CN105415791A - Waterproof hayner molar viscosity macromolecule coiled material and preparation process thereof - Google Patents
Waterproof hayner molar viscosity macromolecule coiled material and preparation process thereof Download PDFInfo
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- CN105415791A CN105415791A CN201510877952.6A CN201510877952A CN105415791A CN 105415791 A CN105415791 A CN 105415791A CN 201510877952 A CN201510877952 A CN 201510877952A CN 105415791 A CN105415791 A CN 105415791A
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- 239000000463 material Substances 0.000 title claims abstract description 49
- 238000002360 preparation method Methods 0.000 title claims description 17
- 229920002521 macromolecule Polymers 0.000 title abstract 4
- 239000010410 layer Substances 0.000 claims abstract description 33
- 238000003756 stirring Methods 0.000 claims description 51
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 24
- 229910052799 carbon Inorganic materials 0.000 claims description 24
- 239000011347 resin Substances 0.000 claims description 24
- 229920005989 resin Polymers 0.000 claims description 24
- 239000003292 glue Substances 0.000 claims description 20
- 238000004026 adhesive bonding Methods 0.000 claims description 19
- 239000003921 oil Substances 0.000 claims description 18
- 239000004902 Softening Agent Substances 0.000 claims description 15
- 239000000654 additive Substances 0.000 claims description 15
- 230000000996 additive effect Effects 0.000 claims description 15
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 15
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 15
- 238000005516 engineering process Methods 0.000 claims description 12
- 229920005597 polymer membrane Polymers 0.000 claims description 12
- 239000002174 Styrene-butadiene Substances 0.000 claims description 9
- 239000002199 base oil Substances 0.000 claims description 9
- 229920005549 butyl rubber Polymers 0.000 claims description 9
- 239000000084 colloidal system Substances 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 8
- 238000010422 painting Methods 0.000 claims description 7
- 239000011247 coating layer Substances 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 238000004806 packaging method and process Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 238000010276 construction Methods 0.000 abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 238000002955 isolation Methods 0.000 abstract 3
- 239000004698 Polyethylene Substances 0.000 abstract 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 2
- -1 polyethylene Polymers 0.000 abstract 2
- 229920000573 polyethylene Polymers 0.000 abstract 2
- 229910052710 silicon Inorganic materials 0.000 abstract 2
- 239000010703 silicon Substances 0.000 abstract 2
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- 230000006750 UV protection Effects 0.000 abstract 1
- 239000012792 core layer Substances 0.000 abstract 1
- 229920006262 high density polyethylene film Polymers 0.000 abstract 1
- 238000007731 hot pressing Methods 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- KVYJZPBHJJJKOT-UHFFFAOYSA-J silicon(4+) terephthalate Chemical compound [Si+4].C(C1=CC=C(C(=O)[O-])C=C1)(=O)[O-].C(C1=CC=C(C(=O)[O-])C=C1)(=O)[O-] KVYJZPBHJJJKOT-UHFFFAOYSA-J 0.000 abstract 1
- 239000002585 base Substances 0.000 description 11
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 3
- 230000006378 damage Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003513 alkali Substances 0.000 description 1
- 230000001458 anti-acid effect Effects 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000009938 salting Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B11/00—Layered products comprising a layer of bituminous or tarry substances
- B32B11/04—Layered products comprising a layer of bituminous or tarry substances comprising such bituminous or tarry substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B11/00—Layered products comprising a layer of bituminous or tarry substances
- B32B11/04—Layered products comprising a layer of bituminous or tarry substances comprising such bituminous or tarry substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B11/046—Layered products comprising a layer of bituminous or tarry substances comprising such bituminous or tarry substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/02—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/08—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the cooling method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
- B32B37/1284—Application of adhesive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
- B32B2037/1269—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives multi-component adhesive
Landscapes
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a waterproof hayner molar viscosity macromolecule coiled material. The waterproof hayner molar viscosity macromolecule coiled material sequentially comprises an upper covering layer, a first oiling layer, a core layer matrix, a second oiling layer and a lower covering layer from top to bottom, wherein the upper covering layer is a strong cross-superposed polyethylene film, and the strong cross-superposed polyethylene film is formed by cross-compositing and hot-pressing two layers of high-density polyethylene films at 45 degrees; and the lower covering layer also employs a silicon-coated isolation film, and the silicon-coated isolation film is a polyethylene glycol terephthalate silicon-coated isolation film. The waterproof hayner molar viscosity macromolecule coiled material has the advantages that: the service life of the waterproof coiled material is prolonged, the construction is more convenient, the size stability, weather resistance, ultraviolet resistance and two-way tear resistance are excellent, and firmness in adhesion and no water leakage can be realized; and the self-healing capacity is good, and a local punctured point can be autonomously healed.
Description
Technical field
The present invention relates to a kind of adhesive waterproof coil, specifically a kind of CMS sea nanomole glues polymer membranes and preparation technology thereof, belongs to adhesive waterproof coil field.
Background technology
Along with expanding economy, the progress in epoch, also more and more higher to the requirement of architectural waterproof material, therefore various forms of waterproof roll arises at the historic moment.But underground waterproof, due to the particularity in its geographical position etc., has special performance requirement to waterproof material.Various coiled material is cemented in body structure surface and is formed by underground engineering coil waterproof layer asphalt adhesive continuously.Underground waterproof coiled material requires that the waterproof roll performance used will be got well, and has certain toughness and changeability, adapts to that underground engineering is sunk, the flexible and micro-strain that causes, can antiacid, the erosion of alkali, salting liquid or the underground engineering of vibrated effect.In construction, also exist that quality not easily ensures, working condition is poor simultaneously, atmosphere pollution, uneasy congruent factor, particularly construction quality be difficult to inspection, once there is percolating water, repair more difficult.
The appearance of adhesive waterproof coil, substantially reduces the difficulty of construction of waterproof roll, particularly polymer membranes due to its performance advantage, is widely used in recent years in building waterproofing industry.But still there is many drawbacks in high-polymer self-adhesion waterproof coiled material sold in the market, as antiseep poor effect, string water leaks seriously, collapse resistance power is poor, easily occur puncturing or tearing phenomenon etc., cause the destruction of waterproof system, need labor intensive material resources to repair, shorten the service life of waterproof roll, cause the waste of fund and resource.Particularly for the mountain ridge and subaqueous tunnel, due to its long-term existence hydraulic pressure, and affect seriously by factors such as natural environments, the performance requirement therefore for waterproof material is more strict.
Summary of the invention
In order to solve the problem, the present invention devises a kind of extra large nanomole and glues polymer membranes and preparation technology thereof, excellent performance, easy construction and can tackle various construction environment, improves the performance inferior position of high-polymer self-adhesion waterproof coiled material.
Technical scheme of the present invention is:
Sea nanomole glues polymer membranes, comprises sandwich layer tire base, the gluing bed of material and coating layer; Described gluing material comprises the first oiling bed of material and the second oiling bed of material, after cooling, is separately positioned on the both sides of described sandwich layer tire basal plane; Described coating layer comprises powerful rete and the PET separating film layer of intersecting, and described brute force intersection rete is arranged on the outside of the described first oiling bed of material, and described PET separating film layer is arranged on the outside of the described second oiling bed of material.
The described gluing bed of material is made up of the raw material of following weight portion:
No. 100 pitch 40-50 parts, powder styrene butadiene rubber (SBR) 10-15 part, carbon 9 resin 6-8 part, softening agent base oil 15-16 part, talcum powder 10-20 part, additive butyl rubber 10-28 part.
The preparation method of the described gluing bed of material, comprises the following steps:
A. pitch is squeezed into material-compound tank by proportioning to stir, material-compound tank is heated, when temperature rises to 160 ± 5 DEG C, adds softening agent;
B. when temperature rises to 180 ± 5 DEG C, add SBR glue, stir 1.5 hours, temperature controls at 185 ~ 200 DEG C, grinds 1.5 hours while stirring with colloid mill;
C. carbon 9 resin is added in agitator tank and stir 0.5 hour, when temperature in material-compound tank is down to 155 ~ 160 DEG C, carbon 9 resin is squeezed into material-compound tank;
When d. making temperature be raised to 175 ~ 180 DEG C by heat-conducting oil heating, be blended into talcum powder, additive etc., stir 25 ~ 35 minutes, stir fully and lower the temperature, when temperature is down to 150 ± 5 DEG C, obtains the gluing bed of material and be coated with oil plant.
Above-mentioned extra large nanomole glues the preparation technology of polymer membranes, comprises the following steps:
(1) sandwich layer tire base is prepared
Sandwich layer tire base adopts the powerful film that intersects;
(2) gluing material is prepared
A. pitch is squeezed into material-compound tank by proportioning to stir, material-compound tank is heated, when temperature rises to 160 ± 5 DEG C, adds softening agent;
B. when temperature rises to 180 ± 5 DEG C, add SBR glue, stir 1.5 hours, temperature controls at 185 ~ 200 DEG C, grinds 1.5 hours while stirring with colloid mill;
C. carbon 9 resin is added in agitator tank and stir 0.5 hour, when temperature in material-compound tank is down to 155 ~ 160 DEG C, carbon 9 resin is squeezed into material-compound tank;
When d. making temperature be raised to 175 ~ 180 DEG C by heat-conducting oil heating, be blended into talcum powder, additive etc., stir 25 ~ 35 minutes, stir fully and lower the temperature, when temperature is down to 150 ± 5 DEG C, obtain painting oil plant;
(3) the painting oil flow made is entered oiling groove, sandwich layer tire base is launched to put into oiling groove oiling, control the thickness of the oiling bed of material at 0.8mm;
(4) by the sandwich layer tire base cooling after oiling;
(5) overlay film, curling, packaging, warehouse-in.
Wherein, described brute force intersection film is made up of the raw material of following weight portion:
No. 100 pitch 42-52 parts, powder styrene butadiene rubber (SBR) 9-14 part, carbon 9 resin 8-10 part, softening agent base oil 12-14 part, talcum powder 10-20 part, additive butyl rubber 10-28 part.
The preparation method of described brute force intersection film, comprises the following steps:
(1) in agitator tank, add 100# pitch, be warming up to 160 ± 5 DEG C, add softening agent base oil;
(2) when temperature rises to 180 ± 5 DEG C, add SBR glue, stir 1.5 ~ 2 hours, temperature controls at 185 ~ 200 DEG C, after dissolving, grinds 1.5 hours while stirring with colloid mill, adds carbon 9 resin to when fully mixing, and continues stirring 0.5 hour;
(3) when material-compound tank is cooled to 155 ~ 160 DEG C, carbon 9 resin is squeezed into material-compound tank;
(4) when making temperature be raised to 175 ~ 180 DEG C by heat-conducting oil heating, be blended into talcum powder and additive butyl rubber, stir 25 ~ 35 minutes, stir fully and lower the temperature, when temperature is down to 150 ± 5 DEG C, namely obtain.
The invention has the advantages that: compared with prior art not only there is the excellent properties that conventional polymer self-adhesive coiled material has, also have the following advantages:
(1) can to reach 0.6MPa waterproof for impermeability measured value, it is 2 times that national standard requires, can reach the pressure of keeping out 60 heads in underground waterproof engineering, that resists that building may run in the life-cycle superlatively descends water level, effectively improves the reliability of underground structure waterproof;
(2) it is held viscosity measured value and saw more than 60 minutes, can close and firm bonding with basal plane, effectively prevents string water from leaking;
(3) the pulling force measured value of this waterproof roll is at more than 500N simultaneously, and superpower tensile strength can effectively be resisted sedimentation, be out of shape the destruction of causing watertight composition
(4) overcome mill run and this harsh shortcoming is required to construction environment, great tolerance is had to construction environment, not only concrete can be carried out, cardboard, glass, timber, pottery, the self-adhesion of metal etc. and gluing mutually, can also realize the band water bonding between coiled material, be applicable to various underground waterproof engineering.Meanwhile, the present invention is directed to the difference of basic unit's concrete condition in practice of construction process, the construction method adopting wet paving construction or overlay construction can be selected.
Below in conjunction with drawings and Examples, the invention will be further described.
Accompanying drawing explanation
Fig. 1 is the structural representation of the embodiment of the present invention;
Fig. 2 be the gluing bed of material of the embodiment of the present invention preparation technology's flow chart;
Fig. 3 is preparation technology's flow chart of embodiment of the present invention waterproof roll.
Detailed description of the invention
Below the preferred embodiments of the present invention are described, should be appreciated that preferred embodiment described herein is only for instruction and explanation of the present invention, is not intended to limit the present invention.
Except as otherwise noted, the percentage adopted in the present invention is percetage by weight.
Embodiment 1
Sea nanomole glues polymer membranes, comprises sandwich layer tire base, the gluing bed of material and coating layer; Described gluing material comprises the first oiling bed of material and the second oiling bed of material, after cooling, is separately positioned on the both sides of described sandwich layer tire basal plane; Described coating layer comprises powerful rete and the PET separating film layer of intersecting, and described brute force intersection rete is arranged on the outside of the described first oiling bed of material, and described PET separating film layer is arranged on the outside of the described second oiling bed of material.
The described gluing bed of material is made up of the raw material of following weight portion:
No. 100 pitch 40-50 parts, powder styrene butadiene rubber (SBR) 10-15 part, carbon 9 resin 6-8 part, softening agent base oil 15-16 part, talcum powder 10-20 part, additive butyl rubber 10-28 part.
As shown in Figure 1, the preparation method of the described gluing bed of material, comprises the following steps:
A. pitch is squeezed into material-compound tank by proportioning to stir, material-compound tank is heated, when temperature rises to 160 ± 5 DEG C, adds softening agent;
B. when temperature rises to 180 ± 5 DEG C, add SBR glue, stir 1.5 hours, temperature controls at 185 ~ 200 DEG C, grinds 1.5 hours while stirring with colloid mill;
C. carbon 9 resin is added in agitator tank and stir 0.5 hour, when temperature in material-compound tank is down to 155 ~ 160 DEG C, carbon 9 resin is squeezed into material-compound tank;
When d. making temperature be raised to 175 ~ 180 DEG C by heat-conducting oil heating, be blended into talcum powder, additive etc., stir 25 ~ 35 minutes, stir fully and lower the temperature, when temperature is down to 150 ± 5 DEG C, obtain painting oil plant;
As shown in Figure 2, above-mentioned extra large nanomole glues the preparation technology of polymer membranes, comprises the oiling of sandwich layer tire base, oiling material cooled, overlay film, curling and packaging, warehouse-in, specifically comprises the following steps:
(1) sandwich layer tire base is prepared
Sandwich layer tire base adopts the powerful film that intersects;
(2) gluing material is prepared
A. pitch is squeezed into material-compound tank by proportioning to stir, material-compound tank is heated, when temperature rises to 160 ± 5 DEG C, adds softening agent;
B. when temperature rises to 180 ± 5 DEG C, add SBR glue, stir 1.5 hours, temperature controls at 185 ~ 200 DEG C, grinds 1.5 hours while stirring with colloid mill;
C. carbon 9 resin is added in agitator tank and stir 0.5 hour, when temperature in material-compound tank is down to 155 ~ 160 DEG C, carbon 9 resin is squeezed into material-compound tank;
When d. making temperature be raised to 175 ~ 180 DEG C by heat-conducting oil heating, be blended into talcum powder, additive etc., stir 25 ~ 35 minutes, stir fully and lower the temperature, when temperature is down to 150 ± 5 DEG C, obtain painting oil plant;
(3) the painting oil flow made is entered oiling groove, sandwich layer tire base is launched to put into oiling groove oiling, control the thickness of the oiling bed of material at 0.8mm;
(4) by the sandwich layer tire base cooling after oiling;
(5) overlay film, curling, packaging, warehouse-in.
Wherein, described brute force intersection film is made up of the raw material of following weight portion:
No. 100 pitch 42-52 parts, powder styrene butadiene rubber (SBR) 9-14 part, carbon 9 resin 8-10 part, softening agent base oil 12-14 part, talcum powder 10-20 part, additive butyl rubber 10-28 part.
The preparation method of described brute force intersection film, comprises the following steps:
(1) in agitator tank, add 100# pitch, be warming up to 160 ± 5 DEG C, add softening agent base oil;
(2) when temperature rises to 180 ± 5 DEG C, add SBR glue, stir 1.5 ~ 2 hours, temperature controls at 185 ~ 200 DEG C, after dissolving, grinds 1.5 hours while stirring with colloid mill, adds carbon 9 resin to when fully mixing, and continues stirring 0.5 hour;
(3) when material-compound tank is cooled to 155 ~ 160 DEG C, carbon 9 resin is squeezed into material-compound tank;
(4) when making temperature be raised to 175 ~ 180 DEG C by heat-conducting oil heating, be blended into talcum powder and additive butyl rubber, stir 25 ~ 35 minutes, stir fully and lower the temperature, when temperature is down to 150 ± 5 DEG C, namely obtain.
In the present invention, raw materials used being during this area produces commonly uses raw material, all can obtain from market, and can not have an impact for production result; The various equipment adopted in the present invention, are the conventional equipment used in the production technology of this area, and the operation of each equipment, parameter etc. all conveniently operate and carry out, and there is no special feature.
Claims (6)
1. extra large nanomole glues polymer membranes, it is characterized in that: comprise sandwich layer tire base, the gluing bed of material and coating layer; Described gluing material comprises the first oiling bed of material and the second oiling bed of material, after cooling, is separately positioned on the both sides of described sandwich layer tire basal plane; Described coating layer comprises powerful rete and the PET separating film layer of intersecting, and described brute force intersection rete is arranged on the outside of the described first oiling bed of material, and described PET separating film layer is arranged on the outside of the described second oiling bed of material.
2. extra large nanomole according to claim 1 glues polymer membranes, it is characterized in that, the described gluing bed of material is made up of the raw material of following weight portion:
No. 100 pitch 40-50 parts, powder styrene butadiene rubber (SBR) 10-15 part, carbon 9 resin 6-8 part, softening agent base oil 15-16 part, talcum powder 10-20 part, additive butyl rubber 10-28 part.
3. extra large nanomole according to claim 1 and 2 glues polymer membranes, it is characterized in that, the preparation method of the described gluing bed of material, comprises the following steps:
A. pitch is squeezed into material-compound tank by proportioning to stir, material-compound tank is heated, when temperature rises to 160 ± 5 DEG C, adds softening agent;
B. when temperature rises to 180 ± 5 DEG C, add SBR glue, stir 1.5 hours, temperature controls at 185 ~ 200 DEG C, grinds 1.5 hours while stirring with colloid mill;
C. carbon 9 resin is added in agitator tank and stir 0.5 hour, when temperature in material-compound tank is down to 155 ~ 160 DEG C, carbon 9 resin is squeezed into material-compound tank;
When d. making temperature be raised to 175 ~ 180 DEG C by heat-conducting oil heating, be blended into talcum powder, additive etc., stir 25 ~ 35 minutes, stir fully and lower the temperature, when temperature is down to 150 ± 5 DEG C, obtains the gluing bed of material and be coated with oil plant.
4. as described in claim 1-3 any one, extra large nanomole glues a preparation technology for polymer membranes, it is characterized in that, comprises the following steps:
(1) sandwich layer tire base is prepared
Sandwich layer tire base adopts the powerful film that intersects;
(2) gluing material is prepared
A. pitch is squeezed into material-compound tank by proportioning to stir, material-compound tank is heated, when temperature rises to 160 ± 5 DEG C, adds softening agent;
B. when temperature rises to 180 ± 5 DEG C, add SBR glue, stir 1.5 hours, temperature controls at 185 ~ 200 DEG C, grinds 1.5 hours while stirring with colloid mill;
C. carbon 9 resin is added in agitator tank and stir 0.5 hour, when temperature in material-compound tank is down to 155 ~ 160 DEG C, carbon 9 resin is squeezed into material-compound tank;
When d. making temperature be raised to 175 ~ 180 DEG C by heat-conducting oil heating, be blended into talcum powder, additive etc., stir 25 ~ 35 minutes, stir fully and lower the temperature, when temperature is down to 150 ± 5 DEG C, obtain painting oil plant;
(3) the painting oil flow made is entered oiling groove, sandwich layer tire base is launched to put into oiling groove oiling, control the thickness of the oiling bed of material at 0.8mm;
(4) by the sandwich layer tire base cooling after oiling;
(5) overlay film, curling, packaging, warehouse-in.
5. preparation technology according to claim 4, is characterized in that: described brute force intersection film is made up of the raw material of following weight portion:
No. 100 pitch 42-52 parts, powder styrene butadiene rubber (SBR) 9-14 part, carbon 9 resin 8-10 part, softening agent base oil 12-14 part, talcum powder 10-20 part, additive butyl rubber 10-28 part.
6. the preparation technology according to claim 4 or 5, is characterized in that, the preparation method of described brute force intersection film, comprises the following steps:
(1) in agitator tank, add 100# pitch, be warming up to 160 ± 5 DEG C, add softening agent base oil;
(2) when temperature rises to 180 ± 5 DEG C, add SBR glue, stir 1.5 ~ 2 hours, temperature controls at 185 ~ 200 DEG C, after dissolving, grinds 1.5 hours while stirring with colloid mill, adds carbon 9 resin to when fully mixing, and continues stirring 0.5 hour;
(3) when material-compound tank is cooled to 155 ~ 160 DEG C, carbon 9 resin is squeezed into material-compound tank;
(4) when making temperature be raised to 175 ~ 180 DEG C by heat-conducting oil heating, be blended into talcum powder and additive butyl rubber, stir 25 ~ 35 minutes, stir fully and lower the temperature, when temperature is down to 150 ± 5 DEG C, namely obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510877952.6A CN105415791A (en) | 2015-12-04 | 2015-12-04 | Waterproof hayner molar viscosity macromolecule coiled material and preparation process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510877952.6A CN105415791A (en) | 2015-12-04 | 2015-12-04 | Waterproof hayner molar viscosity macromolecule coiled material and preparation process thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105415791A true CN105415791A (en) | 2016-03-23 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110330910A (en) * | 2019-06-20 | 2019-10-15 | 江苏凯伦建材股份有限公司 | Cross-level press mold overlays the preparation process of waterproof roll |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110330910A (en) * | 2019-06-20 | 2019-10-15 | 江苏凯伦建材股份有限公司 | Cross-level press mold overlays the preparation process of waterproof roll |
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