CN105164032B - 使用油或水包油乳液润滑转移板 - Google Patents
使用油或水包油乳液润滑转移板 Download PDFInfo
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- CN105164032B CN105164032B CN201480022112.5A CN201480022112A CN105164032B CN 105164032 B CN105164032 B CN 105164032B CN 201480022112 A CN201480022112 A CN 201480022112A CN 105164032 B CN105164032 B CN 105164032B
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- Prior art keywords
- acid
- oil
- ester
- lubricant compositions
- transfer blade
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- 238000012546 transfer Methods 0.000 title claims abstract description 53
- 238000005461 lubrication Methods 0.000 title description 18
- 239000007764 o/w emulsion Substances 0.000 title description 3
- 239000002569 water oil cream Substances 0.000 title description 3
- 239000000203 mixture Substances 0.000 claims abstract description 103
- 239000000314 lubricant Substances 0.000 claims abstract description 67
- 238000000034 method Methods 0.000 claims abstract description 31
- 230000003068 static effect Effects 0.000 claims abstract description 22
- 150000002148 esters Chemical class 0.000 claims description 47
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- 239000003995 emulsifying agent Substances 0.000 claims description 21
- 150000005846 sugar alcohols Polymers 0.000 claims description 15
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 13
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 9
- 150000002894 organic compounds Chemical class 0.000 claims description 9
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 7
- 125000004185 ester group Chemical group 0.000 claims description 6
- 230000001050 lubricating effect Effects 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
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- 238000010790 dilution Methods 0.000 claims 9
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- 239000004519 grease Substances 0.000 claims 2
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- -1 silica Alkane Chemical class 0.000 description 66
- 239000002253 acid Substances 0.000 description 49
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 41
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- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 8
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- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 7
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- 235000019388 lanolin Nutrition 0.000 description 7
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- 239000000787 lecithin Substances 0.000 description 7
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- 239000005720 sucrose Substances 0.000 description 7
- 229910019142 PO4 Inorganic materials 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
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- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 6
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Classifications
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
- C10M173/025—Lubricating compositions containing more than 10% water not containing mineral or fatty oils for lubricating conveyor belts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B65/00—Details peculiar to packaging machines and not otherwise provided for; Arrangements of such details
- B65B65/06—Details peculiar to packaging machines and not otherwise provided for; Arrangements of such details coated or treated with anti-friction or anti-sticking materials, e.g. polytetrafluoroethylene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/102—Aliphatic fractions
- C10M2203/1025—Aliphatic fractions used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/289—Partial esters containing free hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
Abstract
本发明的公开内容涉及转移板的润滑剂组合物和输送敞开容器通过静止转移板的方法。
Description
相关申请的交叉参考
本申请要求2013年3月11日提交的标题为“Lubrication of Transfer PlatesUsing Oil in Water Emulsions”的美国临时申请序列No.61/776,049的权益。
技术领域
本发明的公开内容涉及转移板润滑剂,和将在静态元件上的装填有液体产品的未密闭容器从装填器运输到施加盖板到容器上的装置的方法。
背景技术
在大多数运输步骤过程中,在商业容器的装填或包装操作中,密闭容器并驻留在移动传送带或链上。一个例外是转移板,其中敞开的容器在静止板上从它们由其装填的位置移动到它们在其中密闭的位置。这一转移板具有挑战性,因为容器是敞开的,且易于溢出其内容物。若它们溢出太多,则当检查时,它们会被拒绝。此外,若包装没有合适地对准进入到密封器内,则密闭可能差或者整个机器可能堵塞。这些担心因敞开的容器非常快速地移动这一事实而复杂化。针对这一背景技术,作出了本发明的公开内容。
发明概述
令人惊奇地,已发现,可使用包括油或水包油乳液的基本上含水润滑剂组合物,润滑转移板。特别地,已发现,存在分散的水不溶性化合物大大地降低了用于充分润滑转移板通常要求的表面活性剂的量。进一步令人惊奇的是,油加上乳化性表面活性剂一起的总浓度可以显著小于不含水不溶性油的常规容器转移润滑所要求的表面活性剂的浓度。
在一个方面中,本发明的公开内容提供沿着容器转移板润滑敞开容器的通路的方法,该方法包括提供包括油的含水分散体的润滑液体层。
附图简述
图1示出了罐转移板的示意图。
详细说明
在商业容器装填或包装操作中,诸如饮料容器之类的容器被装填并从装填点运输到装填线上的其他站以供随后的加工步骤,例如密闭,漂洗,温热或冷却,贴标签和包装。在大多数运输步骤过程中,密闭容器,且容器沿着传送带表面移动。当容器通过移动传送带或链运输时,可使用传送带润滑剂来降低容器和传送带表面之间的摩擦系数,从而有助于在容器和传送带之间平移速度(即,滑动)的差别,所述差别来自于容器的加速(其中包括速度的增加或降低或者方向上的变化)或者来自于位于下方移动的传送带上的容器的停止。一般地,通过移动传送带或链运输的容器被密闭,和容器相对于移动传送带的相对运动相对低(小于约40英尺/分钟相对运动)或甚至接近于零。在移动的传送带或链上运输的情况下,容器的加速度(例如加速、减速或方向变化)直接来自于容器和传送带之间的牵引力。在这一情况下,在没有降低摩擦系数到最小量的情况下,润滑剂控制了摩擦系数,否则在重力影响下,容器将简单地不会移动或者不可接受地往回或者横向移动或者与其他容器或设备接触。例举的润滑剂包括湿和干的润滑剂。
当已装填的未密闭的容器从它们被装填的位置移动到它们被密闭的位置时,出现了在运输容器中比较困难的步骤之一。
在运输敞开的饮料容器情况下,产品的溢出必须最小化,以便提供合适的液体体积以供销售。此外,被运输的敞开容器必须平稳地移动而没有过大的晃动或横向移动,因为在与密闭装置相互作用的点处敞开容器的错位将导致机器堵塞和损坏。由于搬运中的敞开容器从装填器到密闭装置以单一的纵列移动,因此,正向平移速度可达到250英尺/分钟的速度,或者甚至610英尺/分钟或更高或大致2200个罐/分钟。由于容器在静止板上移动,因此用于润滑的要求特别地苛刻,且重要的是实现并维持最小可能的摩擦系数。
由于容器相对于静止板非常高的相对运动且要求非常低的摩擦系数,因此,在装填器和密闭装置之间润滑静止转移板的方法不同于润滑移动传送带所使用的方法。特别地,通过维持板表面被含水润滑剂组合物淹没(flooded)来提供转移板的润滑。淹没是指板基本上被含水润滑剂组合物的胶浆(puddle)浸没且覆盖率为约0.05-约0.2mL/cm2(约0.5-2mm深)。可通过从转移板中心内的孔向上泵送润滑剂组合物来实现板的连续淹没。这示于图1中,图1一般地示出了罐10移动通过转移板12。润滑剂源(未示出)连接到润滑剂供应线14上。润滑剂供应线14与转移板12的底部上的一个或多个喷嘴或鼓泡器16流体连通。在操作过程中,润滑剂从润滑剂源流动经过润滑剂供应线14到达一个或多个喷嘴或鼓泡器16并离开转移板12的底部,以给移动通过静止转移板12的罐10提供润滑。喷嘴或鼓泡器可以与转移板一起冲洗,以便罐可以在它们之上通过,或者可定位它们到转移板的一侧上,以便罐可绕过它们。
与位于移动传送带或链上的容器的情形不同,并不容易地可测量移动容器和静止板之间的摩擦系数,因为得不到测量在传动链的钉齿和容器之间力的方法,所述力起到克服容器与板之间的摩擦移动容器的作用。为了在静止板上运输,当不存在震颤、抖动和旋转容器时,观察到有效的润滑。也可通过饮料的溢出量来测量润滑的有效性。使用装填高度检测仪装置,溢出的饮料量的方便和可容易获得的数值与从密闭装置下游的传送带中拒绝的密闭容器成比例。
对于有效的转移板操作来说,认为要求充足的液体润滑剂覆盖深度,以便允许已装填的未密闭容器“水面滑行(hydroplane)”或掠过液体润滑剂层的表面,使得基本上防止了在容器和静止板之间的实际接触。
因此,有效的转移板润滑可以被视为水动力润滑。纯粹的水动力润滑取决于液体(水-)、相对运动(-动力)的存在,液体的粘稠性能,和流体的会聚楔在其内产生的滑动表面之间的表面的几何形状。由于容器底部的几何形状可以显著偏离平坦或平面,因此并不总是可能维持容器和板之间流体的会聚楔。结果,容器并不总是可能保持与转移板完全物理分离。容器轻微的摇摆或振动被预期为在与静止板直接接触的容器底部上驱动相对非平面的几何形状特征,从而增加振动和摇摆,这将进一步增加自增强漩涡内的接触。
在静止的容器转移板上的润滑剂层内存在表面活性化合物可改进转移,最小化摇摆、震颤、溢出和机器堵塞事故。尽管不希望束缚于理论,但认为,在会聚的水动力流体层和接触故障的情况下,在静止板的润滑中表面活性化合物的作用是最小化容器和板之间的相互作用。
由于要求大体积的液体流动以维持板的淹没状况,因此要求高浓度的润滑剂化合物,通常超过约1500ppm润滑剂,例如Klenz Glide 20(一种商购于Ecolab Inc.的油酸润滑剂)或Lubodrive RX(一种商购于Ecolab Inc.的表面活性剂润滑剂)。大体积的流动和高的润滑剂浓度的组合导致过度浪费,成本和环境影响。此外,可因水硬度或溢出的饮料引起的失活,导致降低润滑剂化合物的有效性。在因水硬度导致的失活情况下,可要求软化制备润滑剂操作溶液所使用的水,使用环境不友好的多价螯合剂,或这二者。通常通过与溢出饮料的相互作用引起的失活的唯一解决方案是增加表面活性化合物的浓度,以允许一些牺牲性损失,这意味着更多的润滑剂和进一步糟糕的浪费和环境影响。
组合物
本发明的公开内容一般地涉及使用含悬浮或乳化油的基本上含水的润滑剂组合物来润滑静止转移板的方法。油是指与水不混溶的化合物或化合物的混合物,它们在25℃下在水中不可溶,且当与水混合时,得到第二分离的液相或者形成分散胶体(第二互不混溶相的胶状体),这会引起组合物显示出丁达尔效应,半透明或不透明。油也可包括基本上在水中不混溶或者不可溶的材料,从而提供小于约1000ppm的溶解度。
所公开的组合物提供润滑剂膜或含油的悬浮的细亚微米尺寸的分散胶体的胶浆,这会降低容器和静止转移板之间的摩擦系数,从而最小化震颤,旋转和产品溢出。该润滑剂组合物可优选通过喷洒它而施加到静止转移板上,或者它可作为连续物流,例如通过向上泵送穿过在静止板的接触容器的顶表面上的垂直定位的孔隙而施加(如图1所示)。
油可以是天然或合成的。“天然”是指从天然来源中萃取、纯化或衍生且没有化学改变或反应或者制备或断裂共价键的水不溶性油化合物。
在一些实施方案中,油是水不溶性油,它可作为乳液掺入到润滑剂内。因此,在一些实施方案中,所公开的组合物包含任选的乳化剂。所公开的组合物也可包括其他额外的功能材料。
所公开的组合物可以浓缩物或者以备用产品形式提供。所述“浓缩物”是指被稀释形成备用产品的产品。“备用产品”是指施加到转移板上的产品。由于施加到转移板上的润滑剂组合物大多数是水,因此有益的可以是提供浓缩物形式的润滑剂组合物,在施加到转移板上之前,将其稀释。
油
所公开的组合物包含油。例举的油类(也称为润滑剂)可以是有机硅-基或亲脂-基的。有用的油可以是两种或更多种不同化合物的混合物。优选的油类(不管是单一的化合物还是化合物的混合物)在0℃以上的温度下为液体。
有机硅-基润滑剂
例举的有机硅-基润滑剂是有机硅乳液。使用优选的乳化剂制备的合适的有机硅乳液包括E2175高粘度聚二甲基硅氧烷(商购自Lambent Technologies,Inc.的60%的硅氧烷乳液)、E2140聚二甲基硅氧烷(商购自Lambent Technologies,Inc.的35%的硅氧烷乳液)、E2140 FG食品级中等粘度聚二甲基硅氧烷(商购自Lambent Technologies,Inc.的35%的硅氧烷乳液)、Dow Corning HV600乳液(获自Dow Corning的非离子55%三甲基甲硅烷基封端的聚二甲基硅氧烷分散体)、Dow Corning 1664乳液(获自Dow Corning的非离子50%三甲硅基封端的聚二甲基硅氧烷分散体)、Dow Corning 1101(获自Dow Corning的,基于硅烷醇封端的高粘度聚二甲基硅氧烷的,非离子的,50%浓度的活性乳液)、Dow Corning346(获自Dow Corning,Midland MI的非离子的,60%浓度的活性三甲基甲硅烷基封端的聚二甲基硅氧烷乳液)、GE SM 2068 A(获自General Electric Silicones,Wilton NY的阴离子35%硅烷醇封端的聚二甲基硅氧烷分散体)、GE SM 2128(获自General ElectricSilicones的非离子35%三甲基甲硅烷基封端的聚二甲基硅氧烷分散体)、GE SM 2135(获自General Electric Silicones的非离子50%三甲基甲硅烷基封端的聚二甲基硅氧烷分散体)、GE SM 2138(获自General Electric Silicones的非离子60%硅烷醇封端的聚二甲基硅氧烷分散体)、GE SM 2140(获自General Electric Silicones的非离子50%三甲基甲硅烷基封端的聚二甲基硅氧烷分散体)、GE SM 2154(获自General Electric Silicones的非离子50%甲基己基异丙基苄基硅氧烷分散体)、GE SM 2162(获自General ElectricSilicones的非离子50%三甲基甲硅烷基封端的聚二甲基硅氧烷分散体)、GE SM 2163(获自General Electric Silicones的非离子60%三甲基甲硅烷基封端的聚二甲基硅氧烷分散体)、GE SM 2167(获自General Electric Silicones的阳离子50%三甲基甲硅烷基封端的聚二甲基硅氧烷分散体)、GE SM 2169(获自General Electric Silicones的非离子60%三甲基甲硅烷基封端的聚二甲基硅氧烷分散体)、GE SM 2725(获自General ElectricSilicones的阴离子50%硅烷醇封端的聚二甲基硅氧烷分散体)、KM 901(获自Shin-EtsuSilicones of America,Inc.Akron,OH的非离子50%三甲基甲硅烷基封端的聚二甲基硅氧烷分散体)、Fluid Emulsion E10(获自Wacker Silicones,Adrian,MI的非离子38%有机硅乳液)、Fluid Emulsion E1044(获自Wacker silicones,Adrian,MI的非离子39%浓度的有机硅乳液)、KM 902(获自Shin-Etsu Silicones of America,Inc.Akron,OH的非离子50%三甲基甲硅烷基封端的聚二甲基硅氧烷分散体)以及等同产品。优选的有机硅乳液典型地含有约30wt%-约70wt%的水。
非-水-混溶的有机硅材料(例如,非水溶性有机硅流体和非水分散性有机硅粉末)也可在该润滑剂中使用,若与合适的乳化剂(例如,非离子、阴离子或阳离子乳化剂)结合的话。应当仔细避免使用在塑料容器内促进环境应力开裂的乳化剂或其他表面活性剂。
聚二甲基硅氧烷乳液是优选的有机硅材料。
亲脂-基润滑剂。油或润滑剂可以是亲脂性化合物。该亲脂性化合物可以用其化学结构描述。例如,合适的亲脂性化合物包括但不限于:(1)包括两个或者多个酯连接的水不溶性有机化合物;(2)包括三个或者更多个氧原子的水不溶性有机化合物;(3)含三个或更多个氧原子、一个酯基团(其可以包括这些氧原子中的两个)和一个或多个剩余的或游离的羟基的水不溶性有机化合物;(4)长链羧酸(例如脂肪酸)与短链(即5个或者更少的碳原子)醇(例如甲醇)的酯;(5)包括具有2个或更多个羟基的二-、三-或者多元醇(例如甘油)的酯,其中所述羟基各自与羧酸偶联为酯基;及其混合物。
该亲脂性化合物也可用它们的化学组分来描述。例如,合适的亲脂性化合物包括单羧基脂肪酸和二-与多-羧酸化合物的酯。该酯的合适的脂肪酸组分包括辛酸、壬酸、癸酸、十一烷酸、十二烷酸、棕榈酸、硬脂酸、油酸或者其混合物。该酯中的合适的二-及多-羧酸组分包括己二酸、琥珀酸、戊二酸、癸二酸、邻苯二甲酸、偏苯三酸和其混合物。在与二-,三-或多元醇的酯中,合适的羧酸组分包括上面所列的那些,以及例如,一元羧酸组分,例如丁酸、己酸、庚酸或其混合物。
酯类可以包括任何各种醇部分,例如单羟基脂肪醇类和二-和多羟基化合物。该酯中的合适的单羟基醇类组分包括伯脂肪族醇类,例如脂肪族烃醇类,例如甲醇、乙醇,以及直链和支链的3-25个碳原子的伯醇类。该酯中的合适的二-和多元醇类组分包括含有2-约8个羟基的那些,例如亚烷基二元醇,例如乙二醇,二甘醇,新戊二醇,四甘醇或者其混合物。该酯中的另外的合适的醇类组分包括甘油,赤藓糖醇,甘露醇,山梨糖醇,葡萄糖,三羟甲基丙烷(TMP),季戊四醇,二季戊四糖醇,脱水山梨糖醇,或者其混合物。
该酯可以包括任何的各种羧酸和醇残基,该残基提供了水不溶性(在室温和大于约0.1重量%的浓度时不能溶解在水中产生透明溶液)的酯,该酯是液体、半固体或者低熔点固体。在所公开的润滑剂组合物中,亲脂性化合物可以是胶态分散体中的分散相。
其中R3、R4和R5独立地是直链或者支链的、饱和和/或不饱和的、任选地羟基-和/或环氧基-取代的具有6-22或12-18个碳原子的残基。
该甘油三酯可以是天然来源或者是合成制备的。在一个实施方案中,该甘油三酯具有链长为6到22个碳原子的直链和饱和的亚烷基残基。它们任选是羟基-和/或环氧官能化的物质,例如蓖麻油或者氢化蓖麻油,环氧化蓖麻油,不同环氧值的环氧化蓖麻油与水的开环产物以及平均1-100mol、20-80mol或者甚至40-60mol在这些所述的甘油三酯上的加成产物。
合适的甘油三酯包括商购于Cognis的以商品名Myritol 331,Myritol 312,Myritol 318,Terradrill V988,the Terradrill
其中R6、R7和R8独立地表示直链或支链的、饱和的和/或不饱和的具有6-22个(例如12-18个)碳原子的残基或者H,条件是两个残基R7和R8中至少一个是H。
合适的单甘油酯类,二甘油酯类或者三甘油酯类包括下面的酸的酯类:己酸,辛酸,2-乙基己酸,癸酸,月桂酸,异十三烷酸,肉豆蔻酸,棕榈酸,棕榈油酸,硬脂酸,异硬脂酸,油酸,反油酸,岩芹酸,亚油酸,亚麻酸,桐酸,花生酸,顺二十碳烯酸,山萮酸,芥酸或者其混合物。合适的甘油酯类包括月桂酸甘油酯类,棕榈酸甘油酯类,硬脂酸甘油酯类,异硬脂酸甘油酯类,油酸甘油酯类,山萮酸甘油酯类,芥酸甘油酯类,或者其混合物且包括表现出约50-约95wt%或约60-约90wt%的单甘油酯含量的那些。
合适的磷脂类包括例如磷脂酸、天然卵磷脂、心磷脂、溶血磷脂、溶血卵磷脂、缩醛磷脂、鞘磷脂、神经磷脂。合适的磷脂类包括磷脂酰胆碱、磷脂酰乙醇胺、磷脂酰肌醇、或者N-酰基磷脂酰乙醇胺、或者它们的混合物。合适的磷脂类包括卵磷脂类。卵磷脂类包括已经被去油的、分馏的、喷雾干燥的、酰化的、水解的、羟基化的或者氢化的粗制卵磷脂。它们可商购。合适的卵磷脂包括大豆卵磷脂。如本文中使用的,通用术语“卵磷脂”包括磷脂类。
磷脂酸类是在1-sn-位和2-位已经用脂肪酸酯化(1-sn-位:主要是饱和的,2-位:主要是单-或者多未饱和的)或在3-sn原子上用磷酸酯化的甘油衍生物。磷酸酯基团可以用氨基醇酯化,所述氨基醇例如胆碱(卵磷脂=3-sn-磷脂酰胆碱)、2-氨基乙醇(乙醇胺)、L-丝氨酸(脑磷脂=3-sn-磷脂酰乙醇胺或者sn-磷脂酰-L-丝氨酸),用肌醇酯化而得到磷酸肌醇[1-(3-sn-磷脂酰)-D-肌醇],用甘油酯化而得到磷脂酰甘油。
心磷脂类(1,3-二磷脂酰甘油)是通过甘油连接的两个磷脂酸的磷脂。当通过来自磷脂(例如溶血卵磷脂)中的磷脂酶A裂解酰基团时获得溶血磷脂。磷脂还包括缩醛磷脂,其中代替脂肪酸,醛(烯醇醚的形式)被键合在1-位上。鞘磷脂基于鞘氨醇或者植物鞘氨醇的基本结构。
在本发明的组合物中使用的合适的磷脂包括可商购于Lipoid的以商品名S 20S,Lipoid S 75,Lipoid S 100,Lipoid S 100-3,Lipoid S 75-3N,Lipoid SL 80和LipoidSL 80-3销售的那些;商购于德国Phospholipon,Cologne的以商品名Phospholipon 85G,Phospholipon 80,Phospholipon 80H,Phospholipon 90G,Phospholipon 90H,Phospholipon 90NG,Phospholipon 100H,Phosal 35B,Phosal 50G,Phosal 50SA,Phosal53MCT和Phosal 75SA销售的那些;商购于American Lecthin Company,Oxford CT的Alcolec Z-3;商购于Cargill(Degussa Texturant Systems)的以商品名Emulfluid F30,Emulfluid,Lipotin NE,Lipotin 100,Lipotin SB,Lipotin 100J,Lipotin H,LipotinNA,Lipotin AH,and Lipopur销售的那些;商购于Cognis的以商品名Terradrill V 408和Terradrill V 1075销售的那些;商购于Sternchemie的以商品名Yellowthin 100,Yellowthin 200,Lecistar Sun 100,和Yellowthin Sun 200销售的那些;和商购于Lambent Technologies,Gurnee,IL的Lanchem PE-130K。
合适的亲脂性化合物还包括下述:甘油的偏脂肪酸酯;脱水山梨糖醇的部分或者高级脂肪酸酯;二元醇或者聚(亚烷基二元醇)化合物的脂肪酸二酯;多元醇例如蔗糖、季戊四醇或者二季戊四醇的脂肪酸酯;脂肪酸的甲酯;苯甲酸的脂肪醇酯;对苯二酸或者间苯二酸的脂肪醇酯;羊毛脂或者羊毛脂衍生物;三羟甲基丙烷的脂肪酸酯,或者其混合物。
甘油与直链或支链的长链(大于约8个碳原子)脂肪酸的合适的偏酯类包括甘油单油酸酯,甘油单蓖麻醇酸酯,甘油单硬脂酸酯,和甘油单妥尔油脂肪酸酯(例如获自LambentTechnologies的Lumulse GMO-K,Lumulse GMR-K,Lumulse GMS-K和Lumulse GMT-K,获自Goldschmidt Chemical Corporation,Hopewell,VA的Gurnee IL和Tegin OV),或者其混合物。合适的偏甘油酯类还包括商购于Cognis的以商品名Cutina EGMS,Cutina GMS-SE,Cutina GMS V,Cutina MD,or Cutina AGS销售的那些。
合适的部分和高级脱水山梨糖醇酯类包括例如与直链或支链的长链(大于约8个碳原子)脂肪酸的二-或者三-酯类,例如脱水山梨糖醇三硬脂酸酯,和脱水山梨糖醇三油酸酯,和脱水山梨糖醇倍半油酸酯(例如获自Lambent Technologies,Gurnee IL的LumisorbSTSK,和获自Lipo Chemicals,Paterson NJ的Liposorb TO以及Liposorb SQO),或者这些化合物的混合物。
二元醇或者聚(亚烷基二元醇)化合物与直链或支链的长链(大于约8个碳原子)脂肪酸的合适的二酯包括新戊二醇二辛酸酯/二癸酸酯和PEG-4二庚酸酯(例如获自LipoChemicals,Paterson NJ的Liponate NPCG-2和Liponate 2-DH)。
合适的多元醇的脂肪酸酯包括多元醇脂肪酸多酯,该术语是指用直链或者支链的长链(大于约8个碳原子)脂肪酸基团将其两个或者更多个羟基酯化的多元醇。例如,所述多元醇可以用四个或更多个脂肪酸基团酯化。合适的多元醇脂肪酸多酯包括每一蔗糖分子平均具有至少四个或五个酯键的蔗糖多酯;所述脂肪酸链可以具有约8个至约24个碳原子。其它合适的多元醇脂肪酸多酯是酯化连接的烷氧基化甘油,其中包括含聚醚二元醇连接链段的那些和含多羧酸酯连接链段的那些。合适的多元醇包括含有至少两个游离羟基的脂族或芳族化合物,且可包括诸如下述主链:饱和及不饱和直链和支链脂族烃;饱和及不饱和环状脂族烃,其中包括杂环脂族烃;或单核或多核芳族烃,其中包括杂环芳族烃。多元醇包括碳水化合物和无毒的二元醇类。合适的蔗糖的脂肪酸酯包括蔗糖的豆油酸酯脂肪酸酯和蔗糖的硬脂酸酯脂肪酸酯(例如可从Proctor and Gamble Chemicals,Cincinnati OH获得的Sefose1618S和Sefose 1618H)。合适的季戊四醇和二季戊四醇的脂肪酸酯包括季戊四醇四辛酸酯/四己酸酯和二季戊四醇六辛酸酯/六己酸酯(例如可从Lipo Chemicals,PatersonNJ获得的Liponate PE-810和Liponate DPC-6)。
合适的脂肪酸甲基酯包括棕榈酸甲酯和硬脂酸甲酯(例如获自Proctor andGamble Chemicals,Cincinnati OH的CE-1695和CE-1897)。
合适的苯甲酸的脂肪醇酯包括苯甲酸C12-C15烷基酯(例如获自Lipo Chemicals,Paterson NJ的Liponate NEB)。
合适的对苯二酸或者间苯二酸的脂肪醇酯包括对苯二甲酸二辛基酯。
合适的偏苯三酸的脂肪醇酯包括偏苯三酸十三烷基酯(例如获自LipoChemicals,Paterson NJ的Liponate TDTM)。
合适的羊毛脂和羊毛脂衍生物包括氢化的羊毛脂和羊毛脂醇(例如获自RitaCorporation,Crystal Lake IL的Technical Grade Lanolin,Ritawax和Supersat)。
合适的三羟甲基丙烷的脂肪酸酯包括三羟甲基丙烷三油酸酯和三羟甲基丙烷三癸酸酯/辛酸酯(例如获自Cognis的Synative ES2964和获自德国Uniqema New Castle的Priolube 3970)。
在一种实施方案中,亲脂性化合物是矿物油或者包括矿物油。
在一种实施方案中,亲脂性化合物是或者包括长链(大于约8个碳原子)脂肪酸化合物,其中包括衍生自植物或者动物脂肪或油的皂化的脂肪酸,例如妥尔油脂肪酸,椰油脂肪酸,油酸,蓖麻油酸或者羧酸封端的羟基官能的脂肪酸的短链聚合物,例如蓖麻油酸及其盐(例如获自Clariant Corporation,Mount Holly NJ的Hostagliss L4),或这些化合物的混合物。合适的脂肪酸亲脂性化合物包括己酸,月桂酸,肉豆蔻酸,油酸,硬脂酸(例如,获自Proctor and Gamble Chemicals,Cincinnati OH的C-698,C-1299,C-1495,OL-800和V-1890),或者其混合物。
例举的亲脂性化合物包括甘油的三(癸酸酯/辛酸酯);辛酸甘油三酯、癸酸甘油三酯、椰油酸甘油三酯;蔗糖的豆油脂肪酸酯;聚(乙二醇)的二庚酸酯;和三羟甲基丙烷三油酸酯。
其他例举的油
合成酯油。所述油可以是合成酯油。合适的合成酯油包括单羧基脂肪酸和单-,二-和多元醇化合物的酯。该酯中的合适的单羧基脂肪酸组分包括苯甲酸,辛酸、壬酸、癸酸、十一烷酸、十二烷酸、肉豆蔻酸、棕榈酸、硬脂酸、油酸、山萮酸或其混合物。该酯可包括任何的各种醇部分,例如单羟基脂肪醇,和二-及多羟基化合物。该酯中的合适的单羟基醇组分包括伯脂族醇,例如脂族烃醇,例如甲醇,乙醇,和具有3-25个碳原子的直链和支链伯醇。该酯中的合适的二-和多元醇组分包括含有2-约8个羟基的那些,例如亚烷基二醇类,例如乙二醇,二甘醇,新戊二醇,四甘醇或其混合物。该酯中的额外的合适的醇组分包括甘油,赤藓糖醇,甘露醇,山梨糖醇,葡萄糖,蔗糖,三羟甲基丙烷(TMP),季戊四醇,二季戊四糖醇,脱水山梨糖醇,或者其混合物。
合适的合成酯油包括二-和多羧酸与单羟基醇化合物的酯。该酯中的合适的二-和多羧酸组分包括己二酸,丁二酸,戊二酸,癸二酸,对苯二甲酸,间苯二甲酸,偏苯三酸,及其混合物。该酯中的合适的单羟基醇组分包括伯脂族醇,例如脂族烃醇,例如甲醇,乙醇,和具有3-25个碳原子的直链和支链伯醇。
合成酯油可包括任何的各种羧酸和醇残基,该残基提供了水不溶性(在室温和大于约0.1重量%的浓度时不能溶解在水中产生透明溶液)的酯,该酯是液体、半固体或者低熔点固体。在所公开的润滑剂组合物中,优选的合成酯油包括合成生产的甘油三酯化合物和三羟甲基丙烷的三酯,例如三羟甲基丙烷三椰油酸酯,三羟甲基丙烷三(己酸酯/辛酸酯)和甘油三(己酸酯/辛酸酯)。
游离脂肪酸。所述油可以是游离脂肪酸。合适的游离脂肪酸包括辛酸,壬酸,癸酸、十一烷酸、十二烷酸、肉豆蔻酸、棕榈酸、硬脂酸、油酸、山萮酸或其混合物。
烃。所述油可包括合成或天然烃化合物。合适的合成烃包括聚丁烯类,例如Indopol(Ineos Oligomers,League City TX),氢化聚丁烯类,例如Panalane(IneosOligomers),聚(α烯烃),例如SpectraSyn产品(ExxonMobil Chemical,Houston TX),和合成异烷属烃流体,例如Isopar(ExxonMobil Chemical)。
所公开的备用组合物可含有约0.0001wt%-约0.15wt%,约0.005wt%-约0.15wt%,约0.001wt%-约0.10wt%,约0.001wt%-约0.05wt%的油,约0.0001-约0.001wt%的油,或约0.0005wt%-约0.001wt%。所公开的浓缩组合物可含有约0.1wt%-约50wt%,约0.5wt%-约20wt%,或约0.5wt%-约5wt%的油。施加到转移板上的润滑油的用量优选为约1至约250g/h,约1至约100mg/h,或约1至约20mg/h。
乳化剂
所公开的组合物可任选地包括乳化剂,以辅助增溶油。例举的乳化剂包括非离子表面活性剂,例如:
(1)甘油与直链或支链的长链(大于约8个碳原子)脂肪酸的单-和二-酯类,例如单油酸甘油酯,单蓖麻醇酸甘油酯,单硬脂酸甘油酯,和单妥尔油酸甘油酯(例如获自LambentTechnologies,Gurnee IL的Lumulse GMO-K,Lumulse GMR-K,Lumulse GMS-K和LumulseGMT-K,和获自Goldschmidt Chemical Corporation,Hopewell,VA的Tegin OV),或者这些表面活性剂的混合物;
(2)与直链或支链的长链(大于约8个碳原子)脂肪酸的多甘油基单酯类,例如单油酸甘油三酯(例如获自Lambent Technologies,Gurnee IL的Lumulse PGO-K),或者这些表面活性剂的混合物;
(3)甘油与直链或支链的长链(大于约8个碳原子)脂肪酸的乙氧基化的单-和二-酯类,例如聚(氧化乙烯)甘油基单月桂酸酯(例如获自Lambent Technologies,Gurnee IL的Lumulse POE(7)GML和Lumulse POE(20)GMS-K),或者这些表面活性剂的混合物;
(4)与直链或支链的长链(大于约8个碳原子)脂肪酸的脱水山梨糖醇酯类,例如脱水山梨糖醇单月桂酸酯,脱水山梨糖醇单棕榈酸酯,脱水山梨糖醇单硬脂酸酯和脱水山梨糖醇单油酸酯(例如获自德国Uniqema,New Castle的SPAN系列20,40,60和80,和获自LambentTechnologies,Gurnee IL的Lumisorb SMO),或者这些表面活性剂的混合物;
(5)与直链或支链的长链(大于约8个碳原子)脂肪酸的乙氧基化的脱水山梨糖醇酯类,例如聚氧化乙烯(20)脱水山梨糖醇单月桂酸酯(聚山梨酸酯20),聚氧化乙烯(20)脱水山梨糖醇单棕榈酸酯(聚山梨酸酯40),聚氧化乙烯(20)脱水山梨糖醇单硬脂酸酯(聚山梨酸酯60)和聚氧化乙烯(20)脱水山梨糖醇单油酸酯(聚山梨酸酯80)(例如获自德国Uniqema,New Castle的TWEEN系列20,40,60和80),或者这些表面活性剂的混合物;
(6)乙氧基化的蓖麻油类,例如PEG-5蓖麻油,PEG-25蓖麻油,和PEG-40蓖麻油(例如获自Lambent Technologies,Gurnee IL的Lumulse CO-5,Lumulse CO-25和Lumulse CO-40),或者这些表面活性剂的混合物;
(7)乙二醇和聚(乙二醇)与直链或支链的长链(大于约8个碳原子)脂肪酸的单-和二-酯类,例如二硬脂酸乙二醇酯,PEG-400单油酸酯,PEG-400单月桂酸酯,PEG-400二月桂酸酯和PEG-4二庚酸酯(例如获自Lipo Chemicals,Paterson NJ的Lipo EGDS,获自LambentTechnologies,Gurnee IL的Lumulse 40-OK,Lumulse 40-L和Lumulse 42-L和LipoChemicals,Paterson NJ生产的LIPONATE 2-DH),或者这些表面活性剂的混合物;
(8)EO-PO嵌段共聚物,例如聚(环氧乙烷)-聚(环氧丙烷)-聚(环氧乙烷)嵌段共聚物和聚(环氧丙烷)-聚(环氧乙烷)-聚(环氧丙烷)嵌段共聚物(例如获自BASFCorporation,Florham Park NJ的Pluronic和Pluronic R系列产品),或者这些表面活性剂的混合物;
(9)将环氧乙烷和/或环氧丙烷加成到直链或支链的长链(C8或者更高的)脂肪醇上所形成的醇乙氧基化物,醇丙氧基化物和醇乙氧基化物丙氧基化物,例如聚(环氧乙烷)十一烷基醚,与(C12-C15)线型伯醇的聚(环氧乙烷)醚,与(C14-C15)线型伯醇的聚(环氧乙烷)醚,和乙氧基化丙氧基化的C8-10醇类(例如获自Air Products,Inc.,AllentownPA的Tomadol 1-3醇乙氧基化物,Tomadol 25-7醇乙氧基化物和Tomadol 45-7醇乙氧基化物;和获自Rhodia,Cranbury NJ的Antarox BL-214),或者这些表面活性剂的混合物;
(10)将环氧乙烷加成到直链和支链的烷基酚化合物上所形成的醇乙氧基化物,例如与壬基酚的聚(环氧乙烷)醚(例如获自HuntsmanChemical Corporat ion,TheWoodlands TX的Surfonic N95),或者这些表面活性剂的混合物;
(11)含有8-22个碳原子的烷基的烷基化的单-、二-和低聚糖苷和含有8-22个碳原子的烷基的乙氧基化的烷基化的单-、二-和低聚糖苷,例如与(C8-C14)直链伯醇的聚(D-吡喃葡萄糖)醚(例如获自Cognis North America,Cincinnati OH的Glucopon 425N/HH),或者这些表面活性剂的混合物;
(12)由直链或支链的长链(大于约8个碳原子)脂肪酸形成的酰胺化合物,例如椰酸二乙醇酰胺和油酸二乙醇酰胺(例如获自Stepan Corporation,Northfield IL的Ninol40-CO和Ninol 201,和获自Clariant Corporation,Mount Holly,NC的Hostacor DT),或者这些表面活性剂的混合物;
(13)将环氧乙烷加成到由直链或支链的长链(大于约8个碳原子)脂肪酸所形成的酰胺化合物上而形成的乙氧基化物化合物,例如与椰酸乙醇酰胺的聚(环氧乙烷)醚(例如获自Stepan Corporation,Northfield IL的Ninol C-5),或者这些表面活性剂的混合物;
(14)非离子的有机硅表面活性剂,例如与甲基双(三甲基甲硅烷氧基)甲硅烷基丙醇的聚(环氧乙烷)醚(例如获自Momentive Performance Materials,Wilton NJ的SilwetL 77),或者这些表面活性剂的混合物。
(15)磷酸三烷基酯类,或者磷酸三烷基酯类的混合物;
(16)进一步用短链一元羧酸进行酯化的甘油与直链或支链的长链(大于约8个碳原子)脂肪酸的单-和二-酯类,例如甘油单硬脂酸酯乳酸酯(例如获自Danisco,CopenhagenDenmark的Grindsted Lactem P22),或者这些表面活性剂的混合物;或者
(17)这样的表面活性剂的混合物。
例举的乳化剂包括卵磷脂,单硬脂酸乙氧基脱水山梨糖醇酯,单油酸甘油酯和20mol乙氧基化的蓖麻油。
所公开的组合物可包括乳化剂的组合,其中包括具有不同HLB值的乳化剂。
随着时间变化,乳液倾向于恢复油水分离的稳定状态,该过程通过乳化剂而延缓。可以理解,在本发明的上下文中,“稳定的乳液”不仅仅指的是热力学稳定的体系,而且还包括其中分解动力已经被很大程度的地变慢的体系,即,亚稳定体系。在某些实施方案中,所公开的乳液不是物理相分离的,不表现出乳状液分层或者聚结,或者不形成沉淀。在一个实施方案中,该乳液是足够稳定,这样它在所公开的润滑剂组合物储存和运输的条件下是稳定的。例如,在一个实施方案中,本发明的稳定的乳液在4-50℃下在一个月内不发生相分离,或者在这样的温度下甚至在两个月或者三个月内不发生相分离。
所公开的备用组合物可含有约0.0001wt%-约0.05wt%,约0.0001wt%-约0.02wt%,或约0.0005wt%-约0.05wt%的乳化剂。所公开的浓缩组合物可含有约0.1wt%-约10wt%,约0.1wt%-约4wt%,或约0.1wt%-约1wt%的乳化剂。
在一些实施方案中,在备用组合物内的油和乳化剂的浓缩物小于5000ppm,小于2000ppm,小于1500ppm,小于1000ppm,或小于500ppm。
额外的组分
所公开的组合物可视需要任选地包括额外的组分。例如,该组合物可含有助剂,例如亲水稀释剂,抗微生物剂,稳定或偶联剂,表面活性剂,腐蚀抑制剂,螯合剂,pH缓冲剂,和水溶性润滑剂。
亲水稀释剂
例举的亲水稀释剂包括水,醇例如异丙醇,多元醇例如乙二醇和甘油,酮例如甲乙酮,和环醚例如四氢呋喃。若存在的话,则亲水稀释剂可占施加到转移板上的组合物的大多数。
抗微生物剂
所公开的组合物可任选地包括抗微生物剂。例举的抗微生物剂包括消毒剂、杀菌剂和防腐剂。一些非限定性实例包括酚类(其包括卤素-和硝基酚和取代双酚,例如4-己基间苯二酚、2-苄基-4-氯苯酚及2,4,4′-三氯-2′-羟基二苯醚);有机酸和无机酸以及相应的脂和盐,例如脱氢乙酸、过氧羧酸、过氧乙酸、过氧辛酸、甲基对羟基苯甲酸;诸如季铵化合物之类的阳离子试剂;胺或胺盐,例如油基二氨基丙烷双乙酸盐、椰油基二氨基丙烷双乙酸盐、月桂基丙烷基二胺双乙酸盐、二甲基月桂基醋酸铵;异噻唑啉酮类化合物,例如2-甲基-4-异噻唑啉-3-酮和5-氯-2-甲基-4-异噻唑啉-3-酮;鏻化合物,例如四羟甲基季鏻硫酸盐(THPS),醛,例如戊二醛,抗菌染料,例如吖啶、三苯甲烷染料和奎宁;以及包含碘和氯类化合物的卤素类。可大量使用抗菌剂以提供所需的抗微生物性能。
稳定剂/偶联剂
所公开的组合物可任选地包括稳定剂或偶联剂,以保持组合物均匀。例举的稳定剂或偶联剂包括异丙醇、乙醇、脲、辛烷磺酸盐和诸如异己二醇、丙二醇等的二醇。
清洁剂/分散剂
所公开的组合物可任选地包括清洁剂或分散剂。一些清洁剂和分散剂的实例包括烷基苯磺酸、烷基膦酸及它们的钙、钠和镁盐、聚丁烯丁二酸衍生物、有机硅表面活性剂、氟表面活性剂以及含有连接到油增溶性脂肪烃链上的极性基的分子。
合适的分散剂的一些实例包括烷氧基化脂肪烷基单胺和二胺,例如椰油基双(2-羟乙基)胺、聚氧乙烯(5)-椰油基胺、聚氧乙烯(15)-椰油基胺、牛脂双(-2羟乙基)胺、聚氧乙烯(15)胺、聚氧乙烯(5)油基胺等。
腐蚀抑制剂
所公开的组合物可任选地包括腐蚀抑制剂。例举的腐蚀抑制剂包括多羧酸,例如短链羧二酸、三酸的多羧酸,还有磷酸酯,以及它们的组合。有用的磷酸酯包括烷基磷酸酯、单烷基芳基磷酸酯、二烷基芳基磷酸酯、三烷基芳基磷酸酯、及其混合物,例如获自WitcoChemical Company的Emphos PS 236。其他有用的缓蚀剂包括三唑类,例如苯并三唑、甲苯三唑和巯基苯并噻唑,以及与如下物质的组合:膦酸酯,例如1-羟基乙叉-1,1-二膦酸,和表面活性剂,例如油酸二乙醇酰胺和椰油基两性羟基丙磺酸钠等。有用的腐蚀抑制剂包括多羧酸,例如二羧酸。优选的酸包括己二酸、戊二酸、丁二酸及其混合物。
螯合剂
所公开的组合物可任选地包括螯合剂或多价螯合剂。例举的多价螯合剂包括乙二胺四乙酸(EDTA),亚氨基二琥珀酸钠盐,反式-1,2-二氨基环己烷四乙酸一水合物,二亚乙基三胺五乙酸,次氮基三乙酸的钠盐,N-羟基亚乙基二胺三乙酸的五钠盐,N,N-二(β-羟乙基)甘油的三钠盐,葡庚糖酸钠的钠盐,等等。
水溶性润滑剂
所公开的组合物可任选地包括与水混溶或者水溶性乳化剂。例举的水溶性乳化剂包括含羟基的化合物,例如多元醇(如甘油和丙二醇);聚烷撑二醇(例如,CarbowaxTM系列的聚乙二醇和甲氧基聚乙二醇);环氧乙烷和环氧丙烷的线型共聚物(例如UconTM50-HB-100水溶性环氧乙烷:环氧丙烷共聚物);以及脱水山梨醇酯(例如TweenTM系列20,40,60,80和85聚氧乙烯脱水山梨醇单油酸酯及SpanTM系列20,80,83和85脱水山梨醇酯)。其他例举的与水混溶的润滑剂包括磷酸酯,胺及它们的衍生物。也可使用衍生物,例如以上润滑剂的偏酯或乙氧基化物。在一些实施方案中,所公开的组合物基本上不含与水混溶的润滑剂。
使用方法
罐或容器转移应用涉及用稀释在水中的润滑剂组合物淹没转移板。可用各种材料(其中包括不锈钢或超高分子量聚乙烯)制造转移板。该板典型地在底部具有孔以及具有与该孔连通的喷嘴或鼓泡器以供分配润滑剂组合物到板上。对于转移板的润滑来说,鼓泡器是施加润滑剂到转移板上的最常见的方法。然而,要理解,喷嘴也可单独或者与转移板下方的鼓泡器联合喷洒润滑剂到转移板的顶部和侧面上。
如前所述,典型地通过维持转移板的表面被含水润滑剂组合物淹没,从而提供转移板的润滑。淹没是指板基本上被含水润滑剂组合物的胶浆浸没且覆盖率为约0.05-约0.2mL/cm2(约0.5-2mm深)。转移板可具有1,2,3,4,5或6个鼓泡器。为了淹没转移板,每一鼓泡器优选每小时分配约1-约10加仑,约2-约8加仑,或约6-约8加仑备用的润滑剂组合物。在操作期间,喷嘴可连续或间断地淹没板。
所公开的润滑剂可与各种容器一起使用,所述容器可以转移通过静止转移板,其中包括饮料容器,食品容器,家用或者商用清洁产品容器,和用于油类、抗冻流体或者其它工业流体的容器。所述容器可以由多种材料制成,所述材料包括玻璃,塑料(例如聚烯烃例如聚乙烯和聚丙烯,聚苯乙烯,聚酯例如PET和聚萘二甲酸乙二醇酯(PEN),聚酰胺、聚碳酸酯,和它们的混合物或者共聚物),金属(例如铝、锡或者钢),纸(例如未处理的、处理的、上蜡的或者其涂布的纸),陶瓷,和两种或者更多种这些材料的层压体或者复合体(例如PET、PEN或者它们的混合物与其它塑料材料的层压体)。所述容器可以具有多种尺寸和型式,其中包括硬纸盒(例如上蜡的硬纸盒或者TETRAPACKTM盒)、罐、瓶等。
在没有脱离本发明的精神和范围的情况下,本发明公开内容的各种改性和变化对本领域技术人员来说是显而易见的,且意欲在下述权利要求的范围内。
Claims (17)
1.一种润滑用于运输已装填的、未密闭的容器的静止转移板的方法,该方法包括:稀释浓缩的润滑剂组合物,以形成稀释的润滑剂组合物,和在2-10加仑的稀释的润滑剂组合物/小时/喷嘴或鼓泡器的流量下,从转移板下方的与用于分配所述润滑剂组合物到所述转移板上的孔连通的至少一个喷嘴或鼓泡器施加所述稀释的润滑剂组合物到静止转移板上,所述稀释的润滑剂组合物包含:
0.0001wt%-0.05wt%的油;
乳化剂;和
水。
2.权利要求1的方法,其中所述油是硅油。
3.权利要求1的方法,其中所述油选自:
(a)含两个或更多个酯键的水不溶性有机化合物;
(b)含三个或更多个氧原子的水不溶性有机化合物;
(c)含三个或更多个氧原子、一个酯基团和一个或多个剩余的或游离的羟基的水不溶性有机化合物;
(d)长链羧酸与短链醇的酯;
(e)包括具有2个或更多个羟基的二-、三-或多元醇的酯,其中所述羟基各自与羧酸偶联为酯基;和
(f)它们的混合物。
4.权利要求1的方法,其中乳化剂是非离子表面活性剂。
5.权利要求1的方法,其中存在0.0005wt%-0.001wt%的油。
6.权利要求1的方法,其中从最多6个喷嘴或鼓泡器中施加稀释的润滑剂组合物。
7.权利要求1的方法,其中以6-8加仑/小时/喷嘴或鼓泡器的流量,施加稀释的润滑剂组合物。
8.权利要求1的方法,其中连续施加所述稀释的润滑剂组合物。
9.权利要求1的方法,其中间断地施加所述稀释的润滑剂组合物。
10.一种润滑静止转移板的方法,该方法包括:
施加润滑剂组合物到静止转移板上,所述润滑剂组合物包含:
0.0001wt%-1wt%的油;
乳化剂;和
水,
其中在6-8加仑/小时/鼓泡器的流量下,从转移板下方的与用于分配所述润滑剂组合物到所述转移板上的孔连通的2-6个鼓泡器施加所述润滑剂组合物。
11.权利要求10的方法,其中所述油是硅油。
12.权利要求10的方法,其中所述油选自:
(a)含两个或更多个酯键的水不溶性有机化合物;
(b)含三个或更多个氧原子的水不溶性有机化合物;
(c)含三个或更多个氧原子、一个酯基团和一个或多个剩余的或游离的羟基的水不溶性有机化合物;
(d)长链羧酸与短链醇的酯;
(e)包括具有2个或更多个羟基的二-、三-或多元醇的酯,其中所述羟基各自与羧酸偶联为酯基;和
(f)它们的混合物。
13.权利要求10的方法,其中乳化剂是非离子表面活性剂。
14.权利要求10的方法,其中存在0.0005wt%-0.001wt%的油。
15.权利要求10的方法,其中从6个鼓泡器中施加所述润滑剂组合物。
16.权利要求10的方法,其中连续施加所述润滑剂组合物。
17.权利要求10的方法,其中间断地施加所述润滑剂组合物。
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BR112015022512A2 (pt) | 2017-07-18 |
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US11312919B2 (en) | 2022-04-26 |
EP4410935A2 (en) | 2024-08-07 |
BR112015022512B1 (pt) | 2022-09-13 |
CN105164032A (zh) | 2015-12-16 |
WO2014164468A1 (en) | 2014-10-09 |
EP2969864B1 (en) | 2024-04-24 |
US9873853B2 (en) | 2018-01-23 |
MX2015012067A (es) | 2016-01-12 |
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