CN110359643A - A kind of high-temperature resistant self-adhesive waterproof roll and preparation method thereof - Google Patents
A kind of high-temperature resistant self-adhesive waterproof roll and preparation method thereof Download PDFInfo
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- CN110359643A CN110359643A CN201810250441.5A CN201810250441A CN110359643A CN 110359643 A CN110359643 A CN 110359643A CN 201810250441 A CN201810250441 A CN 201810250441A CN 110359643 A CN110359643 A CN 110359643A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/25—Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
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- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D31/00—Protective arrangements for foundations or foundation structures; Ground foundation measures for protecting the soil or the subsoil water, e.g. preventing or counteracting oil pollution
- E02D31/02—Protective arrangements for foundations or foundation structures; Ground foundation measures for protecting the soil or the subsoil water, e.g. preventing or counteracting oil pollution against ground humidity or ground water
- E02D31/025—Draining membranes, sheets or fabric specially adapted therefor, e.g. with dimples
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
- E04D5/00—Roof covering by making use of flexible material, e.g. supplied in roll form
- E04D5/10—Roof covering by making use of flexible material, e.g. supplied in roll form by making use of compounded or laminated materials, e.g. metal foils or plastic films coated with bitumen
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/006—Presence of polyester in the substrate
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Abstract
The invention belongs to architectural waterproof material technical fields, and in particular to a kind of high-temperature resistant self-adhesive waterproof roll and preparation method thereof.High-temperature resistant self-adhesive waterproof roll of the present invention, prepare using the dubbin feed composition of different compositions the surface layer Waterproof glue line and bottom Waterproof glue line of the waterproof roll, the high-temperature resistant self-adhesive waterproof roll obtained, in addition to performances such as intensity etc. reach and use standard, the high temperature resistance of end surfaces more can reach 110-130 DEG C thereon, low temperature resistance reaches -20~-30 DEG C, the high temperature resistance of bottom face can also reach 90 DEG C, phenomenon of trickling caused by because of summer weather sweltering heat can be effectively avoided, there is preferable high temperature resistance and stability in use.
Description
Technical field
The invention belongs to architectural waterproof material technical fields, and in particular to a kind of high-temperature resistant self-adhesive waterproof roll and its preparation
Method.
Background technique
It rises sheer from level ground such as spring bamboo with social progress, various buildings, but is built in various engineerings with the development of economy
If when, often will appear roofing, ground, basement infiltration leak the problems such as, in order to solve this problem, construction waterproofing engineering is answered
It transports and gives birth to, widely applied construction material is waterproof roll usually in construction waterproofing engineering.
Waterproof roll is commonly called as malthoid or asphalt felt, is often referred to prevent in rolls made of pitch, rubber or other organic materials
Water material, or pitch class or high score subclass waterproof material are immersed on carcass, the waterproof material product being fabricated to, with coiled material
Form provides.Different according to main composition material, waterproof roll is generally divided into asphalt water-proof coiled material, high-polymer modified pitch waterproof
Coiled material and synthetic polymeric waterproofing material；It is divided into no carcass coiled material, paper tire coiled material, glass fibre tire volume according to the difference of carcass
Material, glass cloth tire coiled material and polyethylene tire coiled material.No matter which kind of material requires that waterproof roll has preferable waterproofness, flexible
Property, temperature change stability (do not trickle under high temperature, is not blistering, not confusing, not embrittlement under low temperature), and have certain machine
Tool intensity, extensibility and resistance to fracture and the performances such as certain flexibility and ageing resistance.
Adhesive waterproof coil has been developed in recent years a kind of novel high-grade waterproof material, is mainly used for the base of building
Face water-proofing treatment is a kind of waterproof material of great development prospect, at home with excellent flexibility and viscous stickiness
Also increasingly had become " new lover " of current waterproofing industry by liking in the industry.However, with adhesive waterproof coil application
The continuous expansion in field, the shortcomings that also gradually having highlighted adhesive waterproof coil.The production of existing adhesive waterproof coil, on tire base
Lower surface has been all made of identical self-adhesion component, this mainly considers in process simple and easy to do.However, it is known that from
Viscous its heat resistance of component is lower, and usually only 70 DEG C, generally in high temperature season, cement basal plane is shining upon underlaying surface temperature
It can reach 70 DEG C or more, along with some metal Roofs easily absorb heat, surface temperature can reach 80 DEG C or more, the prior art
In usually used adhesive waterproof coil the problems such as drum, trickling, cracking can occur at this temperature, heat resistance is unable to satisfy
Normal requirement has seriously affected the service performance and waterproof effect of waterproof roll.Therefore, it is resistant to high temperature certainly to develop one kind
Viscous waterproof roll is very necessary.
Summary of the invention
For this purpose, technical problem to be solved by the present invention lies in a kind of high-temperature resistant self-adhesive waterproof roll is provided, it is existing to solve
There is the problem that adhesive waterproof coil high temperature resistance is poor in technology.
In order to solve the above technical problems, one kind of the present invention is used to prepare high-temperature resistant self-adhesive waterproof roll surface layer waterproof
The composition of oil plant, in terms of the total amount of the composition, the component including following parts by weight: 100# pitch 30-40wt%, 10# drip
Green 10-20wt%, SIS 2-8wt%, APP 0.1-2wt%, eliminating smell agent 0.1-1wt%, high temperature resistant asphalt modifying agent 1-3wt%, plasticising
Agent 10-20wt%, softening agent 5-15wt%, filler material 15-18wt%.
Preferably, the composition for being used to prepare high-temperature resistant self-adhesive waterproof roll surface layer waterproof oil plant, with described group
Close the total amount meter of object, the component including following parts by weight: 100# pitch 35%, 10# pitch 15%, SIS 5%, APP 1%, eliminating smell agent
0.5%, high temperature resistant asphalt modifying agent 2%, plasticizer 15%, softening agent 10%, filler material 16.5%.
Specifically, described is used to prepare in the composition of high-temperature resistant self-adhesive waterproof roll surface layer waterproof oil plant:
The eliminating smell agent is the mixture eliminating smell agent of aluminium triphosphate and polyvinyl alcohol；
The high temperature resistant asphalt modifying agent includes alpha-olefine polymers APAO；
The plasticizer includes surface layer waterproof roll rubber powder, and preferably its fineness is 60 mesh；It is preferred that the surface layer waterproof roll rubber
Rubber powder includes cover tire rubber powder 25%, inner tube of a tyre rubber powder 50% and sbr powder 25%；
The softening agent includes aromatic naphtha, preferred aromatic hydrocarbons content > 80%；
The filler material includes talcum powder, and preferably its fineness is 200 mesh.
The invention also discloses a kind of compositions for being used to prepare high-temperature resistant self-adhesive waterproof roll bottom waterproof oil plant, with institute
The total amount meter of composition is stated, the component including following parts by weight: 100# pitch 30-35wt%, 10# pitch 15-20wt%, SBS 2-
8 wt %, tackifier 2-8 wt %, C9 resin 1-5wt%, SBR 2-8wt%, plasticizer 10-16wt%, softening agent 10-15wt%,
Filler material 5-10wt%.
Preferably, the composition for being used to prepare high-temperature resistant self-adhesive waterproof roll bottom waterproof oil plant, with described group
Close the total amount meter of object, the component including following parts by weight: 100# pitch 32%, 10# pitch 18%, SBS 5%, tackifier 5%, C9 tree
Rouge 3%, SBR 5%, plasticizer 13%, softening agent 12%, filler material 7%.
Specifically, described is used to prepare in the composition of high-temperature resistant self-adhesive waterproof roll bottom waterproof oil plant:
The tackifier include polymethacrylates or ethylene-propylene copolymer；
The C9 resin includes C9 Petropols；
The plasticizer includes bottom waterproof roll rubber powder, and preferably its fineness is 60 mesh；It is preferred that the bottom waterproof roll rubber
Rubber powder includes cover tire rubber powder 15%, inner tube of a tyre rubber powder 25% and sbr powder 60%；
The softening agent includes aromatic naphtha, preferred aromatic hydrocarbons content > 80%；
The filler material includes talcum powder, and preferably its fineness is 60 mesh.
The invention also discloses a kind of high-temperature resistant self-adhesive waterproof rolls, from top to bottom successively include surface layer isolation film, surface layer
Waterproof compound layer, tire based material layer, bottom waterproof compound layer and bottom self-adhesive film；
The surface layer waterproof compound layer is by the composition for being used to prepare high-temperature resistant self-adhesive waterproof roll surface layer waterproof oil plant
It is prepared；
The bottom waterproof compound layer is by the composition for being used to prepare high-temperature resistant self-adhesive waterproof roll bottom waterproof oil plant
It is prepared.
The surface layer waterproof compound layer with a thickness of 1.5-2mm, the bottom waterproof compound layer with a thickness of 1.5-2mm.
The tire based material layer is polyester carcass or combined type copper tire base.
The invention also discloses a kind of methods for preparing the high-temperature resistant self-adhesive waterproof roll, include the following steps:
(1) prepared by surface layer waterproof oil plant:
It takes a selected amount of 100# pitch and 10# pitch to mix, is warming up to 150-160 DEG C, and the pitch eliminating smell agent is added
And the part softening agent, it stirs evenly；
A selected amount of described SIS, APP and high temperature resistant asphalt modifying agent is added, is warming up to 170-180 DEG C of stirring to being completely dissolved；
A selected amount of the plasticizer is added, and is continuously heating to 190-200 DEG C, stirs evenly；
The softening agent and the filler material of surplus is added, stirs evenly to get required surface layer waterproof oil plant, keeps temperature
It is 160-170 DEG C, spare；
(2) prepared by bottom waterproof oil plant:
It takes a selected amount of 100# pitch and 10# pitch to mix, is warming up to 150-160 DEG C, and the part softening agent is added,
It stirs evenly；
The a selected amount of SBS, tackifier and SBR is added, is warming up to 170-180 DEG C of stirring to dissolution；
A selected amount of the plasticizer is added, and is continuously heating to 190-200 DEG C, stirs evenly；
The softening agent, C9 resin and the filler material of surplus is added, stirs evenly to get required bottom waterproof oil plant,
160-170 DEG C of temperature of holding, it is spare；
(3) take selected carcass as the tire based material layer, and oily by bottom waterproof material described in oil sump dip-coating, described in formation
Bottom waterproof compound layer, and the bottom self-adhesive film is covered on the bottom waterproof compound layer；
(4) in the other side of the tire based material layer, the surface layer waterproof oil plant is coated using spraying method, forms the surface layer
Waterproof compound layer, and the surface layer isolation film is covered on the surface layer waterproof compound layer；
(5) be cooled and shaped and pack to get.
High-temperature resistant self-adhesive waterproof roll of the present invention, prepared using the dubbin feed composition of different compositions described in
The surface layer Waterproof glue line and bottom Waterproof glue line of waterproof roll, the surface layer Waterproof glue line with 100# pitch, 10# pitch, SIS,
APP, eliminating smell agent, high temperature resistant asphalt modifying agent, plasticizer, softening agent and filler material are prepared by raw material, the bottom waterproof
Glue-line is prepared using 100# pitch, 10# pitch, SBS, tackifier, C9, SBR, plasticizer, softening agent and filler material as raw material.
The high-temperature resistant self-adhesive waterproof roll obtained, in addition to performances such as intensity etc. reach and use standard, the resistance to height of end surfaces thereon
Warm nature can more can reach 110-130 DEG C, and low temperature resistance reaches -20~-30 DEG C, and bottom face is ensuring the same of its self-adhesion
When, high temperature resistance can also reach 90 DEG C, can effectively avoid because summer weather it is hot caused by trickle phenomenon, have compared with
Good high temperature resistance and stability in use.
High-temperature resistant self-adhesive waterproof roll of the present invention, when use, do not need to heat, easy for construction, and nonirritant gas
Taste facilitates environmental protection, and top surface cost is lower, reduces the cost of material.
Detailed description of the invention
In order to make the content of the present invention more clearly understood, it below according to specific embodiments of the present invention and combines
Attached drawing, the present invention is described in further detail, wherein
Fig. 1 is the structural schematic diagram of waterproof roll of the present invention；
Appended drawing reference indicates in figure are as follows: the surface layer 1- isolation film, the surface layer 2- waterproof compound layer, 3- tire based material layer, 4- bottom waterproof
Compound layer, 5- bottom self-adhesive film.
Specific embodiment
Embodiment 1
High-temperature resistant self-adhesive waterproof roll described in the present embodiment successively includes surface layer isolation film 1, surface layer waterproof compound layer from top to bottom
2, tire based material layer 3, bottom waterproof compound layer 4 and bottom self-adhesive film 5；
The surface layer waterproof compound layer 2 is prepared by surface layer waterproof oil plant, in terms of its total amount, the group including following mass percentage
Point:
100# pitch 30wt%；
10# pitch 20wt%；
SIS 2wt%；
APP 2wt%；
Mixture (1:1) 0.1wt% of aluminium triphosphate and polyvinyl alcohol；
Alpha-olefine polymers 3wt%；
Surface layer waterproof roll rubber powder 12.9wt%；
Aromatic naphtha 15wt%；
Talcum powder 15wt%.
The surface layer waterproof roll rubber powder includes cover tire rubber powder 25%, inner tube of a tyre rubber powder 50% and sbr powder 25%.
The bottom waterproof compound layer 4 is prepared by bottom waterproof oil plant, in terms of its total amount, including following mass percentage
Component:
100# pitch 30wt%；
10# pitch 20wt%；
SBS 2wt %；
8 wt % of polymethacrylates；
C9 Petropols 1wt%；
SBR 8wt%；
Bottom waterproof roll rubber powder 11wt%；
Aromatic naphtha 15wt%；
Talcum powder 5wt%.
The bottom waterproof roll rubber powder includes cover tire rubber powder 15%, inner tube of a tyre rubber powder 25% and sbr powder 60%.
The preparation method of high-temperature resistant self-adhesive waterproof roll, includes the following steps: described in the present embodiment
(1) prepared by surface layer waterproof oil plant:
It takes a selected amount of 100# pitch and 10# pitch to mix, is warming up to 160 DEG C, and the eliminating smell agent and 1/2 amount is added
The softening agent, stirs evenly；
A selected amount of described SIS, APP and high temperature resistant asphalt modifying agent is added, is warming up to 180 DEG C of stirrings to being completely dissolved；
A selected amount of the plasticizer is added, and is continuously heating to 190 DEG C, stirs evenly；
The softening agent and the filler material of remaining 1/2 amount is added, stirs evenly to get required surface layer waterproof oil plant, keeps
It is 160-170 DEG C of temperature, spare；
(2) prepared by bottom waterproof oil plant:
It takes a selected amount of 100# pitch and 10# pitch to mix, is warming up to 160 DEG C, and the softening agent of 2/3 amount is added,
It stirs evenly；
The a selected amount of SBS, tackifier and SBR is added, is warming up to 180 DEG C of stirrings to dissolution；
A selected amount of the plasticizer is added, and is continuously heating to 190 DEG C, stirs evenly；
The softening agent, C9 resin and the filler material of remaining 1/3 amount is added, stirs evenly to get required bottom dubbin
Material, 160-170 DEG C of temperature of holding are spare；
(3) take polyester carcass as the tire based material layer, and by bottom waterproof material oil described in oil sump dip-coating, the bottom is anti-
The dosage of water material oil is advisable with that can submerge the polyester carcass, forms the bottom waterproof compound layer, and control dipping is formed
The bottom waterproof compound layer with a thickness of 1.5-2mm, and on the bottom waterproof compound layer cover PET silicon oil membrane as institute
State bottom self-adhesive film；
(4) in the other side of the tire based material layer, the surface layer waterproof oil plant is coated using spraying method, forms the surface layer
Waterproof compound layer, control the surface layer waterproof compound layer with a thickness of 1.5-2mm, and covered on the surface layer waterproof compound layer
Release film is as the surface layer isolation film；
(5) waterproof roll of formation is cooled and shaped and is packed to get.
Embodiment 2
High-temperature resistant self-adhesive waterproof roll described in the present embodiment successively includes surface layer isolation film 1, surface layer waterproof compound layer from top to bottom
2, tire based material layer 3, bottom waterproof compound layer 4 and bottom self-adhesive film 5；
The surface layer waterproof compound layer is prepared by surface layer waterproof oil plant, in terms of its total amount, the group including following mass percentage
Point:
100# pitch 40wt%；
10# pitch 10wt%；
SIS 8wt%；
APP 0.1wt%；
Aluminium triphosphate and polyvinyl alcohol (1:1) 1wt%；
Alpha-olefine polymers 1wt%；
Surface layer waterproof roll rubber powder (ibid) 20wt%；
Aromatic naphtha 5wt%；
Talcum powder 14.9wt%.
The bottom waterproof compound layer is prepared by bottom waterproof oil plant, in terms of its total amount, including following mass percentage
Component:
100# pitch 35wt%；
10# pitch 15wt%；
SBS 8wt %；
Ethylene-propylene copolymer 2wt %；
C9 Petropols 5wt%；
SBR 2wt%；
Bottom waterproof roll rubber powder (ibid) 16wt%；
Aromatic naphtha 10wt%；
Talcum powder 7wt%.
The preparation method of high-temperature resistant self-adhesive waterproof roll, includes the following steps: described in the present embodiment
(1) prepared by surface layer waterproof oil plant:
It takes a selected amount of 100# pitch and 10# pitch to mix, is warming up to 160 DEG C, and the eliminating smell agent and 1/2 amount is added
The softening agent, stirs evenly；
A selected amount of described SIS, APP and high temperature resistant asphalt modifying agent is added, is warming up to 180 DEG C of stirrings to being completely dissolved；
A selected amount of the plasticizer is added, and is continuously heating to 190 DEG C, stirs evenly；
The softening agent and the filler material of remaining 1/2 amount is added, stirs evenly to get required surface layer waterproof oil plant, keeps
It is 160-170 DEG C of temperature, spare；
(2) prepared by bottom waterproof oil plant:
It takes a selected amount of 100# pitch and 10# pitch to mix, is warming up to 160 DEG C, and the softening agent of 2/3 amount is added,
It stirs evenly；
The a selected amount of SBS, tackifier and SBR is added, is warming up to 180 DEG C of stirrings to dissolution；
A selected amount of the plasticizer is added, and is continuously heating to 190 DEG C, stirs evenly；
The softening agent, C9 resin and the filler material of remaining 1/3 amount is added, stirs evenly to get required bottom dubbin
Material, 160-170 DEG C of temperature of holding are spare；
(3) take polyester carcass as the tire based material layer, and by bottom waterproof material oil described in oil sump dip-coating, the bottom is anti-
The dosage of water material oil is advisable with that can submerge the polyester carcass, forms the bottom waterproof compound layer, and control dipping is formed
The bottom waterproof compound layer with a thickness of 1.5-2mm, and on the bottom waterproof compound layer cover PE silicon oil membrane as institute
State bottom self-adhesive film；
(4) in the other side of the tire based material layer, the surface layer waterproof oil plant is coated using spraying method, forms the surface layer
Waterproof compound layer, control the surface layer waterproof compound layer with a thickness of 1.5-2mm, and covered on the surface layer waterproof compound layer
Release film is as the surface layer isolation film；
(5) waterproof roll of formation is cooled and shaped and is packed to get.
Embodiment 3
High-temperature resistant self-adhesive waterproof roll described in the present embodiment successively includes surface layer isolation film 1, surface layer waterproof compound layer from top to bottom
2, tire based material layer 3, bottom waterproof compound layer 4 and bottom self-adhesive film 5；
The surface layer waterproof compound layer is prepared by surface layer waterproof oil plant, in terms of its total amount, the group including following mass percentage
Point:
100# pitch 35wt%；
10# pitch 15wt%；
SIS 8wt%；
APP 1wt%；
Aluminium triphosphate and polyvinyl alcohol (1:1) 1wt%；
Alpha-olefine polymers APAO 2wt%；
Surface layer waterproof roll rubber powder (ibid) 10wt%；
Aromatic naphtha 10wt%；
Talcum powder 18wt%.
The bottom waterproof compound layer is prepared by bottom waterproof oil plant, in terms of its total amount, including following mass percentage
Component:
100# pitch 32wt%；
10# pitch 18wt%；
SBS 8wt %；
Polymethacrylates 2wt %；
C9 Petropols 5wt%；
SBR 5wt%；
Bottom waterproof roll rubber powder (ibid) 10wt%；
Aromatic naphtha 10wt%；
Talcum powder 10wt%.
The preparation method of high-temperature resistant self-adhesive waterproof roll, includes the following steps: described in the present embodiment
(1) prepared by surface layer waterproof oil plant:
It takes a selected amount of 100# pitch and 10# pitch to mix, is warming up to 160 DEG C, and the eliminating smell agent and 1/2 amount is added
The softening agent, stirs evenly；
A selected amount of described SIS, APP and high temperature resistant asphalt modifying agent is added, is warming up to 180 DEG C of stirrings to being completely dissolved；
A selected amount of the plasticizer is added, and is continuously heating to 190 DEG C, stirs evenly；
The softening agent and the filler material of remaining 1/2 amount is added, stirs evenly to get required surface layer waterproof oil plant, keeps
It is 160-170 DEG C of temperature, spare；
(2) prepared by bottom waterproof oil plant:
It takes a selected amount of 100# pitch and 10# pitch to mix, is warming up to 160 DEG C, and the softening agent of 2/3 amount is added,
It stirs evenly；
The a selected amount of SBS, tackifier and SBR is added, is warming up to 180 DEG C of stirrings to dissolution；
A selected amount of the plasticizer is added, and is continuously heating to 190 DEG C, stirs evenly；
The softening agent, C9 resin and the filler material of remaining 1/3 amount is added, stirs evenly to get required bottom dubbin
Material, 160-170 DEG C of temperature of holding are spare；
(3) take combined type copper tire base as the tire based material layer, and by bottom waterproof material oil, the bottom described in oil sump dip-coating
The dosage of layer waterproof material oil is advisable with that can submerge the polyester carcass, forms the bottom waterproof compound layer, control dipping shape
At the bottom waterproof compound layer with a thickness of 1.5-2mm, and on the bottom waterproof compound layer cover PET silicon oil membrane make
For the bottom self-adhesive film；
(4) in the other side of the tire based material layer, the surface layer waterproof oil plant is coated using spraying method, forms the surface layer
Waterproof compound layer, control the surface layer waterproof compound layer with a thickness of 1.5-2mm, and covered on the surface layer waterproof compound layer
Release film is as the surface layer isolation film；
(5) waterproof roll of formation is cooled and shaped and is packed to get.
Embodiment 4
High-temperature resistant self-adhesive waterproof roll described in the present embodiment successively includes surface layer isolation film 1, surface layer waterproof compound layer from top to bottom
2, tire based material layer 3, bottom waterproof compound layer 4 and bottom self-adhesive film 5；
The surface layer waterproof compound layer is prepared by surface layer waterproof oil plant, in terms of its total amount, the group including following mass percentage
Point:
100# pitch 35wt%；
10# pitch 15wt%；
SIS 5wt%；
APP 1wt%；
Aluminium triphosphate and polyvinyl alcohol 0.5wt%；
Alpha-olefine polymers APAO 2wt%；
Surface layer waterproof roll rubber powder 15wt%；
Aromatic naphtha 10wt%；
Talcum powder 16.5wt%.
The bottom waterproof compound layer is prepared by bottom waterproof oil plant, in terms of its total amount, including following mass percentage
Component:
100# pitch 32wt%；
10# pitch 18wt%；
SBS 5wt %；
Ethylene-propylene copolymer 5wt %；
C9 Petropols 3wt%；
SBR 5wt%；
Bottom waterproof roll rubber powder 13wt%；
Aromatic naphtha 12wt%；
Talcum powder 7wt%.
The preparation method of high-temperature resistant self-adhesive waterproof roll, includes the following steps: described in the present embodiment
(1) prepared by surface layer waterproof oil plant:
It takes a selected amount of 100# pitch and 10# pitch to mix, is warming up to 160 DEG C, and the eliminating smell agent and 1/2 amount is added
The softening agent, stirs evenly；
A selected amount of described SIS, APP and high temperature resistant asphalt modifying agent is added, is warming up to 180 DEG C of stirrings to being completely dissolved；
A selected amount of the plasticizer is added, and is continuously heating to 190 DEG C, stirs evenly；
The softening agent and the filler material of remaining 1/2 amount is added, stirs evenly to get required surface layer waterproof oil plant, keeps
It is 160-170 DEG C of temperature, spare；
(2) prepared by bottom waterproof oil plant:
It takes a selected amount of 100# pitch and 10# pitch to mix, is warming up to 160 DEG C, and the softening agent of 2/3 amount is added,
It stirs evenly；
The a selected amount of SBS, tackifier and SBR is added, is warming up to 180 DEG C of stirrings to dissolution；
A selected amount of the plasticizer is added, and is continuously heating to 190 DEG C, stirs evenly；
The softening agent, C9 resin and the filler material of remaining 1/3 amount is added, stirs evenly to get required bottom dubbin
Material, 160-170 DEG C of temperature of holding are spare；
(3) take combined type copper tire base as the tire based material layer, and by bottom waterproof material oil, the bottom described in oil sump dip-coating
The dosage of layer waterproof material oil is advisable with that can submerge the polyester carcass, forms the bottom waterproof compound layer, control dipping shape
At the bottom waterproof compound layer with a thickness of 1.5-2mm, and on the bottom waterproof compound layer cover PET silicon oil membrane make
For the bottom self-adhesive film；
(4) in the other side of the tire based material layer, the surface layer waterproof oil plant is coated using spraying method, forms the surface layer
Waterproof compound layer, control the surface layer waterproof compound layer with a thickness of 1.5-2mm, and covered on the surface layer waterproof compound layer
Release film is as the surface layer isolation film；
(5) waterproof roll of formation is cooled and shaped and is packed to get.
Through detecting, the high-temperature resistant self-adhesive waterproof roll prepared in the above embodiment of the present invention 1-4, elongation percentage
Average value can reach 108.5%, and mean intensity reaches 6.88MPa, and average elastic modulus reaches 78.29MPa, and maximum dynamics is reachable
To 1375.80N；Also, high-temperature resistant self-adhesive waterproof roll of the present invention, the high temperature resistance of end surfaces can reach 110- thereon
130 DEG C, low temperature resistance reaches -20~-30 DEG C, and the high temperature resistance of bottom face can also reach 90 DEG C, can effectively avoid because
It trickles caused by summer weather is hot phenomenon, and top surface cost is lower, reduces the cost of material.
Obviously, the above embodiments are merely examples for clarifying the description, and does not limit the embodiments.It is right
For those of ordinary skill in the art, can also make on the basis of the above description it is other it is various forms of variation or
It changes.There is no necessity and possibility to exhaust all the enbodiments.And it is extended from this it is obvious variation or
It changes still within the protection scope of the invention.
Claims (10)
1. a kind of composition for being used to prepare high-temperature resistant self-adhesive waterproof roll surface layer waterproof oil plant, which is characterized in that with described group
Close the total amount meter of object, the component including following parts by weight: 100# pitch 30-40wt%, 10# pitch 10-20wt%, SIS 2-
It is 8wt%, APP 0.1-2wt%, pitch eliminating smell agent 0.1-1wt%, high temperature resistant asphalt modifying agent 1-3wt%, plasticizer 10-20wt%, soft
Agent 5-15wt%, filler material 15-18wt%.
2. the composition according to claim 1 for being used to prepare high-temperature resistant self-adhesive waterproof roll surface layer waterproof oil plant, special
Sign is, in terms of the total amount of the composition, the component including following parts by weight: 100# pitch 35%, 10# pitch 15%, SIS
5%, APP 1%, pitch eliminating smell agent 0.5%, high temperature resistant asphalt modifying agent 2%, plasticizer 15%, softening agent 10%, filler material 16.5%.
3. the composition according to claim 1 or 2 for being used to prepare high-temperature resistant self-adhesive waterproof roll surface layer waterproof oil plant,
It is characterized in that:
The pitch eliminating smell agent is the mixture of eliminating smell agent aluminium triphosphate and polyvinyl alcohol；
The high temperature resistant asphalt modifying agent includes alpha-olefine polymers APAO；
The plasticizer includes surface layer waterproof roll rubber powder；
The softening agent includes aromatic naphtha；
The filler material includes talcum powder.
4. a kind of composition for being used to prepare high-temperature resistant self-adhesive waterproof roll bottom waterproof oil plant, which is characterized in that with described group
Close the total amount meter of object, the component including following parts by weight: 100# pitch 30-35wt%, 10# pitch 15-20wt%, SBS 2-8 wt
%, tackifier 2-8 wt %, C9 resin 1-5wt%, SBR 2-8wt%, plasticizer 10-16wt%, softening agent 10-15wt%, filler material
5-10wt%。
5. the composition according to claim 4 for being used to prepare high-temperature resistant self-adhesive waterproof roll bottom waterproof oil plant, special
Sign is, in terms of the total amount of the composition, the component including following parts by weight: 100# pitch 32%, 10# pitch 18%, SBS
5%, tackifier 5%, C9 resin 3%, SBR 5%, plasticizer 13%, softening agent 12%, filler material 7%.
6. the composition according to claim 4 or 5 for being used to prepare high-temperature resistant self-adhesive waterproof roll bottom waterproof oil plant,
It is characterized in that:
The tackifier include polymethacrylates or ethylene-propylene copolymer；
The C9 resin includes C9 Petropols；
The plasticizer includes bottom waterproof roll rubber powder；
The softening agent includes aromatic naphtha；
The filler material includes talcum powder.
7. a kind of high-temperature resistant self-adhesive waterproof roll, which is characterized in that successively anti-including surface layer isolation film (1), surface layer from top to bottom
The glue bed of material (2), tire based material layer (3), bottom waterproof compound layer (4) and bottom self-adhesive film (5)；
The surface layer waterproof compound layer (2) is used to prepare high-temperature resistant self-adhesive waterproof roll by claim 1-3 is described in any item
The composition of surface layer waterproof oil plant is prepared；
The bottom waterproof compound layer (4) is used to prepare high-temperature resistant self-adhesive waterproof roll by claim 4-6 is described in any item
The composition of bottom waterproof oil plant is prepared.
8. high-temperature resistant self-adhesive waterproof roll according to claim 7, which is characterized in that the surface layer waterproof compound layer (2)
With a thickness of 1.5-2mm, the bottom waterproof compound layer (4) with a thickness of 1.5-2mm.
9. high-temperature resistant self-adhesive waterproof roll according to claim 7 or 8, which is characterized in that the tire based material layer (3) is
Polyester carcass or combined type copper tire base.
10. a kind of method for preparing the described in any item high-temperature resistant self-adhesive waterproof rolls of claim 7-9, which is characterized in that packet
Include following steps:
(1) prepared by surface layer waterproof oil plant:
It takes a selected amount of 100# pitch and 10# pitch to mix, is warming up to 150-160 DEG C, and the pitch eliminating smell agent is added
And the part softening agent, it stirs evenly；
A selected amount of described SIS, APP and high temperature resistant asphalt modifying agent is added, is warming up to 170-180 DEG C of stirring to being completely dissolved；
A selected amount of the plasticizer is added, and is continuously heating to 190-200 DEG C, stirs evenly；
The softening agent and the filler material of surplus is added, stirs evenly to get required surface layer waterproof oil plant, keeps temperature
It is 160-170 DEG C, spare；
(2) prepared by bottom waterproof oil plant:
It takes a selected amount of 100# pitch and 10# pitch to mix, is warming up to 150-160 DEG C, and the part softening agent is added,
It stirs evenly；
The a selected amount of SBS, tackifier and SBR is added, is warming up to 170-180 DEG C of stirring to dissolution；
A selected amount of the plasticizer is added, and is continuously heating to 190-200 DEG C, stirs evenly；
The softening agent, C9 resin and the filler material of surplus is added, stirs evenly to get required bottom waterproof oil plant,
160-170 DEG C of temperature of holding, it is spare；
(3) take selected carcass as the tire based material layer, and oily by bottom waterproof material described in oil sump dip-coating, described in formation
Bottom waterproof compound layer, and the bottom self-adhesive film is covered on the bottom waterproof compound layer；
(4) in the other side of the tire based material layer, the surface layer waterproof oil plant is coated using spraying method, forms the surface layer
Waterproof compound layer, and the surface layer isolation film is covered on the surface layer waterproof compound layer；
(5) be cooled and shaped and pack to get.
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Application publication date: 20191022 |