CN105860925A - Molecular adhesive used for TPZ waterproof rolls and preparation method of molecular adhesive - Google Patents
Molecular adhesive used for TPZ waterproof rolls and preparation method of molecular adhesive Download PDFInfo
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- CN105860925A CN105860925A CN201610297514.7A CN201610297514A CN105860925A CN 105860925 A CN105860925 A CN 105860925A CN 201610297514 A CN201610297514 A CN 201610297514A CN 105860925 A CN105860925 A CN 105860925A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J195/00—Adhesives based on bituminous materials, e.g. asphalt, tar, pitch
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses molecular adhesive used for TPZ waterproof rolls and a preparation method of the molecular adhesive. The molecular adhesive comprises, by weight, 50-70 parts of asphalt, 8-15 parts of second-vacuum naphthenic oil, 5-10 parts of SBS rubber, 3-8 parts of SBR rubber, 2-5 parts of chloroprene rubber, 1-3 parts of nitrile rubber, 3-8 parts of oil resin, and 5-10 parts of calcium powder. The adhesive layer formed by the adhesive can be fused and adhered at low temperature, and the molecular adhesive is good in adhesive sealing performance and is used for TPZ waterproof rolls, and performance of the TPZ waterproof rolls is improved.
Description
Technical field
The present invention relates to a kind of adhesive, be specifically related to a kind of molecular glue stick for TPZ waterproof roll and preparation method thereof.
Background technology
Adhesive is the nonmetal media material making object be integrated with another object compact siro spinning technology also known as adhesive.Glued at two
Between object plane, adhesive only accounts for the thinnest one layer volume, but after using adhesive to complete to glued joint construction, gained bonded part is at machinery
Performance and physical and chemical performance aspect, can meet the requirements being actually needed, can by materials from bonding the most together.Along with
Expanding economy synthetic adhesive is increasingly being applied to every field.
The performance of the adhesive that building trade waterproof roll is used is for the waterproof effect important role of waterproof roll.
At present, the adhesive that building trade waterproof roll is used has the disadvantage that, affects the waterproof effect of waterproof roll.
(1) to glue Wen Nengneng poor for glue-line, and when environment temperature≤15 DEG C, glue-line cannot accomplish the tacky state combined together, material
The viscosity of material performance is only table and glues, and now adhesion between components does not possess water resistance.
(2) easily there is the situation that seal bond is failed in coiled material and basic unit's wet-laying construction, increase the risk of engineering large area channeling water seepage
Occur:
1. low temperature wet-laying easily occurs sealing failed situation, common wet-laying coiled material when environment temperature (≤5~10 DEG C) is relatively low, glue
Layer viscosity reduces rapidly, and the coiled material now constructed with the cement mortar bonding of solidification, and cannot occur wet-laying to seal unsuccessfully.
2. easily there is sealing failed situation in high temperature wet-laying, and tradition wet-laying coiled material uses cement mortar to do the bonding medium of overlap edge, executes
4 hours interior coiled materials of work, because of ground cement mortar first cure in overlap edge, therefore cannot be carried out trickle cooling measure, when construction ring
When border temperature is higher, high temperature makes the moisture in cement slurry produce evaporation, and the steam that coiled material can be evaporated with basic unit is isolated, and makes
The wet-laying becoming waterproof layer seals unsuccessfully.
3. in wet-laying work progress, easily there is sealing failed situation in the rainfall of prominent chance, and tradition wet-laying coiled material uses cement mortar to do overlap edge
Bonding medium, as met rainfall because of prominent in wet-laying work progress, rainwater can dilute the non-initial set of coiled material overlap edge in constructing 4 hours
Solidification cement mortar, enters between coiled material and basic unit, causes waterproof layer wet-laying to seal unsuccessfully.
(3) when occurring wet-laying coiled material to seal unsuccessfully, it will usually the situation of engineering large area seepage occurs, and reason is as follows:
1. wet-laying seals failed waterproof layer, and the guarantee of water resistance is mainly by overlap edge continuous sealing, and common wet-laying coiled material is big
Many employing cement mortars are medium bonding, and the cement grout of rigidity is between two layers of flexible material, the most broken, causes overlap edge to ooze
Water, causes engineering large area channeling water seepage.Minority wet-laying coiled material lapping limit uses glue-line bonding, because glue-line viscosity-temperature characteristics is poor, directly
Bonding can not reach waterproof effect, and engineering still can occur channeling water seepage.
2. because wet-laying seals unsuccessfully, coiled material layer has any breakage, at some position of engineering, all can inevitably cause work
The situation of journey large area channeling water seepage occurs.Such as the waterproof layer at underground engineering top board position, because its superstructure level is complicated, have
Backfill soil, square brick, structure reversed beam etc. exist, and the gradient is little or does not look for slope, causes top board impeded drainage, waterproof layer surface
Open fire is had to be detained for a long time.If waterproof layer exists breakage or defect, penetrating into the open fire within waterproof layer will be along mortar levelling
Layer and the channeling water passage large area with structure interlayer spread, and cause engineering leakage.
(4) common wet-laying coiled material construction quality is relatively big by inside even from weather, in too high in environment temperature, too low, work progress
The weather construction of possible burst rainfall, all cannot ensure wet-laying construction quality, easily cause engineering leakage.
Summary of the invention
Present invention aims to the defect of prior art, it is provided that the adhesive-layer that a kind of adhesive is formed can merge bonding by low temperature,
Adhering and sealing is good, molecular glue stick that can be used for TPZ waterproof roll and preparation method thereof.
The technical scheme is that, a kind of molecular glue stick for TPZ waterproof roll, including the component of following parts by weight:
Preferably, described asphalt is preferably No. 100 and heavily hands over asphalt.
Described Petropols are preferably one or both in group aliphatic resin and aliphatic/aromatic copolymer resins.
Preferably, the weight of described SBS rubber, SBR rubber, neoprene and nitrile rubber accounts for the 15-20% of total adhesive weight.
Preferably, described Petropols are maleic anhydride modified Petropols, and it adds Malaysia by initiator at 165-180 DEG C
It is modified being formed by acid anhydrides.
Described calcium powder is preferably dicalcium powder, dicalcium powder granularity be 500-600 mesh.
Preferably, described calcium powder is modified calcium powder, and it passes through silane coupler and lauryl sodium sulfate under the conditions of 65-75 DEG C
It is modified obtaining to it.
Preferably, a kind of molecular glue stick for TPZ waterproof roll, including the component of following parts by weight:
The preparation method of a kind of molecular glue stick for TPZ waterproof roll, comprises the following steps:
(1) open reactor heat conduction fuel tap, squeeze into asphalt, second line of distillation cycloalkanes base oil, with 15-20 turn/min turn
Speed stirring;
(2) temperature to 130-150 DEG C adds SBR rubber, neoprene and nitrile rubber mix and blend, at 190-200 DEG C of meter
Time stirring 1.0-1.5h, to melting completely, obtain mixture A;
(3) in mixture A, add SBS rubber, keep temperature to be 180-200 DEG C, turn/the rotating speed of min stirring with 40-50
40min, crosses colloid mill one time, obtains mixture B;
(4) in mixture B, add Petropols, keep temperature to be 170-190 DEG C, more continuously stirred 0.5-1.0 hour,
Obtain mixture C;
(5) after Petropols dissolve, in mixture C, add plastic after calcium powder, then insulated and stirred 0.5-1.0 hour, become
Glue is incubated summer: 145-155 DEG C, winter: 160-165 DEG C.
Invention adhesive be mainly composed of asphalt, and add SBS rubber, SBR rubber, neoprene and butyronitrile rubber
Glue improves the performance of adhesive, and test shows, these four composition plays synergy, and the content of these four component is to adhesive
Performance has important impact, is effectively improved pitch high temperature performance, increases adhesive layer viscosity and viscosity, makes gluing interlayer possess
Fusion, the performance of low-temperature adhesion, especially, prepared adhesive possesses the performance bonded in the water of excellence.Adhesive adds
Add auxiliary dissolving rubber altered contents second line of distillation cycloalkanes base oil, promote further SBS rubber, SBR rubber, neoprene and
Nitrile rubber plays a role, and improves the performance of adhesive.The interpolation of Petropols especially modified petroleum resin, increases adhesive-layer
Adhesion strength.Wherein calcium powder is after silane coupler and lauryl sodium sulfate modification, further increases the viscous of adhesive
Connect performance.
The preparation method of invention adhesive, first by SBS rubber, SBR rubber, neoprene and nitrile rubber, with second line of distillation
After cycloalkanes base oil heat treatment, then substep adds the components such as asphalt, Petropols and calcium powder, improves between each component
Compatibility and dissolubility, and then improve the adhesive property of adhesive.
Adhesive applications prepared by the application can be effectively improved the properties of TPZ waterproof roll in TPZ waterproof roll.
Adhesive prepared by the present invention has the advantages that
(1) adhesive realizes low temperature (0 DEG C and more than) and merges bonding, it is adaptable to all construction temperatures of wet-laying coiled material, coiled material is taken
Edge fit uses adhesive layer to bond with glue-line.Only needing contact between glue-line, just can combine together, waterproof construction, without technology, is executed
Work is easy, safety.
(2) realize safer with the sealing of basic unit wet-laying:
1. adhesive realizes low temperature wet-laying secure bond sealing characteristics, and adhesive ,-5 DEG C of temperatures above, all can ensure that coiled material is wet
Spread bonding sealing property.
2. the adhesive prepared by the present invention is used for waterproof roll, and coiled material still can ensure good bonding close in the construction of high temperature wet-laying
Envelope security, coiled material lapping limit uses adhesive-layer to bond with adhesive-layer, seals water resistance good, and coiled material is in construction at high temperature process
In, spraying cooling measure can be done in time on waterproof layer surface, it is to avoid the moisture evaporation in wet-laying cement mortar, it is ensured that waterproof layer and water
Earth rubber pulp layer is combined closely, it is achieved coiled material and basic unit's seal bond.
3. the adhesive prepared by the present invention is used for waterproof roll, and the rainfall that happens suddenly in coiled material wet-laying work progress does not results in coiled material
Wet-laying seals unsuccessfully, and coiled material lapping limit uses glue-line to bond with glue-line, seals water resistance good, and burst rainfall does not interferes with volume
Material wet-laying sealing effectiveness.
(3) adhesive prepared by the present invention is used for TPZ waterproof roll, and water proof structure level is simpler, saves duration and engineering
Direct cost, coiled material and basic unit's wet-laying can form safe seal bond interface, even if coil waterproof layer is damaged, not affect
Waterproof layer integral waterproofing effect.Can save the cement slurry protective layer of waterproof layer and rigidity interlayer, reason has three: 1. coiled material and base
Layer wet-laying can form the seal bond interface of safe not channeling water;The wet-laying coiled material being bonded in basal plane the most completely is very difficult to breakage;
Even if 3. coil waterproof layer is damaged, the most do not affect waterproof layer integral waterproofing effect, it is achieved layer of structure is simpler, saves engineering
Direct cost.
(4) adhesion characteristic during glue-line has water, solves rainy season construction duration problem, as long as can ensure that coiled material wet-laying seal process
Middle wet-laying rubber cement is not diluted to affect seal station and effect, can realize the construction of coiled material little band in the rain rain, waterproof construction duration base
Originally it is protected from weather influences.
Detailed description of the invention
Embodiment 1
A kind of molecular glue stick for TPZ waterproof roll, including the component of following parts by weight:
Wherein, described Petropols are group aliphatic resin, and it uses maleic anhydride to be modified obtaining: by initiator at 175 DEG C
It is modified being formed by lower addition maleic anhydride.
Described dicalcium powder granularity be 500-600 mesh, by silane coupler and lauryl sodium sulfate under the conditions of 75 DEG C right
It is modified.
According to the proportioning of above-mentioned adhesive, make to prepare as follows:
(1) open reactor heat conduction fuel tap, squeeze into asphalt, second line of distillation cycloalkanes base oil, with 15-20 turn/min turn
Speed stirring;
(2) temperature to 130-150 DEG C adds SBR rubber, neoprene and nitrile rubber mix and blend, at 190-200 DEG C of meter
Time stirring 1.2h, to melting completely, obtain mixture A;
(3) in mixture A, add SBS rubber, keep temperature to be 180-200 DEG C, turn/the rotating speed of min stirring with 40-50
40min, crosses colloid mill one time, obtains mixture B;
(4) in mixture B, add Petropols, keep temperature to be 170-190 DEG C, more continuously stirred 0.5 hour, obtain mixed
Compound C;
(5) after Petropols dissolve, adding calcium powder, then insulated and stirred plastic after 0.5 hour in mixture C, plastic is protected
Warm summer: 145-155 DEG C, winter: 160-165 DEG C.
Embodiment 2
A kind of molecular glue stick for TPZ waterproof roll, including the component of following parts by weight:
Wherein, described Petropols are group aliphatic resin, and it uses maleic anhydride to be modified obtaining: by initiator at 165 DEG C
It is modified being formed by lower addition maleic anhydride.
Described dicalcium powder granularity be 500-600 mesh, by silane coupler and lauryl sodium sulfate under the conditions of 65 DEG C right
It is modified.
According to the proportioning of above-mentioned adhesive, make to prepare as follows:
(1) open reactor heat conduction fuel tap, squeeze into asphalt, second line of distillation cycloalkanes base oil, with 15-20 turn/min turn
Speed stirring;
(2) temperature to 130-150 DEG C adds SBR rubber, neoprene and nitrile rubber mix and blend, at 190-200 DEG C of meter
Time stirring 1.0h, to melting completely, obtain mixture A;
(3) in mixture A, add SBS rubber, keep temperature to be 180-200 DEG C, turn/the rotating speed of min stirring with 40-50
40min, crosses colloid mill one time, obtains mixture B;
(4) in mixture B, add Petropols, keep temperature to be 170-190 DEG C, more continuously stirred 0.5 hour, obtain mixed
Compound C;
(5) after Petropols dissolve, adding calcium powder, then insulated and stirred plastic after 0.5 hour in mixture C, plastic is protected
Warm summer: 145-155 DEG C, winter: 160-165 DEG C.
Embodiment 3
A kind of molecular glue stick for TPZ waterproof roll, including the component of following parts by weight:
Wherein, described Petropols are group aliphatic resin, and it uses maleic anhydride to be modified obtaining: by initiator at 180 DEG C
It is modified being formed by lower addition maleic anhydride.
Described dicalcium powder granularity be 500-600 mesh, by silane coupler and lauryl sodium sulfate under the conditions of 70 DEG C right
It is modified.
According to the proportioning of above-mentioned adhesive, make to prepare as follows:
(1) open reactor heat conduction fuel tap, squeeze into asphalt, second line of distillation cycloalkanes base oil, with 15-20 turn/min turn
Speed stirring;
(2) temperature to 130-150 DEG C adds SBR rubber, neoprene and nitrile rubber mix and blend, at 190-200 DEG C of meter
Time stirring 1.5h, to melting completely, obtain mixture A;
(3) in mixture A, add SBS rubber, keep temperature to be 180-200 DEG C, turn/the rotating speed of min stirring with 40-50
40min, crosses colloid mill one time, obtains mixture B;
(4) in mixture B, add Petropols, keep temperature to be 170-190 DEG C, more continuously stirred 1.0 hours, obtain mixed
Compound C;
(5) after Petropols dissolve, adding calcium powder, then insulated and stirred plastic after 1.0 hours in mixture C, plastic is protected
Warm summer: 145-155 DEG C, winter: 160-165 DEG C.
Embodiment 4
A kind of molecular glue stick for TPZ waterproof roll, including the component of following parts by weight:
Wherein, described Petropols are group aliphatic resin, and it uses maleic anhydride to be modified obtaining: by initiator at 175 DEG C
It is modified being formed by lower addition maleic anhydride.
Described dicalcium powder granularity be 500-600 mesh, by silane coupler and lauryl sodium sulfate under the conditions of 75 DEG C right
It is modified.
According to the proportioning of above-mentioned adhesive, make to prepare as follows:
(1) open reactor heat conduction fuel tap, squeeze into asphalt, second line of distillation cycloalkanes base oil, with 15-20 turn/min turn
Speed stirring;
(2) temperature to 130-150 DEG C adds SBR rubber, neoprene and nitrile rubber mix and blend, at 190-200 DEG C of meter
Time stirring 1.2h, to melting completely, obtain mixture A;
(3) in mixture A, add SBS rubber, keep temperature to be 180-200 DEG C, turn/the rotating speed of min stirring with 40-50
40min, crosses colloid mill one time, obtains mixture B;
(4) in mixture B, add Petropols, keep temperature to be 170-190 DEG C, more continuously stirred 0.5 hour, obtain mixed
Compound C;
(5) after Petropols dissolve, adding calcium powder, then insulated and stirred plastic after 0.5 hour in mixture C, plastic is protected
Warm summer: 145-155 DEG C, winter: 160-165 DEG C.
Embodiment 5
A kind of molecular glue stick for TPZ waterproof roll, including the component of following parts by weight:
Wherein, described Petropols are group aliphatic resin, are provided without maleic anhydride and are modified processing.
Described dicalcium powder granularity be 500-600 mesh, not to its be modified process.
According to the proportioning of above-mentioned adhesive, make to prepare as follows:
(1) open reactor heat conduction fuel tap, squeeze into asphalt, second line of distillation cycloalkanes base oil, with 15-20 turn/min turn
Speed stirring;
(2) temperature to 130-150 DEG C adds SBR rubber, neoprene and nitrile rubber mix and blend, at 190-200 DEG C of meter
Time stirring 1.2h, to melting completely, obtain mixture A;
(3) in mixture A, add SBS rubber, keep temperature to be 180-200 DEG C, turn/the rotating speed of min stirring with 40-50
40min, crosses colloid mill one time, obtains mixture B;
(4) in mixture B, add Petropols, keep temperature to be 170-190 DEG C, more continuously stirred 0.5 hour, obtain mixed
Compound C;
(5) after Petropols dissolve, adding calcium powder, then insulated and stirred plastic after 0.5 hour in mixture C, plastic is protected
Warm summer: 145-155 DEG C, winter: 160-165 DEG C.
Adhesive prepared by embodiment 1-5 is respectively used to waterproof layer-cement interlayer, the performance (25 DEG C) of adhesive is entered
Row test, test result is shown in Table 1.
Table 1 Adhensive performance test result
As can be drawn from Table 1, the adhesive prepared by the application has more preferable adhesion strength and shear strength.
A kind of molecular glue stick for TPZ waterproof roll provided the embodiment of the present invention above and preparation method thereof, is carried out
Being discussed in detail, principle and the embodiment of the present invention are set forth by specific case used herein, above example
Method and the core concept thereof being only intended to help to understand the present invention is described;Simultaneously for one of ordinary skill in the art, depend on
According to the thought of the present invention, the most all will change, in sum, this specification content
Should not be construed as limitation of the present invention.
Claims (8)
1. the molecular glue stick for TPZ waterproof roll, it is characterised in that described adhesive includes following parts by weight
Component:
Adhesive the most according to claim 1, it is characterised in that described Petropols be group aliphatic resin and aliphatic/
One or both in aromatic copolyester resin.
Adhesive the most according to claim 1, it is characterised in that described SBS rubber, SBR rubber, neoprene and
The weight of nitrile rubber accounts for the 15-20% of total adhesive weight.
Adhesive the most according to claim 1, it is characterised in that described Petropols are maleic anhydride modified Petropols,
It adds maleic anhydride at 165-180 DEG C by initiator and is modified being formed to it.
Adhesive the most according to claim 1, it is characterised in that described calcium powder is preferably dicalcium powder, dicalcium powder grain
Degree is 500-600 mesh.
Adhesive the most according to claim 1, it is characterised in that described calcium powder is modified calcium powder, and it is by silane coupled
It is modified obtaining under the conditions of 65-75 DEG C by agent and lauryl sodium sulfate.
7. the molecular glue stick for TPZ waterproof roll, it is characterised in that described adhesive includes following parts by weight
Component:
8. it is used for a preparation method for the molecular glue stick of TPZ waterproof roll, comprises the following steps:
(1) open reactor heat conduction fuel tap, squeeze into asphalt, second line of distillation cycloalkanes base oil, with 15-20 turn/min turn
Speed stirring;
(2) temperature to 130-150 DEG C adds SBR rubber, neoprene and nitrile rubber mix and blend, at 190-200 DEG C of meter
Time stirring 1.0-1.5h, to melting completely, obtain mixture A;
(3) in mixture A, add SBS rubber, keep temperature to be 180-200 DEG C, turn/the rotating speed of min stirring with 40-50
40min, crosses colloid mill one time, obtains mixture B;
(4) in mixture B, add Petropols, keep temperature to be 170-190 DEG C, more continuously stirred 0.5-1.0 hour,
Obtain mixture C;
(5) after Petropols dissolve, in mixture C, add plastic after calcium powder, then insulated and stirred 0.5-1.0 hour, become
Glue is incubated summer: 145-155 DEG C, winter: 160-165 DEG C.
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CN108527979A (en) * | 2018-03-14 | 2018-09-14 | 合肥尚涵装饰工程有限公司 | A kind of roof waterproof layer construction composite of water-proof coiled material |
CN109370469A (en) * | 2018-10-24 | 2019-02-22 | 辽宁女娲防水建材科技集团有限公司 | Protective layer macromolecular compounded waterproof material and preparation method thereof, application are exempted from a kind of reinforcing of clad can |
CN111155564A (en) * | 2020-01-21 | 2020-05-15 | 辽宁大禹防水科技发展有限公司 | Synchronous construction process for efficient waterproof TPZ (thermoplastic vulcanizate) red core molecular adhesive waterproof coiled material |
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CN105255203A (en) * | 2015-08-14 | 2016-01-20 | 广西金雨伞防水装饰有限公司 | Softening oil in bridging agent-modified asphalt waterproof coiled material and adjustment method thereof |
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CN103361025A (en) * | 2013-07-19 | 2013-10-23 | 北京东方雨虹防水技术股份有限公司 | Self-adhesive waterproof coiled material having high initial stickiness and preparation method thereof |
CN105238080A (en) * | 2014-07-12 | 2016-01-13 | 卢桂才 | Reactive type modified asphalt and production method therefor |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN108527979A (en) * | 2018-03-14 | 2018-09-14 | 合肥尚涵装饰工程有限公司 | A kind of roof waterproof layer construction composite of water-proof coiled material |
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CN111155564A (en) * | 2020-01-21 | 2020-05-15 | 辽宁大禹防水科技发展有限公司 | Synchronous construction process for efficient waterproof TPZ (thermoplastic vulcanizate) red core molecular adhesive waterproof coiled material |
CN111155564B (en) * | 2020-01-21 | 2020-08-07 | 辽宁大禹防水科技发展有限公司 | Synchronous construction process for efficient waterproof TPZ (thermoplastic vulcanizate) red core molecular adhesive waterproof coiled material |
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CN105860925B (en) | 2017-05-31 |
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Effective date of registration: 20181206 Address after: Room 3-2, 20 Qixin Avenue, Yanjia Street, Changshou District, Chongqing Patentee after: Chongqing Dayu Waterproof Technology Development Co., Ltd. Address before: 124121 Liaoning Panjin new waterproof material industry base Liaoning Dayu waterproof technology development Co., Ltd. Patentee before: LIAONING DAYU WATERPROOF TECHNOLOGY DEVELOPMENT CO., LTD. |