CN104937014B - 经浸渍的增强纤维纱及其在生产复合材料中的用途 - Google Patents
经浸渍的增强纤维纱及其在生产复合材料中的用途 Download PDFInfo
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- CN104937014B CN104937014B CN201480005671.5A CN201480005671A CN104937014B CN 104937014 B CN104937014 B CN 104937014B CN 201480005671 A CN201480005671 A CN 201480005671A CN 104937014 B CN104937014 B CN 104937014B
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- 238000007598 dipping method Methods 0.000 title claims description 16
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- 239000011347 resin Substances 0.000 claims abstract description 237
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000000203 mixture Substances 0.000 claims abstract description 38
- 125000003118 aryl group Chemical group 0.000 claims abstract description 18
- 229940106691 bisphenol a Drugs 0.000 claims abstract description 17
- 239000002245 particle Substances 0.000 claims abstract description 17
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims abstract description 14
- 238000002844 melting Methods 0.000 claims abstract description 14
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- 239000005056 polyisocyanate Substances 0.000 claims abstract description 4
- 239000000835 fiber Substances 0.000 claims description 71
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 21
- 239000004917 carbon fiber Substances 0.000 claims description 21
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 21
- 150000002924 oxiranes Chemical class 0.000 claims description 19
- 239000004744 fabric Substances 0.000 claims description 16
- 239000000853 adhesive Substances 0.000 claims description 15
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- 150000002148 esters Chemical class 0.000 claims description 12
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 9
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- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229920002647 polyamide Polymers 0.000 claims description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- 229920000297 Rayon Polymers 0.000 claims description 2
- 239000004760 aramid Substances 0.000 claims description 2
- 229920003235 aromatic polyamide Polymers 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- 229920005610 lignin Polymers 0.000 claims description 2
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 2
- 229920002994 synthetic fiber Polymers 0.000 claims description 2
- 239000012209 synthetic fiber Substances 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 229920001281 polyalkylene Polymers 0.000 claims 1
- 238000000034 method Methods 0.000 description 33
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- 239000003822 epoxy resin Substances 0.000 description 20
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- 239000000463 material Substances 0.000 description 17
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 15
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- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
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- 239000011342 resin composition Substances 0.000 description 5
- 239000002759 woven fabric Substances 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 230000004888 barrier function Effects 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000004416 thermosoftening plastic Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
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- 238000005259 measurement Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
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- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
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- 238000002156 mixing Methods 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- RZJRJXONCZWCBN-UHFFFAOYSA-N octadecane Chemical compound CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 229940098695 palmitic acid Drugs 0.000 description 2
- YCOZIPAWZNQLMR-UHFFFAOYSA-N pentadecane Chemical compound CCCCCCCCCCCCCCC YCOZIPAWZNQLMR-UHFFFAOYSA-N 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
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- 238000003892 spreading Methods 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
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- 206010063493 Premature ageing Diseases 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
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- 239000004568 cement Substances 0.000 description 1
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- 238000000605 extraction Methods 0.000 description 1
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- 239000003365 glass fiber Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
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- 238000003780 insertion Methods 0.000 description 1
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- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
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- 235000021110 pickles Nutrition 0.000 description 1
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- 238000003825 pressing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- ZPWFUIUNWDIYCJ-UHFFFAOYSA-N propan-2-yl octadecanoate Chemical class CCCCCCCCCCCCCCCCCC(=O)OC(C)C ZPWFUIUNWDIYCJ-UHFFFAOYSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
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- 239000008117 stearic acid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- KJAMZCVTJDTESW-UHFFFAOYSA-N tiracizine Chemical compound C1CC2=CC=CC=C2N(C(=O)CN(C)C)C2=CC(NC(=O)OCC)=CC=C21 KJAMZCVTJDTESW-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000001721 transfer moulding Methods 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
- C08L75/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
- C08J5/243—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Reinforced Plastic Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Woven Fabrics (AREA)
- Laminated Bodies (AREA)
- Epoxy Resins (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13152863.0 | 2013-01-28 | ||
EP13152863 | 2013-01-28 | ||
PCT/EP2014/051084 WO2014114617A1 (de) | 2013-01-28 | 2014-01-21 | Imprägniertes verstärkungsfasergarn und dessen verwendung zur herstellung von verbundwerkstoffen |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104937014A CN104937014A (zh) | 2015-09-23 |
CN104937014B true CN104937014B (zh) | 2017-11-28 |
Family
ID=47623951
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201480005671.5A Active CN104937014B (zh) | 2013-01-28 | 2014-01-21 | 经浸渍的增强纤维纱及其在生产复合材料中的用途 |
Country Status (13)
Country | Link |
---|---|
US (1) | US9540509B2 (de) |
EP (1) | EP2948499B1 (de) |
JP (1) | JP6250068B2 (de) |
CN (1) | CN104937014B (de) |
AR (1) | AR094597A1 (de) |
AU (1) | AU2014210052B2 (de) |
BR (1) | BR112015015915B1 (de) |
CA (1) | CA2899268C (de) |
ES (1) | ES2635502T3 (de) |
PL (1) | PL2948499T3 (de) |
PT (1) | PT2948499T (de) |
TW (1) | TWI602671B (de) |
WO (1) | WO2014114617A1 (de) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107207346B (zh) | 2015-01-19 | 2020-07-28 | 帝人株式会社 | 水泥补强用纤维材料 |
CA3000799A1 (en) * | 2015-10-09 | 2017-04-13 | Dsm Ip Assets B.V. | Composite lengthy body |
US10259157B2 (en) * | 2015-12-21 | 2019-04-16 | Palo Alto Research Center Incorporated | Fiber reinforced thermoplastic sheets for thermoforming |
WO2018092500A1 (ja) * | 2016-11-16 | 2018-05-24 | 三菱瓦斯化学株式会社 | 成形品の製造方法 |
JP6875538B2 (ja) * | 2017-09-21 | 2021-05-26 | 帝人株式会社 | 固定炭素繊維束の製造方法 |
JP7082217B2 (ja) * | 2018-03-06 | 2022-06-07 | アーライト、インコーポレイテッド. | 繊維強化複合材料並びに同繊維強化複合材料の形成方法及び使用方法 |
CN108752932B (zh) * | 2018-05-10 | 2023-09-05 | 本影科技(中山)有限公司 | 一种硅橡胶弹性体/纤维复合材料及其制备方法和应用 |
BR112021020400A2 (pt) | 2019-04-18 | 2021-12-07 | Teijin Carbon Europe Gmbh | Carga de raio de pré-forma trançada, método para produzir uma carga de raio de pré-forma trançada, e, compósito |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005080501A1 (en) * | 2004-01-20 | 2005-09-01 | Hexcel Composites, Ltd. | Gelator-stabilized crystalline resins |
CN1976787A (zh) * | 2004-03-31 | 2007-06-06 | 东邦泰纳克丝欧洲有限公司 | 环氧树脂浸渍纱线以及其在制作预成型物中的应用 |
CN102834440A (zh) * | 2010-03-30 | 2012-12-19 | 东丽株式会社 | 预浸料坯、纤维增强复合材料及预浸料坯的制造方法 |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0133825B1 (de) | 1983-06-28 | 1987-09-09 | Elf Atochem S.A. | Flexibles Verbundmaterial und Verfahren zu seiner Herstellung |
JPS61138617A (ja) * | 1984-12-11 | 1986-06-26 | Toyo Tire & Rubber Co Ltd | ウレタンプレポリマ−組成物 |
FR2648957B1 (fr) | 1989-06-22 | 1991-11-15 | France Etat Armement | Materiau composite a caracteristiques modulables par preimpregnation d'une fibre continue |
JP3098267B2 (ja) * | 1991-03-12 | 2000-10-16 | 敷島紡績株式会社 | 複合材用繊維の処理剤 |
JPH05117423A (ja) * | 1991-10-29 | 1993-05-14 | Asahi Chem Ind Co Ltd | プリプレグ用エポキシ樹脂組成物 |
JP3222512B2 (ja) * | 1991-11-11 | 2001-10-29 | 三菱レイヨン株式会社 | 炭素繊維用サイジング剤 |
IT1254197B (it) | 1992-02-06 | 1995-09-14 | Donegani Guido Ist | Procedimento per la preparazione di corpi formati in polimeri termoplastici rinforzati con fibra lunga |
JP2957406B2 (ja) * | 1993-12-28 | 1999-10-04 | 東邦レーヨン株式会社 | 炭素繊維ストランド用サイジング剤、サイズ処理された炭素繊維ストランド、及びその炭素繊維ストランドを強化繊維としたプリプレグ |
ATE296851T1 (de) * | 1996-02-21 | 2005-06-15 | Toray Industries | Verbundfaden und daraus hergestellte faserverstärkte verbundwerkstoffe |
JP2957467B2 (ja) * | 1996-03-11 | 1999-10-04 | 東邦レーヨン株式会社 | 炭素繊維ストランド用サイジング剤、サイズ処理された炭素繊維ストランド、及びその炭素繊維ストランドを強化繊維としたプリプレグ |
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- 2014-01-21 US US14/655,898 patent/US9540509B2/en active Active
- 2014-01-21 EP EP14701948.3A patent/EP2948499B1/de active Active
- 2014-01-21 PL PL14701948T patent/PL2948499T3/pl unknown
- 2014-01-21 WO PCT/EP2014/051084 patent/WO2014114617A1/de active Application Filing
- 2014-01-21 BR BR112015015915-0A patent/BR112015015915B1/pt active IP Right Grant
- 2014-01-21 AU AU2014210052A patent/AU2014210052B2/en active Active
- 2014-01-21 JP JP2015554125A patent/JP6250068B2/ja active Active
- 2014-01-21 CA CA2899268A patent/CA2899268C/en active Active
- 2014-01-21 CN CN201480005671.5A patent/CN104937014B/zh active Active
- 2014-01-21 ES ES14701948.3T patent/ES2635502T3/es active Active
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Also Published As
Publication number | Publication date |
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PL2948499T3 (pl) | 2017-10-31 |
BR112015015915A2 (pt) | 2017-07-11 |
CN104937014A (zh) | 2015-09-23 |
ES2635502T3 (es) | 2017-10-04 |
WO2014114617A1 (de) | 2014-07-31 |
AU2014210052B2 (en) | 2016-12-22 |
US9540509B2 (en) | 2017-01-10 |
BR112015015915B1 (pt) | 2020-10-13 |
EP2948499B1 (de) | 2017-06-14 |
CA2899268C (en) | 2020-11-24 |
TW201434607A (zh) | 2014-09-16 |
TWI602671B (zh) | 2017-10-21 |
JP6250068B2 (ja) | 2017-12-20 |
JP2016509638A (ja) | 2016-03-31 |
AR094597A1 (es) | 2015-08-12 |
PT2948499T (pt) | 2017-08-09 |
EP2948499A1 (de) | 2015-12-02 |
CA2899268A1 (en) | 2014-07-31 |
AU2014210052A1 (en) | 2015-07-02 |
US20150376404A1 (en) | 2015-12-31 |
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