CN104085144B - Polymeric laminate adhesive waterproof coil and preparation method thereof - Google Patents

Polymeric laminate adhesive waterproof coil and preparation method thereof Download PDF

Info

Publication number
CN104085144B
CN104085144B CN201410322850.3A CN201410322850A CN104085144B CN 104085144 B CN104085144 B CN 104085144B CN 201410322850 A CN201410322850 A CN 201410322850A CN 104085144 B CN104085144 B CN 104085144B
Authority
CN
China
Prior art keywords
pitch
hour
bitumen layer
add
waterproof coil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201410322850.3A
Other languages
Chinese (zh)
Other versions
CN104085144A (en
Inventor
刘冠麟
黎家国
李再参
樊哲新
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yunnan Glad City Defence Water Science And Technology Ltd
Original Assignee
Yunnan Glad City Defence Water Science And Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yunnan Glad City Defence Water Science And Technology Ltd filed Critical Yunnan Glad City Defence Water Science And Technology Ltd
Priority to CN201410322850.3A priority Critical patent/CN104085144B/en
Publication of CN104085144A publication Critical patent/CN104085144A/en
Application granted granted Critical
Publication of CN104085144B publication Critical patent/CN104085144B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The present invention relates to a kind of polymeric laminate adhesive waterproof coil and preparation method thereof, belong to building waterproof coil technical field.It comprises glued membrane and the bitumen layer of dip-coating on glued membrane, and described bitumen layer is made up of the component of following parts by weight: 100 #pitch 0.5 ~ 2.5 part, 10 #pitch 0.1 ~ 1.2 part, SBS0.1 ~ 0.6 part, SBR0.05 ~ 0.25 part, hydrogenated petroleum resin 0.05 ~ 0.25 part, stone flour 0.1 ~ 2 part.Advantage of the present invention is: water resistance is good, ageing-resistant, and hot strength is high, good extending performance, has excellent low-temperature tenderness and heat resistance.

Description

Polymeric laminate adhesive waterproof coil and preparation method thereof
Technical field
The invention belongs to building waterproof coil technical field, be specifically related to a kind of polymeric laminate adhesive waterproof coil and preparation method thereof.
Background technology
Waterproof roll is mainly used for the place such as construction wall, roofing and tunnel, highway, refuse landfill, play the flexible building material product of a kind of rollable one-tenth web-like resisting extraneous rainwater, underground water seepage, be connected as ne-leakage between engineering foundation with building, be the first barrier of whole engineering waterproofing, vital effect is played to whole engineering.Product mainly contains asphalt water-proof coiled material and polymer membranes.
Application number be 2007101208098 Chinese invention patent " a kind of low-temperature resistant self-adhesive rubber asphalt waterproofing coiled material " disclose a kind of by asphalt, subtract third fractional oil, waterproof roll that bitumen layer that thermoplastic styrene butadiene rubber, powder styrene butadiene rubber, coumarone indene resin, Petropols, terpene resin, small-molecular-weight polyisobutene, ultra-violet absorber, antioxidant, calcium carbonate are made makes.This waterproof roll also exists the shortcomings such as non-refractory.
Application number be 2009100663136 Chinese invention patent " a kind of preparation method of polymer membranes " disclose the polymer membranes be made up of pitch, rubber, carbon black and antiaging agent.The shortcomings such as this waterproof roll also also exists non-refractory, and the scope of application is little.
Because present extreme weather is given prominence to, the performance of existing waterproof roll can not satisfy the demands, therefore the performance improving waterproof roll has become the technical problem needing solution badly.
Summary of the invention
The object of this invention is to provide a kind of high temperature-resistant polymer glued membrane adhesive waterproof coil.
The technical solution used in the present invention is a kind of polymeric laminate adhesive waterproof coil, and comprise glued membrane and the bitumen layer of dip-coating on glued membrane, described bitumen layer is made up of the component of following parts by weight: 100 #pitch 0.5 ~ 2.5 part, 10 #pitch 0.1 ~ 1.2 part, SBS0.1 ~ 0.6 part, SBR0.05 ~ 0.25 part, hydrogenated petroleum resin 0.05 ~ 0.25 part, stone flour 0.1 ~ 2 part.
Preferably, described bitumen layer is made up of the component of following parts by weight: 100 #pitch 1 ~ 2 part, 10 #pitch 0.4 ~ 0.8 part, SBS0.2 ~ 0.4 part, SBR0.1 ~ 0.2 part, hydrogenated petroleum resin 0.1 ~ 0.2 part, stone flour 0.5 ~ 1.5 part.
Preferably, described bitumen layer is made up of the component of following parts by weight: 100 #pitch 1.5 parts, 10 #pitch 0.6 part, SBS0.3 part, SBR0.15 part, hydrogenated petroleum resin 0.15 part, stone flour 1 part.
The present invention also provides a kind of preparation method of described polymeric laminate adhesive waterproof coil, comprises the following steps:
A, preparation bitumen layer: get 100 #pitch and 10 #after pitch mixing, be warming up to 185 DEG C ~ 195 DEG C, add SBS oxidation 0.5 ~ 1.5 hour, grind 0.5 ~ 1.5 hour again, be cooled to 165 DEG C ~ 175 DEG C, then add SBR oxidation 0.5 ~ 1.5 hour, again grind 0.5 ~ 1.5 hour, add hydrogenated petroleum resin oxidation 0.5 ~ 1.5 hour subsequently, be warming up to 175 DEG C ~ 185 DEG C, then add stone flour, stir 0.5 ~ 1.5 hour, be cooled to 115 DEG C ~ 125 DEG C, the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer prepared uniform fold on glued membrane.
In the present invention, SBS is the abbreviation of s-B-S; SBR is the abbreviation of butadiene-styrene rubber.
Beneficial effect of the present invention is: water resistance is good, ageing-resistant, and hot strength is high, good extending performance, has excellent low-temperature tenderness and heat resistance.The waterproof, seepage control of industry and the engineering such as civil building roof covering, body of wall, kitchen and toilet, basement, swimming pool and bridge, subway, reservoir can be applicable to, also be applicable to canister and pipeline corrosion protection protection.Be specially adapted to the engineering waterproofing construction should not employing naked light, be also applicable to moisture substrate construction.
Detailed description of the invention
For making those skilled in the art understand production technology of the present invention and technique effect in detail, introduce application of the present invention and technique effect further with concrete production instance below.
Embodiment 1:
A, preparation bitumen layer: get 1.5 ton 100 #pitch and 0.6 ton 10 #after pitch mixing, be warming up to 190 DEG C, add 0.3 ton of SBS and be oxidized 1 hour, be placed in colloid mill grinding 1 hour, be cooled to 170 DEG C, then add 0.15 ton of SBR and be oxidized 1 hour, be again placed in colloid mill grinding 1 hour, add 0.15 ton of hydrogenated petroleum resin subsequently and be oxidized 1 hour, be warming up to 180 DEG C, then add 1 ton of stone flour, stir 1 hour, be cooled to 120 DEG C, the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer prepared uniform fold on glued membrane.
Embodiment 2:
A, preparation bitumen layer: get 2.5 ton 100 #pitch and 0.1 ton 10 #after pitch mixing, be warming up to 195 DEG C, add 0.1 ton of SBS and be oxidized 1.5 hours, be placed in colloid mill grinding 0.5 hour, be cooled to 175 DEG C, then add 0.05 ton of SBR and be oxidized 0.5 hour, be again placed in colloid mill grinding 1.5 hours, add 0.25 ton of hydrogenated petroleum resin subsequently and be oxidized 0.5 hour, be warming up to 175 DEG C, then add 0.1 ton of stone flour, stir 1.5 hours, be cooled to 115 DEG C, the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer prepared uniform fold on glued membrane.
Embodiment 3:
A, preparation bitumen layer: get 0.5 ton 100 #pitch and 1.2 ton 10 #after pitch mixing, be warming up to 185 DEG C, add 0.6 ton of SBS and be oxidized 0.5 hour, be placed in colloid mill grinding 1.5 hours, be cooled to 165 DEG C, then add 0.25 ton of SBR and be oxidized 1.5 hours, be again placed in colloid mill grinding 0.5 hour, add 0.05 ton of hydrogenated petroleum resin subsequently and be oxidized 1.5 hours, be warming up to 185 DEG C, then add 2 tons of stone flours, stir 0.5 hour, be cooled to 125 DEG C, the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer prepared uniform fold on glued membrane.
Embodiment 4:
A, preparation bitumen layer: get 2 ton 100 #pitch and 0.4 ton 10 #after pitch mixing, be warming up to 185 DEG C, add 0.4 ton of SBS and be oxidized 1 hour, be placed in colloid mill grinding 1 hour, be cooled to 165 DEG C, then add 0.2 ton of SBR and be oxidized 1.5 hours, be again placed in colloid mill grinding 0.5 hour, add 0.1 ton of hydrogenated petroleum resin subsequently and be oxidized 1.5 hours, be warming up to 185 DEG C, then add 0.5 ton of stone flour, stir 0.5 hour, be cooled to 125 DEG C, the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer prepared uniform fold on glued membrane.
Embodiment 5:
A, preparation bitumen layer: get 1 ton 100 #pitch and 0.8 ton 10 #after pitch mixing, be warming up to 190 DEG C, add 0.2 ton of SBS and be oxidized 1 hour, be placed in colloid mill grinding 1 hour, be cooled to 165 DEG C, then add 0.1 ton of SBR and be oxidized 1 hour, be again placed in colloid mill grinding 0.5 hour, add 0.2 ton of hydrogenated petroleum resin subsequently and be oxidized 1 hour, be warming up to 185 DEG C, then add 1.5 tons of stone flours, stir 0.5 hour, be cooled to 120 DEG C, the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer prepared uniform fold on glued membrane.
Comparative example 1:
Hydrogenated petroleum resin is replaced by Petropols, and all the other are implemented by the method for embodiment 1 completely, obtain comparative example 1.
Comparative example 2-5:
The consumption of SBS is changed to 0.02 ton, 0.04 ton, 0.26 ton and 0.28 ton, all the other are implemented by the method for embodiment 1 completely, obtain comparative example 2-5.
For verifying technique effect of the present invention, the following inspection of special do:
Above-described embodiment gained waterproof roll water resistance is good, ageing-resistant, and hot strength is high, good extending performance, has excellent low-temperature tenderness and heat resistance.The waterproof, seepage control of industry and the engineering such as civil building roof covering, body of wall, kitchen and toilet, basement, swimming pool and bridge, subway, reservoir can be applicable to, also be applicable to canister and pipeline corrosion protection protection.Be specially adapted to the engineering waterproofing construction should not employing naked light, be also applicable to moisture substrate construction.
Finally it should be noted that, above embodiment is the unrestricted technical scheme of the present invention in order to explanation only, although with reference to above-described embodiment to invention has been detailed description, those skilled in the art are to be understood that, still can modify to the present invention or equivalent replacement, and not departing from any modification or partial replacement of the spirit and scope of the present invention, it all should be encompassed in right of the present invention.

Claims (3)

1. a polymeric laminate adhesive waterproof coil, comprise glued membrane and the bitumen layer of dip-coating on glued membrane, it is characterized in that, described bitumen layer is made up of the component of following parts by weight: 100 #pitch 0.5 ~ 2.5 part, 10 #pitch 0.1 ~ 1.2 part, SBS0.1 ~ 0.6 part, SBR0.05 ~ 0.25 part, hydrogenated petroleum resin 0.05 ~ 0.25 part, stone flour 0.1 ~ 2 part;
The preparation method of described polymeric laminate adhesive waterproof coil, comprises the following steps:
A, preparation bitumen layer: get 100 #pitch and 10 #after pitch mixing, be warming up to 185 DEG C ~ 195 DEG C, add SBS oxidation 0.5 ~ 1.5 hour, grind 0.5 ~ 1.5 hour again, be cooled to 165 DEG C ~ 175 DEG C, then add SBR oxidation 0.5 ~ 1.5 hour, again grind 0.5 ~ 1.5 hour, add hydrogenated petroleum resin oxidation 0.5 ~ 1.5 hour subsequently, be warming up to 175 DEG C ~ 185 DEG C, then add stone flour, stir 0.5 ~ 1.5 hour, be cooled to 115 DEG C ~ 125 DEG C, the bitumen layer that must prepare;
B, by the above-mentioned bitumen layer prepared uniform fold on glued membrane.
2. polymeric laminate adhesive waterproof coil according to claim 1, is characterized in that, described bitumen layer is made up of the component of following parts by weight: 100 #pitch 1 ~ 2 part, 10 #pitch 0.4 ~ 0.8 part, SBS0.2 ~ 0.4 part, SBR0.1 ~ 0.2 part, hydrogenated petroleum resin 0.1 ~ 0.2 part, stone flour 0.5 ~ 1.5 part.
3. polymeric laminate adhesive waterproof coil according to claim 2, is characterized in that, described bitumen layer is made up of the component of following parts by weight: 100 #pitch 1.5 parts, 10 #pitch 0.6 part, SBS0.3 part, SBR0.15 part, hydrogenated petroleum resin 0.15 part, stone flour 1 part.
CN201410322850.3A 2014-07-08 2014-07-08 Polymeric laminate adhesive waterproof coil and preparation method thereof Active CN104085144B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410322850.3A CN104085144B (en) 2014-07-08 2014-07-08 Polymeric laminate adhesive waterproof coil and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410322850.3A CN104085144B (en) 2014-07-08 2014-07-08 Polymeric laminate adhesive waterproof coil and preparation method thereof

Publications (2)

Publication Number Publication Date
CN104085144A CN104085144A (en) 2014-10-08
CN104085144B true CN104085144B (en) 2016-02-17

Family

ID=51632957

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410322850.3A Active CN104085144B (en) 2014-07-08 2014-07-08 Polymeric laminate adhesive waterproof coil and preparation method thereof

Country Status (1)

Country Link
CN (1) CN104085144B (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105419364A (en) * 2016-01-05 2016-03-23 四川杨氏达防水材料有限公司 Preparation method and application of SBS/rubber compound modification asphalt
CN109849452B (en) * 2018-11-20 2021-06-29 苏州卓宝科技有限公司 Modified asphalt waterproof coiled material and preparation method thereof
CN110001174A (en) * 2019-03-27 2019-07-12 四川环图材料科技有限公司 Anti-low-temperature cracking self-adhesive modified asphalt waterproof rolling material and preparation method
CN114106574A (en) * 2021-12-30 2022-03-01 四川蜀羊防水材料有限公司 Anti-stripping self-adhesive asphalt waterproof coiled material and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101481931A (en) * 2009-01-20 2009-07-15 北京市建国伟业防水材料有限公司 Sticking modified asphalt waterproof coiled material and adhesive, as well as preparation method and application thereof
CN102559135A (en) * 2012-02-09 2012-07-11 深圳市卓宝科技股份有限公司 Asphalt self-adhesive and high-polymer self-adhesion rubber waterproof coiled material prepared from asphalt self-adhesive
CN103612429A (en) * 2013-11-30 2014-03-05 郑恩成 Dry-and-wet neutral detergent fiber (NDF) macromolecular self-adhesive waterproof coiled material, as well as production process and equipment thereof
CN103740122A (en) * 2014-01-24 2014-04-23 郑家玉 Waterproof coiled material of self-adhesive polymer modified asphalt polyester tire and preparation method for waterproof coiled material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101481931A (en) * 2009-01-20 2009-07-15 北京市建国伟业防水材料有限公司 Sticking modified asphalt waterproof coiled material and adhesive, as well as preparation method and application thereof
CN102559135A (en) * 2012-02-09 2012-07-11 深圳市卓宝科技股份有限公司 Asphalt self-adhesive and high-polymer self-adhesion rubber waterproof coiled material prepared from asphalt self-adhesive
CN103612429A (en) * 2013-11-30 2014-03-05 郑恩成 Dry-and-wet neutral detergent fiber (NDF) macromolecular self-adhesive waterproof coiled material, as well as production process and equipment thereof
CN103740122A (en) * 2014-01-24 2014-04-23 郑家玉 Waterproof coiled material of self-adhesive polymer modified asphalt polyester tire and preparation method for waterproof coiled material

Also Published As

Publication number Publication date
CN104085144A (en) 2014-10-08

Similar Documents

Publication Publication Date Title
CN104085145B (en) Modified asphalt waterproof coiled material with self-adhesive layer and preparation method thereof
CN104085144B (en) Polymeric laminate adhesive waterproof coil and preparation method thereof
CN104369512B (en) Stereo colour self-adhesion polymer membranes
CN103924691A (en) High-polymer wet laid waterproof coiled material
CN206352400U (en) Positively fixed type parapet of roofing position waterproof modular repair structure
CN104264561A (en) A non-earthing composite structure for a waterproof pavement layer of a top plate for a road tunnel
CN203499128U (en) Waterproof structure for roof surface
CN202440709U (en) Polyester felt and fiber glass gridding cloth reinforced asphalt waterproof roll
CN205890044U (en) Self -adhesion polymer modified asphalt waterproofing membrane
CN205185462U (en) Novel plastic body modified asphalt waterproofing membrane
KR101300406B1 (en) selective non-exposure complex waterproof structure using soft rubber-asphalt coating material
CN206987213U (en) One kind building compound waterproofing roof
CN203766159U (en) Waterproof coiled material with polyurethane film
CN203876318U (en) EPDM (ethylene-propylene-diene monomer) waterproof roll material
CN105505217A (en) Self-bonding waterproof roll applied to planted roof and preparation method of self-bonding waterproof roll
CN207105806U (en) A kind of wet-laying self-adhesive coiled material
CN202685428U (en) Self-healing elastic body modified asphalt waterproof roll
CN205272780U (en) Expose non - asphalt base polymer self -adhered waterproofing membrane
CN209194863U (en) Ripple asphalt waterproofing plate roof structure
CN204850264U (en) Roofing structure
CN203994913U (en) A kind of compound resistance to waterproof system
CN203080703U (en) Macromolecule wet-paving waterproof coiled materials
CN202440940U (en) Flexible waterproof coiled material of asphalt composite tire
CN206048951U (en) A kind of CPE waterproof rolls
CN207432938U (en) A kind of non-bituminous base adhesive waterproof coil

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant