CN108610756A - A kind of hyalomitome response type Self-adhesive waterproof material - Google Patents

A kind of hyalomitome response type Self-adhesive waterproof material Download PDF

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Publication number
CN108610756A
CN108610756A CN201710031985.8A CN201710031985A CN108610756A CN 108610756 A CN108610756 A CN 108610756A CN 201710031985 A CN201710031985 A CN 201710031985A CN 108610756 A CN108610756 A CN 108610756A
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CN
China
Prior art keywords
hyalomitome
response type
type self
waterproof material
adhesive waterproof
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710031985.8A
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Chinese (zh)
Inventor
吴冬
周章华
王敏
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Guizhou Maintenance Master Technology Co Ltd
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Guizhou Maintenance Master Technology Co Ltd
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Priority to CN201710031985.8A priority Critical patent/CN108610756A/en
Publication of CN108610756A publication Critical patent/CN108610756A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D109/00Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C09D109/06Copolymers with styrene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D145/00Coating compositions based on homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic system; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D153/00Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D153/02Vinyl aromatic monomers and conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D157/00Coating compositions based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D157/02Copolymers of mineral oil hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/10Transparent films; Clear coatings; Transparent materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of hyalomitome response type Self-adhesive waterproof material, raw material includes by weight percentage:The extremely strong liquid resin of White softening oil, hot melt adhesive grade elastomer, styrene styrene block copolymer, tackified rubber, rubber latex, ultraviolet screener, penetrating power, tackifying resin, interfacial agents.In the present invention by rationally controlling White softening oil, hot melt adhesive grade elastomer, styrene styrene block copolymer, tackified rubber content can significantly increase the mechanical strength of product;Additionally by the extremely strong liquid resin of addition rubber latex, ultraviolet screener, penetrating power, tackifying resin and its content is controlled, the high mechanical strength of coating, excellent anti-corrosion performance can be increased.

Description

A kind of hyalomitome response type Self-adhesive waterproof material
Technical field
The present invention relates to technical field of coatings more particularly to a kind of hyalomitome response type Self-adhesive waterproof materials.
Background technology
Water-proof acrylic acid paint be using pure acrylic acid polymer emulsion as base-material, prepared by other additives are added single group Part water-emulsifying type waterproof coatings.The waterproofing membrane formed after water-repellent paint is cured has certain extensibility, elastoplasticity, cracking resistance Property, impermeability and weatherability, waterproof can be played, anti-blend protective effect.Water-repellent paint has good thermal adaptability, operation letter Just, for ease of maintenaince with maintenance.
Waterproof material has been applied in many fields of our lives, and composition proportion is respectively formed in water-repellent paint now Unevenness causes coating that cannot use for a long time, for this purpose, it is proposed that a kind of hyalomitome response type Self-adhesive waterproof material.
Invention content
Technical problems based on background technology, the present invention propose a kind of hyalomitome response type Self-adhesive waterproof material.
The present invention proposes a kind of hyalomitome response type Self-adhesive waterproof material, and raw material includes by weight percentage:White Softening oil 15-20%, hot melt adhesive grade elastomer 4-6%, styrene-styrene block copolymer (SBS) 3-9%, tackified rubber 20- 30%, the extremely strong liquid resin 5-6% of rubber latex 4-6%, ultraviolet screener 0.1-0.5%, penetrating power, tackifying resin 15- 25%, remaining group is divided into interfacial agents.
Preferably, White softening oil includes any one or a few the mixing in butyl oil, white oil and wax oil.
Preferably, the hot melt adhesive grade elastomer includes ethane-acetic acid ethyenyl(Sour person of outstanding talent's ethylene)Ester copolymer(EVA), third Any one or a few mixing in olefin(e) acid, butyl rubber
Preferably, the tackified rubber includes butadiene-styrene rubber, styrene-isoprene-styrene block copolymer(SBB)In Any one or a few mixing.
Preferably, rubber latex includes any one or a few the mixing in benzene lotion, styrene-butadiene emulsion and silicon benzene lotion.
Preferably, the UV resistance agent include in UV531, UV327, UV328, UV320, UV1164 any one or Several mixing.
Preferably, the extremely strong liquid resin of the penetrating power includes arbitrary in low molecular polyisobutylene, epoxy resin One or more of mixing.
Preferably, the tackifying resin includes appointing in light C5 Petropols, light terpene resin plus hydrogen terpene resin The mixing for one or more of anticipating.
Preferably, the interfacial agents are mainly used for improving the penetration with base material.
The present invention also proposes a kind of preparation method of hyalomitome response type Self-adhesive waterproof material, includes the following steps:
S1, first by White softening oil be added reaction kettle in, 130 DEG C be dehydrated 20 minutes;
S2,170-190 DEG C is then heated to, part tackifying resin is added by formula, temperature control stirs thickening between 180-190 DEG C Resin is completely dissolved;
S3, hot melt adhesive grade elastomer, Styrene-Butadiene-Styrene Block Copolymer is added by formula(SBB)With thickening elasticity Body, temperature control are stirred at 180-190 DEG C to melten gel grade elasticity, styrene block copolymer(SBB)It is completely dissolved with tackified elastomers;
S4, remaining tackifying resin is added, stirring is as a child slowly rear to be added rubber latex;
S5, it waits for that rubber latex is completely dissolved and moisture content all plays, the strong liquid of ultraviolet screener, anti-aging agent, penetrating power is added Body rubber and basal plane agent;
S6, temperature control are molded at 160 DEG C on coating base.
The present invention by adding said components, and rationally controls the content of each component, and Mechanical Properties of Products is good, rub resistance, Excellent anti-corrosion performance.By rationally control White softening oil, hot melt adhesive grade elastomer, styrene-styrene block copolymer, Tackified rubber content can significantly increase the mechanical strength of product;Additionally by addition rubber latex, ultraviolet screener, penetrating power Extremely strong liquid resin, tackifying resin simultaneously control its content, can increase the high mechanical strength of coating, excellent anti-corrosion performance.
Specific implementation mode
With reference to specific embodiment, the present invention will be further described.
Embodiment 1
A kind of hyalomitome response type Self-adhesive waterproof material, raw material include by weight percentage:White softening oil 15%, hot melt adhesive Grade elastomer 4%, tackified rubber 20%, rubber latex 4%, ultraviolet screener 0.1%, oozes styrene-styrene block copolymer 4% Very competent liquid resin 5%, tackifying resin 15%, interfacial agents 32.9% thoroughly.
Embodiment 2
A kind of hyalomitome response type Self-adhesive waterproof material, raw material include by weight percentage:White softening oil 17%, hot melt adhesive Grade elastomer 5%, styrene-styrene block copolymer 5%, tackified rubber 24%, rubber latex 4.5%, ultraviolet screener 0.2%, The extremely strong liquid resin 5.2% of penetrating power, tackifying resin 17%, interfacial agents 22.1%.
Embodiment 3
A kind of hyalomitome response type Self-adhesive waterproof material, raw material include by weight percentage:White softening oil 17%, hot melt adhesive Grade elastomer 5%, styrene-styrene block copolymer 6%, tackified rubber 27%, rubber latex 5.3%, ultraviolet screener 0.4%, The extremely strong liquid resin 5.6% of penetrating power, tackifying resin 22%, interfacial agents 11.7%.
Embodiment 4
A kind of hyalomitome response type Self-adhesive waterproof material, raw material include by weight percentage:White softening oil 18%, hot melt adhesive Grade elastomer 6%, tackified rubber 20%, rubber latex 6%, ultraviolet screener 0.5%, oozes styrene-styrene block copolymer 9% Very competent liquid resin 6%, tackifying resin 24%, interfacial agents 10.5% thoroughly.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (10)

1. a kind of hyalomitome response type Self-adhesive waterproof material, which is characterized in that its raw material includes by weight percentage:White softening Oily 15-20%, hot melt adhesive grade elastomer 4-6%, styrene-styrene block copolymer 3-9%, tackified rubber 20-30%, latex rubber The extremely strong liquid resin 5-6% of liquid 4-6%, ultraviolet screener 0.1-0.5%, penetrating power, tackifying resin 15-25%, remaining component For interfacial agents.
2. hyalomitome response type Self-adhesive waterproof material according to claim 1, which is characterized in that White softening oil includes fourth Any one or a few mixing in base oil, white oil and wax oil.
3. hyalomitome response type Self-adhesive waterproof material according to claim 1, which is characterized in that the hot melt adhesive grade elasticity Body includes any one or a few the mixing in vinyl-vinyl acetate copolymer, acrylic acid, butyl rubber.
4. hyalomitome response type Self-adhesive waterproof material according to claim 1, which is characterized in that the tackified rubber includes Any one or a few mixing in butadiene-styrene rubber, styrene-isoprene-styrene block copolymer.
5. hyalomitome response type Self-adhesive waterproof material according to claim 1, which is characterized in that rubber latex includes benzene breast Any one or a few mixing in liquid, styrene-butadiene emulsion and silicon benzene lotion.
6. hyalomitome response type Self-adhesive waterproof material according to claim 1, which is characterized in that the UV resistance agent packet Include the mixing of any one or a few in UV531, UV327, UV328, UV320, UV1164.
7. hyalomitome response type Self-adhesive waterproof material according to claim 1, which is characterized in that the penetrating power is extremely strong Liquid resin include any one or a few mixing in low molecular polyisobutylene, epoxy resin.
8. hyalomitome response type Self-adhesive waterproof material according to claim 1, which is characterized in that the tackifying resin includes Any one or a few mixing in light C5 Petropols, light terpene resin plus hydrogen terpene resin.
9. hyalomitome response type Self-adhesive waterproof material according to claim 1, which is characterized in that the interfacial agents are mainly used Way is the penetration improved with base material.
10. a kind of preparation method according to claim 1-9 any one of them hyalomitome response type Self-adhesive waterproof materials, special Sign is, includes the following steps:
S1, first by White softening oil be added reaction kettle in, 130 DEG C be dehydrated 20 minutes;
S2,170-190 DEG C is then heated to, part tackifying resin is added by formula, temperature control stirs thickening between 180-190 DEG C Resin is completely dissolved;
S3, hot melt adhesive grade elastomer, Styrene-Butadiene-Styrene Block Copolymer and tackified elastomers, control are added by formula Temperature is stirred to melten gel grade elasticity, styrene block copolymer and tackified elastomers at 180-190 DEG C and is completely dissolved;
S4, remaining tackifying resin is added, stirring is as a child slowly rear to be added rubber latex;
S5, it waits for that rubber latex is completely dissolved and moisture content all plays, the strong liquid of ultraviolet screener, anti-aging agent, penetrating power is added Body rubber and basal plane agent;
S6, temperature control are molded at 160 DEG C on coating base.
CN201710031985.8A 2017-01-17 2017-01-17 A kind of hyalomitome response type Self-adhesive waterproof material Pending CN108610756A (en)

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CN201710031985.8A CN108610756A (en) 2017-01-17 2017-01-17 A kind of hyalomitome response type Self-adhesive waterproof material

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Application Number Priority Date Filing Date Title
CN201710031985.8A CN108610756A (en) 2017-01-17 2017-01-17 A kind of hyalomitome response type Self-adhesive waterproof material

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115418149A (en) * 2022-08-01 2022-12-02 北京东方雨虹防水技术股份有限公司 Non-asphalt-based non-cured waterproof coating and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1198312B (en) * 1979-07-13 1988-12-21 Nichiban Kk PRESSURE-SENSITIVE ADHESIVE COMPOSITION, ADHESIVE TAPE PREPARED WITH IT
CN102993754A (en) * 2012-12-12 2013-03-27 湖北蓝盾之星科技股份有限公司 Self-adhesive waterproof material and preparation method thereof
CN103361025A (en) * 2013-07-19 2013-10-23 北京东方雨虹防水技术股份有限公司 Self-adhesive waterproof coiled material having high initial stickiness and preparation method thereof
CN104723652A (en) * 2015-03-10 2015-06-24 大禹伟业(北京)国际科技有限公司 Method for preparing and constructing composite coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1198312B (en) * 1979-07-13 1988-12-21 Nichiban Kk PRESSURE-SENSITIVE ADHESIVE COMPOSITION, ADHESIVE TAPE PREPARED WITH IT
CN102993754A (en) * 2012-12-12 2013-03-27 湖北蓝盾之星科技股份有限公司 Self-adhesive waterproof material and preparation method thereof
CN103361025A (en) * 2013-07-19 2013-10-23 北京东方雨虹防水技术股份有限公司 Self-adhesive waterproof coiled material having high initial stickiness and preparation method thereof
CN104723652A (en) * 2015-03-10 2015-06-24 大禹伟业(北京)国际科技有限公司 Method for preparing and constructing composite coating

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115418149A (en) * 2022-08-01 2022-12-02 北京东方雨虹防水技术股份有限公司 Non-asphalt-based non-cured waterproof coating and preparation method thereof

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Application publication date: 20181002

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