CN105073634B - 一种用于制造纯化的过氧化氢水溶液的方法 - Google Patents
一种用于制造纯化的过氧化氢水溶液的方法 Download PDFInfo
- Publication number
- CN105073634B CN105073634B CN201380073370.1A CN201380073370A CN105073634B CN 105073634 B CN105073634 B CN 105073634B CN 201380073370 A CN201380073370 A CN 201380073370A CN 105073634 B CN105073634 B CN 105073634B
- Authority
- CN
- China
- Prior art keywords
- hydrogen peroxide
- organic solvent
- purification
- solution
- unit
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims abstract description 97
- 238000000034 method Methods 0.000 title claims abstract description 74
- 238000000746 purification Methods 0.000 title claims abstract description 43
- 238000004519 manufacturing process Methods 0.000 title abstract description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 77
- 239000003960 organic solvent Substances 0.000 claims description 48
- 229910052757 nitrogen Inorganic materials 0.000 claims description 38
- 239000002904 solvent Substances 0.000 claims description 33
- 238000004140 cleaning Methods 0.000 claims description 29
- 239000003495 polar organic solvent Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 9
- 238000005984 hydrogenation reaction Methods 0.000 claims description 7
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 5
- 238000006701 autoxidation reaction Methods 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 238000004821 distillation Methods 0.000 claims 1
- QOSATHPSBFQAML-UHFFFAOYSA-N hydrogen peroxide;hydrate Chemical compound O.OO QOSATHPSBFQAML-UHFFFAOYSA-N 0.000 claims 1
- 229960002163 hydrogen peroxide Drugs 0.000 description 20
- 239000012224 working solution Substances 0.000 description 10
- 239000012535 impurity Substances 0.000 description 7
- -1 phosphate ester Chemical class 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 238000000605 extraction Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 239000000498 cooling water Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000004088 simulation Methods 0.000 description 3
- 241001672694 Citrus reticulata Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 102100036685 Growth arrest-specific protein 2 Human genes 0.000 description 2
- 101001072710 Homo sapiens Growth arrest-specific protein 2 Proteins 0.000 description 2
- 101150012532 NANOG gene Proteins 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 241000183024 Populus tremula Species 0.000 description 2
- 101100396520 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) TIF3 gene Proteins 0.000 description 2
- 101100184148 Xenopus laevis mix-a gene Proteins 0.000 description 2
- 239000003570 air Substances 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 150000004056 anthraquinones Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000010908 decantation Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 2
- 101150077246 gas5 gene Proteins 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 238000011031 large-scale manufacturing process Methods 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 101150038107 stm1 gene Proteins 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- ADHYTCPJVXOAJX-UHFFFAOYSA-N 1,3-dimethylanthracene-9,10-dione Chemical class C1=CC=C2C(=O)C3=CC(C)=CC(C)=C3C(=O)C2=C1 ADHYTCPJVXOAJX-UHFFFAOYSA-N 0.000 description 1
- DVFAVJDEPNXAME-UHFFFAOYSA-N 1,4-dimethylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(C)=CC=C2C DVFAVJDEPNXAME-UHFFFAOYSA-N 0.000 description 1
- INPHIYULSHLAHR-UHFFFAOYSA-N 1-pentylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2CCCCC INPHIYULSHLAHR-UHFFFAOYSA-N 0.000 description 1
- KIJPZYXCIHZVGP-UHFFFAOYSA-N 2,3-dimethylanthracene-9,10-dione Chemical class O=C1C2=CC=CC=C2C(=O)C2=C1C=C(C)C(C)=C2 KIJPZYXCIHZVGP-UHFFFAOYSA-N 0.000 description 1
- RATJDSXPVPAWJJ-UHFFFAOYSA-N 2,7-dimethylanthracene-9,10-dione Chemical class C1=C(C)C=C2C(=O)C3=CC(C)=CC=C3C(=O)C2=C1 RATJDSXPVPAWJJ-UHFFFAOYSA-N 0.000 description 1
- SJEBAWHUJDUKQK-UHFFFAOYSA-N 2-ethylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC=C3C(=O)C2=C1 SJEBAWHUJDUKQK-UHFFFAOYSA-N 0.000 description 1
- BQUNPXRABCSKJZ-UHFFFAOYSA-N 2-propan-2-ylanthracene-9,10-dione Chemical class C1=CC=C2C(=O)C3=CC(C(C)C)=CC=C3C(=O)C2=C1 BQUNPXRABCSKJZ-UHFFFAOYSA-N 0.000 description 1
- 150000004058 9,10-anthraquinones Chemical class 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 101001000631 Homo sapiens Peripheral myelin protein 22 Proteins 0.000 description 1
- 102100035917 Peripheral myelin protein 22 Human genes 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 125000000373 fatty alcohol group Chemical group 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/013—Separation; Purification; Concentration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0488—Flow sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0492—Applications, solvents used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/245—Stationary reactors without moving elements inside placed in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/022—Preparation from organic compounds
- C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12198510 | 2012-12-20 | ||
| EP12198510.5 | 2012-12-20 | ||
| PCT/EP2013/077444 WO2014096223A1 (en) | 2012-12-20 | 2013-12-19 | A process for manufacturing a purified aqueous hydrogen peroxide solution |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105073634A CN105073634A (zh) | 2015-11-18 |
| CN105073634B true CN105073634B (zh) | 2017-03-29 |
Family
ID=47435804
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201380073370.1A Expired - Fee Related CN105073634B (zh) | 2012-12-20 | 2013-12-19 | 一种用于制造纯化的过氧化氢水溶液的方法 |
Country Status (7)
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107556426B (zh) * | 2017-09-30 | 2019-08-30 | 江山市双氧水有限公司 | 一种双氧水提纯用吸附剂的制备方法 |
| CN111714922A (zh) * | 2019-03-22 | 2020-09-29 | 中国石油化工股份有限公司 | 一种应急处理装置及包括其的双氧水生产装置 |
| CN109908626B (zh) * | 2019-04-26 | 2023-10-20 | 北京凯迪森科技有限公司 | 一种强化萃取器及包括其的高效萃取系统和萃取工艺 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85103225A (zh) * | 1985-04-01 | 1987-01-10 | 化学工业部黎明化工研究院 | 过氧化氢的精制浓缩 |
| US6224845B1 (en) * | 1998-06-18 | 2001-05-01 | Solvay S.A. | Process for manufacturing an aqueous hydrogen peroxide solution |
| WO2005014471A1 (en) * | 2003-08-11 | 2005-02-17 | Degussa Ag | Process for the preparation of hydrogen peroxide by the anthraquinone cyclic process |
| CN101631743A (zh) * | 2007-03-15 | 2010-01-20 | Fmc有限公司 | 在自动氧化过氧化氢生产中回收水性过氧化氢 |
| CN101687639A (zh) * | 2007-04-05 | 2010-03-31 | 索尔维公司 | 水性过氧化氢溶液、它的制备方法及其用途 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3362939A (en) * | 1964-09-25 | 1968-01-09 | Exxon Research Engineering Co | Batch hydrogenation of petroleum resins |
| US3890113A (en) * | 1973-06-25 | 1975-06-17 | Texaco Inc | Production of methane |
| US4242108A (en) * | 1979-11-07 | 1980-12-30 | Air Products And Chemicals, Inc. | Hydrogen sulfide concentrator for acid gas removal systems |
| US4390418A (en) * | 1982-05-12 | 1983-06-28 | Texaco Inc. | Recovery of solvent in hydrocarbon processing systems |
| US4594148A (en) * | 1984-12-31 | 1986-06-10 | Sun Refining And Marketing Company | Extraction of aromatics with ethyl acetoacetate |
| BE1005199A3 (fr) | 1991-08-27 | 1993-05-25 | Interox Internat Sa | Procede pour l'obtention de solutions aqueuses de peroxyde d'hydrogene. |
| JPH09100106A (ja) * | 1995-10-02 | 1997-04-15 | Mitsubishi Gas Chem Co Inc | 過酸化水素中の有機質不純物除去方法 |
| PL200229B1 (pl) * | 1999-05-14 | 2008-12-31 | Ge Energy Usa | Sposób odzyskiwania strumienia gazu wodorowego z gazu syntezowego |
| JP2002161079A (ja) * | 2000-11-28 | 2002-06-04 | Asahi Kasei Corp | 未反応炭化水素の分離・回収方法 |
| FR2864101B1 (fr) * | 2003-12-19 | 2006-03-17 | Total France | Procede catalytique de purification des hydrocarbures legers |
-
2013
- 2013-12-19 BR BR112015014440A patent/BR112015014440A2/pt not_active Application Discontinuation
- 2013-12-19 WO PCT/EP2013/077444 patent/WO2014096223A1/en active Application Filing
- 2013-12-19 JP JP2015548582A patent/JP2016506354A/ja active Pending
- 2013-12-19 EP EP13811223.0A patent/EP2935096B1/en not_active Not-in-force
- 2013-12-19 CN CN201380073370.1A patent/CN105073634B/zh not_active Expired - Fee Related
- 2013-12-19 US US14/653,202 patent/US10570014B2/en not_active Expired - Fee Related
-
2015
- 2015-06-14 SA SA515360588A patent/SA515360588B1/ar unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85103225A (zh) * | 1985-04-01 | 1987-01-10 | 化学工业部黎明化工研究院 | 过氧化氢的精制浓缩 |
| US6224845B1 (en) * | 1998-06-18 | 2001-05-01 | Solvay S.A. | Process for manufacturing an aqueous hydrogen peroxide solution |
| WO2005014471A1 (en) * | 2003-08-11 | 2005-02-17 | Degussa Ag | Process for the preparation of hydrogen peroxide by the anthraquinone cyclic process |
| CN101631743A (zh) * | 2007-03-15 | 2010-01-20 | Fmc有限公司 | 在自动氧化过氧化氢生产中回收水性过氧化氢 |
| CN101687639A (zh) * | 2007-04-05 | 2010-03-31 | 索尔维公司 | 水性过氧化氢溶液、它的制备方法及其用途 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20160185598A1 (en) | 2016-06-30 |
| JP2016506354A (ja) | 2016-03-03 |
| BR112015014440A2 (pt) | 2017-07-11 |
| SA515360588B1 (ar) | 2017-01-18 |
| EP2935096A1 (en) | 2015-10-28 |
| WO2014096223A1 (en) | 2014-06-26 |
| EP2935096B1 (en) | 2018-10-03 |
| CN105073634A (zh) | 2015-11-18 |
| US10570014B2 (en) | 2020-02-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR100616355B1 (ko) | 과산화수소 수용액의 제조방법과 과산화수소 수용액 | |
| CN105073634B (zh) | 一种用于制造纯化的过氧化氢水溶液的方法 | |
| CN208964546U (zh) | 过氧化氢制造系统 | |
| EP3915933A1 (en) | Device and process for producing hydrogen peroxide by an anthraquinone process | |
| US20220290317A1 (en) | Electrolyser system of water electrolysis and process therefor | |
| CN106674292A (zh) | 一种三氯蔗糖水结晶母液的提纯处理方法 | |
| JPH05201707A (ja) | 精製された過酸化水素水溶液を得る方法 | |
| JP3328854B2 (ja) | 過酸化水素の濃縮精製方法 | |
| US11220430B2 (en) | Method and system for producing purified aqueous hydrogen peroxide solution | |
| EP4132672B1 (en) | Process and facility for recovering methoxypropanols from an aqueous stream | |
| KR20240125582A (ko) | 과산화수소를 생산하기 위한 신규한 프로세스 | |
| JP3250591B2 (ja) | 過酸化水素水溶液の濃縮精製方法 | |
| CN104909340B (zh) | 一种直接萃取50%以上高浓度h2o2的方法 | |
| CN112390713A (zh) | 一种乙醛回收方法 | |
| RU2778540C1 (ru) | Установка и способ получения перекиси водорода посредством антрахинонового процесса | |
| JP2642909B2 (ja) | 精製エタノールの製法 | |
| EP4337603B1 (en) | Optimized steam network for the ao process | |
| CN119258944A (zh) | 一种生产双氧水的氧化反应萃取装置及方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170329 Termination date: 20201219 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |