CN102086349A - Non-curing waterproof glue with double character - Google Patents
Non-curing waterproof glue with double character Download PDFInfo
- Publication number
- CN102086349A CN102086349A CN 201010583461 CN201010583461A CN102086349A CN 102086349 A CN102086349 A CN 102086349A CN 201010583461 CN201010583461 CN 201010583461 CN 201010583461 A CN201010583461 A CN 201010583461A CN 102086349 A CN102086349 A CN 102086349A
- Authority
- CN
- China
- Prior art keywords
- post
- filled
- pitch
- asphalt
- curing waterproof
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003292 glue Substances 0.000 title claims abstract description 15
- 239000000463 material Substances 0.000 claims abstract description 24
- 229920005989 resin Polymers 0.000 claims abstract description 15
- 239000011347 resin Substances 0.000 claims abstract description 15
- 229920003048 styrene butadiene rubber Polymers 0.000 claims abstract description 12
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 12
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 12
- 239000006229 carbon black Substances 0.000 claims abstract description 10
- 238000007789 sealing Methods 0.000 claims abstract description 9
- 229920002725 thermoplastic elastomer Polymers 0.000 claims abstract description 7
- 239000000945 filler Substances 0.000 claims abstract description 5
- 238000004519 manufacturing process Methods 0.000 claims abstract description 5
- 239000011295 pitch Substances 0.000 claims description 16
- 239000012752 auxiliary agent Substances 0.000 claims description 13
- 238000010790 dilution Methods 0.000 claims description 13
- 239000012895 dilution Substances 0.000 claims description 13
- 230000009977 dual effect Effects 0.000 claims description 13
- 238000004026 adhesive bonding Methods 0.000 claims description 12
- 239000011301 petroleum pitch Substances 0.000 claims description 11
- 229920002367 Polyisobutene Polymers 0.000 claims description 10
- 239000004902 Softening Agent Substances 0.000 claims description 10
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 239000004615 ingredient Substances 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- 229920000098 polyolefin Polymers 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 3
- 239000003208 petroleum Substances 0.000 claims description 3
- 229920003987 resole Polymers 0.000 claims description 3
- -1 tackifier Substances 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 239000010426 asphalt Substances 0.000 abstract description 21
- 230000032683 aging Effects 0.000 abstract description 5
- 238000004513 sizing Methods 0.000 abstract description 5
- 239000007787 solid Substances 0.000 abstract description 4
- 230000003014 reinforcing effect Effects 0.000 abstract description 3
- 238000012545 processing Methods 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- 239000003607 modifier Substances 0.000 abstract 2
- 239000004014 plasticizer Substances 0.000 abstract 2
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 238000007865 diluting Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 238000000576 coating method Methods 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 8
- 229920001971 elastomer Polymers 0.000 description 8
- 239000005060 rubber Substances 0.000 description 8
- 238000010276 construction Methods 0.000 description 6
- 230000007774 longterm Effects 0.000 description 6
- 229920003051 synthetic elastomer Polymers 0.000 description 6
- 239000005061 synthetic rubber Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000003044 adaptive effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Abstract
The invention relates to non-curing waterproof glue with double character. The non-curing waterproof glue is mixed by asphalt used as main material and auxiliary materials which contain thermoplastic elastomer, modifier, tackifier, plasticizer, diluting additive and filler. As the modified asphalt sizing material uses high quality thermoplastic styrene-butadiene rubber as raw material to improve the high temperature performance, uses tackifying resin to increase the viscosity of asphalt, uses the plasticizer to improve the compatibility and processing performance between asphalt and the modifier and uses carbon black and calcium carbonate with stable chemical properties as filler, the ultraviolet ray aging resistance of the non-curing waterproof glue of the invention can be improved, the reinforcing effect can be realized and the production cost can be reduced; and the non-curing waterproof glue product can remain solid at the room temperature and can be in a flexible glue state and be not cured in a sealing state.
Description
Technical field
The present invention relates to architectural waterproof material manufacturing technology field, particularly a kind ofly can adapt to certain deformation of basic unit and bearing certain pressure, help to solve waterproof layer and scurry water problems, have at normal temperatures and be solid-state behind the ingress of air, in sealed environment, keep flexible glue can glue the non-curing waterproof gluing of state dual nature.
Background technology
In recent years, along with the fast development of social economy and urban construction cause, people had proposed the high-level requirement of long-term non-leakage water to building waterproof, to this, had become one of scientific research project of countries in the world industry at present.In the building waterproof field, the rubber asphalt material is gone through because of its excellent water resistance and is occupied dominant position, and rubber-asphalt waterproof material product commonly used at present mainly contains synthetic rubber asphalt water-proof coiled material and Rubber Modified Asphalt Waterproof Coating.Existing synthetic rubber asphalt water-proof coiled material because of its material thickness evenly, easy construction and fast being used widely, but find that in practice its weak point is: (1) reliable long-term working is relatively poor, waterproof layer in use takes place easily heave, peel off or the phenomenon of be full of cracks and seam crossing percolating water; (2) applicable surface is wideless, and the stickiness on non-smooth surface is relatively poor; (3) adopt the hot melt process construction, not only consumes energy but also contaminate environment, and security is also poor, causes fire easily, and (4) construction quality and human factor relation are very big, require high to workmen's technical quality of laying the rubber asphalt coiled material.The advantage of Rubber Modified Asphalt Waterproof Coating is: (1) can adopt direct coating process that waterproof layer is set, and easy construction and overall cost are lower; (2) widely applicable, regular or irregular substrate surface of buildings and complex node position all there are very strong attaching adaptive faculty, the rubberised layer of formation does not have the handing-over seam, and mass permanence is better.Its weak point is that coat-thickness and degree of uniformity are all wayward when constructing operation, and drainage takes place to cause because of the part is thin easily.So, existing rubber-asphalt waterproof material, no matter be synthetic rubber asphalt water-proof coiled material or Rubber Modified Asphalt Waterproof Coating, the waterproof layer that generation is set by them separately all exists actual waterproof effect and useful working life to cannot say for sure the weak point demonstrate,proved, can't satisfy the high-level waterproof requirement of long-term non-leakage water.For this reason, the someone has proposed to adopt simultaneously Rubber Modified Asphalt Waterproof Coating and synthetic rubber asphalt water-proof coiled material that the imagination of complex waterproof layer is set, and to remedy weak point separately, satisfies the high-level waterproof requirement of long-term non-leakage water.But owing to existing Rubber Modified Asphalt Waterproof Coating is to aim at direct coating to be arranged at develop on the building surface concrete a kind of and to have the waterproof paint of ability to cure faster, and the coating after solidification process be exactly contact with material around bonding, mutual location process, so in the construction process of complex waterproof layer is set, except the requirement that will certainly produce quick setting, also surrounding edge is existed the requirement of positiver sealing, with the basic waterproof layer and the building concrete surface of realizing constituting by Rubber Modified Asphalt Waterproof Coating, and the reliable bonding and surrounding edge between the appearance waterproof layer internal surface that is made of the synthetic rubber asphalt water-proof coiled material is to the positiver sealing effect of complex waterproof layer.To this scheme, meet reason in theory, also be feasible in the practice, can greatly improve and prolong the water resistance of buildings.But its a fly in the ointment is: since the buildings of building finished product in the course of the work the concrete surface sealing ply that can take place to solidify on crack, the complex waterproof layer edge also the rimose situation can take place in the course of the work, thereby influence the long-term water resistance of buildings.
Summary of the invention
But the objective of the invention is to provide a kind of not only had be solid-state under the normal temperature behind the ingress of air, but also have the non-curing waterproof gluing that under air-proof condition, keeps flexible glue tacky state dual nature.
The non-curing waterproof gluing of dual nature of the present invention has at normal temperatures and is solid-state behind the ingress of air, but under the sealing oxygen free condition, keep flexible glue tacky state dual nature, by major ingredient pitch with include thermoplastic elastomer, properties-correcting agent, tackifier, softening agent, the pair material blend of dilution auxiliary agent and stopping composition constitutes, wherein: described major ingredient pitch is filled the post of by petroleum pitch, described thermoplastic elastomer is filled the post of by thermoplastic styrene butadiene rubber, described properties-correcting agent is filled the post of by low-molecular-weight polyisobutene, the tackifying resin that described tackifier are made up of petroleum resin or resol is filled the post of, described softening agent is filled the post of by polyolefine, described dilution auxiliary agent is filled the post of by the ethyl acetate organic solvent, and described stopping composition includes carbon black and the lime carbonate of fineness between 160～200 orders is filled the post of.
The component weight proportion is as follows:
Major ingredient pitch 40～50%
Thermoplastic styrene butadiene rubber 5～10%
Polyisobutene 4～8%
Tackifying resin 3～8%
Polyolefine 8～10%
Carbon black, lime carbonate 19～21%
Dilution auxiliary agent 8～10%
In addition, described major ingredient pitch uses 90 respectively
#Petroleum pitch, 10
#Petroleum pitch is filled the post of, or as required also with 90
#Petroleum pitch and 10
#Petroleum pitch.
Production technique is as follows:
Earlier pitch is dropped in the reactor, heat up about 200 ℃, added the thermoplastic styrene butadiene rubber dispersed with stirring 2 hours, then through colloidal mill circulation 30 minutes, lower the temperature about 160 ℃, add tackifying resin, polyisobutene, dilution auxiliary agent etc. and stir, add filler again, under this temperature, fully stirred 1 hour, be cooled to 60 ℃ with bottom discharge.
Non-curing waterproof gluing based on the tool dual nature of the present invention of above-mentioned design, because the modifying asphalt sizing material has adopted high-quality thermoplastic styrene butadiene rubber raw material to improve the bituminous high-temperature behavior, adopt tackifying resin to increase bituminous viscosity, the employing softening agent improves consistency and the processing characteristics between pitch and the properties-correcting agent, adopt stable carbon black and the lime carbonate of chemical property to make filler, both helped improving the non-curing waterproof gummed anti-ultraviolet aging performance of tool dual nature of the present invention, the effect that has reinforcing effect again and reduce production costs, and the non-curing waterproof gluing product that can guarantee tool dual nature of the present invention is solid-state at normal temperatures, under sealed state, can keep flexible glue to glue state and do not solidify, be convenient in complex waterproof layer, both can be set under sealed state, to keep flexible glue can glue state and solidified inner base waterproof layer not, can be coated with again and be arranged on the edge that is covered in the appearance waterproof layer that constitutes on the inner base waterproof layer by the synthetic rubber asphalt water-proof coiled material and play the curing sealing function, automatically inserted the effect of solidifying sealing in the time of can also solving contingency building surface generation micro-cracks, or just in case the appearance waterproof layer meets accident to hinder splits, when the inner base waterproof layer is exposed, rises automatically and solidify, the effect on enhanced leaktightness surface.So this dual nature of the present invention can be made substantive contribution for the high-level waterproof requirement that complex waterproof layer satisfies long-term non-leakage water, thereby have tangible technical advance, very good economy and extremely strong practicality.
Embodiment
The invention will be further described below in conjunction with exemplary embodiments.
The non-curing waterproof gluing of tool dual nature of the present invention is by major ingredient pitch and include thermoplastic elastomer, properties-correcting agent, tackifier, softening agent, the pair material blend of dilution auxiliary agent and stopping composition constitutes, wherein: described pitch is filled the post of by petroleum pitch, described thermoplastic elastomer is filled the post of by thermoplastic styrene butadiene rubber, described properties-correcting agent is filled the post of by low-molecular-weight polyisobutene, the tackifying resin that described tackifier are made up of petroleum resin or resol is filled the post of, described softening agent is filled the post of by polyolefine, described dilution auxiliary agent is filled the post of by the ethyl acetate organic solvent, and described stopping composition includes carbon black and the lime carbonate of fineness between 160～200 orders is filled the post of.
Embodiment 12000# product (being applicable to the plane)
Sizing compound formula: pitch 48%, thermoplastic styrene butadiene rubber 6%, polyisobutene 4%, tackifying resin 3%, softening agent 8%, carbon black, lime carbonate 21%, dilution auxiliary agent 10%.
Product performance: solid content: 〉=70%; Ash: 15%-30%; Water regain :≤2.0g; Thermotolerance (70 ℃, 120min): 2.0mm, stripping strength after the thermal ageing (N/mm, 70 ℃ of gluing and coiled materials, 168h): 〉=0.5, qualified.
Embodiment 23000# product (being applicable to facade)
Sizing compound formula: pitch 47%, thermoplastic styrene butadiene rubber 7%, polyisobutene 5%, tackifying resin 4%, softening agent 9%, carbon black, lime carbonate 20%, dilution auxiliary agent 8%.
Product performance: solid content: 〉=70%; Ash: 15%-30%; Water regain :≤2.0g; Thermotolerance (70 ℃, 120min): 2.0mm, stripping strength after the thermal ageing (N/mm, 70 ℃ of gluing and coiled materials, 168h): 〉=0.5, qualified.
Embodiment 35000# product (reinforcing sealing uses)
Sizing material weight proportion: pitch 45%, thermoplastic styrene butadiene rubber 8%, polyisobutene 6%, tackifying resin 7%, softening agent 8%, carbon black, lime carbonate 20%, dilution auxiliary agent 6%.
Product performance: solid content: 〉=70%; Ash: 20%-40%; Water regain :≤2.0g; Thermotolerance (70 ℃, 120min): 2.0mm, stripping strength after the thermal ageing (N/mm, 70 ℃ of gluing and coiled materials, 168h): 〉=1.0, qualified.
Claims (2)
1. the non-curing waterproof gluing of a tool dual nature, but it is characterized in that having at normal temperatures and to be solid-state behind the ingress of air, under the sealing oxygen free condition, keep flexible glue tacky state dual nature, constitute by major ingredient pitch and the pair material blend that includes thermoplastic elastomer, properties-correcting agent, tackifier, softening agent, dilution auxiliary agent and stopping composition, wherein:
A. described pitch is filled the post of by petroleum pitch, described thermoplastic elastomer is filled the post of by thermoplastic styrene butadiene rubber, described properties-correcting agent is filled the post of by low-molecular-weight polyisobutene, the tackifying resin that described tackifier are made up of petroleum resin or resol is filled the post of, described softening agent is filled the post of by polyolefine, described dilution auxiliary agent is filled the post of by the ethyl acetate organic solvent, and described stopping composition includes carbon black and the lime carbonate of fineness between 160～200 orders is filled the post of;
B. the component weight proportion is as follows:
Major ingredient pitch 40～50%,
Thermoplastic styrene butadiene rubber 5～10%,
Polyisobutene 4～8%,
Tackifying resin 3～8%,
Polyolefine 8～10%,
Carbon black, lime carbonate 19～21%,
Dilution auxiliary agent 8～10%.
C. production technique is as follows:
Earlier pitch is dropped in the reactor, heat up about 200 ℃, added the thermoplastic styrene butadiene rubber dispersed with stirring 2 hours, then through colloidal mill circulation 30 minutes, lower the temperature about 160 ℃, add tackifying resin, polyisobutene, dilution auxiliary agent etc. and stir, add filler again, under this temperature, fully stirred 1 hour, lower the temperature 60 ℃ with bottom discharge.
2. the non-curing waterproof gluing of tool dual nature according to claim 1 is characterized in that described major ingredient pitch uses 90 respectively
#Petroleum pitch, 10
#Petroleum pitch is filled the post of, or as required also with 90
#Petroleum pitch and 10
#Petroleum pitch.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010583461A CN102086349B (en) | 2010-12-10 | 2010-12-10 | Non-curing waterproof glue with double character |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010583461A CN102086349B (en) | 2010-12-10 | 2010-12-10 | Non-curing waterproof glue with double character |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102086349A true CN102086349A (en) | 2011-06-08 |
| CN102086349B CN102086349B (en) | 2012-10-03 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010583461A Active CN102086349B (en) | 2010-12-10 | 2010-12-10 | Non-curing waterproof glue with double character |
Country Status (1)
| Country | Link |
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| CN (1) | CN102086349B (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102408854A (en) * | 2011-08-26 | 2012-04-11 | 江苏达胜热缩材料有限公司 | High-temperature mastic cement for corrosion protection and preparation method thereof |
| CN103554678A (en) * | 2013-09-30 | 2014-02-05 | 潍坊市宏源防水材料有限公司 | Adhesive ethylene propylene diene monomer rubber waterproof coiled material |
| CN103937407A (en) * | 2013-01-22 | 2014-07-23 | 张秀君 | Non-curing rubber asphalt waterproof paint |
| CN104109505A (en) * | 2014-07-17 | 2014-10-22 | 北京中联天盛建材有限公司 | Self-adhesive rubber high-polymer water-resistant caulking mastic and preparation method thereof |
| CN104017512B (en) * | 2014-06-24 | 2016-04-06 | 上海台安实业集团有限公司 | Reaction selfadhesive EPDM waterproof rolled sheet |
| CN105778533A (en) * | 2016-03-29 | 2016-07-20 | 河南省交通运输厅京珠高速公路新乡至郑州管理处 | High-permeability composite high-molecular polymer hot-melt crack filling material and preparation method |
| CN106494008A (en) * | 2016-10-25 | 2017-03-15 | 上海岱山电力科技股份有限公司 | A kind of air-tightness heat insulation type thermal insulating coiled material |
| CN106515142A (en) * | 2016-10-19 | 2017-03-22 | 嘉兴潮源新型建材股份有限公司 | Metal core self-repairing root resisting waterproof coiled material and preparation method thereof |
| CN109111852A (en) * | 2018-07-26 | 2019-01-01 | 中建友（唐山）科技有限公司 | A kind of uncured rubber asphalt waterproof coating and preparation method thereof |
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| US5451621A (en) * | 1994-08-15 | 1995-09-19 | Bridgestone/Firestone, Inc. | SBS-modified, asphalt-based material with resistance to crosslinking |
| CN1195362A (en) * | 1996-05-10 | 1998-10-07 | 埃尔弗安塔法国公司 | Bitumen/polymer compositions with improved stability and their application in carrying out surfacing operations |
| EP1698669A2 (en) * | 2005-03-04 | 2006-09-06 | Axter | Bituminous binder for sealing and sealing membrane |
| CN1834160A (en) * | 2004-11-15 | 2006-09-20 | 韩本产业株式会社 | Stretchy rubberized asphalt felt for waterproofing and waterproofing material of duplex rubberized asphalt membrane plus felt |
| CN101074357A (en) * | 2007-06-26 | 2007-11-21 | 程雪峰 | Modifed asphalt waterproof curling material of environmental-protective plastic |
-
2010
- 2010-12-10 CN CN201010583461A patent/CN102086349B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5451621A (en) * | 1994-08-15 | 1995-09-19 | Bridgestone/Firestone, Inc. | SBS-modified, asphalt-based material with resistance to crosslinking |
| CN1195362A (en) * | 1996-05-10 | 1998-10-07 | 埃尔弗安塔法国公司 | Bitumen/polymer compositions with improved stability and their application in carrying out surfacing operations |
| CN1834160A (en) * | 2004-11-15 | 2006-09-20 | 韩本产业株式会社 | Stretchy rubberized asphalt felt for waterproofing and waterproofing material of duplex rubberized asphalt membrane plus felt |
| EP1698669A2 (en) * | 2005-03-04 | 2006-09-06 | Axter | Bituminous binder for sealing and sealing membrane |
| CN101074357A (en) * | 2007-06-26 | 2007-11-21 | 程雪峰 | Modifed asphalt waterproof curling material of environmental-protective plastic |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102408854A (en) * | 2011-08-26 | 2012-04-11 | 江苏达胜热缩材料有限公司 | High-temperature mastic cement for corrosion protection and preparation method thereof |
| CN103937407A (en) * | 2013-01-22 | 2014-07-23 | 张秀君 | Non-curing rubber asphalt waterproof paint |
| CN103937407B (en) * | 2013-01-22 | 2016-06-15 | 张秀君 | Uncured rubber asphalt waterproof coating |
| CN103554678A (en) * | 2013-09-30 | 2014-02-05 | 潍坊市宏源防水材料有限公司 | Adhesive ethylene propylene diene monomer rubber waterproof coiled material |
| CN103554678B (en) * | 2013-09-30 | 2015-09-30 | 潍坊市宏源防水材料有限公司 | A kind of gluing EPDM rubber waterproof rolling material |
| CN104017512B (en) * | 2014-06-24 | 2016-04-06 | 上海台安实业集团有限公司 | Reaction selfadhesive EPDM waterproof rolled sheet |
| CN104109505A (en) * | 2014-07-17 | 2014-10-22 | 北京中联天盛建材有限公司 | Self-adhesive rubber high-polymer water-resistant caulking mastic and preparation method thereof |
| CN105778533A (en) * | 2016-03-29 | 2016-07-20 | 河南省交通运输厅京珠高速公路新乡至郑州管理处 | High-permeability composite high-molecular polymer hot-melt crack filling material and preparation method |
| CN106515142A (en) * | 2016-10-19 | 2017-03-22 | 嘉兴潮源新型建材股份有限公司 | Metal core self-repairing root resisting waterproof coiled material and preparation method thereof |
| CN106494008A (en) * | 2016-10-25 | 2017-03-15 | 上海岱山电力科技股份有限公司 | A kind of air-tightness heat insulation type thermal insulating coiled material |
| CN109111852A (en) * | 2018-07-26 | 2019-01-01 | 中建友（唐山）科技有限公司 | A kind of uncured rubber asphalt waterproof coating and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102086349B (en) | 2012-10-03 |
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| CP01 | Change in the name or title of a patent holder |
Address after: 201823, No. 301, Qian Qian Road, Wai Gang Town, Shanghai, Jiading District Patentee after: SHANGHAI TERRA INDUSTRIAL GROUP CO.,LTD. Patentee after: Shanghai Rui Xin new building materials Co.,Ltd. Address before: 201823, No. 301, Qian Qian Road, Wai Gang Town, Shanghai, Jiading District Patentee before: Shanghai Terra Engineering & Industry Co.,Ltd. Patentee before: Shanghai Taian Novel Building Materials Co.,Ltd. |
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| CP03 | Change of name, title or address |
Address after: 201823, No. 301, Qian Qian Road, Wai Gang Town, Shanghai, Jiading District Patentee after: Shanghai Beixin YUEHUANG New Material Group Co.,Ltd. Patentee after: North Crescent Emperor Flooring Materials (Shanghai) Co.,Ltd. Address before: 201823, No. 301, Qian Qian Road, Wai Gang Town, Shanghai, Jiading District Patentee before: SHANGHAI TERRA INDUSTRIAL GROUP CO.,LTD. Patentee before: Shanghai Rui Xin new building materials Co.,Ltd. |
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| CP03 | Change of name, title or address |