CN104796081A - 一种以镍氢锂为原料的自持发热方法及设备 - Google Patents
一种以镍氢锂为原料的自持发热方法及设备 Download PDFInfo
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- CN104796081A CN104796081A CN201510035036.8A CN201510035036A CN104796081A CN 104796081 A CN104796081 A CN 104796081A CN 201510035036 A CN201510035036 A CN 201510035036A CN 104796081 A CN104796081 A CN 104796081A
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- nickel
- self
- lithium
- hydrogen
- heating
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 238000010438 heat treatment Methods 0.000 title claims abstract description 19
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 239000001257 hydrogen Substances 0.000 title claims abstract description 12
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 12
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 12
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 8
- 238000000034 method Methods 0.000 title abstract description 10
- 239000000463 material Substances 0.000 claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000446 fuel Substances 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims abstract 2
- 229910000103 lithium hydride Inorganic materials 0.000 claims description 6
- 150000002431 hydrogen Chemical class 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 claims 2
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 claims 2
- 241000720974 Protium Species 0.000 claims 2
- YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical compound [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 claims 2
- 229910052805 deuterium Inorganic materials 0.000 claims 2
- 150000002739 metals Chemical class 0.000 claims 2
- 229910052722 tritium Inorganic materials 0.000 claims 2
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims 1
- 239000002196 Pyroceram Substances 0.000 claims 1
- 239000013626 chemical specie Substances 0.000 claims 1
- 238000004146 energy storage Methods 0.000 claims 1
- 239000012280 lithium aluminium hydride Substances 0.000 claims 1
- 239000012528 membrane Substances 0.000 claims 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims 1
- 239000012780 transparent material Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 230000002159 abnormal effect Effects 0.000 abstract description 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 abstract 1
- 238000007599 discharging Methods 0.000 abstract 1
- 239000010453 quartz Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- KTSFMFGEAAANTF-UHFFFAOYSA-N [Cu].[Se].[Se].[In] Chemical compound [Cu].[Se].[Se].[In] KTSFMFGEAAANTF-UHFFFAOYSA-N 0.000 description 2
- 238000005485 electric heating Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- -1 after filtration Chemical compound 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02S—GENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
- H02S40/00—Components or accessories in combination with PV modules, not provided for in groups H02S10/00 - H02S30/00
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B10/00—Integration of renewable energy sources in buildings
- Y02B10/10—Photovoltaic [PV]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
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- Hybrid Cells (AREA)
- Photovoltaic Devices (AREA)
- Fuel Cell (AREA)
Abstract
镍在一定条件下(如加热,放电等)可以和氢发生反应,并产生异常的放热,发光效应。其释放出来的光热可以大于输入能量,在过去的试验中由于重现性不好并未引起我们的重视。本发明采用镍,氢,锂三元素或包含三种元素的化合物为原料,使用耐高温透明石英玻璃或其他透明耐高温材料制备成反应腔体,通过电流激发使燃料发生反应。该方法解决了以往重现问题,反应器产生大量的光和热,其中光能量通过聚光光伏器件转化为电能回流给反应器,热量通过热交换系统输出。整个系统所用材料充裕,结构简单易于实现,并且高效,环保,为家用或商业供暖提供了一条新的解决方案。
Description
技术领域
新型能源及设备。
背景技术
随着经济的发展,人类对能源的需求越来越大,传统化石能源由于储量有限,且对环境有不良影响,因此我们迫切需要一种清洁,高效,无污染的新型能源。随着凝聚态物理学的发展,科学家发现储氢金属如钯,镍在一定条件下(如加热,放电等)可以和氢发生反应,并产生异常的放热,发光效应。其释放出来的光热可以大于输入能量,在过去的试验中由于重现性不好并未引起我们的重视。本发明采用金属锂元素作为催化剂,使用耐高温透明石英玻璃作为反应器材料,通过电流激发使燃料发生反应。该方法解决了以往重现问题,反应器产生大量的光和热,其中光能量通过聚光光伏器件转化为电能回流给反应器,热量通过热交换系统输出。整个系统所用材料充裕,结构简单易于实现,并且高效,环保,为家用或商业供暖提供了一条新的解决方案。
发明内容
本发明公开了一种属于能源领域的以镍氢锂三种元素(1)为原料的自持发热方法及设备,所述方法采用石英玻玻璃等耐高温材料制备成反应容器(2),反应容器在密封之前加入处理过的镍粉,锂的氢化物或金属锂和氢气,采用在反应器两端金属电极输入电流使三元素组成的燃料电离,并发生反应,同时以发光发热的形式输出能量(反应器结构参看所附图2)。
本发明主要由耐高温石英等材料制备出反应腔体,镍,锂,氢及锂氢化物组成的发热原料,电加热或激发输入系统,薄膜聚光光伏系统(3),以及水或者风形成的输出热量外循环五部分组成。该系统具有结构简单,电热光转换效率高,输出能量大于输入能量,可以有效的节约电力资源,广泛应用于家庭,商业采暖,为工业提供热力资源等(自持反应设备结构参看图1)。
附图说明
图1是反应器总体结构外观图
图2是反应器腔体封装示意图
方法实例:将纳米镍粉用0.5~1%左右的稀盐酸浸泡数个小时,去掉表面的氧化层,然后用去离子水浸泡洗涤至PH值中性,再用乙醇中浸泡,过滤后将镍粉放入真空干燥箱内干燥备用。在惰性气体保护的情况下,将处理过的镍粉和氢化锂混合均匀后备用。氢化锂,镍粉约50毫克装入两头具有电极的的石英反应器内,中间抽真空处理,然后用氢氧火焰密封(氢化锂在高温下容易发生分解,因此封口的侧管可以适当留长一点)。密封完以后,将石英反应器放入电炉中避光加温,使氢化锂分解成氢气和锂蒸汽,反应器腔体制备完成(如图1所示)。启动反应器可以采用外接220伏电源或者蓄电池,通过镇流器和触发器启动反应器。反应器释放的光能通过高效铜铟镓硒(CIGS)聚光式光伏组件将反应器发出的强光转 化成电流经过逆变器和镇流器使反应器自持工作,产生的热量则由外部热交换系统输出。
Claims (6)
1.反应器所采用的燃料由镍,氢,锂三种元素构成,或者包含这三种元素组成的燃料。
2.镍可以是单体金属镍,镍的同位素,或者是化学形式的镍,如:氯化镍,等。
3.氢包含氢的同位素,如氕,氘,氚,以及由氕氘氚三元素所构成的化合物。
4.锂元素包括单质金属锂,氢化锂,氢化铝锂等。
5. 反应器外壳所采用的材料为透明石英,也可以为耐高温玻璃,以及其他耐高温透明材料。
6. 反应器的所发出的强光由薄膜光伏组件转化为电能,所产生的电能使反应器自持发热发光,也可以采用外接电源,如:外部电网或者储能电池启动或者辅助反应器达到自持。
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105702559A (zh) * | 2016-03-28 | 2016-06-22 | 毛智杰 | 一种新型高效节能气体放电灯管的制备 |
CN106449125A (zh) * | 2016-09-24 | 2017-02-22 | 毛智杰 | 一种新型镍氢锂固态电解质的制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101863454A (zh) * | 2009-04-17 | 2010-10-20 | 财团法人工业技术研究院 | 固态氢燃料及其制造方法和使用方法 |
CN103061885A (zh) * | 2012-12-25 | 2013-04-24 | 国电新能源技术研究院 | 一种互补式绿色能源供给系统 |
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Patent Citations (2)
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CN101863454A (zh) * | 2009-04-17 | 2010-10-20 | 财团法人工业技术研究院 | 固态氢燃料及其制造方法和使用方法 |
CN103061885A (zh) * | 2012-12-25 | 2013-04-24 | 国电新能源技术研究院 | 一种互补式绿色能源供给系统 |
Non-Patent Citations (1)
Title |
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张轼超: ""温度和压力触发氢镍气固系统异常发热的研究"", 《工程科技Ⅰ辑》 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105702559A (zh) * | 2016-03-28 | 2016-06-22 | 毛智杰 | 一种新型高效节能气体放电灯管的制备 |
CN106449125A (zh) * | 2016-09-24 | 2017-02-22 | 毛智杰 | 一种新型镍氢锂固态电解质的制备方法 |
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