CN101921545B - Asphalt waterproof paint for building and preparation method thereof - Google Patents
Asphalt waterproof paint for building and preparation method thereof Download PDFInfo
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- 239000010426 asphalt Substances 0.000 title claims abstract description 42
- 239000003973 paint Substances 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000007822 coupling agent Substances 0.000 claims abstract description 17
- 239000000945 filler Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 72
- 239000003795 chemical substances by application Substances 0.000 claims description 38
- 239000000203 mixture Substances 0.000 claims description 36
- 239000007788 liquid Substances 0.000 claims description 25
- 239000005060 rubber Substances 0.000 claims description 21
- 239000010425 asbestos Substances 0.000 claims description 20
- 239000011347 resin Substances 0.000 claims description 20
- 229920005989 resin Polymers 0.000 claims description 20
- 229910052895 riebeckite Inorganic materials 0.000 claims description 20
- 210000002268 wool Anatomy 0.000 claims description 20
- 239000010913 used oil Substances 0.000 claims description 17
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 16
- 239000000843 powder Substances 0.000 claims description 16
- -1 aluminic acid ester Chemical class 0.000 claims description 13
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 13
- 239000001488 sodium phosphate Substances 0.000 claims description 13
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical group [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 13
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 13
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 13
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical group O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 10
- 238000002844 melting Methods 0.000 claims description 9
- 239000004902 Softening Agent Substances 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 239000003292 glue Substances 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 4
- 230000008901 benefit Effects 0.000 abstract description 4
- 238000013461 design Methods 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 239000011295 pitch Substances 0.000 description 38
- 239000000463 material Substances 0.000 description 19
- 239000003921 oil Substances 0.000 description 17
- 238000005516 engineering process Methods 0.000 description 8
- 238000010276 construction Methods 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 238000004078 waterproofing Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 230000032683 aging Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
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- 230000001804 emulsifying effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000003566 sealing material Substances 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000003487 anti-permeability effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000010412 perfusion Effects 0.000 description 1
- 238000009428 plumbing Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
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- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
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Landscapes
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to an asphalt waterproof paint for a building and a preparation method thereof, belonging to the technical field of chemical industry. The asphalt waterproof paint for a building comprises the following raw materials according to parts by weight: 20-25 parts of plasticizer, 6-8 parts of modifier, 25-30 parts of asphalt, 20-30 parts of filler, 4-6 parts of tackifier, 0.2-0.3 parts of crosslink coupling agent, and 0.3-0.5 parts of dispersing agent. The invention has the advantages of reasonable compound design, good intensity, safety, environmental protection and stable product quality, and is capable of adapting the climatic conditions at high and low temperatures.
Description
Technical field
The present invention relates to a kind of asphalt waterproof paint for building and preparation method thereof, belong to chemical technology field.
Background technology
Architectural waterproof material refers to prevent the material of intrusion buildingss such as rainwater, underground water, plumbing, corrosive liquid and airborne moisture, steam.The position that buildings need carry out WATER REPELLENT mainly is roofing, metope, ground and vault, mainly through coating, sprawl, clog, perfusion, technology such as bonding construct.Domestic water-proof material development so far; Basically form that class is more complete, production and the fairly perfect industrial system of utilisation technology, kind comprises five big series products such as modified bituminous pitch coiled material, polymer membranes, waterproof paint, sealing material, patching materials and rigidity water-proofing material.
Pitch is used for waterproof and has very long history, but remains the important materials of buildings waterproof so far, outstanding features such as it has, and low in raw material cost is abundant, easy construction, water-proof function is strong, the waterproof cycle is long.As the principal mode of water-proof material web form and coating form are arranged with pitch.Wherein asphalt felt is to use material the most widely; Product comprises that mainly SBS, APP etc. make material modified polymer modified bituminous waterproof sheet material, and the tire base is main with polyester blank and glass fiber blank, but its use also has restriction; Comparatively suitable as only to large area region, like roof, ground etc.; Can only can not fill up groove, crackle etc. as surface waterproofing; Relatively poor to basic unit's cohesiveness, the whole regional water-proof function of run-down back influence occurs, can not comply with building displacement and distortion etc.The another kind of form of pitch is to use as coating, and main making method is emulsifying water bituminous composition and solvent-borne type bituminous composition.Wherein emulsifying water pitch is made loaded down with trivial detailsly, and disadvantage is owing to be water-based, and its film forming compactness is poor, thereby water-repellancy and stability to aging are all relatively poor; And solvent-borne type is owing to exist a large amount of deleterious organism, can not wait construction indoor.
In view of the shortcoming of two types of materials of above-mentioned pitch, a kind of novel asphalt waterproofing paint is proposed by the people, promptly with a kind of form of sealer pitch is processed water-proof material, generally is called non-curing bituminous composition.Non-curing bituminous composition is in the market mainly processed with modifying asphalt and non-volatile solvent, and it can be used as fills the sealing material, also can big area apply, and be the thickness attitude that can flow at normal temperatures, need not heating and use.It has excellent antiseepage leak resistance, adhesive property, and is easy to use, so very suitable in some occasion.But still there is shortcoming in it: intensity is too low, can trickle, have certain harmful evaporating into when temperature is high grades.Fusing point is than higher, narrow application range.
Summary of the invention
Technical problem to be solved by this invention provides that a kind of formulating of recipe is reasonable, intensity good, can adapt to the asphalt waterproof paint for building of the cryogenic weather condition of high temperature, safety and environmental protection, constant product quality.
Another technical problem to be solved by this invention provides that a kind of technological design is reasonable, production process is simple to operation, the preparation method of the asphalt waterproof paint for building of constant product quality, excellent performance.
It is this asphalt waterproof paint for building that the present invention solves the problems of the technologies described above the technical scheme that is adopted, and its raw material composition is:
Softening agent: 20-25 weight part, properties-correcting agent: 6-8 weight part, pitch: 25-30 weight part, filler: 20-30 weight part, tackifier: 4-6 weight part, crosslinked coupling agent: 0.2-0.3 weight part, dispersion agent: 0.3-0.5 weight part.
As preferably, softening agent of the present invention is third fractional oil and used oil, and the content of third fractional oil is 8%, and the content of used oil is 92%.
As preferably, properties-correcting agent of the present invention is SBS, rubber powder and PP, and the content of SBS is 30%, and the content of rubber powder is 60%, and the content of PP is 10%, and described rubber powder is 80 order tread reclaimed rubber powder.
As preferably, pitch of the present invention is 10# pitch and the 100# pitch mixture according to the 1:4 mixed.
As preferably, filler of the present invention is talcum powder and asbestos wool, and wherein talcous content is 80%, and the content of asbestos wool is 20%.
As preferably, tackifier of the present invention are Gum Rosin and terpine resin, and the content of Gum Rosin is 80%, and the content of terpine resin is 20%.
As preferably, crosslinked coupling agent of the present invention is maleic anhydride and aluminic acid ester, and the content of maleic anhydride is 45%, and the content of aluminic acid ester is 55%.
As preferably, dispersion agent of the present invention is a trisodium phosphate and increase dewaxing, and the content of trisodium phosphate is 33%, and the content that increases dewaxing is 67%.
Pitch uses as water-proof material, and what at first will solve is the drawback that pitch heat is dropped down cold shortness, improves the heat-resisting and cold-resistant ground performance of pitch.The pitch of different labels has certain difference, and 100# and two kinds of pitches of 10# are adopted in this invention, through experiment find both proportionings use to coating heat-resistingly resist cold, performance such as viscosity is favourable, also is beneficial to the allotment of other component.This kind asphalt waterproofing material modification composition mainly is ground rubber and SBS resin; Ground rubber is the rubber grain that is ground into after damaged tire reclaims; Comparatively cheap, pitch heat dropped down cold short to improve effect better, and bituminous aging resistance and physical strength are also had bigger improvement; 5% above SBS makes pitch have island structure, has strengthened the heat-resisting winter hardiness of pitch greatly, and gives pitch excellent intensity; A small amount of PP can increase the thermotolerance of modifying asphalt effectively.Secondly, must be comparatively convenient during bitumen construction.Because the modifying asphalt yield temperature wants more than 180 ℃, the fusion construction is cumbersome, thus with third fractional oil and used oil as softening agent, make it have lower yield temperature, convenient construction; Can make that bituminous composition intensity significantly reduces, not anti-extruding but too much increase third fractional oil, and thermotolerance is reduced.Adding modified rubber is contradiction with adding softening agent heat-resisting and cold-resistant to bituminous, must seek suitable proportioning, and bituminous composition (like 60 ℃ of STs) under weather high temperature is not trickled, and can it melt construction (as being heated to 120 ℃) easily again.Moreover for pitch is bondd with base material better, need to add tackifier, be to add rosin and terpine resin here, owing to both softening temperatures, price, viscosity difference, so need be used, this system can keep viscosity preferably under-10 ℃ of environment.Talcum powder and bitumen compatibility are good, and be beneficial to the pitch thermotolerance; Asbestos wool can strengthen the pitch network structure, increases.Maleic anhydride and aluminic acid ester can make pitch matrix and rubber, mineral filler better combine, thereby increase anti-permeability performance, and strengthen intensity and thermotolerance.The favourable fillers dispersed of trisodium phosphate ability, and wax more is prone to melt after making the asphalt system heating.
This system bituminous composition also has characteristics, and existing bigger intensity has good thixotropic creep effect again.Promptly creep property is preferably arranged, and under less external force effect, can keep intensity preferably again when big (being more than 50% of shearing resistance), do not produce obvious creep stressed.So this coating can well move with building, can discharge internal stress long-term when stressed, it is aging to slow down stress.In addition, this invention coating is stabbed at the figure layer to be split under the situation, can be well self-closing, when temperature is high, can the oneself bond again, and promptly have the ability of self-healing.
The SBS structure is star-like in the above material, the better network structure of favourable formation; Rubber powder is 80 order tread reclaimed rubber powder, in heating easy desulfurization and reacting with pitch during blend; The talcum powder particle diameter is bigger to the oil number influence, and fineness is 100 orders here, and meticulous mistake slightly all is unfavorable for asphalt performance; Asbestos wool length is 2mm, selects easy dispersive kind; The rosin softening temperature is 110 ℃ here, and the terpenes softening temperature is 150 ℃.
The present invention solves the problems of the technologies described above the preparation method of a kind of asphalt waterproof paint for building of technical scheme that is adopted, and its process step is:
A, pour softening agent into reaction kettle heating, and stirring at low speed, stirring velocity is 80 commentaries on classics/min, after 180 ℃, adds properties-correcting agent, increases stirring velocity to 200 commentaries on classics/min simultaneously.Fully stir that 40min is above all to be melted to properties-correcting agent;
B, adding 100# and 10# pitch stir 15min, to all melting;
C, adding talcum powder and asbestos wool reduce stirring velocity to 200 commentaries on classics/min, add trisodium phosphate again and fully stir 30min;
D, add Gum Rosin, terpine resin, increase dewaxing,, stir 15min, revolution is 200 commentaries on classics/min;
E, adding maleic anhydride, aluminic acid ester stir 30min, and revolution is 200 commentaries on classics/min, makes the black thick liquid, and this black thick liquid is about 2500cps at 120 ℃ of viscositys;
F, the black thick liquid is poured in the little iron flask that scribbles releasing agent, be certain elastic flexible glue after the room temperature cooling, peel off then, obtain asphalt waterproof paint for building.
The present invention has the following advantages and characteristics with existing compared with techniques: hot-melting type asphalt waterproofing paint of the present invention has kept the advantage of general non-curing asphalt waterproofing paint, and has particular performances.Be both to have had the heat-resisting classical advantages of modified asphalt material such as cold short performance, antiseepage leak resistance, ageing-resistant performance, low temperature bonding property are good, the one type of novel asphalt waterproof paint that has the specific function of outstanding creep properties and self-healing function again of dropping down.Over-all properties of the present invention is good, can under lower Heating temperature, make its fusing construction, can all can use excellent performance, the significant a kind of water-proof material of characteristics in the multiple structure of building.
Embodiment
Below in conjunction with embodiment the present invention is done further detailed description, following examples are to explanation of the present invention and the present invention is not limited to following examples.
Embodiment 1:
Present embodiment has been described a kind of preparation method of asphalt waterproof paint for building, and concrete process step is following:
At first, pour 22 kilograms third fractional oils and used oil mixture into the reaction kettle heating, wherein; The content of third fractional oil is 8%, and the content of used oil is 92%, the beginning stirring at low speed; Stirring velocity is 80 commentaries on classics/min; Add 6.5 kilograms of properties-correcting agent after 180 ℃, the content of SBS is 30% in the properties-correcting agent, the content of rubber powder is 60%, the content of PP is 10%, increases stirring velocity to 200 commentaries on classics/min simultaneously.Fully stir that 40min is above all to be melted to properties-correcting agent.
Then, add 27 kilograms of 100# and 10# bituminous mixture, 10# pitch and 100# pitch stir 15min according to the 1:4 mixed, to all melting.
Then, add the mixture of 26 kilograms of talcum powder and asbestos wool, talcous content is 80%, and the content of asbestos wool is 20%, reduces stirring velocity to 200 commentaries on classics/min, adds 0.12 kilogram of trisodium phosphate again and fully stirs 30min.
Then, add the mixture of 4 kilograms of Gum Rosins and terpine resin, the content of Gum Rosin is 80%, and the content of terpine resin is 20%, adds 0.23 kilogram and increases dewaxing, stirs 15min, and revolution is 200 commentaries on classics/min;
Then, add 0.2 kilogram of crosslinked coupling agent, contain 45% maleic anhydride, 55% aluminic acid ester in the crosslinked coupling agent, stir 30min, revolution is 200 commentaries on classics/min, makes the black thick liquid, and this black thick liquid is about 2500cps at 120 ℃ of viscositys;
At last, the black thick liquid is poured in the little iron flask that scribbles releasing agent, be certain elastic flexible glue after the room temperature cooling, peel off then, obtain asphalt waterproof paint for building.
Embodiment 2:
Present embodiment has been described a kind of preparation method of asphalt waterproof paint for building, and concrete process step is following:
At first, pour 20 kilograms third fractional oils and used oil mixture into the reaction kettle heating, wherein; The content of third fractional oil is 8%, and the content of used oil is 92%, the beginning stirring at low speed; Stirring velocity is 80 commentaries on classics/min; Add 7.5 kilograms of properties-correcting agent after 180 ℃, the content of SBS is 30% in the properties-correcting agent, the content of rubber powder is 60%, the content of PP is 10%, increases stirring velocity to 200 commentaries on classics/min simultaneously.Fully stir that 40min is above all to be melted to properties-correcting agent.
Then, add 30 kilograms of 100# and 10# bituminous mixture, 10# pitch and 100# pitch stir 15min according to the 1:4 mixed, to all melting.
Then, add the mixture of 20 kilograms of talcum powder and asbestos wool, talcous content is 80%, and the content of asbestos wool is 20%, reduces stirring velocity to 200 commentaries on classics/min, adds 0.15 kilogram of trisodium phosphate again and fully stirs 30min.
Then, add the mixture of 4.5 kilograms of Gum Rosins and terpine resin, the content of Gum Rosin is 80%, and the content of terpine resin is 20%, adds 0.3 kilogram and increases dewaxing, stirs 15min, and revolution is 200 commentaries on classics/min;
Then, add 0.3 kilogram of crosslinked coupling agent, contain 45% maleic anhydride, 55% aluminic acid ester in the crosslinked coupling agent, stir 30min, revolution is 200 commentaries on classics/min, makes the black thick liquid, and this black thick liquid is about 2500cps at 120 ℃ of viscositys;
At last, the black thick liquid is poured in the little iron flask that scribbles releasing agent, be certain elastic flexible glue after the room temperature cooling, peel off then, obtain asphalt waterproof paint for building.
Embodiment 3:
Present embodiment has been described a kind of preparation method of asphalt waterproof paint for building, and concrete process step is following:
At first, pour 21 kilograms third fractional oils and used oil mixture into the reaction kettle heating, wherein; The content of third fractional oil is 8%, and the content of used oil is 92%, the beginning stirring at low speed; Stirring velocity is 80 commentaries on classics/min; Add 7 kilograms of properties-correcting agent after 180 ℃, the content of SBS is 30% in the properties-correcting agent, the content of rubber powder is 60%, the content of PP is 10%, increases stirring velocity to 200 commentaries on classics/min simultaneously.Fully stir that 40min is above all to be melted to properties-correcting agent.
Then, add 25 kilograms of 100# and 10# bituminous mixture, 10# pitch and 100# pitch stir 15min according to the 1:4 mixed, to all melting.
Then, add the mixture of 24 kilograms of talcum powder and asbestos wool, talcous content is 80%, and the content of asbestos wool is 20%, reduces stirring velocity to 200 commentaries on classics/min, adds 0.17 kilogram of trisodium phosphate again and fully stirs 30min.
Then, add the mixture of 5 kilograms of Gum Rosins and terpine resin, the content of Gum Rosin is 80%, and the content of terpine resin is 20%, adds 0.33 kilogram and increases dewaxing, stirs 15min, and revolution is 200 commentaries on classics/min;
Then, add 0.25 kilogram of crosslinked coupling agent, contain 45% maleic anhydride, 55% aluminic acid ester in the crosslinked coupling agent, stir 30min, revolution is 200 commentaries on classics/min, makes the black thick liquid, and this black thick liquid is about 2500cps at 120 ℃ of viscositys;
At last, the black thick liquid is poured in the little iron flask that scribbles releasing agent, be certain elastic flexible glue after the room temperature cooling, peel off then, obtain asphalt waterproof paint for building.
Embodiment 4:
Present embodiment has been described a kind of preparation method of asphalt waterproof paint for building, and concrete process step is following:
At first, pour 25 kilograms third fractional oils and used oil mixture into the reaction kettle heating, wherein; The content of third fractional oil is 8%, and the content of used oil is 92%, the beginning stirring at low speed; Stirring velocity is 80 commentaries on classics/min; Add 8 kilograms of properties-correcting agent after 180 ℃, the content of SBS is 30% in the properties-correcting agent, the content of rubber powder is 60%, the content of PP is 10%, increases stirring velocity to 200 commentaries on classics/min simultaneously.Fully stir that 40min is above all to be melted to properties-correcting agent.
Then, add 28 kilograms of 100# and 10# bituminous mixture, 10# pitch and 100# pitch stir 15min according to the 1:4 mixed, to all melting.
Then, add the mixture of 27 kilograms of talcum powder and asbestos wool, talcous content is 80%, and the content of asbestos wool is 20%, reduces stirring velocity to 200 commentaries on classics/min, adds 0.13 kilogram of trisodium phosphate again and fully stirs 30min.
Then, add the mixture of 5.5 kilograms of Gum Rosins and terpine resin, the content of Gum Rosin is 80%, and the content of terpine resin is 20%, adds 0.25 kilogram and increases dewaxing, stirs 15min, and revolution is 200 commentaries on classics/min;
Then, add 0.28 kilogram of crosslinked coupling agent, contain 45% maleic anhydride, 55% aluminic acid ester in the crosslinked coupling agent, stir 30min, revolution is 200 commentaries on classics/min, makes the black thick liquid, and this black thick liquid is about 2500cps at 120 ℃ of viscositys;
At last, the black thick liquid is poured in the little iron flask that scribbles releasing agent, be certain elastic flexible glue after the room temperature cooling, peel off then, obtain asphalt waterproof paint for building.
Embodiment 5:
Present embodiment has been described a kind of preparation method of asphalt waterproof paint for building, and concrete process step is following:
At first, pour 24 kilograms third fractional oils and used oil mixture into the reaction kettle heating, wherein; The content of third fractional oil is 8%, and the content of used oil is 92%, the beginning stirring at low speed; Stirring velocity is 80 commentaries on classics/min; Add 6 kilograms of properties-correcting agent after 180 ℃, the content of SBS is 30% in the properties-correcting agent, the content of rubber powder is 60%, the content of PP is 10%, increases stirring velocity to 200 commentaries on classics/min simultaneously.Fully stir that 40min is above all to be melted to properties-correcting agent.
Then, add 26 kilograms of 100# and 10# bituminous mixture, 10# pitch and 100# pitch stir 15min according to the 1:4 mixed, to all melting.
Then, add the mixture of 30 kilograms of talcum powder and asbestos wool, talcous content is 80%, and the content of asbestos wool is 20%, reduces stirring velocity to 200 commentaries on classics/min, adds 0.1 kilogram of trisodium phosphate again and fully stirs 30min.
Then, add the mixture of 5.8 kilograms of Gum Rosins and terpine resin, the content of Gum Rosin is 80%, and the content of terpine resin is 20%, adds 0.2 kilogram and increases dewaxing, stirs 15min, and revolution is 200 commentaries on classics/min;
Then, add 0.22 kilogram of crosslinked coupling agent, contain 45% maleic anhydride, 55% aluminic acid ester in the crosslinked coupling agent, stir 30min, revolution is 200 commentaries on classics/min, makes the black thick liquid, and this black thick liquid is about 2500cps at 120 ℃ of viscositys;
At last, the black thick liquid is poured in the little iron flask that scribbles releasing agent, be certain elastic flexible glue after the room temperature cooling, peel off then, obtain asphalt waterproof paint for building.
Embodiment 6:
Present embodiment has been described a kind of preparation method of asphalt waterproof paint for building, and concrete process step is following:
At first, pour 23 kilograms third fractional oils and used oil mixture into the reaction kettle heating, wherein; The content of third fractional oil is 8%, and the content of used oil is 92%, the beginning stirring at low speed; Stirring velocity is 80 commentaries on classics/min; Add 6.9 kilograms of properties-correcting agent after 180 ℃, the content of SBS is 30% in the properties-correcting agent, the content of rubber powder is 60%, the content of PP is 10%, increases stirring velocity to 200 commentaries on classics/min simultaneously.Fully stir that 40min is above all to be melted to properties-correcting agent.
Then, add 29 kilograms of 100# and 10# bituminous mixture, 10# pitch and 100# pitch stir 15min according to the 1:4 mixed, to all melting.
Then, add the mixture of 22 kilograms of talcum powder and asbestos wool, talcous content is 80%, and the content of asbestos wool is 20%, reduces stirring velocity to 200 commentaries on classics/min, adds 0.14 kilogram of trisodium phosphate again and fully stirs 30min.
Then, add the mixture of 6 kilograms of Gum Rosins and terpine resin, the content of Gum Rosin is 80%, and the content of terpine resin is 20%, adds 0.28 kilogram and increases dewaxing, stirs 15min, and revolution is 200 commentaries on classics/min;
Then, add 0.24 kilogram of crosslinked coupling agent, contain 45% maleic anhydride, 55% aluminic acid ester in the crosslinked coupling agent, stir 30min, revolution is 200 commentaries on classics/min, makes the black thick liquid, and this black thick liquid is about 2500cps at 120 ℃ of viscositys;
At last, the black thick liquid is poured in the little iron flask that scribbles releasing agent, be certain elastic flexible glue after the room temperature cooling, peel off then, obtain asphalt waterproof paint for building.
In addition, need to prove, the specific embodiment described in this specification sheets, its prescription, title that technology is named etc. can be different.Allly conceive equivalence or the simple change that described structure, characteristic and principle are done, include in the protection domain of patent of the present invention according to patent of the present invention.Person of ordinary skill in the field of the present invention can make various modifications or replenishes or adopt similar mode to substitute described specific embodiment; Only otherwise depart from structure of the present invention or surmount the defined scope of these claims, all should belong to protection scope of the present invention.
Though the present invention with embodiment openly as above; But it is not in order to limit protection scope of the present invention; Any technician who is familiar with this technology, change and the retouching in not breaking away from design of the present invention and scope, done all should belong to protection scope of the present invention.
Claims (4)
1. asphalt waterproof paint for building, its raw material are formed:
Softening agent: 20-25 weight part, properties-correcting agent: 6-8 weight part, pitch: 25-30 weight part, filler: 20-30 weight part, tackifier: 4-6 weight part, crosslinked coupling agent: 0.2-0.3 weight part, dispersion agent: 0.3-0.5 weight part;
Described softening agent is third fractional oil and used oil, and the content of third fractional oil is 8%, and the content of used oil is 92%; Described properties-correcting agent is SBS, rubber powder and PP, and the content of SBS is 30%, and the content of rubber powder is 60%, and the content of PP is 10%; Pitch is 10# pitch and the 100# pitch mixture according to the 1:4 mixed; Described tackifier are Gum Rosin and terpine resin, and the content of Gum Rosin is 80%, and the content of terpine resin is 20%; Described crosslinked coupling agent is maleic anhydride and aluminic acid ester, and the content of maleic anhydride is 45%, and the content of aluminic acid ester is 55%; Described dispersion agent is a trisodium phosphate and increase dewaxing, and the content of trisodium phosphate is 33%, and the content that increases dewaxing is 67%.
2. asphalt waterproof paint for building according to claim 1 is characterized in that: described filler is talcum powder and asbestos wool, and wherein talcous content is 80%, and the content of asbestos wool is 20%.
3. asphalt waterproof paint for building according to claim 1 is characterized in that: described rubber powder is 80 order tread reclaimed rubber powder.
4. according to the preparation method of any described asphalt waterproof paint for building in the claim 1,2 or 3, its process step is:
A, pour softening agent into reaction kettle heating, and stirring at low speed, stirring velocity is 80 commentariess on classics/min, after 180 ℃, adds properties-correcting agent, increases stirring velocity to 200 commentaries on classics/min simultaneously, fully stirs more than the 40min to properties-correcting agent all to melt;
B, adding 100# and 10# pitch stir 15min, to all melting;
C, adding filler talcum powder and asbestos wool reduce stirring velocity to 200 commentaries on classics/min, add trisodium phosphate again and fully stir 30min;
D, add Gum Rosin, terpine resin, increase dewaxing, stir 15min, revolution is 200 commentaries on classics/min;
E, adding maleic anhydride, aluminic acid ester stir 30min, and revolution is 200 commentaries on classics/min, makes the black thick liquid, and this black thick liquid is 2500cps at 120 ℃ of viscositys;
F, the black thick liquid is poured in the little iron flask that scribbles releasing agent, be certain elastic flexible glue after the room temperature cooling, peel off then, obtain asphalt waterproof paint for building.
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| CN102329561B (en) * | 2011-07-01 | 2012-12-26 | 湘潭宏远工程材料科技有限公司 | Waterproof coating for roads and bridges and production process thereof |
| CN102408829A (en) * | 2011-10-27 | 2012-04-11 | 北京东方雨虹防水技术股份有限公司 | Hot melt type modified asphalt waterproof paint and preparation method thereof |
| CN102399493A (en) * | 2011-10-27 | 2012-04-04 | 北京东方雨虹防水技术股份有限公司 | Creep deformation type hot melt rubber asphalt waterproof paint |
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| CN103937407B (en) * | 2013-01-22 | 2016-06-15 | 张秀君 | Uncured rubber asphalt waterproof coating |
| CN103275619B (en) * | 2013-06-18 | 2015-09-30 | 邵昌元 | A kind of styrene butadiene rubber modified asphalt waterproof paint for building |
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| CN103756565A (en) * | 2014-01-25 | 2014-04-30 | 王勇 | Non-curing asphalt rubber waterproof coating film and processing technology thereof |
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| CN106634602A (en) * | 2016-08-04 | 2017-05-10 | 中国人民武装警察部队后勤学院 | Non-cured rubber asphalt waterproof paint and preparation method thereof |
| CN107779098A (en) * | 2017-11-08 | 2018-03-09 | 吉林省豫王建能实业股份有限公司 | A kind of uncured Rubber Modified Asphalt Waterproof Coating of normal temperature and preparation method thereof |
| CN109627798A (en) * | 2018-12-29 | 2019-04-16 | 东莞东交沥青有限公司 | A kind of enhancing blending type butadiene-styrene rubber modified emulsifying asphalt and preparation method thereof |
| CN115772368A (en) * | 2022-11-29 | 2023-03-10 | 北京中铁科新材料技术有限公司 | Hot-bonding modified asphalt waterproof coating and preparation method and application thereof |
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| US4818367A (en) * | 1986-04-14 | 1989-04-04 | J. H. Diamond Company | Asphalt, copolymer and elastomer composition |
| CN101113297A (en) * | 2006-07-28 | 2008-01-30 | 中宏（天津）实业有限公司 | Waterproofing paint using asphalt base-material for construction about zero degree centigrade |
| CN100999893A (en) * | 2006-12-31 | 2007-07-18 | 河南百和国际公路科技有限公司 | Anti-splitting paster and preparation method thereof |
| CN101074345A (en) * | 2007-06-22 | 2007-11-21 | 郑州大学 | Color SBS modified waterproof asphalt material |
| CN101597944B (en) * | 2009-07-07 | 2010-12-08 | 北京科顺建筑材料有限公司 | Self-adhesive waterproof tile block for building |
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Denomination of invention: Asphalt waterproof paint for building and preparation method thereof Effective date of registration: 20170728 Granted publication date: 20120425 Pledgee: Bank of Beijing, Limited by Share Ltd, Hangzhou branch Pledgor: Hangzhou ZFC New Materials Technology Co., Ltd. Registration number: 2017330000075 |
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Effective date of registration: 20191113 Address after: No.30, Ninghong Road, Tianning Town, Jiashan County, Jiaxing City, Zhejiang Province Patentee after: Jiaxing Bohao Home Textile Co., Ltd Address before: Hangzhou City, Zhejiang Province, Gongshu District Cambridge 310000 Zhenkang No. 22 Zheng Lu Patentee before: Hangzhou ZFC New Materials Technology Co., Ltd. |
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