CN105165844A - Fluensulfone-containing nematode killing composition - Google Patents

Fluensulfone-containing nematode killing composition Download PDF

Info

Publication number
CN105165844A
CN105165844A CN201510629240.2A CN201510629240A CN105165844A CN 105165844 A CN105165844 A CN 105165844A CN 201510629240 A CN201510629240 A CN 201510629240A CN 105165844 A CN105165844 A CN 105165844A
Authority
CN
China
Prior art keywords
thiophene worm
worm sulfone
fluorine
nematicidal composition
fluorine thiophene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201510629240.2A
Other languages
Chinese (zh)
Other versions
CN105165844B (en
Inventor
王泊理
陈翠锦
赵勇
阮宏浩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangzhou Zhenge Agricultural Science & Technology Co Ltd
ZHAOQING ZHENGE BIOTECHNOLOGY CO Ltd
Original Assignee
Guangzhou Zhenge Agricultural Science & Technology Co Ltd
ZHAOQING ZHENGE BIOTECHNOLOGY CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangzhou Zhenge Agricultural Science & Technology Co Ltd, ZHAOQING ZHENGE BIOTECHNOLOGY CO Ltd filed Critical Guangzhou Zhenge Agricultural Science & Technology Co Ltd
Priority to CN201510629240.2A priority Critical patent/CN105165844B/en
Priority to CN201710326682.9A priority patent/CN106993621A/en
Publication of CN105165844A publication Critical patent/CN105165844A/en
Application granted granted Critical
Publication of CN105165844B publication Critical patent/CN105165844B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention relates to the field of agricultural pesticides, in particular to a fluensulfone-containing nematode killing composition. The nematode killing composition comprises an effective ingredient A and an effective ingredient B. The effective ingredient A is fluensulfone, and the effective ingredient B is one kind of amino-oligosaccharin, azadirachtin and ivermectin. The weight ratio of the effective ingredient A to the effective ingredient B is 1-25 to 25-1, the weight percent of the effective ingredient A accounting for the nematode killing composition ranges from 0.1% to 80%, and the weight percent of the effective ingredient B accounting for the nematode killing composition ranges from 0.1% to 80%. The nematode killing composition can be prepared into various preparations suitable for agriculture and used for preventing and treating nematode diseases of vegetable crops, grain crops, lawns and fruit trees; in addition, the problems of a large pesticide use amount and frequent pesticide using can be solved, environment stress can be reduced, and the service life of pesticides can be prolonged.

Description

A kind of nematicidal composition of fluorine-containing thiophene worm sulfone
Technical field
The present invention relates to disinfectant use in agriculture field, be specifically related to a kind of nematicidal composition of fluorine-containing thiophene worm sulfone.
Background technology
Fluorine thiophene worm sulfone (Fluensulfone, CAS accession number: 318290-98-1, chemical name: the fluoro-1,3-thiazoles of 5--2-base-3, the fluoro-3-butene-1 of 3,3-tri--Ji sulfone) be the fluoroolefins nematocide developed by MakhteshimChemicalWorks company.Fluorine thiophene worm sulfone in polypide, can control polypide activity by multiple physiological action, and then paralysis nematode movement; Hinder and reduce egg counts or egg hatch rate, controlling nematode and occur on a large scale; Directly kill nematode by contacting, larva cannot be survived, irreversible nematocidal effect can make nematode dead.
Amino-oligosaccharide (chitosan oligosaccharide) a kind of is first degraded degraded is obtained again after shitosan by chitin, or extracted the low toxicity bactericide obtained by fermentable.This compound not only has extremely strong control and eradicant action to fungi, bacterium, virus, but also has nutrition, adjustment, removing toxic substances, antibacterial effect.Research finds that amino-oligosaccharide can inducing plant disease resistance, the preferably generation of control cucumber root-knot nematode.
Nimbin is the insecticide of wide spectrum recognized in the world, efficient, low toxicity, easily degraded, noresidue, all has to nearly all plant insect, indoor sanitary insect pest etc. the effect of killing, and to people and animals and surrounding environment without any pollution.
Ivermectin is novel wide spectrum, high-efficiency low-toxicity antibiotics antiparasitic agent, the mechanism of action is the release of the inhibitory transmitter γ-aminobutyric acid (GABA) increasing polypide, and open the Cl ion channel of glutamic acid control, strengthen neu to the permeability of Cl, thus the transmission of block nerves signal, play neural paralysis effect, make muscle cell lose contractility, thus cause polypide dead.Good preventive effect is all had to animal parasitic nematodes and agriculture nematode.
The agriculture chemical compounding of reasonable science or mixture can expand insecticidal spectrum, improve control efficiency, reduce dosage, less residue of pesticide, extend the Pesticide use life-span, delay the generation of pest resistance, be conducive to sustainable development.There is no the report about fluorine thiophene worm sulfone nematicidal composition composite with amino-oligosaccharide, nimbin, ivermectin respectively and application thereof at present.
Summary of the invention
In view of this, in order to solve the problem, the invention provides a kind of nematicidal composition of fluorine-containing thiophene worm sulfone.The present invention, through lot of experiments, filters out fluorine thiophene worm sulfone and carries out composite with amino-oligosaccharide, nimbin, ivermectin respectively, and obtained nematicidal composition has obvious synergistic effect, also shows good control efficiency for field trial.
For achieving the above object, the present invention adopts following technical scheme:
The nematicidal composition of fluorine-containing thiophene worm sulfone of the present invention, comprises effective constituents A and active ingredient B; Described effective constituents A is fluorine thiophene worm sulfone, and described active ingredient B is the one in amino-oligosaccharide, nimbin or ivermectin.
Further, the weight ratio of described effective constituents A and active ingredient B is 1 ~ 25:25 ~ 1.
Further, described effective constituents A and active ingredient B account for the percentage by weight of nematicidal composition is 0.1% ~ 80%.
Further, described nematicidal composition also comprises pesticidal preparations auxiliary element, and described pesticidal preparations auxiliary element comprises stabilizing agent, solvent, auxiliary agent and carrier.
Further, described nematicidal composition can make the various formulations being suitable for agricultural production, comprises suspending agent, aqueous emulsion, microemulsion, granule, water dispersible granules, wetting powder.
The application of nematicidal composition in control vegetable crop, cereal crops, lawn, Pomology disease of fluorine-containing thiophene worm sulfone.
Beneficial effect of the present invention is:
The active component of nematicidal composition of the present invention adopts fluorine thiophene worm sulfone to carry out scientific and reasonable composite with the one be selected from amino-oligosaccharide, nimbin and ivermectin, between built reactive composition, there is synergistic function, this nematicidal composition can make the various formulations be agriculturally suitable for, effectively can prevent and treat nematode, solution dosage is large, medication problem frequently, slow down environmental pressure, extend the Pesticide use life-span.
Embodiment
For a better understanding of the present invention, below in conjunction with specific embodiment, the present invention is further illustrated.
The nematicidal composition of fluorine-containing thiophene worm sulfone of the present invention, comprises effective constituents A and active ingredient B; Described effect composition A is fluorine thiophene worm sulfone, and described active ingredient B is the one in amino-oligosaccharide, nimbin or ivermectin; The weight ratio of described effective constituents A and active ingredient B is 1 ~ 25:25 ~ 1; The percentage by weight of described effective constituents A and active ingredient B accounts for 0.1% ~ 80% of nematicidal composition.Indoor virulence test is below adopted to be described:
Toxicity Determination
Dip method: the Cucumber root of picking artificial infection cucumber root-knot nematode, smash with tissue mashing machine, cross 200 orders, 325 orders, 500 order nematode standard screens successively, with the worm's ovum on aseptic water washing 500 mesh sieve, hatch in sterile water, get the larva (2 instar larvae) hatched for the 2nd day and supply test.With liquid-transfering gun from low concentration to high concentration, once draw liquid 3mL and add respectively in test tube, then draw the equivalent nematode suspension 3mL prepared and add in vitro, make liquid and nematode suspension mixed in equal amounts even.Pipette the above-mentioned mixed liquor of certain volume in the aperture of porous biochemical test plate with liquid-transfering gun, add a cover, in 25 DEG C of constant temperature culture.Each process repeats, if sterile water is control treatment for 4 times.Nematode death condition is observed under anatomical lens, the bus borer population of record investigation and verge of death borer population after 48h.Dead nematode is stiff, still can not bending motion with the touching of hair pin.Calculate lethality and corrected mortality.
Probability value according to drug concentration logarithm value and corresponding plant pathogeny line insect corrected mortality does regression analysis, calculates the LC of each medicament 50, and the co-toxicity coefficient (CTC value) of mixture is calculated according to the abundant method of Sun Yun.
Actual measurement toxicity index (ATI)=(standard agent LC 50/ reagent agent LC 50) × 100
In theoretical toxicity index (TTI)=A medicament toxicity index × mixture A percentage composition+B medicament toxicity index × mixture in the percentage composition of B
Co-toxicity coefficient (CTC)=[the theoretical toxicity index (TTI) of mixture actual measurement toxicity index (ATI)/mixture] × 100
The co-toxicity coefficient of built agent: CTC >=120 are judged as synergistic effect; CTC≤80 are judged as antagonism; 80<CTC<120 is judged as summation action.
Table 1 fluorine thiophene worm sulfone and the composite Toxicity Determination result to cucumber root-knot nematode of amino-oligosaccharide
Reagent agent Proportioning LC50(mg/ml) ATI TTI CTC
Fluorine thiophene worm sulfone — 4.47 100 — —
Amino-oligosaccharide — 8.13 54.98 — —
Fluorine thiophene worm sulfone: amino-oligosaccharide 1:25 6.32 70.69 56.71 124.64
Fluorine thiophene worm sulfone: amino-oligosaccharide 1:10 5.26 85.01 59.07 143.91
Fluorine thiophene worm sulfone: amino-oligosaccharide 1:5 4.74 94.21 62.48 150.78
Fluorine thiophene worm sulfone: amino-oligosaccharide 1:3 4.08 109.44 66.23 165.23
Fluorine thiophene worm sulfone: amino-oligosaccharide 1:2 3.60 124.15 69.99 177.39
Fluorine thiophene worm sulfone: amino-oligosaccharide 1:1 2.98 150.04 77.49 193.62
Fluorine thiophene worm sulfone: amino-oligosaccharide 2:1 2.83 157.88 84.99 185.76
Fluorine thiophene worm sulfone: amino-oligosaccharide 3:1 3.10 144.02 88.74 162.28
Fluorine thiophene worm sulfone: amino-oligosaccharide 5:1 3.28 136.44 92.50 147.51
Fluorine thiophene worm sulfone: amino-oligosaccharide 10:1 3.48 128.28 95.91 133.76
Fluorine thiophene worm sulfone: amino-oligosaccharide 25:1 3.55 125.92 98.27 128.14
Table 2 fluorine thiophene worm sulfone and azadirachtin complex are to the Toxicity Determination result of cucumber root-knot nematode
Reagent agent Proportioning LC50(mg/ml) ATI TTI CTC
Fluorine thiophene worm sulfone — 4.16 100 — —
Nimbin — 15.74 26.43 — —
Fluorine thiophene worm sulfone: nimbin 1:25 11.75 35.42 29.26 121.05
Fluorine thiophene worm sulfone: nimbin 1:10 9.27 44.87 33.12 135.49
Fluorine thiophene worm sulfone: nimbin 1:5 8.51 48.90 38.69 126.38
Fluorine thiophene worm sulfone: nimbin 1:3 6.41 64.87 44.82 144.72
Fluorine thiophene worm sulfone: nimbin 1:2 5.07 82.11 50.95 161.15
Fluorine thiophene worm sulfone: nimbin 1:1 3.53 117.72 63.21 186.23
Fluorine thiophene worm sulfone: nimbin 2:1 2.79 148.88 75.48 197.25
Fluorine thiophene worm sulfone: nimbin 3:1 2.92 142.66 81.61 174.81
Fluorine thiophene worm sulfone: nimbin 5:1 3.05 136.31 87.74 155.36
Fluorine thiophene worm sulfone: nimbin 10:1 2.99 139.25 93.31 149.23
Fluorine thiophene worm sulfone: nimbin 25:1 3.22 129.28 97.17 133.04
Table 3 fluorine thiophene worm sulfone and the composite Toxicity Determination result to cucumber root-knot nematode of ivermectin
Reagent agent Proportioning LC50(mg/ml) ATI TTI CTC
Fluorine thiophene worm sulfone — 4.29 100 — —
Ivermectin — 7.46 57.51 — —
Fluorine thiophene worm sulfone: ivermectin 1:25 5.42 79.08 59.14 133.72
Fluorine thiophene worm sulfone: ivermectin 1:10 4.93 86.95 61.37 141.68
Fluorine thiophene worm sulfone: ivermectin 1:5 4.36 98.28 64.59 152.17
Fluorine thiophene worm sulfone: ivermectin 1:3 3.76 114.02 68.13 167.35
Fluorine thiophene worm sulfone: ivermectin 1:2 3.44 124.64 71.67 173.90
Fluorine thiophene worm sulfone: ivermectin 1:1 2.96 145.17 78.75 184.33
Fluorine thiophene worm sulfone: ivermectin 2:1 2.52 170.01 85.84 198.06
Fluorine thiophene worm sulfone: ivermectin 3:1 2.56 167.65 89.38 187.58
Fluorine thiophene worm sulfone: ivermectin 5:1 2.61 164.31 92.92 176.83
Fluorine thiophene worm sulfone: ivermectin 10:1 3.08 139.12 96.14 144.71
Fluorine thiophene worm sulfone: ivermectin 25:1 3.45 124.19 98.36 126.25
As can be seen from table 1,2,3, fluorine thiophene worm sulfone is composite with amino-oligosaccharide, nimbin, ivermectin respectively, in the ratio range of 1 ~ 25:25 ~ 1, co-toxicity coefficient (CTC) is all greater than 120, shows synergistic function to cucumber root-knot nematode.
Nematicidal composition of the present invention can be prepared into the various formulations being suitable for agricultural production, and be below specific embodiment, in formula, percentage is mass percent.
Embodiment 1
6% fluorine thiophene worm sulfone amino-oligosaccharide granule: fluorine thiophene worm sulfone 3%, amino-oligosaccharide 3%, alkylphenol polyoxyethylene 3%, sodium butylnaphthalenesulfonate 2%, 5% polyvinyl alcohol water solution 10%, kaolin complements to 100%.
Embodiment 2
6% fluorine thiophene worm sulfone nimbin granule: fluorine thiophene worm sulfone 4%, nimbin 2%, alkylphenol polyoxyethylene 5%, sodium butylnaphthalenesulfonate 2%, 5% polyvinyl alcohol water solution 10%, kaolin complements to 100%.
Embodiment 3
6% fluorine thiophene worm sulfone ivermectin granule: fluorine thiophene worm sulfone 4%, ivermectin 2%, alkylphenol polyoxyethylene 5%, sodium butylnaphthalenesulfonate 2%, 5% polyvinyl alcohol water solution 10%, kaolin complements to 100%.
Embodiment 4
30% fluorine thiophene worm sulfone ivermectin aqueous emulsion: fluorine thiophene worm sulfone 20%, ivermectin 10%, dimethylbenzene 5%, cyclohexanone 15%, castor oil polyoxyethylene ether 15%, sodium lignin sulfonate 2%, glycerine 1%, xylitol 1%, deionized water supply 100%.
Embodiment 5
24% fluorine thiophene worm sulfone amino-oligosaccharide suspending agent: fluorine thiophene worm sulfone 16%, amino-oligosaccharide 8%, sodium lignin sulfonate 2%, lauryl sodium sulfate 2%, glycerine 1%, xanthans 1%, C-18 fatty alcohol 0.1%, aluminium-magnesium silicate 1%, deionized water supplies 100%.
Embodiment 6
11% fluorine thiophene worm sulfone nimbin suspending agent: fluorine thiophene worm sulfone 10%, nimbin 1%, sodium lignin sulfonate 2%, pull open powder 2%, glycerine 1%, xanthans 1%, silicone oil 0.1%, deionized water supply 100%.
Embodiment 7
55% fluorine thiophene worm sulfone ivermectin wetting powder: fluorine thiophene worm sulfone 30%, ivermectin 25%, naphthalenesulfonate condensation compound 1.5%, lignosulfonates 3%, kaolin stone supply 100%.
Embodiment 8
10% fluorine thiophene worm sulfone micro nimbin emulsion: fluorine thiophene worm sulfone 7%, nimbin 3%, alkylphenol polyoxyethylene 10%, Tween-20 5%, acetone 10%, dimethyl sulfoxide (DMSO) 5%, propane diols 5%, deionized water supply 100%.
Embodiment 9
50% fluorine thiophene worm sulfone amino-oligosaccharide water dispersible granules: fluorine thiophene worm sulfone 25%, amino-oligosaccharide 25%, sodium alkyl benzene sulfonate 3%, polyoxyethylene carboxylate 5%, sodium carboxymethyl starch 2%, ammonium sulfate 5%, diatomite supply 100%.
Embodiment 10
70% fluorine thiophene worm sulfone ivermectin water dispersible granules: fluorine thiophene worm sulfone 50%, ivermectin 20%, sodium alkyl benzene sulfonate 3%, polyoxyethylene carboxylate 5%, soluble corn starch 2%, sodium sulphate 5%, diatomite supply 100%.
Field control effectiveness test
The field experiment of the nematicidal composition of fluorine-containing thiophene worm sulfone of the present invention, for preventing and treating Cucumber root-knot nematode disease:
The result of the test of table 4 each treatment agent field control Cucumber root-knot nematode disease
Treatment agent Dosage g.a.i./ha 30 days preventive effects (%) after medicine
6% fluorine thiophene worm sulfone GR 400 68.60
1% amino-oligosaccharide GR 1000 82.97
10% nimbin GR 1000 70.58
10% ivermectin GR 1000 72.53
6% fluorine thiophene worm sulfone amino-oligosaccharide GR 800 95.84
6% fluorine thiophene worm sulfone nimbin GR 800 92.43
6% fluorine thiophene worm sulfone ivermectin GR 800 90.86
Blank — —
Note: in table 4, GR represents granule.6% fluorine thiophene worm sulfone amino-oligosaccharide granule, 6% fluorine thiophene worm sulfone nimbin granule, 6% fluorine thiophene worm sulfone ivermectin granule corresponding embodiment 1-3 respectively.
As can be seen from Table 4, for preventing and treating cucumber root-knot nematode, its successful is better than single dose, does not produce poisoning phenomenon in process of the test, and this composite nematicidal composition has synergistic function, can agriculturally promote the use of.
The above embodiment only have expressed several embodiment of the present invention, and it describes comparatively concrete and detailed, but therefore can not be interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.

Claims (6)

1. a nematicidal composition for fluorine-containing thiophene worm sulfone, is characterized in that: comprise effective constituents A and active ingredient B; Described effective constituents A is fluorine thiophene worm sulfone, and described active ingredient B is the one in amino-oligosaccharide, nimbin or ivermectin.
2. the nematicidal composition of fluorine-containing thiophene worm sulfone according to claim 1, is characterized in that: the weight ratio of described effective constituents A and active ingredient B is 1 ~ 25: 25 ~ 1.
3. the nematicidal composition of fluorine-containing thiophene worm sulfone according to claim 1, is characterized in that: the percentage by weight that described effective constituents A and active ingredient B account for nematicidal composition is 0.1% ~ 80%.
4. the nematicidal composition of fluorine-containing thiophene worm sulfone according to claim 1, it is characterized in that: also comprise pesticidal preparations auxiliary element, described pesticidal preparations auxiliary element comprises stabilizing agent, solvent, auxiliary agent and carrier.
5. the nematicidal composition of fluorine-containing thiophene worm sulfone according to claim 4, it is characterized in that: described nematicidal composition can make the various formulations being suitable for agricultural production, comprises suspending agent, aqueous emulsion, microemulsion, granule, water dispersible granules, wetting powder.
6. the application of nematicidal composition in control vegetable crop, cereal crops, lawn, Pomology disease of fluorine-containing thiophene worm sulfone.
CN201510629240.2A 2015-09-25 2015-09-25 A kind of nematicidal composition of fluorine-containing thiophene worm sulfone Active CN105165844B (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201510629240.2A CN105165844B (en) 2015-09-25 2015-09-25 A kind of nematicidal composition of fluorine-containing thiophene worm sulfone
CN201710326682.9A CN106993621A (en) 2015-09-25 2015-09-25 A kind of nematicidal composition of fluorine-containing thiophene worm sulfone

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510629240.2A CN105165844B (en) 2015-09-25 2015-09-25 A kind of nematicidal composition of fluorine-containing thiophene worm sulfone

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201710326682.9A Division CN106993621A (en) 2015-09-25 2015-09-25 A kind of nematicidal composition of fluorine-containing thiophene worm sulfone

Publications (2)

Publication Number Publication Date
CN105165844A true CN105165844A (en) 2015-12-23
CN105165844B CN105165844B (en) 2017-10-31

Family

ID=54888719

Family Applications (2)

Application Number Title Priority Date Filing Date
CN201710326682.9A Pending CN106993621A (en) 2015-09-25 2015-09-25 A kind of nematicidal composition of fluorine-containing thiophene worm sulfone
CN201510629240.2A Active CN105165844B (en) 2015-09-25 2015-09-25 A kind of nematicidal composition of fluorine-containing thiophene worm sulfone

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CN201710326682.9A Pending CN106993621A (en) 2015-09-25 2015-09-25 A kind of nematicidal composition of fluorine-containing thiophene worm sulfone

Country Status (1)

Country Link
CN (2) CN106993621A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106259379A (en) * 2016-08-05 2017-01-04 广州市真格农业科技有限公司 A kind of nematicidal composition containing trifluorobutene base class compound
CN106342825A (en) * 2016-08-25 2017-01-25 佛山市盈辉作物科学有限公司 Nematicidal composition containing fluensulfone
CN106489955A (en) * 2016-10-15 2017-03-15 佛山市盈辉作物科学有限公司 A kind of fluorine-containing thiophene worm sulfone and the nematicidal composition of chitosan
CN107006489A (en) * 2017-05-10 2017-08-04 广西南宁黑泥巴农业科技有限公司 A kind of nematicidal composition of fluorine-containing thiophene worm sulfone and recinine
CN107668044A (en) * 2016-08-01 2018-02-09 江苏龙灯化学有限公司 A kind of nematicidal agent composition and its application method
CN107691457A (en) * 2016-08-08 2018-02-16 深圳诺普信农化股份有限公司 Nematicidal composition
WO2018104787A1 (en) * 2016-12-09 2018-06-14 Adama Makhteshim Ltd. High-concentration fluensulfone formulations, their uses and processes of preparation
US11533910B2 (en) 2015-12-10 2022-12-27 Adama Makhteshim Ltd. Polyelectrolyte-layer forming block copolymers and compositions and uses thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104430477A (en) * 2014-11-25 2015-03-25 广东中迅农科股份有限公司 Pesticide composition containing fluensulfone and neonicotinoid insecticide
CN104488921A (en) * 2014-12-30 2015-04-08 海利尔药业集团股份有限公司 Nematicidal composition containing fluensulfone and abamectin
CN104855392A (en) * 2015-02-04 2015-08-26 东莞市瑞德丰生物科技有限公司 Nematode killing composition

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10319590A1 (en) * 2003-05-02 2004-11-18 Bayer Cropscience Ag Drug combinations with nematicidal and insecticidal properties based on trifluorobutenyl compounds

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104430477A (en) * 2014-11-25 2015-03-25 广东中迅农科股份有限公司 Pesticide composition containing fluensulfone and neonicotinoid insecticide
CN104488921A (en) * 2014-12-30 2015-04-08 海利尔药业集团股份有限公司 Nematicidal composition containing fluensulfone and abamectin
CN104855392A (en) * 2015-02-04 2015-08-26 东莞市瑞德丰生物科技有限公司 Nematode killing composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
胡文明等: ""植物源杀虫剂印楝素的研究进展"", 《中国茶叶加工》 *

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11533910B2 (en) 2015-12-10 2022-12-27 Adama Makhteshim Ltd. Polyelectrolyte-layer forming block copolymers and compositions and uses thereof
CN107668044A (en) * 2016-08-01 2018-02-09 江苏龙灯化学有限公司 A kind of nematicidal agent composition and its application method
CN106259379B (en) * 2016-08-05 2018-06-29 广州市真格农业科技有限公司 A kind of nematicidal composition containing trifluorobutene base class compound
CN106259379A (en) * 2016-08-05 2017-01-04 广州市真格农业科技有限公司 A kind of nematicidal composition containing trifluorobutene base class compound
CN107691457A (en) * 2016-08-08 2018-02-16 深圳诺普信农化股份有限公司 Nematicidal composition
CN106342825A (en) * 2016-08-25 2017-01-25 佛山市盈辉作物科学有限公司 Nematicidal composition containing fluensulfone
CN106489955A (en) * 2016-10-15 2017-03-15 佛山市盈辉作物科学有限公司 A kind of fluorine-containing thiophene worm sulfone and the nematicidal composition of chitosan
JP2020513411A (en) * 2016-12-09 2020-05-14 アダマ・マクテシム・リミテッド High concentration fluene sulfone agent, its use, and preparation process
CN110049673A (en) * 2016-12-09 2019-07-23 阿达玛马克西姆股份有限公司 High concentration fluorine thiophene worm sulfone preparation, its Use and preparation method
WO2018104787A1 (en) * 2016-12-09 2018-06-14 Adama Makhteshim Ltd. High-concentration fluensulfone formulations, their uses and processes of preparation
JP7123049B2 (en) 2016-12-09 2022-08-22 アダマ・マクテシム・リミテッド High-concentration fluenesulfone agent, its use, and preparation process
AU2017371909B2 (en) * 2016-12-09 2022-11-17 Adama Makhteshim Ltd. High-concentration fluensulfone formulations, their uses and processes of preparation
CN107006489A (en) * 2017-05-10 2017-08-04 广西南宁黑泥巴农业科技有限公司 A kind of nematicidal composition of fluorine-containing thiophene worm sulfone and recinine

Also Published As

Publication number Publication date
CN105165844B (en) 2017-10-31
CN106993621A (en) 2017-08-01

Similar Documents

Publication Publication Date Title
CN105165844A (en) Fluensulfone-containing nematode killing composition
CN101554170A (en) Chlorantraniliprole and emamectin benzoate insecticidal composition
CN102487952B (en) Insecticidal composition containing cycloxaprid and biological insecticide
CN101564038B (en) Insecticidal composition containing metaflumizone
CN104186514A (en) Pesticide composition containing cyhalodiamide
CN103734171A (en) Pesticide composition containing imidacloprid
CN101480188A (en) Insecticidal composition containing emamectin benzoate and indoxacarb
CN104839180A (en) Fungicide composition and application thereof
CN102362601A (en) Insecticidal composition containing spinetoram and lythidathion
CN102047915B (en) Insecticidal composition containing thiacloprid amide
CN102349524B (en) Sterilizing composition containing Cyflufenamid
CN106973937B (en) Nematicidal composition containing cyflumetofen
CN102835396A (en) Sterilization composition, pesticide and application
CN104996439A (en) Pesticide composition and application thereof
CN103262848B (en) Insecticidal composition containing cycloxaprid and biological insecticide
CN108849961A (en) Composition pesticide containing pyridine quinazoline
CN106879609A (en) A kind of Pesticidal combination containing doractin and Nylar
CN103155938B (en) Clothianidin/Diafenthiuron compound insecticidal composition
CN102318636A (en) A kind of Synergistic insecticidal compositions
CN106212463B (en) A kind of composition pesticide containing propylene glycol alginate and methoxyfenozide
CN105028442A (en) Insecticidal composition containing diflubenzuron and pymetrozine and application thereof
CN103749530B (en) A kind of Pesticidal combination containing Avermectin
CN103380779B (en) A kind of Pesticidal combination containing cycolxylidin and biological source insecticide
CN102246759A (en) Pesticide composition containing flonicamid and spinosad
CN107372541A (en) A kind of Pesticidal combination containing doractin and Nylar

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
CB02 Change of applicant information

Address after: 526000 District, Gaoyao Industrial Park, Gaoyao District, Guangdong, Zhaoqing

Applicant after: Guangdong Zhenge Biotechnology Co. Ltd.

Applicant after: GUANGZHOU ZHENGE AGRICULTURAL SCIENCE & TECHNOLOGY CO., LTD.

Address before: 526108 Zhaoqing District, Gaoyao Town, Gaoyao City, Guangdong,

Applicant before: Zhaoqing Zhenge Biotechnology Co.,Ltd.

Applicant before: GUANGZHOU ZHENGE AGRICULTURAL SCIENCE & TECHNOLOGY CO., LTD.

CB02 Change of applicant information
CB03 Change of inventor or designer information

Inventor after: Wang Boli

Inventor after: Chen Cuijin

Inventor after: Zhao Yong

Inventor after: Ruan Honghao

Inventor after: Geng Shuaifeng

Inventor before: Wang Boli

Inventor before: Chen Cuijin

Inventor before: Zhao Yong

Inventor before: Ruan Honghao

CB03 Change of inventor or designer information
GR01 Patent grant
GR01 Patent grant