5-1.0 hours in mixture C,
Plastic is incubated summer：145-155 DEG C, winter：160-165℃.
The main component of invention adhesive is asphalt, and adds SBS rubber, SBR rubber, neoprene and butyronitrile
Rubber improves the performance of adhesive, and experiment shows, these four compositions play synergy, and the content of these four components is to adhesive
Performance have important influence, effectively improve pitch high temperature performance, increase adhesive layer viscosity and viscosity, have gluing interlayer
Standby fusion, the performance of low-temperature adhesion, especially, prepared adhesive possesses the performance bonded in excellent water.In adhesive
Addition auxiliary dissolving rubber altered contents second line of distillation cycloalkanes base oil, further promote SBS rubber, SBR rubber, neoprene and
Nitrile rubber plays a role, and improves the performance of adhesive.The addition of Petropols especially modified petroleum resin, increases adhesive-layer
Adhesion strength.Wherein calcium powder through silane coupler and lauryl sodium sulfate modification after, further increase adhesive
Adhesive property.
The preparation method of invention adhesive, first by SBS rubber, SBR rubber, neoprene and nitrile rubber, and subtracts two
After wire loop alkane base oil heat treatment, then substep adds the components such as asphalt, Petropols and calcium powder, between improve each component
Compatibility and dissolubility, and then improve adhesive adhesive property.
Adhesive applications prepared by the application can effectively improve the properties of TPZ waterproof rolls in TPZ waterproof rolls.
Adhesive prepared by the present invention has the advantages that：
(1) adhesive realizes low temperature (0 DEG C and more than) fusion bonding, it is adaptable to all construction temperatures of wet-laying coiled material, coiled material
Overlap edge is bonded using gluing oxidant layer with glue-line.Between glue-line only need contact, just can combine together, waterproof construction without technology,
Easy construction, safety.
(2) realize sealing safer with basic unit wet-laying：
1. adhesive realizes low temperature wet-laying secure bond sealing characteristics, and adhesive can ensure volume in -5 DEG C of temperatures above
The sealing property of material wet-laying bonding.
2. the adhesive prepared by the present invention is used for waterproof roll, and coiled material can still ensure good gluing in the construction of high temperature wet-laying
Sealing security is connect, coiled material lapping side is bonded using adhesive-layer with adhesive-layer, sealing water resistance is good, and coiled material is in construction at high temperature
During, can in time do spraying cooling measure in waterproof layer surface, it is to avoid the moisture evaporation in wet-laying cement mortar, it is ensured that waterproof layer
Combined closely with cement gel pulp layer, realize coiled material and basic unit's seal bond.
3. the adhesive prepared by the present invention is used for waterproof roll, and the rainfall that happened suddenly in coiled material wet-laying work progress is not resulted in
The wet-laying sealing failure of coiled material, coiled material lapping side is bonded using glue-line with glue-line, and sealing water resistance is good, and burst rainfall will not
Influence coiled material wet-laying sealing effectiveness.
(3) adhesive prepared by the present invention is used for TPZ waterproof rolls, and water proof structure level is simpler, save the duration and
Engineering direct cost, coiled material can form safe seal bond interface with basic unit's wet-laying, even if coil waterproof layer is damaged, still not
Influence waterproof layer integral waterproofing effect.The cement slurry protective layer of waterproof layer and rigid interlayer can be saved, reason has three：1. coiled material
With the seal bond interface that basic unit wet-laying can form safe not channeling water；2. the wet-laying coiled material for being bonded in basal plane completely is very difficult to
It is damaged；Even if 3. coil waterproof layer is damaged, waterproof layer integral waterproofing effect is not influenceed still, layers time are simpler, section
About engineering direct cost.
(4) glue-line has adhesion characteristic in water, solves the problems, such as the rainy season construction duration, as long as can ensure that coiled material wet-laying was sealed
Wet-laying rubber cement is not diluted to influence seal station and effect in journey, you can realize that the small rain of band in the rain of coiled material is constructed, waterproof construction work
Phase is protected from weather influences substantially.
Specific embodiment
Embodiment 1
A kind of molecule adhesive for TPZ waterproof rolls, including following parts by weight component：
Wherein, the Petropols are group aliphatic resin, and it uses maleic anhydride to be modified and obtains：Existed by initiator
Maleic anhydride is added to be modified to be formed to it at 175 DEG C.
The granularity of the dicalcium powder is 500-600 mesh, by silane coupler and lauryl sodium sulfate in 75 DEG C of bars
It is modified under part.
According to the proportioning of above-mentioned adhesive, make following preparation：
(1) reactor heat conduction fuel tap is opened, asphalt, second line of distillation cycloalkanes base oil is squeezed into, with turns for 15-20 turns/min
Speed stirring；
(2) temperature adds SBR rubber, neoprene and nitrile rubber to mix to 130-150 DEG C, at 190-200 DEG C
1.2h is stirred in timing, complete to melting, and obtains mixture A；
(3) to SBS rubber is added in mixture A, keeping temperature is 180-200 DEG C, is stirred with the rotating speed of 40-50 turns/min
40min, crosses colloid mill one time, obtains mixture B；
(4) to Petropols are added in mixture B, keeping temperature is 170-190 DEG C, then is persistently stirred 0.5 hour, obtains mixed
Compound C；
(5) after after Petropols dissolving, to adding calcium powder in mixture C, then insulated and stirred plastic, plastic after 0.5 hour
Insulation summer：145-155 DEG C, winter：160-165℃.
Embodiment 2
A kind of molecule adhesive for TPZ waterproof rolls, including following parts by weight component：
Wherein, the Petropols are group aliphatic resin, and it uses maleic anhydride to be modified and obtains：Existed by initiator
Maleic anhydride is added to be modified to be formed to it at 165 DEG C.
The granularity of the dicalcium powder is 500-600 mesh, by silane coupler and lauryl sodium sulfate in 65 DEG C of bars
It is modified under part.
According to the proportioning of above-mentioned adhesive, make following preparation：
(1) reactor heat conduction fuel tap is opened, asphalt, second line of distillation cycloalkanes base oil is squeezed into, with turns for 15-20 turns/min
Speed stirring；
(2) temperature adds SBR rubber, neoprene and nitrile rubber to mix to 130-150 DEG C, at 190-200 DEG C
1.0h is stirred in timing, complete to melting, and obtains mixture A；
(3) to SBS rubber is added in mixture A, keeping temperature is 180-200 DEG C, is stirred with the rotating speed of 40-50 turns/min
40min, crosses colloid mill one time, obtains mixture B；
(4) to Petropols are added in mixture B, keeping temperature is 170-190 DEG C, then is persistently stirred 0.5 hour, obtains mixed
Compound C；
(5) after after Petropols dissolving, to adding calcium powder in mixture C, then insulated and stirred plastic, plastic after 0.5 hour
Insulation summer：145-155 DEG C, winter：160-165℃.
Embodiment 3
A kind of molecule adhesive for TPZ waterproof rolls, including following parts by weight component：
Wherein, the Petropols are group aliphatic resin, and it uses maleic anhydride to be modified and obtains：Existed by initiator
Maleic anhydride is added to be modified to be formed to it at 180 DEG C.
The granularity of the dicalcium powder is 500-600 mesh, by silane coupler and lauryl sodium sulfate in 70 DEG C of bars
It is modified under part.
According to the proportioning of above-mentioned adhesive, make following preparation：
(1) reactor heat conduction fuel tap is opened, asphalt, second line of distillation cycloalkanes base oil is squeezed into, with turns for 15-20 turns/min
Speed stirring；
(2) temperature adds SBR rubber, neoprene and nitrile rubber to mix to 130-150 DEG C, at 190-200 DEG C
1.5h is stirred in timing, complete to melting, and obtains mixture A；
(3) to SBS rubber is added in mixture A, keeping temperature is 180-200 DEG C, is stirred with the rotating speed of 40-50 turns/min
40min, crosses colloid mill one time, obtains mixture B；
(4) to Petropols are added in mixture B, keeping temperature is 170-190 DEG C, then is persistently stirred 1.0 hours, obtains mixed
Compound C；
(5) after after Petropols dissolving, to adding calcium powder in mixture C, then insulated and stirred plastic, plastic after 1.0 hours
Insulation summer：145-155 DEG C, winter：160-165℃.
Embodiment 4
A kind of molecule adhesive for TPZ waterproof rolls, including following parts by weight component：
Wherein, the Petropols are group aliphatic resin, and it uses maleic anhydride to be modified and obtains：Existed by initiator
Maleic anhydride is added to be modified to be formed to it at 175 DEG C.
The granularity of the dicalcium powder is 500-600 mesh, by silane coupler and lauryl sodium sulfate in 75 DEG C of bars
It is modified under part.
According to the proportioning of above-mentioned adhesive, make following preparation：
(1) reactor heat conduction fuel tap is opened, asphalt, second line of distillation cycloalkanes base oil is squeezed into, with turns for 15-20 turns/min
Speed stirring；
(2) temperature adds SBR rubber, neoprene and nitrile rubber to mix to 130-150 DEG C, at 190-200 DEG C
1.2h is stirred in timing, complete to melting, and obtains mixture A；
(3) to SBS rubber is added in mixture A, keeping temperature is 180-200 DEG C, is stirred with the rotating speed of 40-50 turns/min
40min, crosses colloid mill one time, obtains mixture B；
(4) to Petropols are added in mixture B, keeping temperature is 170-190 DEG C, then is persistently stirred 0.5 hour, obtains mixed
Compound C；
(5) after after Petropols dissolving, to adding calcium powder in mixture C, then insulated and stirred plastic, plastic after 0.5 hour
Insulation summer：145-155 DEG C, winter：160-165℃.
Embodiment 5
A kind of molecule adhesive for TPZ waterproof rolls, including following parts by weight component：
Wherein, the Petropols are group aliphatic resin, are provided without maleic anhydride and are modified treatment.
The granularity of the dicalcium powder is 500-600 mesh, is not modified treatment to it.
According to the proportioning of above-mentioned adhesive, make following preparation：
(1) reactor heat conduction fuel tap is opened, asphalt, second line of distillation cycloalkanes base oil is squeezed into, with turns for 15-20 turns/min
Speed stirring；
(2) temperature adds SBR rubber, neoprene and nitrile rubber to mix to 130-150 DEG C, at 190-200 DEG C
1.2h is stirred in timing, complete to melting, and obtains mixture A；
(3) to SBS rubber is added in mixture A, keeping temperature is 180-200 DEG C, is stirred with the rotating speed of 40-50 turns/min
40min, crosses colloid mill one time, obtains mixture B；
(4) to Petropols are added in mixture B, keeping temperature is 170-190 DEG C, then is persistently stirred 0.5 hour, obtains mixed
Compound C；
(5) after after Petropols dissolving, to adding calcium powder in mixture C, then insulated and stirred plastic, plastic after 0.5 hour
Insulation summer：145-155 DEG C, winter：160-165℃.
Adhesive prepared by embodiment 1-5 is respectively used to waterproof layer-cement interlayer, to the performance (25 of adhesive
DEG C) tested, test result is listed in Table 1 below.
The Adhensive performance test result of table 1
As can be drawn from Table 1, the adhesive prepared by the application has more preferable adhesion strength and shear strength.
The embodiment of the present invention is provided above is a kind of for the molecule adhesive of TPZ waterproof rolls and its preparation side
Method, is described in detail, and specific case used herein is set forth to principle of the invention and implementation method, the above
The explanation of embodiment is only intended to help and understands the method for the present invention and its core concept；Simultaneously for the general skill of this area
Art personnel, according to thought of the invention, will change in specific embodiments and applications, in sum, this
Description should not be construed as limiting the invention.
Claims (3)
1. a kind of molecule adhesive for TPZ waterproof rolls, it is characterised in that the adhesive includes following parts by weight
Component：
Wherein, the Petropols are group aliphatic resin, and it uses maleic anhydride modified obtaining：By initiator in 165-180
Maleic anhydride is added to be modified to be formed to it at DEG C；
The weight of the SBS rubber, SBR rubber, neoprene and nitrile rubber accounts for the 15-20% of total adhesive weight；
The calcium powder is dicalcium powder, and the granularity of dicalcium powder is 500-600 mesh, and it passes through silane coupler and dodecyl sulphate
Sodium is modified to it under the conditions of 65-75 DEG C and obtains.
2. molecule adhesive according to claim 1, it is characterised in that the adhesive includes the group of following parts by weight
Point：
3. a kind of preparation method of the as claimed in claim 1 or 2 molecule adhesive for being used for TPZ waterproof rolls, including it is following
Step：
(1) reactor heat conduction fuel tap is opened, asphalt, second line of distillation cycloalkanes base oil is squeezed into, is stirred with the rotating speed of 15-20 turns/min
Mix；
(2) temperature adds SBR rubber, neoprene and nitrile rubber to mix to 130-150 DEG C, in 190-200 DEG C of timing
Stirring 1.0-1.5h, to melting completely, obtains mixture A；
(3) to SBS rubber is added in mixture A, keeping temperature is 180-200 DEG C, is stirred with the rotating speed of 40-50 turns/min
40min, crosses colloid mill one time, obtains mixture B；
(4) to Petropols are added in mixture B, keeping temperature is 170-190 DEG C, then is persistently stirred 0.5-1.0 hours, obtains mixed
Compound C；
(5) after after Petropols dissolving, to adding plastic, plastic after calcium powder, then insulated and stirred 0.5-1.0 hours in mixture C
Insulation summer：145-155 DEG C, winter：160-165℃.
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| CN108527979A (en) * | 2018-03-14 | 2018-09-14 | 合肥尚涵装饰工程有限公司 | A kind of roof waterproof layer construction composite of water-proof coiled material |
| CN109370469A (en) * | 2018-10-24 | 2019-02-22 | 辽宁女娲防水建材科技集团有限公司 | Protective layer macromolecular compounded waterproof material and preparation method thereof, application are exempted from a kind of reinforcing of clad can |
| CN111155564B (en) * | 2020-01-21 | 2020-08-07 | 辽宁大禹防水科技发展有限公司 | Synchronous construction process for efficient waterproof TPZ (thermoplastic vulcanizate) red core molecular adhesive waterproof coiled material |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103361025A (en) * | 2013-07-19 | 2013-10-23 | 北京东方雨虹防水技术股份有限公司 | Self-adhesive waterproof coiled material having high initial stickiness and preparation method thereof |
| CN105238080A (en) * | 2014-07-12 | 2016-01-13 | 卢桂才 | Reactive type modified asphalt and production method therefor |
| CN105238081A (en) * | 2014-07-12 | 2016-01-13 | 卢桂才 | Reactive modified asphalt and production method therefor |
| CN105255203A (en) * | 2015-08-14 | 2016-01-20 | 广西金雨伞防水装饰有限公司 | Softening oil in bridging agent-modified asphalt waterproof coiled material and adjustment method thereof |
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2016
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103361025A (en) * | 2013-07-19 | 2013-10-23 | 北京东方雨虹防水技术股份有限公司 | Self-adhesive waterproof coiled material having high initial stickiness and preparation method thereof |
| CN105238080A (en) * | 2014-07-12 | 2016-01-13 | 卢桂才 | Reactive type modified asphalt and production method therefor |
| CN105238081A (en) * | 2014-07-12 | 2016-01-13 | 卢桂才 | Reactive modified asphalt and production method therefor |
| CN105255203A (en) * | 2015-08-14 | 2016-01-20 | 广西金雨伞防水装饰有限公司 | Softening oil in bridging agent-modified asphalt waterproof coiled material and adjustment method thereof |
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Effective date of registration: 20181206 Address after: Room 3-2, 20 Qixin Avenue, Yanjia Street, Changshou District, Chongqing Patentee after: Chongqing Dayu Waterproof Technology Development Co., Ltd. Address before: 124121 Liaoning Panjin new waterproof material industry base Liaoning Dayu waterproof technology development Co., Ltd. Patentee before: LIAONING DAYU WATERPROOF TECHNOLOGY DEVELOPMENT CO., LTD. |