CN107474793B - Self-adhesive waterproof roll cementing material, preparation method thereof and waterproof roll prepared from self-adhesive waterproof roll cementing material - Google Patents

Self-adhesive waterproof roll cementing material, preparation method thereof and waterproof roll prepared from self-adhesive waterproof roll cementing material Download PDF

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CN107474793B
CN107474793B CN201610407758.6A CN201610407758A CN107474793B CN 107474793 B CN107474793 B CN 107474793B CN 201610407758 A CN201610407758 A CN 201610407758A CN 107474793 B CN107474793 B CN 107474793B
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adhesive
coiled material
waterproof roll
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CN107474793A (en
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贾丽凤
高淑美
马鹏程
许金山
刘爱华
毛冬梅
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China Petroleum and Chemical Corp
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J195/00Adhesives based on bituminous materials, e.g. asphalt, tar, pitch
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/40Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/408Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2495/00Presence of bitume

Abstract

The invention belongs to the technical field of building waterproof engineering, and particularly relates to a self-adhesive waterproof roll cementing material, a preparation method thereof and a waterproof roll prepared from the self-adhesive waterproof roll cementing material. The self-adhesive waterproof roll cementing material is prepared from the following raw materials in parts by weight: 46-55 parts of I type waterproof coiled material asphalt, 6-9 parts of SBS, 6-15 parts of waste rubber powder, 8-12 parts of aromatic oil, 5-10 parts of tackifying resin, 4-9 parts of vinyl bis stearamide and 10-25 parts of nano calcium carbonate. The invention solves the problems of easy agglomeration and easy pipeline blockage of the traditional waterproof coiled material rubber material prepared from SBR styrene-butadiene rubber powder; the processing temperature is reduced, the production time of the self-adhesive waterproof roll is greatly shortened, and the production cost is reduced. The invention also provides a waterproof coiled material prepared from the composite material, which has the advantages of good waterproof performance, high tensile strength, good extensibility, excellent low-temperature flexibility and heat resistance.

Description

Self-adhesive waterproof roll cementing material, preparation method thereof and waterproof roll prepared from self-adhesive waterproof roll cementing material
Technical Field
The invention belongs to the technical field of building waterproof engineering, and particularly relates to a self-adhesive waterproof roll cementing material, a preparation method thereof and a waterproof roll prepared from the self-adhesive waterproof roll cementing material.
Background
With the development of economy and the progress of times, the requirements on building materials are higher and higher, and the original building materials cannot meet the development requirements of the times. Many buildings have a reduced life span due to water erosion. Along with the higher and higher requirements of people on the service life of buildings, the more and more attention is paid to the quality of waterproof materials. At present, the elastomer (SBS) modified asphalt waterproof coiled material is still a mainstream product, particularly when a roof is exposed for use, other materials are difficult to replace due to excellent high-temperature resistance, however, the elastomer (SBS) modified asphalt waterproof coiled material needs to be subjected to hot melting construction during construction, a fire hazard exists when a blast burner is baked, and dioxin, hydrocarbon substances and the like can be generated due to combustion of a surface PE film and partial modified asphalt rubber materials during baking and are decomposed by heating, so that the environment is seriously polluted.
In view of the above, researchers have developed a number of self-adhesive waterproofing sheets with various characteristics. The self-adhesive coiled material is a novel waterproof material which can be constructed at normal temperature and does not need hot melting construction, is favored by the market at present, and has the growth rate far exceeding that of an elastomer (SBS) modified asphalt waterproof coiled material. CN200610127174.X and CN200610200760.2 are both self-adhesive waterproof rolls, but the rolls mainly include waterproof base material and self-adhesive layer, which is equivalent to adding self-adhesive layer on the basis of traditional rolls. Although the composite self-adhesive waterproof coiled material solves the problem of difficult construction, the compatibility between layers and the creep property of the waterproof base material are still important factors for limiting the performance of the waterproof coiled material. In contrast, it seems to be more advantageous to apply the self-adhesive waterproofing material directly onto the substrate to make a waterproofing roll. The invention patent of China with application number 200710120809.8 discloses a low temperature resistant self-adhesive rubber asphalt waterproof coiled material which is made of an asphalt layer made of petroleum asphalt, trilinear oil, thermoplastic styrene-butadiene rubber, powdered styrene-butadiene rubber, coumarone resin, petroleum resin, terpene resin, small molecular weight polyisobutylene, an ultraviolet absorbent, an antioxidant and calcium carbonate. The waterproof coiled material is prepared from SBR (styrene butadiene rubber) rubber powder, and has the problems of easy agglomeration and easy pipeline blockage, and the waterproof coiled material has the defects of no high temperature resistance and the like.
Because the current extreme weather is outstanding, the performance of the existing waterproof roll cannot meet the requirement, so that the improvement of the high-low temperature performance of the self-adhesive waterproof roll becomes a technical problem which needs to be solved urgently.
Disclosure of Invention
Aiming at the defects of the prior art, the invention aims to provide a self-adhesive waterproof coiled material cementing material, which solves the problems of easy agglomeration and easy pipeline blockage of the traditional waterproof coiled material prepared by SBR styrene-butadiene rubber powder; the invention also provides a preparation method thereof and a waterproof roll prepared by the preparation method.
The invention relates to a self-adhesive waterproof coiled material cementing material which is prepared from the following raw materials in parts by weight:
Figure BDA0001011438210000021
wherein:
the I type waterproof coiled material asphalt is special asphalt for I type waterproof coiled materials and is a product sold in the field.
The tackifying resin comprises coumarone resin, terpene resin and carbon nine resin; preferably, the tackifying resin is composed of the following raw materials in parts by weight: 10-30 parts of coumarone resin, 10-30 parts of terpene resin and 10-30 parts of carbon nine resin.
The preparation method of the self-adhesive waterproof coiled material cementing material comprises the steps of heating the asphalt of the I-type waterproof coiled material, adding the aromatic oil and the vinyl bis-stearamide, uniformly stirring, cooling, adding the SBS, heating, stirring, adding the tackifying resin and the waste rubber powder, stirring, adding the nano calcium carbonate, and stirring to obtain the product.
As a preferred technical scheme, the preparation method of the self-adhesive waterproof coiled material cementing material comprises the steps of heating the asphalt of the I-type waterproof coiled material to 190-200 ℃, adding the aromatic oil and the vinyl bis stearamide, uniformly stirring, cooling to 180-190 ℃, adding the SBS, heating to 190-200 ℃, stirring for 1.5 hours, adding the tackifying resin and the waste rubber powder, continuously stirring for 0.5 hour at the temperature, adding the nano calcium carbonate, and stirring for 0.5 hour to obtain the product.
The waterproof coiled material prepared by the self-adhesive waterproof coiled material cementing material is uniformly covered on a polyester tire, and a film is covered and cooled.
The waterproof roll prepared by the self-adhesive waterproof roll cementing material comprises an upper protective film, a self-adhesive waterproof cementing material layer consisting of the self-adhesive waterproof roll cementing material, a polyester tire, a self-adhesive waterproof cementing material layer consisting of the self-adhesive waterproof roll cementing material and a lower protective film which are sequentially arranged from top to bottom. The upper protective film can be an anti-sticking silicone oil isolating film; the lower protective film may be a polyethylene film.
In summary, the invention has the following advantages:
(1) the invention adopts the waste rubber powder, thereby not only fully utilizing waste resources and greatly reducing the production cost, but also improving the dimensional stability of the waterproof coiled material. Solves the problems of easy agglomeration and easy pipeline blockage of the traditional waterproof coiled material rubber material prepared from SBR styrene-butadiene rubber powder.
(2) According to the invention, the EBS is added, the compatibility of the EBS and the SBS is good, the glass transition temperature of the system can be reduced, the processing temperature is reduced, the production time of the self-adhesive waterproof roll is greatly shortened, and the production cost is reduced;
(3) the invention provides a self-adhesive waterproof coiled material sizing material with high strength and excellent high and low temperature performance and a preparation method of a waterproof coiled material, wherein cement or base oil does not need to be coated on a base surface.
(4) The self-adhesive waterproof coiled material cementing material and the waterproof coiled material have the advantages of low cost, simple manufacture, good waterproof performance, high tensile strength, good extensibility, and excellent low-temperature flexibility and heat resistance. The water-proof and seepage-proof paint can be suitable for water proofing and seepage proofing of industrial and civil building roofs, walls, kitchens and bathrooms, basements, swimming pools, roads, bridges, subways, reservoirs and other projects, and is also suitable for corrosion prevention protection of metal containers and pipelines. It is especially suitable for the engineering waterproof construction which is not suitable for open fire, and is also suitable for the construction of wet base surface.
Detailed Description
The present invention will be further described with reference to the following examples.
Example 1
The modified asphalt waterproof coiled material with excellent high and low temperature performance comprises an upper protective film, an upper self-adhesive waterproof coiled material cementing material layer, a tire base layer, a lower self-adhesive waterproof coiled material cementing material layer and a lower protective film which are sequentially arranged from top to bottom.
The preparation method of the upper self-adhesive waterproof coiled material cementing material layer and the lower self-adhesive waterproof coiled material cementing material layer comprises the following steps: firstly, heating 46 parts of I-type waterproof coiled material asphalt to 190-200 ℃, adding 8 parts of aromatic oil and 4 parts of EBS, uniformly stirring, cooling to 180-190 ℃, adding 6 parts of SBS, heating to 190-200 ℃, controlling the temperature, stirring for 1.5h, adding 5 parts of tackifying resin (15 parts of coumarone resin, 15 parts of terpene resin and 15 parts of carbon nine resin) and 6 parts of waste rubber powder, continuously stirring for 0.5h at the temperature, adding 10 parts of nano calcium carbonate, and stirring for 0.5h to obtain the product.
The modified asphalt waterproof coiled material prepared in the embodiment is subjected to performance test, and the test results are shown in table 1.
Example 2
The modified asphalt waterproof coiled material with excellent high and low temperature performance comprises an upper protective film, an upper self-adhesive waterproof coiled material cementing material layer, a tire base layer, a lower self-adhesive waterproof coiled material cementing material layer and a lower protective film which are sequentially arranged from top to bottom.
The preparation method of the upper self-adhesive waterproof coiled material cementing material layer and the lower self-adhesive waterproof coiled material cementing material layer comprises the following steps: firstly, heating 46 parts of I-type waterproof coiled material asphalt to 190-200 ℃, adding 12 parts of aromatic oil and 8 parts of EBS, uniformly stirring, cooling to 180-190 ℃, adding 8 parts of SBS, heating to 190-200 ℃, controlling the temperature, stirring for 1.5h, adding 9 parts of tackifying resin (15 parts of coumarone resin, 15 parts of terpene resin and 15 parts of carbon nine resin) and 6 parts of waste rubber powder, continuously stirring for 0.5h at the temperature, adding 17.5 parts of nano calcium carbonate, and stirring for 0.5h to obtain the product.
The modified asphalt waterproof coiled material prepared in the embodiment is subjected to performance test, and the test results are shown in table 1.
Example 3
The modified asphalt waterproof coiled material with excellent high and low temperature performance comprises an upper protective film, an upper self-adhesive waterproof coiled material cementing material layer, a tire base layer, a lower self-adhesive waterproof coiled material cementing material layer and a lower protective film which are sequentially arranged from top to bottom.
The preparation method of the upper self-adhesive waterproof coiled material cementing material layer and the lower self-adhesive waterproof coiled material cementing material layer comprises the following steps: firstly heating 50.5 parts of I-type waterproof coiled material asphalt to 190-200 ℃, adding 10 parts of aromatic oil and 6.5 parts of EBS, uniformly stirring, cooling to 180-190 ℃, adding 7.5 parts of SBS, heating to 190-200 ℃, controlling the temperature, stirring for 1.5h, adding 7.5 parts of tackifying resin (15 parts of coumarone resin, 15 parts of terpene resin and 15 parts of carbon nine resin) and 10.5 parts of waste rubber powder, continuously stirring for 0.5h at the temperature, adding 17.5 parts of nano calcium carbonate, and stirring for 0.5h to obtain the product.
The modified asphalt waterproof coiled material prepared in the embodiment is subjected to performance test, and the test results are shown in table 1.
Example 4
The modified asphalt waterproof coiled material with excellent high and low temperature performance comprises an upper protective film, an upper self-adhesive waterproof coiled material cementing material layer, a tire base layer, a lower self-adhesive waterproof coiled material cementing material layer and a lower protective film which are sequentially arranged from top to bottom.
The preparation method of the upper self-adhesive waterproof coiled material cementing material layer and the lower self-adhesive waterproof coiled material cementing material layer comprises the following steps: firstly heating 50.5 parts of I-type waterproof coiled material asphalt to 190-200 ℃, adding 9 parts of aromatic oil and 6.5 parts of EBS, uniformly stirring, cooling to 180-190 ℃, adding 7 parts of SBS, heating to 190-200 ℃, controlling the temperature, stirring for 1.5h, adding 6 parts of tackifying resin (15 parts of coumarone resin, 15 parts of terpene resin and 15 parts of carbon nine resin) and 12 parts of waste rubber powder, continuously stirring for 0.5h at the temperature, adding 15 parts of nano calcium carbonate, and stirring for 0.5h to obtain the product.
The modified asphalt waterproof coiled material prepared in the embodiment is subjected to performance test, and the test results are shown in table 1.
Example 5
The modified asphalt waterproof coiled material with excellent high and low temperature performance comprises an upper protective film, an upper self-adhesive waterproof coiled material cementing material layer, a tire base layer, a lower self-adhesive waterproof coiled material cementing material layer and a lower protective film which are sequentially arranged from top to bottom.
The preparation method of the upper self-adhesive waterproof coiled material cementing material layer and the lower self-adhesive waterproof coiled material cementing material layer comprises the following steps: firstly, heating 52 parts of I-type waterproof coiled material asphalt to 190-200 ℃, adding 11.5 parts of aromatic oil and 8 parts of EBS, uniformly stirring, cooling to 180-190 ℃, adding 8.5 parts of SBS, heating to 190-200 ℃, controlling the temperature, stirring for 1.5h, adding 9 parts of tackifying resin (15 parts of coumarone resin, 15 parts of terpene resin and 15 parts of carbon nine resin) and 13 parts of waste rubber powder, continuously stirring for 0.5h at the temperature, adding 20 parts of nano calcium carbonate, and stirring for 0.5h to obtain the product.
The modified asphalt waterproof coiled material prepared in the embodiment is subjected to performance test, and the test results are shown in table 1.
Example 6
The modified asphalt waterproof coiled material with excellent high and low temperature performance comprises an upper protective film, an upper self-adhesive waterproof coiled material cementing material layer, a tire base layer, a lower self-adhesive waterproof coiled material cementing material layer and a lower protective film which are sequentially arranged from top to bottom.
The preparation method of the upper self-adhesive waterproof coiled material cementing material layer and the lower self-adhesive waterproof coiled material cementing material layer comprises the following steps: firstly, 55 parts of I-type waterproof coiled material asphalt is heated to 190-200 ℃, 12 parts of aromatic oil and 9 parts of EBS are added, the mixture is uniformly stirred and cooled to 180-190 ℃, 9 parts of SBS is added, the mixture is heated to 190-200 ℃, the temperature is controlled, the mixture is stirred for 1.5h, 10 parts of tackifying resin (15 parts of coumarone resin, 15 parts of terpene resin and 15 parts of carbon nine resin) and 15 parts of waste rubber powder are added, the mixture is continuously stirred for 0.5h at the temperature, 25 parts of nano calcium carbonate are added, and the product is obtained after stirring for 0.5 h.
The modified asphalt waterproof coiled material prepared in the embodiment is subjected to performance test, and the test results are shown in table 1.
Comparative example 1
The modified asphalt waterproof coiled material with excellent high and low temperature performance comprises an upper protective film, an upper self-adhesive waterproof coiled material cementing material layer, a tire base layer, a lower self-adhesive waterproof coiled material cementing material layer and a lower protective film which are sequentially arranged from top to bottom.
The preparation method of the upper self-adhesive waterproof coiled material cementing material layer and the lower self-adhesive waterproof coiled material cementing material layer comprises the following steps: firstly heating 46 parts of I-type waterproof coiled material asphalt to 190-200 ℃, adding 8 parts of aromatic oil, uniformly stirring, cooling to 180-190 ℃, adding 6 parts of SBS, heating to 190-200 ℃, controlling the temperature, stirring for 1.5h, then adding 5 parts of tackifying resin (15 parts of coumarone resin, 15 parts of terpene resin and 15 parts of carbon nine resin) and 6 parts of waste rubber powder, continuously stirring for 0.5h at the temperature, adding 10 parts of nano calcium carbonate, and stirring for 0.5h to obtain the product.
The modified asphalt waterproof coiled material prepared by the comparative example is subjected to performance test, and the test result is shown in table 1.
Table 1 results of performance test of products prepared in examples 1 to 6 and comparative example 1
Figure BDA0001011438210000051
As can be seen from the data in table 1: the waterproof coiled material prepared by the invention has the advantages of good waterproof performance, high tensile strength, good extensibility, excellent low-temperature flexibility and heat resistance. The method can solve the defects of easy agglomeration and pipeline blockage caused by using SBR styrene-butadiene rubber powder.

Claims (4)

1. The utility model provides a glued material of self-adhesion waterproofing membrane which characterized in that: the feed is prepared from the following raw materials in parts by weight:
Figure FDA0002184211120000011
the tackifying resin comprises coumarone resin, terpene resin and carbon nine resin;
the preparation method of the self-adhesive waterproof roll cementing material comprises the following steps: firstly heating the I type waterproof coiled material asphalt, then adding the aromatic oil and the vinyl bis stearamide, uniformly stirring, cooling, then adding the SBS, heating, stirring, then adding the tackifying resin and the waste rubber powder, stirring, finally adding the nano calcium carbonate, and stirring to obtain the product.
2. The self-adhesive waterproof roll cementing material of claim 1, which is characterized in that: the tackifying resin is prepared from the following raw materials in parts by weight: 10-30 parts of coumarone resin, 10-30 parts of terpene resin and 10-30 parts of carbon nine resin.
3. The self-adhesive waterproof roll cementing material of claim 1, which is characterized in that: firstly heating the I type waterproof coiled material asphalt to 190-200 ℃, then adding aromatic oil and vinyl bis stearamide, uniformly stirring, cooling to 180-190 ℃, then adding SBS, heating to 190-200 ℃, stirring for 1.5h, then adding tackifying resin and waste rubber powder, continuously stirring for 0.5h at the temperature, finally adding nano calcium carbonate, and stirring for 0.5h to obtain the product.
4. A waterproofing roll prepared by the self-adhesive waterproofing roll binder of any one of claims 1 to 2, characterized in that: the self-adhesive waterproof roll comprises an upper protective film, a self-adhesive waterproof adhesive layer, a polyester tire, a self-adhesive waterproof adhesive layer and a lower protective film, wherein the upper protective film, the self-adhesive waterproof adhesive layer and the polyester tire are sequentially arranged from top to bottom.
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CN109054644A (en) * 2018-06-27 2018-12-21 安徽省万帮新型建材科技有限公司 A kind of rubber powder-elastomer composite modified asphalt waterproof coating material preparation method for adding nanometer calcium carbonate
CN112646547B (en) * 2019-10-11 2022-08-12 中国石油化工股份有限公司 Self-cleaning noise-reducing self-adhesive waterproof coiled material cementing material and preparation method thereof
CN113858740A (en) * 2020-06-30 2021-12-31 中国石油化工股份有限公司 Modified asphalt sizing material and low heat accumulation type waterproof coiled material prepared from same
CN112980362A (en) * 2021-03-02 2021-06-18 江苏凯伦建材股份有限公司 Preparation method of self-adhesive waterproof material
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