CN107474793A - Adhesive waterproof coil cementitious matter, its preparation method and waterproof roll prepared therefrom - Google Patents

Adhesive waterproof coil cementitious matter, its preparation method and waterproof roll prepared therefrom Download PDF

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Publication number
CN107474793A
CN107474793A CN201610407758.6A CN201610407758A CN107474793A CN 107474793 A CN107474793 A CN 107474793A CN 201610407758 A CN201610407758 A CN 201610407758A CN 107474793 A CN107474793 A CN 107474793A
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parts
waterproof
adhesive waterproof
coil
resin
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CN107474793B (en
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贾丽凤
高淑美
马鹏程
许金山
刘爱华
毛冬梅
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China Petroleum and Chemical Corp
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China Petroleum and Chemical Corp
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J195/00Adhesives based on bituminous materials, e.g. asphalt, tar, pitch
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/40Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/408Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2495/00Presence of bitume

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention belongs to construction waterproofing engineering technical field, and in particular to a kind of adhesive waterproof coil cementitious matter, its preparation method and waterproof roll prepared therefrom.Adhesive waterproof coil cementitious matter is prepared from the following raw materials in parts by weight:I 46 55 parts of type waterproof roll pitch, 69 parts of SBS, 6 15 parts of shoddy, 8 12 parts of aromatic naphtha, 5 10 parts of tackifying resin, 49 parts of vinyl bis-stearamides, 10 25 parts of nano-calcium carbonate.The present invention solve it is traditional with SBR butadiene-styrene rubber rubber powders prepare waterproof roll sizing material occur easy to knot groups, easily block pipeline problem;Processing temperature reduces, and substantially reduces the production time of adhesive waterproof coil, reduces production cost.The present invention also provides a kind of waterproof roll prepared therefrom, and water resistance is good, and tensile strength is high, good extending performance, has excellent low-temperature tenderness and heat resistance.

Description

Adhesive waterproof coil cementitious matter, its preparation method and waterproof roll prepared therefrom
Technical field
The invention belongs to construction waterproofing engineering technical field, and in particular to a kind of adhesive waterproof coil cementitious matter, its preparation method and Waterproof roll prepared therefrom.
Background technology
With expanding economy and the progress in epoch, the requirement more and more higher to construction material, original construction material can not expire The demand of sufficient era development.Many buildings are all to reduce service life because of the erosion of water.As people make to building With the requirement more and more higher of the time limit, requirement of the people to waterproof material quality is increasingly paid attention to.Domestic elastomer (SBS) is modified at present Asphalt water-proof coiled material is still main product, especially exposed in roofing in use, because its superior resistance to elevated temperatures is other materials Material is difficult to what is replaced, however, elastomer (SBS) modified asphalt waterproof coiled material is applying man-hour requirement progress hot melt application, is dried in blowtorch When roasting there is great disaster hidden-trouble in naked light, and the burning of surface PE films and partially modified asphalt size are due to adding in baking process Thermal decomposition can also produce some bioxin, hydrocarbons etc., and environment is caused seriously to pollute.
Based on above mentioned problem, researcher have developed the different self-adhesive waterproof roll material of numerous characteristics.Self-adhesive coiled material is that one kind can Normal temperature is constructed, it is not necessary to a kind of waterproof material of hot melt application, is now subjected to the favor in market, its rate of rise exceeds well over Elastomer (SBS) modified asphalt waterproof coiled material.CN200610127174.X and CN200610200760.2 is adhesive waterproof coil, But coiled material mainly includes waterproof substrate and self-adhesive layer, and self-adhesive layer is additionally arranged equivalent on the basis of traditional coiled material.Combined type self-adhesion Property waterproof roll although solve the problems, such as construction it is difficult, but the compatibility of layer and interlayer, the croop property of waterproof substrate be still limit An important factor for making its performance.By contrast, tack waterproof material is directly seemed coated on waterproof roll is made on tire base Advantageously.A kind of Chinese invention patent " low-temperature resistant self-adhesive rubber asphalt waterproofing coiled material " of Application No. 200710120809.8 is open It is a kind of by asphalt, subtract third fractional oil, thermoplastic styrene butadiene rubber, powder styrene butadiene rubber, coumarone indene resin, Petropols, The waterproof volume that terpene resin, small-molecular-weight polyisobutene, ultra-violet absorber, antioxidant, bitumen layer made of calcium carbonate make Material.The waterproof roll is prepared using SBR butadiene-styrene rubber rubber powder, and the waterproof roll sizing material has easy to knot groups, easily blocks the difficulty of pipeline Topic, and there is the shortcomings of non-refractory for waterproof roll.
Because present extreme weather protrudes, the performance of existing waterproof roll has been unable to meet demand, therefore improves adhesive waterproof coil High temperature performance has become the technical problem of urgent need to resolve.
The content of the invention
In view of the shortcomings of the prior art, it is an object of the invention to provide a kind of adhesive waterproof coil cementitious matter, solves traditional use SBR butadiene-styrene rubber rubber powders prepare the easy to knot groups of waterproof roll sizing material appearance, easily block pipeline problem;The present invention also provides its preparation Method and waterproof roll prepared therefrom.
Adhesive waterproof coil cementitious matter of the present invention, is prepared from the following raw materials in parts by weight:
Wherein:
I type waterproof roll pitch is I type waterproof roll special asphalt, is this area commercially available prod.
Tackifying resin includes coumarone indene resin, terpene resin and the resin of carbon nine;Preferably, tackifying resin is by following parts by weight Raw material forms:Coumarone indene resin 10-30 parts, terpene resin 10-30 parts and the resin 10-30 parts of carbon nine.
The preparation method of adhesive waterproof coil cementitious matter of the present invention, first I type waterproof roll asphalt heating is heated, then Aromatic naphtha and vinyl bis-stearamides are added, is cooled after stirring, is added SBS and heated up, stirred, add increasing Viscosity resin and shoddy are stirred, and are eventually adding nano-calcium carbonate stirring, are produced product.
As a kind of perferred technical scheme, the preparation method of adhesive waterproof coil cementitious matter of the present invention, first prevents I type Water coiled material asphalt heating is to 190~200 DEG C, and then addition aromatic naphtha and vinyl bis-stearamides are cooled to after stirring 180~190 DEG C, add SBS and be warming up to 190~200 DEG C, stir 1.5h, add tackifying resin and shoddy continues at this At a temperature of stir 0.5h, be eventually adding nano-calcium carbonate stirring 0.5h, produce product.
The waterproof roll prepared by adhesive waterproof coil cementitious matter of the present invention, by adhesive waterproof coil glue of the present invention Ramming material uniform fold on polyester blank, overlay film cooling.
The waterproof roll prepared by adhesive waterproof coil cementitious matter of the present invention, including the upper protection set gradually from top to bottom Film, self-adhesion waterproof compound layer, polyester blank, the self-adhesion by adhesive waterproof coil cementitious matter being made up of adhesive waterproof coil cementitious matter Waterproof compound layer and lower diaphragm.Upper protective film can be antiseize silicone oil barrier film;Lower diaphragm can be polyethylene film.
In summary, the present invention has advantages below:
(1) present invention uses shoddy, not only waste and old resource is fully utilized, greatly reduces production cost, and The dimensional stability of waterproof roll can also be improved.Solve it is traditional with SBR butadiene-styrene rubber rubber powders prepare waterproof roll sizing material occur Easy to knot groups, easily block pipeline problem.
(2) it is good present invention adds EBS, EBS and SBS intermiscibility, the glass transition temperature of system can be reduced, makes to add Work temperature reduces, and substantially reduces the production time of adhesive waterproof coil, reduces production cost;
(3) a kind of excellent self-adhesion of high temperature performance that is high the invention provides intensity and being not required to smear basal plane cement or base oil is prevented The preparation method of water coiled material sizing material and waterproof roll.
(4) adhesive waterproof coil cementitious matter of the present invention and waterproof roll cost are low, are simple to manufacture, and water resistance is good, draw Intensity height is stretched, good extending performance, there is excellent low-temperature tenderness and heat resistance.Can be suitably used for industry and civil building roof covering, The waterproof, seepage control of the engineering such as wall, kitchen and toilet, basement, swimming pool and bridge, subway, reservoir, it is also applied for metal appearance Device and pipeline corrosion protection protection.Engineering waterproofing especially suitable for that should not employ naked light is constructed, and is also applied for moisture substrate construction.
Embodiment
With reference to embodiment, the present invention will be further described.
Embodiment 1
A kind of excellent modified asphalt waterproof coiled material of high temperature performance, including upper protective film, the upper self-adhesion set gradually from top to bottom The cementing bed of material of waterproof roll, tire basic unit, the cementing bed of material of lower adhesive waterproof coil and lower diaphragm.
The preparation method of the upper cementing bed of material of adhesive waterproof coil and the lower cementing bed of material of adhesive waterproof coil is as follows:First 46 part of I type is prevented Water coiled material asphalt heating adds 8 parts of aromatic naphtha and 4 parts of EBS and stirred and be cooled to 180~190 DEG C to 190~200 DEG C, then Add 6 parts of SBS and be warming up to 190~200 DEG C, control temperature, stir 1.5h, adding 5 parts of tackifying resins, (coumarone indene resin is 15 parts, 15 parts of terpene resin, the resin of carbon nine is 15 parts) and 6 parts of shoddies continue to stir 0.5h at such a temperature, 10 parts of addition is received Rice calcium carbonate stirring 0.5h, produces product.
Performance test is carried out to modified asphalt waterproof coiled material manufactured in the present embodiment, test result is shown in Table 1.
Embodiment 2
A kind of excellent modified asphalt waterproof coiled material of high temperature performance, including upper protective film, the upper self-adhesion set gradually from top to bottom The cementing bed of material of waterproof roll, tire basic unit, the cementing bed of material of lower adhesive waterproof coil and lower diaphragm.
The preparation method of the upper cementing bed of material of adhesive waterproof coil and the lower cementing bed of material of adhesive waterproof coil is as follows:First 46 part of I type is prevented Water coiled material asphalt heating adds 12 parts of aromatic naphtha and 8 parts of EBS stirs and are cooled to 180~190 DEG C to 190~200 DEG C, Add 8 parts of SBS and be warming up to 190~200 DEG C, control temperature, stir 1.5h, add 9 parts of tackifying resin (coumarone indene resins For 15 parts, 15 parts of terpene resin, the resin of carbon nine is 15 parts) and 6 parts of shoddies continue to stir 0.5h at such a temperature, addition 17.5 Part nano-calcium carbonate stirring 0.5h, produces product.
Performance test is carried out to modified asphalt waterproof coiled material manufactured in the present embodiment, test result is shown in Table 1.
Embodiment 3
A kind of excellent modified asphalt waterproof coiled material of high temperature performance, including upper protective film, the upper self-adhesion set gradually from top to bottom The cementing bed of material of waterproof roll, tire basic unit, the cementing bed of material of lower adhesive waterproof coil and lower diaphragm.
The preparation method of the upper cementing bed of material of adhesive waterproof coil and the lower cementing bed of material of adhesive waterproof coil is as follows:First by 50.5 part of I type Waterproof roll asphalt heating to 190~200 DEG C, add 10 parts of aromatic naphtha and 6.5 parts of EBS stir be cooled to 180~ 190 DEG C, add 7.5 parts of SBS and be warming up to 190~200 DEG C, control temperature, stir 1.5h, it is (ancient to add 7.5 parts of tackifying resins The grand resin of horse is 15 parts, 15 parts of terpene resin, and the resin of carbon nine is 15 parts) and the continuation of 10.5 parts of shoddies stir 0.5h at such a temperature, 17.5 parts of nano-calcium carbonate stirring 0.5h are added, produce product.
Performance test is carried out to modified asphalt waterproof coiled material manufactured in the present embodiment, test result is shown in Table 1.
Embodiment 4
A kind of excellent modified asphalt waterproof coiled material of high temperature performance, including upper protective film, the upper self-adhesion set gradually from top to bottom The cementing bed of material of waterproof roll, tire basic unit, the cementing bed of material of lower adhesive waterproof coil and lower diaphragm.
The preparation method of the upper cementing bed of material of adhesive waterproof coil and the lower cementing bed of material of adhesive waterproof coil is as follows:First by 50.5 part of I type Waterproof roll asphalt heating adds 9 parts of aromatic naphtha and 6.5 parts of EBS stirs and are cooled to 180~190 DEG C to 190~200 DEG C, Add 7 parts of SBS and be warming up to 190~200 DEG C, control temperature, stir 1.5h, add 6 parts of tackifying resin (coumarone indene resins For 15 parts, 15 parts of terpene resin, the resin of carbon nine is 15 parts) and 12 parts of shoddies continue to stir 0.5h at such a temperature, addition 15 Part nano-calcium carbonate stirring 0.5h, produces product.
Performance test is carried out to modified asphalt waterproof coiled material manufactured in the present embodiment, test result is shown in Table 1.
Embodiment 5
A kind of excellent modified asphalt waterproof coiled material of high temperature performance, including upper protective film, the upper self-adhesion set gradually from top to bottom The cementing bed of material of waterproof roll, tire basic unit, the cementing bed of material of lower adhesive waterproof coil and lower diaphragm.
The preparation method of the upper cementing bed of material of adhesive waterproof coil and the lower cementing bed of material of adhesive waterproof coil is as follows:First 52 part of I type is prevented Water coiled material asphalt heating adds 11.5 parts of aromatic naphtha and 8 parts of EBS stirs and are cooled to 180~190 DEG C to 190~200 DEG C, Add 8.5 parts of SBS and be warming up to 190~200 DEG C, control temperature, stir 1.5h, add 9 parts of tackifying resin (coumarone trees Fat is 15 parts, 15 parts of terpene resin, and the resin of carbon nine is 15 parts) and 13 parts of shoddies continue to stir 0.5h at such a temperature, addition 20 parts of nano-calcium carbonates stir 0.5h, produce product.
Performance test is carried out to modified asphalt waterproof coiled material manufactured in the present embodiment, test result is shown in Table 1.
Embodiment 6
A kind of excellent modified asphalt waterproof coiled material of high temperature performance, including upper protective film, the upper self-adhesion set gradually from top to bottom The cementing bed of material of waterproof roll, tire basic unit, the cementing bed of material of lower adhesive waterproof coil and lower diaphragm.
The preparation method of the upper cementing bed of material of adhesive waterproof coil and the lower cementing bed of material of adhesive waterproof coil is as follows:First 55 part of I type is prevented Water coiled material asphalt heating adds 12 parts of aromatic naphtha and 9 parts of EBS stirs and are cooled to 180~190 DEG C to 190~200 DEG C, Add 9 parts of SBS and be warming up to 190~200 DEG C, control temperature, stir 1.5h, add 10 parts of tackifying resin (coumarone trees Fat is 15 parts, 15 parts of terpene resin, and the resin of carbon nine is 15 parts) and 15 parts of shoddies continue to stir 0.5h at such a temperature, addition 25 parts of nano-calcium carbonates stir 0.5h, produce product.
Performance test is carried out to modified asphalt waterproof coiled material manufactured in the present embodiment, test result is shown in Table 1.
Comparative example 1
A kind of excellent modified asphalt waterproof coiled material of high temperature performance, including upper protective film, the upper self-adhesion set gradually from top to bottom The cementing bed of material of waterproof roll, tire basic unit, the cementing bed of material of lower adhesive waterproof coil and lower diaphragm.
The preparation method of the upper cementing bed of material of adhesive waterproof coil and the lower cementing bed of material of adhesive waterproof coil is as follows:First 46 part of I type is prevented For water coiled material asphalt heating to 190~200 DEG C, 8 parts of aromatic naphtha of addition, which stir, is cooled to 180~190 DEG C, adds 6 parts SBS is warming up to 190~200 DEG C, controls temperature, stirs 1.5h, add 5 parts of tackifying resins (coumarone indene resin is 15 parts, 15 parts of terpene resin, the resin of carbon nine are 15 parts) and 6 parts of shoddies continue to stir 0.5h at such a temperature, 10 parts of nano-calcium carbonates of addition Calcium stirs 0.5h, produces product.
Performance test is carried out to modified asphalt waterproof coiled material prepared by this comparative example, test result is shown in Table 1.
The performance test results for the product that the embodiment 1-6 of table 1 and comparative example 1 are prepared
As can be seen from Table 1:The waterproof roll water resistance prepared using the present invention is good, and tensile strength is high, good extending performance, With excellent low-temperature tenderness and heat resistance.Thus method can solve the easy to knot groups using the appearance of SBR butadiene-styrene rubber rubber powder, block up The shortcomings that filling in pipeline.

Claims (6)

  1. A kind of 1. adhesive waterproof coil cementitious matter, it is characterised in that:It is prepared from the following raw materials in parts by weight:
  2. 2. adhesive waterproof coil cementitious matter according to claim 1, it is characterised in that:Tackifying resin include coumarone indene resin, Terpene resin and the resin of carbon nine.
  3. 3. adhesive waterproof coil cementitious matter according to claim 2, it is characterised in that:Tackifying resin is by following parts by weight Raw material composition:Coumarone indene resin 10-30 parts, terpene resin 10-30 parts and the resin 10-30 parts of carbon nine.
  4. A kind of 4. preparation method of any described adhesive waterproof coil cementitious matters of claim 1-3, it is characterised in that:First by I Type waterproof roll asphalt heating heats, and then adds aromatic naphtha and vinyl bis-stearamides, cools after stirring, add SBS is heated up, stirred, and adds tackifying resin and shoddy is stirred, and is eventually adding nano-calcium carbonate stirring, is produced Product.
  5. 5. the preparation method of adhesive waterproof coil cementitious matter according to claim 4, it is characterised in that:First by I type waterproof Coiled material asphalt heating to 190~200 DEG C, then add after aromatic naphtha and vinyl bis-stearamides stir and be cooled to 180~ 190 DEG C, add SBS and be warming up to 190~200 DEG C, stir 1.5h, add tackifying resin and shoddy continues in the temperature Lower stirring 0.5h, nano-calcium carbonate stirring 0.5h is eventually adding, produces product.
  6. A kind of 6. waterproof roll prepared by any described adhesive waterproof coil cementitious matters of claim 1-3, it is characterised in that: Including the upper protective film set gradually from top to bottom, the self-adhesion waterproof compound layer being made up of adhesive waterproof coil cementitious matter, polyester blank, Self-adhesion waterproof compound layer and lower diaphragm by adhesive waterproof coil cementitious matter.
CN201610407758.6A 2016-06-07 2016-06-07 Self-adhesive waterproof roll cementing material, preparation method thereof and waterproof roll prepared from self-adhesive waterproof roll cementing material Active CN107474793B (en)

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Cited By (7)

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CN109054644A (en) * 2018-06-27 2018-12-21 安徽省万帮新型建材科技有限公司 A kind of rubber powder-elastomer composite modified asphalt waterproof coating material preparation method for adding nanometer calcium carbonate
CN110359643A (en) * 2018-03-26 2019-10-22 郑佰生 A kind of high-temperature resistant self-adhesive waterproof roll and preparation method thereof
CN112646547A (en) * 2019-10-11 2021-04-13 中国石油化工股份有限公司 Self-cleaning noise-reducing self-adhesive waterproof coiled material cementing material and preparation method thereof
CN112980362A (en) * 2021-03-02 2021-06-18 江苏凯伦建材股份有限公司 Preparation method of self-adhesive waterproof material
CN113278382A (en) * 2021-05-21 2021-08-20 湖北九阳防水材料科技有限公司 Polymer film-based self-adhesive coiled material and preparation method thereof
CN113858740A (en) * 2020-06-30 2021-12-31 中国石油化工股份有限公司 Modified asphalt sizing material and low heat accumulation type waterproof coiled material prepared from same
CN115305051A (en) * 2021-05-08 2022-11-08 韩爽 Novel chemical material with high melting point and corrosion resistance

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CN103044931A (en) * 2011-10-17 2013-04-17 中国石油化工股份有限公司 Caulking filling material easy for construction and preparation method thereof
CN103361025A (en) * 2013-07-19 2013-10-23 北京东方雨虹防水技术股份有限公司 Self-adhesive waterproof coiled material having high initial stickiness and preparation method thereof
CN105273687A (en) * 2015-11-25 2016-01-27 广东台实实业有限公司 Self-adhered waterproof rubber compound, self-adhered waterproof roll and preparation method

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Publication number Priority date Publication date Assignee Title
CN103044931A (en) * 2011-10-17 2013-04-17 中国石油化工股份有限公司 Caulking filling material easy for construction and preparation method thereof
CN103361025A (en) * 2013-07-19 2013-10-23 北京东方雨虹防水技术股份有限公司 Self-adhesive waterproof coiled material having high initial stickiness and preparation method thereof
CN105273687A (en) * 2015-11-25 2016-01-27 广东台实实业有限公司 Self-adhered waterproof rubber compound, self-adhered waterproof roll and preparation method

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110359643A (en) * 2018-03-26 2019-10-22 郑佰生 A kind of high-temperature resistant self-adhesive waterproof roll and preparation method thereof
CN109054644A (en) * 2018-06-27 2018-12-21 安徽省万帮新型建材科技有限公司 A kind of rubber powder-elastomer composite modified asphalt waterproof coating material preparation method for adding nanometer calcium carbonate
CN112646547A (en) * 2019-10-11 2021-04-13 中国石油化工股份有限公司 Self-cleaning noise-reducing self-adhesive waterproof coiled material cementing material and preparation method thereof
CN112646547B (en) * 2019-10-11 2022-08-12 中国石油化工股份有限公司 Self-cleaning noise-reducing self-adhesive waterproof coiled material cementing material and preparation method thereof
CN113858740A (en) * 2020-06-30 2021-12-31 中国石油化工股份有限公司 Modified asphalt sizing material and low heat accumulation type waterproof coiled material prepared from same
CN112980362A (en) * 2021-03-02 2021-06-18 江苏凯伦建材股份有限公司 Preparation method of self-adhesive waterproof material
CN115305051A (en) * 2021-05-08 2022-11-08 韩爽 Novel chemical material with high melting point and corrosion resistance
CN113278382A (en) * 2021-05-21 2021-08-20 湖北九阳防水材料科技有限公司 Polymer film-based self-adhesive coiled material and preparation method thereof

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