EA201591092A1 - Способ окислительного дегидрирования н-бутена в бутадиен - Google Patents

Способ окислительного дегидрирования н-бутена в бутадиен

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Publication number
EA201591092A1
EA201591092A1 EA201591092A EA201591092A EA201591092A1 EA 201591092 A1 EA201591092 A1 EA 201591092A1 EA 201591092 A EA201591092 A EA 201591092A EA 201591092 A EA201591092 A EA 201591092A EA 201591092 A1 EA201591092 A1 EA 201591092A1
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EA
Eurasian Patent Office
Prior art keywords
catalyst
buten
butadiene
oxidative dehydrogenation
outer diameter
Prior art date
Application number
EA201591092A
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English (en)
Inventor
Филипп Грюнэ
Вольфганг Рюттингер
Оливер Хаммен
Кристиан Вальсдорфф
Original Assignee
Басф Се
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Publication date
Application filed by Басф Се filed Critical Басф Се
Publication of EA201591092A1 publication Critical patent/EA201591092A1/ru

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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878—Chromium
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    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
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    • B01J37/0221—Coating of particles
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
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    • B01J37/033—Using Hydrolysis
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
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    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
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    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
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    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
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    • C07C2523/18—Arsenic, antimony or bismuth
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    • C07C2523/32—Manganese, technetium or rhenium
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    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
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    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
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    • C07C2523/75—Cobalt
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    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil

Abstract

Катализатор, получаемый из предшественника катализатора, содержащий каталитически активный, содержащий молибден и по меньшей мере один дополнительный металл оксид мультиметаллов общей формулы (I) MoBiFeCoNiCrXXO(I), в которой переменные имеют следующие значения: X= W, Sn, Mn, La, Се, Ge, Ti, Zr, Hf, Nb, P, Si, Sb, Al, Cd и/или Mg; X= Li, Na, K, Cs и/или Rb, a = 0,1-7, предпочтительно 0,3-1,5; b = 0-5, предпочтительно 2-4; с = 0-10, предпочтительно 3-10; d = 0-10; e = 0-5, предпочтительно 0,1-2; f = 0-24, предпочтительно 0,1-2; g = 0-2, предпочтительно 0,01-1 и х = число, которое определено по валентности и распространенности отличных от кислорода элементов в формуле (I), отличающийся тем, что катализатор имеет форму полого цилиндра, причем внутренний диаметр равен 0,2-0,8-кратному наружному диаметру, и длина равна 0,5-2,5-кратному наружному диаметру, и предшественник катализатора не содержит порообразователей.
EA201591092A 2012-12-06 2013-12-04 Способ окислительного дегидрирования н-бутена в бутадиен EA201591092A1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP12195846 2012-12-06
PCT/EP2013/075453 WO2014086813A1 (de) 2012-12-06 2013-12-04 Verfahren zur oxidativen dehydrierung von n-butenen zu butadien

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EA201591092A1 true EA201591092A1 (ru) 2015-11-30

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EP (1) EP2928603A1 (ru)
JP (1) JP2016500333A (ru)
KR (1) KR20150091387A (ru)
CN (1) CN104955569A (ru)
EA (1) EA201591092A1 (ru)
WO (1) WO2014086813A1 (ru)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EA029784B1 (ru) * 2013-01-15 2018-05-31 Басф Се СПОСОБ ОКИСЛИТЕЛЬНОГО ДЕГИДРИРОВАНИЯ н-БУТЕНОВ В БУТАДИЕН
KR20170063608A (ko) * 2014-09-26 2017-06-08 바스프 에스이 산화성 탈수소화에 의해 n-부텐으로부터 1,3-부타디엔을 제조하는 방법
CN107428637B (zh) 2015-03-09 2021-06-25 三菱化学株式会社 共轭二烯的制造方法
WO2016177764A1 (de) * 2015-05-06 2016-11-10 Basf Se Verfahren zur herstellung chrom enthaltender katalysatoren für die oxidehydrierung von n-butenen zu butadien unter vermeidung von cr(vi)-intermediaten
CN105175207B (zh) * 2015-10-16 2017-03-22 安徽工业大学 用Bi/Mo/Co/La/Fe五组分复合氧化物催化剂移动床合成1,3‑丁二烯的方法
CN107970945A (zh) * 2016-10-21 2018-05-01 中国石油化工股份有限公司 用于丁烯氧化脱氢制丁二烯的催化剂及其工艺方法
CN107973690A (zh) * 2016-10-21 2018-05-01 中国石油化工股份有限公司 用于丁烯氧化脱氢制丁二烯的催化剂及其方法
CN107970954B (zh) * 2016-10-21 2023-01-31 中国石油化工股份有限公司 用于丁烯氧化脱氢制丁二烯的催化剂及其制备方法
JP7196155B2 (ja) 2018-03-06 2022-12-26 株式会社Ｅｎｅｏｓマテリアル １，３－ブタジエンの製造方法

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JPS58119346A (ja) * 1982-01-06 1983-07-15 Nippon Shokubai Kagaku Kogyo Co Ltd プロピレン酸化用触媒
DE4442346A1 (de) * 1994-11-29 1996-05-30 Basf Ag Verfahren zur Herstellung eines Katalysators, bestehend aus einem Trägerkörper und einer auf der Oberfläche des Trägerkörpers aufgebrachten katalytisch aktiven Oxidmasse
US5989412A (en) * 1996-04-08 1999-11-23 Catalysts & Chemicals Industries Co., Ltd. Hydrodemetallizing catalyst for hydrocarbon oil and process of hydrodemetallizing hydrocarbon oil therewith
CN101066528B (zh) * 2001-11-08 2010-09-29 三菱化学株式会社 复合氧化物催化剂及其制备方法
DE10361824A1 (de) * 2003-12-30 2005-07-28 Basf Ag Verfahren zur Herstellung von Butadien
TW200950880A (en) * 2008-04-09 2009-12-16 Basf Se Coated catalysts comprising a multimetal oxide comprising molybdenum, bismuth and iron

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CN104955569A (zh) 2015-09-30
JP2016500333A (ja) 2016-01-12
KR20150091387A (ko) 2015-08-10
WO2014086813A1 (de) 2014-06-12
EP2928603A1 (de) 2015-10-14

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