CN104981464B - 制备环状酯和环状酰胺的工艺 - Google Patents

制备环状酯和环状酰胺的工艺 Download PDF

Info

Publication number
CN104981464B
CN104981464B CN201480008213.7A CN201480008213A CN104981464B CN 104981464 B CN104981464 B CN 104981464B CN 201480008213 A CN201480008213 A CN 201480008213A CN 104981464 B CN104981464 B CN 104981464B
Authority
CN
China
Prior art keywords
acid
zeolite
alkyl
ratio
process according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201480008213.7A
Other languages
English (en)
Chinese (zh)
Other versions
CN104981464A (zh
Inventor
B.塞尔斯
M.达塞利尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Total Petrochemicals Research Feluy SA
Original Assignee
Total Petrochemicals Research Feluy SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Total Petrochemicals Research Feluy SA filed Critical Total Petrochemicals Research Feluy SA
Publication of CN104981464A publication Critical patent/CN104981464A/zh
Application granted granted Critical
Publication of CN104981464B publication Critical patent/CN104981464B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D319/00—Heterocyclic compounds containing six-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D319/10—1,4-Dioxanes; Hydrogenated 1,4-dioxanes
    • C07D319/12—1,4-Dioxanes; Hydrogenated 1,4-dioxanes not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
    • C07D223/02—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D223/06—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D223/08—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
    • C07D223/02—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D223/06—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D223/08—Oxygen atoms
    • C07D223/10—Oxygen atoms attached in position 2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D313/00—Heterocyclic compounds containing rings of more than six members having one oxygen atom as the only ring hetero atom
    • C07D313/02—Seven-membered rings
    • C07D313/04—Seven-membered rings not condensed with other rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Other In-Based Heterocyclic Compounds (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
  • Pyrane Compounds (AREA)
  • Pyrrole Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
CN201480008213.7A 2013-02-08 2014-02-07 制备环状酯和环状酰胺的工艺 Active CN104981464B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13154707 2013-02-08
EP13154707.7 2013-02-08
PCT/EP2014/052493 WO2014122294A1 (en) 2013-02-08 2014-02-07 Process for preparing cyclic esters and cyclic amides

Publications (2)

Publication Number Publication Date
CN104981464A CN104981464A (zh) 2015-10-14
CN104981464B true CN104981464B (zh) 2017-08-15

Family

ID=47681787

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201480008213.7A Active CN104981464B (zh) 2013-02-08 2014-02-07 制备环状酯和环状酰胺的工艺

Country Status (9)

Country Link
US (2) US9573924B2 (enExample)
EP (1) EP2941422B1 (enExample)
JP (1) JP6422893B2 (enExample)
KR (1) KR20150115792A (enExample)
CN (1) CN104981464B (enExample)
BR (1) BR112015016103A2 (enExample)
EA (1) EA027829B1 (enExample)
ES (1) ES2628803T3 (enExample)
WO (1) WO2014122294A1 (enExample)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20190020746A (ko) * 2016-06-20 2019-03-04 토탈 리서치 앤드 테크놀로지 펠루이 용매에 대해 별도의 유입을 이용한 단일 단계 락티드 제조 방법
CN109563068A (zh) * 2016-06-20 2019-04-02 道达尔研究技术弗吕公司 通过滗析回收水的单步骤丙交酯生产工艺
CN110402246A (zh) 2017-03-15 2019-11-01 巴斯夫欧洲公司 通过使羟基羧酸或酰胺与酸性BEA(H-β多晶型A)型沸石反应而制备环状二酯或环状二酰胺的方法
CN106831700B (zh) * 2017-03-28 2019-05-24 南京大学 一种全绿色封闭循环工艺生产光学纯l-/d-丙交酯的方法
JP6952303B2 (ja) * 2017-08-02 2021-10-20 日本曹達株式会社 環状エステル類の製造方法
US10266512B2 (en) 2017-08-10 2019-04-23 Novus International, Inc. Processes for preparing heteroatom containing cyclic dimers
WO2020081836A1 (en) 2018-10-17 2020-04-23 The Regents Of The University Of California Prodrugs of alpha-ketoglutarate, alpha-ketobutyrate, alpha-ketoisovalerate, and alpha-ketoisohexanoate, and uses thereof
WO2022006023A1 (en) * 2020-06-29 2022-01-06 Zymergen Inc. Dimers from bioreachable molecules as copolymers
CN116113634A (zh) * 2020-06-29 2023-05-12 齐默尔根公司 模量改性剂及其薄膜
CN111995611A (zh) * 2020-08-18 2020-11-27 青岛科技大学 一种己内酯的合成工艺
CN114437017A (zh) * 2020-10-31 2022-05-06 中国石油化工股份有限公司 一种乳酸制备丙交酯的方法
CN112574165B (zh) * 2020-12-30 2022-01-07 安徽丰原生物技术股份有限公司 一步转化生成丙交酯的方法
EP4134365A1 (en) * 2021-08-12 2023-02-15 Sulzer Management AG A plant and an efficient process for producing lactide from lactic acid
CN115028615B (zh) * 2022-07-27 2024-01-09 万华化学(四川)有限公司 一种l,l-丙交酯及其制备方法和应用
CN120004848A (zh) * 2025-02-17 2025-05-16 中国科学院长春应用化学研究所 一种用分子筛催化剂合成的丙交酯衍生物及其合成方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007012979A2 (en) * 2005-04-22 2007-02-01 Universite De Geneve Polylactide compositions and uses thereof
WO2010022966A2 (de) * 2008-08-29 2010-03-04 Uhde Inventa-Fischer Gmbh Verfahren zur herstellung eines gemisches von lactid-derivaten
US20100256398A1 (en) * 2007-12-21 2010-10-07 Base Se Process for preparing epsilon-caprolactone
EP2264020A1 (en) * 2009-05-20 2010-12-22 Korea Research Institute Of Chemical Technology Catalyst for direct conversion of esters of lactic acid to lactide and the method for producing lactide using the same
EP2407463A1 (en) * 2010-07-14 2012-01-18 Solvay SA Process for the manufacture of a cyclic diester of an apha-hydroxyacid

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5326887A (en) * 1991-02-27 1994-07-05 E. I. Du Pont De Nemours And Company Process for the preparation of 1,4-dioxane-2,5-diones
JPH05138022A (ja) * 1991-11-22 1993-06-01 Japan Tobacco Inc ラクトンの製造方法
KR101886434B1 (ko) * 2012-02-29 2018-08-07 현대자동차주식회사 유산으로부터 락타이드의 제조방법
KR101459819B1 (ko) * 2012-04-04 2014-11-07 현대자동차주식회사 유산염으로부터 락타이드의 제조방법
WO2013160485A1 (de) * 2012-04-28 2013-10-31 Uhde Inventa-Fischer Gmbh Verfahren zur kontinuierlichen herstellung von lactid direkt aus konzentrierter milchsäure

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007012979A2 (en) * 2005-04-22 2007-02-01 Universite De Geneve Polylactide compositions and uses thereof
US20100256398A1 (en) * 2007-12-21 2010-10-07 Base Se Process for preparing epsilon-caprolactone
WO2010022966A2 (de) * 2008-08-29 2010-03-04 Uhde Inventa-Fischer Gmbh Verfahren zur herstellung eines gemisches von lactid-derivaten
EP2264020A1 (en) * 2009-05-20 2010-12-22 Korea Research Institute Of Chemical Technology Catalyst for direct conversion of esters of lactic acid to lactide and the method for producing lactide using the same
EP2407463A1 (en) * 2010-07-14 2012-01-18 Solvay SA Process for the manufacture of a cyclic diester of an apha-hydroxyacid

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
Facile Synthesis of ε-Caprolactam by Cyclodehydration of 6-Aminocaproic Acid on Adsorbents;Haruo Ogawa et al.;《J . CHEM. SOC., CHEM. COMMUN.》;19931231(第18期);1393-1394 *
SYNTHESIS OF SUBSTITUTED (+)-3,4-DIHYDROCOUMARINS USING H-Y ZEOLITE;Manojkumar R. Shukla et al.;《SYNTHETIC COMMUNICATIONS》;20001231;第30卷(第1期);39-42 *
Zeolite-Catalyzed Macrolactonization of ω-Hydroxyalkanoic Acids in a Highly Concentrated Solution;Tooru Ookoshi et al.;《Tetrahedron Letters》;19981231;第39卷;293-296 *

Also Published As

Publication number Publication date
EA027829B1 (ru) 2017-09-29
JP2016507545A (ja) 2016-03-10
EA201591022A1 (ru) 2016-02-29
US20150376159A1 (en) 2015-12-31
US9862700B2 (en) 2018-01-09
WO2014122294A1 (en) 2014-08-14
US9573924B2 (en) 2017-02-21
ES2628803T3 (es) 2017-08-04
US20170114036A1 (en) 2017-04-27
CN104981464A (zh) 2015-10-14
EP2941422B1 (en) 2017-04-05
JP6422893B2 (ja) 2018-11-14
EP2941422A1 (en) 2015-11-11
BR112015016103A2 (pt) 2017-07-11
KR20150115792A (ko) 2015-10-14

Similar Documents

Publication Publication Date Title
CN104981464B (zh) 制备环状酯和环状酰胺的工艺
US10195592B2 (en) Zirconium-based metal-organic frameworks as catalyst for transfer hydrogenation
JP2010527769A5 (enExample)
JP2016539893A5 (enExample)
US10562877B2 (en) Single step lactide production process with hydrolysis of oligomers and catalyst by recovered water
CN101161343A (zh) 一种应用于合成吡啶碱的新型催化剂及其制备和使用方法
WO2005014766A2 (en) Metal ion exchanged solid materials as catalysts for the arylation and the skeletal isomerization of fatty acids and alkyl esters thereof
EP3472143B1 (en) Single step lactide production process with recovery of water by decantation
US10858333B2 (en) Single step lactide production process with separate entry for solvent
JP2008502637A (ja) メチルアミン類を連続的に合成する方法
US10851078B2 (en) Single step lactide production process with heat recovery
EP1294481B1 (en) Process for the regeneration of solid acid catalysts
TW201223929A (en) Hydride transfer process for ketone preparation
JP2019026613A (ja) 環状エステル類の製造方法
CN1735459A (zh) 氢化催化剂
Asefa et al. NANOSTRUCTURED CATALYSTS FOR THE ALDOL, KNOEVENAGEL, AND REACTIONS HENRY
JP2010184870A (ja) エチレングリコールの製造方法
JP2012077062A (ja) メチレンジアニリン誘導体の製造方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant