CN104955569A - 将正丁烯氧化脱氢成丁二烯的方法 - Google Patents
将正丁烯氧化脱氢成丁二烯的方法 Download PDFInfo
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- CN104955569A CN104955569A CN201380071781.7A CN201380071781A CN104955569A CN 104955569 A CN104955569 A CN 104955569A CN 201380071781 A CN201380071781 A CN 201380071781A CN 104955569 A CN104955569 A CN 104955569A
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- catalyst
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- butadiene
- butene
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- 238000000034 method Methods 0.000 title claims description 40
- 238000005839 oxidative dehydrogenation reaction Methods 0.000 title claims description 40
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- 239000011733 molybdenum Substances 0.000 claims abstract description 19
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8878—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
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PCT/EP2013/075453 WO2014086813A1 (de) | 2012-12-06 | 2013-12-04 | Verfahren zur oxidativen dehydrierung von n-butenen zu butadien |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105175207A (zh) * | 2015-10-16 | 2015-12-23 | 安徽工业大学 | 用Bi/Mo/Co/La/Fe五组分复合氧化物催化剂移动床合成1,3-丁二烯的方法 |
CN107428637A (zh) * | 2015-03-09 | 2017-12-01 | 三菱化学株式会社 | 共轭二烯的制造方法 |
CN107970945A (zh) * | 2016-10-21 | 2018-05-01 | 中国石油化工股份有限公司 | 用于丁烯氧化脱氢制丁二烯的催化剂及其工艺方法 |
CN107970954A (zh) * | 2016-10-21 | 2018-05-01 | 中国石油化工股份有限公司 | 用于丁烯氧化脱氢制丁二烯的催化剂及其制备方法 |
CN107973690A (zh) * | 2016-10-21 | 2018-05-01 | 中国石油化工股份有限公司 | 用于丁烯氧化脱氢制丁二烯的催化剂及其方法 |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2945923B1 (de) * | 2013-01-15 | 2017-03-15 | Basf Se | Verfahren zur oxidativen dehydrierung von n-butenen zu butadien |
CN106795066A (zh) * | 2014-09-26 | 2017-05-31 | 巴斯夫欧洲公司 | 由正丁烯通过氧化脱氢制备1,3‑丁二烯的方法 |
WO2016177764A1 (de) * | 2015-05-06 | 2016-11-10 | Basf Se | Verfahren zur herstellung chrom enthaltender katalysatoren für die oxidehydrierung von n-butenen zu butadien unter vermeidung von cr(vi)-intermediaten |
WO2019172250A1 (ja) | 2018-03-06 | 2019-09-12 | Jsr株式会社 | 1,3-ブタジエンの製造方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4438217A (en) * | 1982-01-06 | 1984-03-20 | Nippin Shokubai Kagako Kogyo Co., Ltd. | Catalyst for oxidation of propylene |
CN1131583A (zh) * | 1994-11-29 | 1996-09-25 | Basf公司 | 由载体及加到其表面上的催化活性氧化物构成的催化剂的制备方法 |
US5989412A (en) * | 1996-04-08 | 1999-11-23 | Catalysts & Chemicals Industries Co., Ltd. | Hydrodemetallizing catalyst for hydrocarbon oil and process of hydrodemetallizing hydrocarbon oil therewith |
CN101066528A (zh) * | 2001-11-08 | 2007-11-07 | 三菱化学株式会社 | 复合氧化物催化剂及其制备方法 |
CN101990460A (zh) * | 2008-04-09 | 2011-03-23 | 巴斯夫欧洲公司 | 包含含钼、铋和铁的多金属氧化物的涂覆催化剂 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10361824A1 (de) * | 2003-12-30 | 2005-07-28 | Basf Ag | Verfahren zur Herstellung von Butadien |
-
2013
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- 2013-12-04 CN CN201380071781.7A patent/CN104955569A/zh active Pending
- 2013-12-04 EP EP13814454.8A patent/EP2928603A1/de not_active Withdrawn
- 2013-12-04 KR KR1020157017618A patent/KR20150091387A/ko not_active Application Discontinuation
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4438217A (en) * | 1982-01-06 | 1984-03-20 | Nippin Shokubai Kagako Kogyo Co., Ltd. | Catalyst for oxidation of propylene |
US4438217B1 (ru) * | 1982-01-06 | 1990-01-09 | Nippon Shokubai Kagak Kogyo Co | |
CN1131583A (zh) * | 1994-11-29 | 1996-09-25 | Basf公司 | 由载体及加到其表面上的催化活性氧化物构成的催化剂的制备方法 |
US5989412A (en) * | 1996-04-08 | 1999-11-23 | Catalysts & Chemicals Industries Co., Ltd. | Hydrodemetallizing catalyst for hydrocarbon oil and process of hydrodemetallizing hydrocarbon oil therewith |
CN101066528A (zh) * | 2001-11-08 | 2007-11-07 | 三菱化学株式会社 | 复合氧化物催化剂及其制备方法 |
CN101990460A (zh) * | 2008-04-09 | 2011-03-23 | 巴斯夫欧洲公司 | 包含含钼、铋和铁的多金属氧化物的涂覆催化剂 |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107428637A (zh) * | 2015-03-09 | 2017-12-01 | 三菱化学株式会社 | 共轭二烯的制造方法 |
CN107428637B (zh) * | 2015-03-09 | 2021-06-25 | 三菱化学株式会社 | 共轭二烯的制造方法 |
CN105175207A (zh) * | 2015-10-16 | 2015-12-23 | 安徽工业大学 | 用Bi/Mo/Co/La/Fe五组分复合氧化物催化剂移动床合成1,3-丁二烯的方法 |
CN107970945A (zh) * | 2016-10-21 | 2018-05-01 | 中国石油化工股份有限公司 | 用于丁烯氧化脱氢制丁二烯的催化剂及其工艺方法 |
CN107970954A (zh) * | 2016-10-21 | 2018-05-01 | 中国石油化工股份有限公司 | 用于丁烯氧化脱氢制丁二烯的催化剂及其制备方法 |
CN107973690A (zh) * | 2016-10-21 | 2018-05-01 | 中国石油化工股份有限公司 | 用于丁烯氧化脱氢制丁二烯的催化剂及其方法 |
CN107970954B (zh) * | 2016-10-21 | 2023-01-31 | 中国石油化工股份有限公司 | 用于丁烯氧化脱氢制丁二烯的催化剂及其制备方法 |
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WO2014086813A1 (de) | 2014-06-12 |
EA201591092A1 (ru) | 2015-11-30 |
KR20150091387A (ko) | 2015-08-10 |
EP2928603A1 (de) | 2015-10-14 |
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Application publication date: 20150930 |