CN104085144B - Polymeric laminate adhesive waterproof coil and preparation method thereof - Google Patents
Polymeric laminate adhesive waterproof coil and preparation method thereof Download PDFInfo
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- CN104085144B CN104085144B CN201410322850.3A CN201410322850A CN104085144B CN 104085144 B CN104085144 B CN 104085144B CN 201410322850 A CN201410322850 A CN 201410322850A CN 104085144 B CN104085144 B CN 104085144B
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Abstract
The present invention relates to a kind of polymeric laminate adhesive waterproof coil and preparation method thereof, belong to building waterproof coil technical field.It comprises glued membrane and the bitumen layer of dip-coating on glued membrane, and described bitumen layer is made up of the component of following parts by weight: 100
#pitch 0.5 ~ 2.5 part, 10
#pitch 0.1 ~ 1.2 part, SBS0.1 ~ 0.6 part, SBR0.05 ~ 0.25 part, hydrogenated petroleum resin 0.05 ~ 0.25 part, stone flour 0.1 ~ 2 part.Advantage of the present invention is: water resistance is good, ageing-resistant, and hot strength is high, good extending performance, has excellent low-temperature tenderness and heat resistance.
Description
Technical field
The invention belongs to building waterproof coil technical field, be specifically related to a kind of polymeric laminate adhesive waterproof coil and preparation method thereof.
Background technology
Waterproof roll is mainly used for the place such as construction wall, roofing and tunnel, highway, refuse landfill, play the flexible building material product of a kind of rollable one-tenth web-like resisting extraneous rainwater, underground water seepage, be connected as ne-leakage between engineering foundation with building, be the first barrier of whole engineering waterproofing, vital effect is played to whole engineering.Product mainly contains asphalt water-proof coiled material and polymer membranes.
Application number be 2007101208098 Chinese invention patent " a kind of low-temperature resistant self-adhesive rubber asphalt waterproofing coiled material " disclose a kind of by asphalt, subtract third fractional oil, waterproof roll that bitumen layer that thermoplastic styrene butadiene rubber, powder styrene butadiene rubber, coumarone indene resin, Petropols, terpene resin, small-molecular-weight polyisobutene, ultra-violet absorber, antioxidant, calcium carbonate are made makes.This waterproof roll also exists the shortcomings such as non-refractory.
Application number be 2009100663136 Chinese invention patent " a kind of preparation method of polymer membranes " disclose the polymer membranes be made up of pitch, rubber, carbon black and antiaging agent.The shortcomings such as this waterproof roll also also exists non-refractory, and the scope of application is little.
Because present extreme weather is given prominence to, the performance of existing waterproof roll can not satisfy the demands, therefore the performance improving waterproof roll has become the technical problem needing solution badly.
Summary of the invention
The object of this invention is to provide a kind of high temperature-resistant polymer glued membrane adhesive waterproof coil.
The technical solution used in the present invention is a kind of polymeric laminate adhesive waterproof coil, and comprise glued membrane and the bitumen layer of dip-coating on glued membrane, described bitumen layer is made up of the component of following parts by weight: 100
#pitch 0.5 ~ 2.5 part, 10
#pitch 0.1 ~ 1.2 part, SBS0.1 ~ 0.6 part, SBR0.05 ~ 0.25 part, hydrogenated petroleum resin 0.05 ~ 0.25 part, stone flour 0.1 ~ 2 part.
Preferably, described bitumen layer is made up of the component of following parts by weight: 100
#pitch 1 ~ 2 part, 10
#pitch 0.4 ~ 0.8 part, SBS0.2 ~ 0.4 part, SBR0.1 ~ 0.2 part, hydrogenated petroleum resin 0.1 ~ 0.2 part, stone flour 0.5 ~ 1.5 part.
Preferably, described bitumen layer is made up of the component of following parts by weight: 100
#pitch 1.5 parts, 10
#pitch 0.6 part, SBS0.3 part, SBR0.15 part, hydrogenated petroleum resin 0.15 part, stone flour 1 part.
The present invention also provides a kind of preparation method of described polymeric laminate adhesive waterproof coil, comprises the following steps:
A, preparation bitumen layer: get 100
#pitch and 10
#after pitch mixing, be warming up to 185 DEG C ~ 195 DEG C, add SBS oxidation 0.5 ~ 1.5 hour, grind 0.5 ~ 1.5 hour again, be cooled to 165 DEG C ~ 175 DEG C, then add SBR oxidation 0.5 ~ 1.5 hour, again grind 0.5 ~ 1.5 hour, add hydrogenated petroleum resin oxidation 0.5 ~ 1.5 hour subsequently, be warming up to 175 DEG C ~ 185 DEG C, then add stone flour, stir 0.5 ~ 1.5 hour, be cooled to 115 DEG C ~ 125 DEG C, the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer prepared uniform fold on glued membrane.
In the present invention, SBS is the abbreviation of s-B-S; SBR is the abbreviation of butadiene-styrene rubber.
Beneficial effect of the present invention is: water resistance is good, ageing-resistant, and hot strength is high, good extending performance, has excellent low-temperature tenderness and heat resistance.The waterproof, seepage control of industry and the engineering such as civil building roof covering, body of wall, kitchen and toilet, basement, swimming pool and bridge, subway, reservoir can be applicable to, also be applicable to canister and pipeline corrosion protection protection.Be specially adapted to the engineering waterproofing construction should not employing naked light, be also applicable to moisture substrate construction.
Detailed description of the invention
For making those skilled in the art understand production technology of the present invention and technique effect in detail, introduce application of the present invention and technique effect further with concrete production instance below.
Embodiment 1:
A, preparation bitumen layer: get 1.5 ton 100
#pitch and 0.6 ton 10
#after pitch mixing, be warming up to 190 DEG C, add 0.3 ton of SBS and be oxidized 1 hour, be placed in colloid mill grinding 1 hour, be cooled to 170 DEG C, then add 0.15 ton of SBR and be oxidized 1 hour, be again placed in colloid mill grinding 1 hour, add 0.15 ton of hydrogenated petroleum resin subsequently and be oxidized 1 hour, be warming up to 180 DEG C, then add 1 ton of stone flour, stir 1 hour, be cooled to 120 DEG C, the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer prepared uniform fold on glued membrane.
Embodiment 2:
A, preparation bitumen layer: get 2.5 ton 100
#pitch and 0.1 ton 10
#after pitch mixing, be warming up to 195 DEG C, add 0.1 ton of SBS and be oxidized 1.5 hours, be placed in colloid mill grinding 0.5 hour, be cooled to 175 DEG C, then add 0.05 ton of SBR and be oxidized 0.5 hour, be again placed in colloid mill grinding 1.5 hours, add 0.25 ton of hydrogenated petroleum resin subsequently and be oxidized 0.5 hour, be warming up to 175 DEG C, then add 0.1 ton of stone flour, stir 1.5 hours, be cooled to 115 DEG C, the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer prepared uniform fold on glued membrane.
Embodiment 3:
A, preparation bitumen layer: get 0.5 ton 100
#pitch and 1.2 ton 10
#after pitch mixing, be warming up to 185 DEG C, add 0.6 ton of SBS and be oxidized 0.5 hour, be placed in colloid mill grinding 1.5 hours, be cooled to 165 DEG C, then add 0.25 ton of SBR and be oxidized 1.5 hours, be again placed in colloid mill grinding 0.5 hour, add 0.05 ton of hydrogenated petroleum resin subsequently and be oxidized 1.5 hours, be warming up to 185 DEG C, then add 2 tons of stone flours, stir 0.5 hour, be cooled to 125 DEG C, the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer prepared uniform fold on glued membrane.
Embodiment 4:
A, preparation bitumen layer: get 2 ton 100
#pitch and 0.4 ton 10
#after pitch mixing, be warming up to 185 DEG C, add 0.4 ton of SBS and be oxidized 1 hour, be placed in colloid mill grinding 1 hour, be cooled to 165 DEG C, then add 0.2 ton of SBR and be oxidized 1.5 hours, be again placed in colloid mill grinding 0.5 hour, add 0.1 ton of hydrogenated petroleum resin subsequently and be oxidized 1.5 hours, be warming up to 185 DEG C, then add 0.5 ton of stone flour, stir 0.5 hour, be cooled to 125 DEG C, the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer prepared uniform fold on glued membrane.
Embodiment 5:
A, preparation bitumen layer: get 1 ton 100
#pitch and 0.8 ton 10
#after pitch mixing, be warming up to 190 DEG C, add 0.2 ton of SBS and be oxidized 1 hour, be placed in colloid mill grinding 1 hour, be cooled to 165 DEG C, then add 0.1 ton of SBR and be oxidized 1 hour, be again placed in colloid mill grinding 0.5 hour, add 0.2 ton of hydrogenated petroleum resin subsequently and be oxidized 1 hour, be warming up to 185 DEG C, then add 1.5 tons of stone flours, stir 0.5 hour, be cooled to 120 DEG C, the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer prepared uniform fold on glued membrane.
Comparative example 1:
Hydrogenated petroleum resin is replaced by Petropols, and all the other are implemented by the method for embodiment 1 completely, obtain comparative example 1.
Comparative example 2-5:
The consumption of SBS is changed to 0.02 ton, 0.04 ton, 0.26 ton and 0.28 ton, all the other are implemented by the method for embodiment 1 completely, obtain comparative example 2-5.
For verifying technique effect of the present invention, the following inspection of special do:
Above-described embodiment gained waterproof roll water resistance is good, ageing-resistant, and hot strength is high, good extending performance, has excellent low-temperature tenderness and heat resistance.The waterproof, seepage control of industry and the engineering such as civil building roof covering, body of wall, kitchen and toilet, basement, swimming pool and bridge, subway, reservoir can be applicable to, also be applicable to canister and pipeline corrosion protection protection.Be specially adapted to the engineering waterproofing construction should not employing naked light, be also applicable to moisture substrate construction.
Finally it should be noted that, above embodiment is the unrestricted technical scheme of the present invention in order to explanation only, although with reference to above-described embodiment to invention has been detailed description, those skilled in the art are to be understood that, still can modify to the present invention or equivalent replacement, and not departing from any modification or partial replacement of the spirit and scope of the present invention, it all should be encompassed in right of the present invention.
Claims (3)
1. a polymeric laminate adhesive waterproof coil, comprise glued membrane and the bitumen layer of dip-coating on glued membrane, it is characterized in that, described bitumen layer is made up of the component of following parts by weight: 100
#pitch 0.5 ~ 2.5 part, 10
#pitch 0.1 ~ 1.2 part, SBS0.1 ~ 0.6 part, SBR0.05 ~ 0.25 part, hydrogenated petroleum resin 0.05 ~ 0.25 part, stone flour 0.1 ~ 2 part;
The preparation method of described polymeric laminate adhesive waterproof coil, comprises the following steps:
A, preparation bitumen layer: get 100
#pitch and 10
#after pitch mixing, be warming up to 185 DEG C ~ 195 DEG C, add SBS oxidation 0.5 ~ 1.5 hour, grind 0.5 ~ 1.5 hour again, be cooled to 165 DEG C ~ 175 DEG C, then add SBR oxidation 0.5 ~ 1.5 hour, again grind 0.5 ~ 1.5 hour, add hydrogenated petroleum resin oxidation 0.5 ~ 1.5 hour subsequently, be warming up to 175 DEG C ~ 185 DEG C, then add stone flour, stir 0.5 ~ 1.5 hour, be cooled to 115 DEG C ~ 125 DEG C, the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer prepared uniform fold on glued membrane.
2. polymeric laminate adhesive waterproof coil according to claim 1, is characterized in that, described bitumen layer is made up of the component of following parts by weight: 100
#pitch 1 ~ 2 part, 10
#pitch 0.4 ~ 0.8 part, SBS0.2 ~ 0.4 part, SBR0.1 ~ 0.2 part, hydrogenated petroleum resin 0.1 ~ 0.2 part, stone flour 0.5 ~ 1.5 part.
3. polymeric laminate adhesive waterproof coil according to claim 2, is characterized in that, described bitumen layer is made up of the component of following parts by weight: 100
#pitch 1.5 parts, 10
#pitch 0.6 part, SBS0.3 part, SBR0.15 part, hydrogenated petroleum resin 0.15 part, stone flour 1 part.
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| CN201410322850.3A CN104085144B (en) | 2014-07-08 | 2014-07-08 | Polymeric laminate adhesive waterproof coil and preparation method thereof |
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| CN201410322850.3A CN104085144B (en) | 2014-07-08 | 2014-07-08 | Polymeric laminate adhesive waterproof coil and preparation method thereof |
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| CN104085144B true CN104085144B (en) | 2016-02-17 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105419364A (en) * | 2016-01-05 | 2016-03-23 | 四川杨氏达防水材料有限公司 | Preparation method and application of SBS/rubber compound modification asphalt |
| CN109849452B (en) * | 2018-11-20 | 2021-06-29 | 苏州卓宝科技有限公司 | Modified asphalt waterproof coiled material and preparation method thereof |
| CN110001174A (en) * | 2019-03-27 | 2019-07-12 | 四川环图材料科技有限公司 | Anti-low-temperature cracking self-adhesive modified asphalt waterproof rolling material and preparation method |
| CN114106574A (en) * | 2021-12-30 | 2022-03-01 | 四川蜀羊防水材料有限公司 | Anti-stripping self-adhesive asphalt waterproof coiled material and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101481931A (en) * | 2009-01-20 | 2009-07-15 | 北京市建国伟业防水材料有限公司 | Sticking modified asphalt waterproof coiled material and adhesive, as well as preparation method and application thereof |
| CN102559135A (en) * | 2012-02-09 | 2012-07-11 | 深圳市卓宝科技股份有限公司 | Asphalt self-adhesive and high-polymer self-adhesion rubber waterproof coiled material prepared from asphalt self-adhesive |
| CN103612429A (en) * | 2013-11-30 | 2014-03-05 | 郑恩成 | Dry-and-wet neutral detergent fiber (NDF) macromolecular self-adhesive waterproof coiled material, as well as production process and equipment thereof |
| CN103740122A (en) * | 2014-01-24 | 2014-04-23 | 郑家玉 | Waterproof coiled material of self-adhesive polymer modified asphalt polyester tire and preparation method for waterproof coiled material |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101481931A (en) * | 2009-01-20 | 2009-07-15 | 北京市建国伟业防水材料有限公司 | Sticking modified asphalt waterproof coiled material and adhesive, as well as preparation method and application thereof |
| CN102559135A (en) * | 2012-02-09 | 2012-07-11 | 深圳市卓宝科技股份有限公司 | Asphalt self-adhesive and high-polymer self-adhesion rubber waterproof coiled material prepared from asphalt self-adhesive |
| CN103612429A (en) * | 2013-11-30 | 2014-03-05 | 郑恩成 | Dry-and-wet neutral detergent fiber (NDF) macromolecular self-adhesive waterproof coiled material, as well as production process and equipment thereof |
| CN103740122A (en) * | 2014-01-24 | 2014-04-23 | 郑家玉 | Waterproof coiled material of self-adhesive polymer modified asphalt polyester tire and preparation method for waterproof coiled material |
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