CN104796081B - 一种以镍氢锂为原料的自持发热方法及设备 - Google Patents
一种以镍氢锂为原料的自持发热方法及设备 Download PDFInfo
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- CN104796081B CN104796081B CN201510035036.8A CN201510035036A CN104796081B CN 104796081 B CN104796081 B CN 104796081B CN 201510035036 A CN201510035036 A CN 201510035036A CN 104796081 B CN104796081 B CN 104796081B
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- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 15
- 239000002994 raw material Substances 0.000 title claims abstract description 10
- 238000010438 heat treatment Methods 0.000 title abstract description 10
- 238000000034 method Methods 0.000 title abstract description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000006243 chemical reaction Methods 0.000 claims abstract description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 8
- 239000001257 hydrogen Substances 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 5
- 230000000694 effects Effects 0.000 claims abstract description 4
- 150000001875 compounds Chemical class 0.000 claims abstract 4
- 239000000203 mixture Substances 0.000 claims description 7
- 229910000103 lithium hydride Inorganic materials 0.000 claims description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 claims 2
- 241000720974 Protium Species 0.000 claims 2
- 239000007789 gas Substances 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 6
- 238000010276 construction Methods 0.000 abstract description 3
- 239000000446 fuel Substances 0.000 abstract description 3
- 230000002159 abnormal effect Effects 0.000 abstract description 2
- 238000009833 condensation Methods 0.000 abstract description 2
- 230000005494 condensation Effects 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- -1 heating Chemical compound 0.000 abstract description 2
- 150000002431 hydrogen Chemical class 0.000 abstract description 2
- 238000010992 reflux Methods 0.000 abstract description 2
- 239000000843 powder Substances 0.000 description 5
- 239000010453 quartz Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000005492 condensed matter physics Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02S—GENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
- H02S40/00—Components or accessories in combination with PV modules, not provided for in groups H02S10/00 - H02S30/00
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B10/00—Integration of renewable energy sources in buildings
- Y02B10/10—Photovoltaic [PV]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Abstract
镍在一定条件下（如加热，放电等）可以和氢发生反应，并产生异常的放热，发光效应。其释放出来的光热可以大于输入能量，在过去的试验中由于重现性不好并未引起我们的重视。本发明采用镍，氢，锂三元素或包含三种元素的化合物为原料，使用耐高温透明石英玻璃或其他透明耐高温材料制备成反应腔体，通过电流激发使燃料发生反应。该方法解决了以往重现问题，反应器产生大量的光和热，其中光能量通过聚光光伏器件转化为电能回流给反应器，热量通过热交换系统输出。整个系统所用材料充裕，结构简单易于实现，并且高效，环保，为家用或商业供暖提供了一条新的解决方案。
Description
技术领域
新型能源及设备。
背景技术
随着经济的发展，人类对能源的需求越来越大，传统化石能源由于储量有限，且对环境有不良影响，因此我们迫切需要一种清洁，高效，无污染的新型能源。随着凝聚态物理学的发展，科学家发现储氢金属如钯，镍在一定条件下(如加热，放电等)可以和氢发生反应，并产生异常的放热，发光效应。其释放出来的光热可以大于输入能量，在过去的试验中由于重现性不好并未引起我们的重视。本发明采用金属锂元素作为催化剂，使用耐高温透明石英玻璃作为反应器材料，通过电流激发使燃料发生反应。该方法解决了以往重现问题，反应器产生大量的光和热，其中光能量通过聚光光伏器件转化为电能回流给反应器，热量通过热交换系统输出。整个系统所用材料充裕，结构简单易于实现，并且高效，环保，为家用或商业供暖提供了一条新的解决方案。
发明内容
本发明公开了一种属于能源领域的以镍氢锂三种元素(1)为原料的自持发热方法及设备，所述方法采用石英玻玻璃等耐高温材料制备成反应容器(2)，反应容器在密封之前加入处理过的镍粉，锂的氢化物或金属锂和氢气，采用在反应器两端金属电极输入电流使三元素组成的燃料电离，并发生反应，同时以发光发热的形式输出能量(反应器结构参看所附图2)。
本发明主要由耐高温石英等材料制备出反应腔体，镍，锂，氢及锂氢化物组成的发热原料，电加热或激发输入系统，薄膜聚光光伏系统(3)，以及水或者风形成的输出热量外循环五部分组成。该系统具有结构简单，电热光转换效率高，输出能量大于输入能量，可以有效的节约电力资源，广泛应用于家庭，商业采暖，为工业提供热力资源等(自持反应设备结构参看图1)。
附图说明
图1是反应器总体结构外观图
图2是反应器腔体封装示意图
方法实例：将纳米镍粉用0.5～1％左右的稀盐酸浸泡数个小时，去掉表面的氧化层，然后用去离子水浸泡洗涤至PH值中性，再用乙醇中浸泡，过滤后将镍粉放入真空干燥箱内干燥备用。在惰性气体保护的情况下，将处理过的镍粉和氢化锂混合均匀后备用。氢化锂，镍粉约50毫克装入两头具有电极的的石英反应器内，中间抽真空处理，然后用氢氧火焰密封(氢化锂在高温下容易发生分解，因此封口的侧管可以适当留长一点)。密封完以后，将石英反应器放入电炉中避光加温，使氢化锂分解成氢气和锂蒸汽，反应器腔体制备完成(如图一所示)。启动反应器可以采用外接220伏电源或者蓄电池，通过镇流器和触发器启动反应器。反应器释放的光能通过高效铜铟镓硒(CIGS)聚光式光伏组件将反应器发出的强光转化成电流经过逆变器和镇流器使反应器自持工作，产生的热量则由外部热交换系统输出。
Claims (2)
1.一种以镍氢锂为原料的自持发热设备，其由反应器腔体，反应器两端电极以及反应器内 反应原料三部分组成，反应器腔体由透明耐高温材料制备；两端金属电极采用不含金属镍和钯的材料制备，电极的作用是对反应原料进行电离，使其产生气体放电发光效应；反应器内反应原料包含金属锂和氢气组成的混合物或包含有锂和氢元素组成的化合物。
2.根据权利要求1所述的一种以镍氢锂为原料的自持发热设备,反应器内反应原料包含有锂和氢元素组成的化合物，化合物为氢化锂。
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| CN104796081B true CN104796081B (zh) | 2016-11-30 |
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