CN104085144B - Polymeric laminate adhesive waterproof coil and preparation method thereof - Google Patents
Polymeric laminate adhesive waterproof coil and preparation method thereof Download PDFInfo
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- CN104085144B CN104085144B CN201410322850.3A CN201410322850A CN104085144B CN 104085144 B CN104085144 B CN 104085144B CN 201410322850 A CN201410322850 A CN 201410322850A CN 104085144 B CN104085144 B CN 104085144B
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- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000000853 adhesive Substances 0.000 title claims abstract description 12
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 11
- 239000010426 asphalt Substances 0.000 claims abstract description 35
- 239000011347 resin Substances 0.000 claims abstract description 17
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000003208 petroleum Substances 0.000 claims abstract description 15
- 235000013312 flour Nutrition 0.000 claims abstract description 14
- 239000012528 membrane Substances 0.000 claims abstract description 14
- 239000004575 stone Substances 0.000 claims abstract description 14
- 238000003618 dip coating Methods 0.000 claims abstract description 3
- 238000010792 warming Methods 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- 230000032683 aging Effects 0.000 abstract description 3
- 239000000084 colloidal system Substances 0.000 description 10
- 238000000227 grinding Methods 0.000 description 10
- 229920003048 styrene butadiene rubber Polymers 0.000 description 9
- 239000002174 Styrene-butadiene Substances 0.000 description 7
- 238000010276 construction Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000004078 waterproofing Methods 0.000 description 4
- 229920005597 polymer membrane Polymers 0.000 description 3
- DEXFNLNNUZKHNO-UHFFFAOYSA-N 6-[3-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-3-oxopropyl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)C(CCC1=CC2=C(NC(O2)=O)C=C1)=O DEXFNLNNUZKHNO-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 230000009182 swimming Effects 0.000 description 2
- KPAPHODVWOVUJL-UHFFFAOYSA-N 1-benzofuran;1h-indene Chemical compound C1=CC=C2CC=CC2=C1.C1=CC=C2OC=CC2=C1 KPAPHODVWOVUJL-UHFFFAOYSA-N 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to a kind of polymeric laminate adhesive waterproof coil and preparation method thereof, belong to building waterproof coil technical field.It comprises glued membrane and the bitumen layer of dip-coating on glued membrane, and described bitumen layer is made up of the component of following parts by weight: 100
#pitch 0.5 ~ 2.5 part, 10
#pitch 0.1 ~ 1.2 part, SBS0.1 ~ 0.6 part, SBR0.05 ~ 0.25 part, hydrogenated petroleum resin 0.05 ~ 0.25 part, stone flour 0.1 ~ 2 part.Advantage of the present invention is: water resistance is good, ageing-resistant, and hot strength is high, good extending performance, has excellent low-temperature tenderness and heat resistance.
Description
Technical field
The invention belongs to building waterproof coil technical field, be specifically related to a kind of polymeric laminate adhesive waterproof coil and preparation method thereof.
Background technology
Waterproof roll is mainly used for the place such as construction wall, roofing and tunnel, highway, refuse landfill, play the flexible building material product of a kind of rollable one-tenth web-like resisting extraneous rainwater, underground water seepage, be connected as ne-leakage between engineering foundation with building, be the first barrier of whole engineering waterproofing, vital effect is played to whole engineering.Product mainly contains asphalt water-proof coiled material and polymer membranes.
Application number be 2007101208098 Chinese invention patent " a kind of low-temperature resistant self-adhesive rubber asphalt waterproofing coiled material " disclose a kind of by asphalt, subtract third fractional oil, waterproof roll that bitumen layer that thermoplastic styrene butadiene rubber, powder styrene butadiene rubber, coumarone indene resin, Petropols, terpene resin, small-molecular-weight polyisobutene, ultra-violet absorber, antioxidant, calcium carbonate are made makes.This waterproof roll also exists the shortcomings such as non-refractory.
Application number be 2009100663136 Chinese invention patent " a kind of preparation method of polymer membranes " disclose the polymer membranes be made up of pitch, rubber, carbon black and antiaging agent.The shortcomings such as this waterproof roll also also exists non-refractory, and the scope of application is little.
Because present extreme weather is given prominence to, the performance of existing waterproof roll can not satisfy the demands, therefore the performance improving waterproof roll has become the technical problem needing solution badly.
Summary of the invention
The object of this invention is to provide a kind of high temperature-resistant polymer glued membrane adhesive waterproof coil.
The technical solution used in the present invention is a kind of polymeric laminate adhesive waterproof coil, and comprise glued membrane and the bitumen layer of dip-coating on glued membrane, described bitumen layer is made up of the component of following parts by weight: 100
#pitch 0.5 ~ 2.5 part, 10
#pitch 0.1 ~ 1.2 part, SBS0.1 ~ 0.6 part, SBR0.05 ~ 0.25 part, hydrogenated petroleum resin 0.05 ~ 0.25 part, stone flour 0.1 ~ 2 part.
Preferably, described bitumen layer is made up of the component of following parts by weight: 100
#pitch 1 ~ 2 part, 10
#pitch 0.4 ~ 0.8 part, SBS0.2 ~ 0.4 part, SBR0.1 ~ 0.2 part, hydrogenated petroleum resin 0.1 ~ 0.2 part, stone flour 0.5 ~ 1.5 part.
Preferably, described bitumen layer is made up of the component of following parts by weight: 100
#pitch 1.5 parts, 10
#pitch 0.6 part, SBS0.3 part, SBR0.15 part, hydrogenated petroleum resin 0.15 part, stone flour 1 part.
The present invention also provides a kind of preparation method of described polymeric laminate adhesive waterproof coil, comprises the following steps:
A, preparation bitumen layer: get 100
#pitch and 10
#after pitch mixing, be warming up to 185 DEG C ~ 195 DEG C, add SBS oxidation 0.5 ~ 1.5 hour, grind 0.5 ~ 1.5 hour again, be cooled to 165 DEG C ~ 175 DEG C, then add SBR oxidation 0.5 ~ 1.5 hour, again grind 0.5 ~ 1.5 hour, add hydrogenated petroleum resin oxidation 0.5 ~ 1.5 hour subsequently, be warming up to 175 DEG C ~ 185 DEG C, then add stone flour, stir 0.5 ~ 1.5 hour, be cooled to 115 DEG C ~ 125 DEG C, the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer prepared uniform fold on glued membrane.
In the present invention, SBS is the abbreviation of s-B-S; SBR is the abbreviation of butadiene-styrene rubber.
Beneficial effect of the present invention is: water resistance is good, ageing-resistant, and hot strength is high, good extending performance, has excellent low-temperature tenderness and heat resistance.The waterproof, seepage control of industry and the engineering such as civil building roof covering, body of wall, kitchen and toilet, basement, swimming pool and bridge, subway, reservoir can be applicable to, also be applicable to canister and pipeline corrosion protection protection.Be specially adapted to the engineering waterproofing construction should not employing naked light, be also applicable to moisture substrate construction.
Detailed description of the invention
For making those skilled in the art understand production technology of the present invention and technique effect in detail, introduce application of the present invention and technique effect further with concrete production instance below.
Embodiment 1:
A, preparation bitumen layer: get 1.5 ton 100
#pitch and 0.6 ton 10
#after pitch mixing, be warming up to 190 DEG C, add 0.3 ton of SBS and be oxidized 1 hour, be placed in colloid mill grinding 1 hour, be cooled to 170 DEG C, then add 0.15 ton of SBR and be oxidized 1 hour, be again placed in colloid mill grinding 1 hour, add 0.15 ton of hydrogenated petroleum resin subsequently and be oxidized 1 hour, be warming up to 180 DEG C, then add 1 ton of stone flour, stir 1 hour, be cooled to 120 DEG C, the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer prepared uniform fold on glued membrane.
Embodiment 2:
A, preparation bitumen layer: get 2.5 ton 100
#pitch and 0.1 ton 10
#after pitch mixing, be warming up to 195 DEG C, add 0.1 ton of SBS and be oxidized 1.5 hours, be placed in colloid mill grinding 0.5 hour, be cooled to 175 DEG C, then add 0.05 ton of SBR and be oxidized 0.5 hour, be again placed in colloid mill grinding 1.5 hours, add 0.25 ton of hydrogenated petroleum resin subsequently and be oxidized 0.5 hour, be warming up to 175 DEG C, then add 0.1 ton of stone flour, stir 1.5 hours, be cooled to 115 DEG C, the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer prepared uniform fold on glued membrane.
Embodiment 3:
A, preparation bitumen layer: get 0.5 ton 100
#pitch and 1.2 ton 10
#after pitch mixing, be warming up to 185 DEG C, add 0.6 ton of SBS and be oxidized 0.5 hour, be placed in colloid mill grinding 1.5 hours, be cooled to 165 DEG C, then add 0.25 ton of SBR and be oxidized 1.5 hours, be again placed in colloid mill grinding 0.5 hour, add 0.05 ton of hydrogenated petroleum resin subsequently and be oxidized 1.5 hours, be warming up to 185 DEG C, then add 2 tons of stone flours, stir 0.5 hour, be cooled to 125 DEG C, the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer prepared uniform fold on glued membrane.
Embodiment 4:
A, preparation bitumen layer: get 2 ton 100
#pitch and 0.4 ton 10
#after pitch mixing, be warming up to 185 DEG C, add 0.4 ton of SBS and be oxidized 1 hour, be placed in colloid mill grinding 1 hour, be cooled to 165 DEG C, then add 0.2 ton of SBR and be oxidized 1.5 hours, be again placed in colloid mill grinding 0.5 hour, add 0.1 ton of hydrogenated petroleum resin subsequently and be oxidized 1.5 hours, be warming up to 185 DEG C, then add 0.5 ton of stone flour, stir 0.5 hour, be cooled to 125 DEG C, the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer prepared uniform fold on glued membrane.
Embodiment 5:
A, preparation bitumen layer: get 1 ton 100
#pitch and 0.8 ton 10
#after pitch mixing, be warming up to 190 DEG C, add 0.2 ton of SBS and be oxidized 1 hour, be placed in colloid mill grinding 1 hour, be cooled to 165 DEG C, then add 0.1 ton of SBR and be oxidized 1 hour, be again placed in colloid mill grinding 0.5 hour, add 0.2 ton of hydrogenated petroleum resin subsequently and be oxidized 1 hour, be warming up to 185 DEG C, then add 1.5 tons of stone flours, stir 0.5 hour, be cooled to 120 DEG C, the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer prepared uniform fold on glued membrane.
Comparative example 1:
Hydrogenated petroleum resin is replaced by Petropols, and all the other are implemented by the method for embodiment 1 completely, obtain comparative example 1.
Comparative example 2-5:
The consumption of SBS is changed to 0.02 ton, 0.04 ton, 0.26 ton and 0.28 ton, all the other are implemented by the method for embodiment 1 completely, obtain comparative example 2-5.
For verifying technique effect of the present invention, the following inspection of special do:
Above-described embodiment gained waterproof roll water resistance is good, ageing-resistant, and hot strength is high, good extending performance, has excellent low-temperature tenderness and heat resistance.The waterproof, seepage control of industry and the engineering such as civil building roof covering, body of wall, kitchen and toilet, basement, swimming pool and bridge, subway, reservoir can be applicable to, also be applicable to canister and pipeline corrosion protection protection.Be specially adapted to the engineering waterproofing construction should not employing naked light, be also applicable to moisture substrate construction.
Finally it should be noted that, above embodiment is the unrestricted technical scheme of the present invention in order to explanation only, although with reference to above-described embodiment to invention has been detailed description, those skilled in the art are to be understood that, still can modify to the present invention or equivalent replacement, and not departing from any modification or partial replacement of the spirit and scope of the present invention, it all should be encompassed in right of the present invention.
Claims (3)
1. a polymeric laminate adhesive waterproof coil, comprise glued membrane and the bitumen layer of dip-coating on glued membrane, it is characterized in that, described bitumen layer is made up of the component of following parts by weight: 100
#pitch 0.5 ~ 2.5 part, 10
#pitch 0.1 ~ 1.2 part, SBS0.1 ~ 0.6 part, SBR0.05 ~ 0.25 part, hydrogenated petroleum resin 0.05 ~ 0.25 part, stone flour 0.1 ~ 2 part;
The preparation method of described polymeric laminate adhesive waterproof coil, comprises the following steps:
A, preparation bitumen layer: get 100
#pitch and 10
#after pitch mixing, be warming up to 185 DEG C ~ 195 DEG C, add SBS oxidation 0.5 ~ 1.5 hour, grind 0.5 ~ 1.5 hour again, be cooled to 165 DEG C ~ 175 DEG C, then add SBR oxidation 0.5 ~ 1.5 hour, again grind 0.5 ~ 1.5 hour, add hydrogenated petroleum resin oxidation 0.5 ~ 1.5 hour subsequently, be warming up to 175 DEG C ~ 185 DEG C, then add stone flour, stir 0.5 ~ 1.5 hour, be cooled to 115 DEG C ~ 125 DEG C, the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer prepared uniform fold on glued membrane.
2. polymeric laminate adhesive waterproof coil according to claim 1, is characterized in that, described bitumen layer is made up of the component of following parts by weight: 100
#pitch 1 ~ 2 part, 10
#pitch 0.4 ~ 0.8 part, SBS0.2 ~ 0.4 part, SBR0.1 ~ 0.2 part, hydrogenated petroleum resin 0.1 ~ 0.2 part, stone flour 0.5 ~ 1.5 part.
3. polymeric laminate adhesive waterproof coil according to claim 2, is characterized in that, described bitumen layer is made up of the component of following parts by weight: 100
#pitch 1.5 parts, 10
#pitch 0.6 part, SBS0.3 part, SBR0.15 part, hydrogenated petroleum resin 0.15 part, stone flour 1 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410322850.3A CN104085144B (en) | 2014-07-08 | 2014-07-08 | Polymeric laminate adhesive waterproof coil and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410322850.3A CN104085144B (en) | 2014-07-08 | 2014-07-08 | Polymeric laminate adhesive waterproof coil and preparation method thereof |
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| CN104085144B true CN104085144B (en) | 2016-02-17 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105419364A (en) * | 2016-01-05 | 2016-03-23 | 四川杨氏达防水材料有限公司 | Preparation method and application of SBS/rubber compound modification asphalt |
| CN109849452B (en) * | 2018-11-20 | 2021-06-29 | 苏州卓宝科技有限公司 | Modified asphalt waterproof coiled material and preparation method thereof |
| CN110001174A (en) * | 2019-03-27 | 2019-07-12 | 四川环图材料科技有限公司 | Anti-low-temperature cracking self-adhesive modified asphalt waterproof rolling material and preparation method |
| CN114106574A (en) * | 2021-12-30 | 2022-03-01 | 四川蜀羊防水材料有限公司 | Anti-stripping self-adhesive asphalt waterproof coiled material and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101481931A (en) * | 2009-01-20 | 2009-07-15 | 北京市建国伟业防水材料有限公司 | Sticking modified asphalt waterproof coiled material and adhesive, as well as preparation method and application thereof |
| CN102559135A (en) * | 2012-02-09 | 2012-07-11 | 深圳市卓宝科技股份有限公司 | Asphalt self-adhesive and high-polymer self-adhesion rubber waterproof coiled material prepared from asphalt self-adhesive |
| CN103612429A (en) * | 2013-11-30 | 2014-03-05 | 郑恩成 | Dry-and-wet neutral detergent fiber (NDF) macromolecular self-adhesive waterproof coiled material, as well as production process and equipment thereof |
| CN103740122A (en) * | 2014-01-24 | 2014-04-23 | 郑家玉 | Waterproof coiled material of self-adhesive polymer modified asphalt polyester tire and preparation method for waterproof coiled material |
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2014
- 2014-07-08 CN CN201410322850.3A patent/CN104085144B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101481931A (en) * | 2009-01-20 | 2009-07-15 | 北京市建国伟业防水材料有限公司 | Sticking modified asphalt waterproof coiled material and adhesive, as well as preparation method and application thereof |
| CN102559135A (en) * | 2012-02-09 | 2012-07-11 | 深圳市卓宝科技股份有限公司 | Asphalt self-adhesive and high-polymer self-adhesion rubber waterproof coiled material prepared from asphalt self-adhesive |
| CN103612429A (en) * | 2013-11-30 | 2014-03-05 | 郑恩成 | Dry-and-wet neutral detergent fiber (NDF) macromolecular self-adhesive waterproof coiled material, as well as production process and equipment thereof |
| CN103740122A (en) * | 2014-01-24 | 2014-04-23 | 郑家玉 | Waterproof coiled material of self-adhesive polymer modified asphalt polyester tire and preparation method for waterproof coiled material |
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Denomination of invention: Polymer adhesive film self-adhesive waterproofing membrane and its preparation method Granted publication date: 20160217 Pledgee: Agricultural Bank of China Co.,Ltd. Kunming Jinning District Branch Pledgor: YUNNAN XINCHENG WATERPROOF SCIENCE & TECHNOLOGY CO.,LTD. Registration number: Y2024980024546 |