CN104736238B - 用于获得高级醇的催化剂 - Google Patents

用于获得高级醇的催化剂 Download PDF

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CN104736238B
CN104736238B CN201380034827.8A CN201380034827A CN104736238B CN 104736238 B CN104736238 B CN 104736238B CN 201380034827 A CN201380034827 A CN 201380034827A CN 104736238 B CN104736238 B CN 104736238B
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catalyst
butanol
catalysts
hydrotalcite
precipitation
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CN104736238A (zh
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R·阿尔霍纳安托林
J·L·桑斯阿格
A·科尔曼卡诺斯
M·E·多米内
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Carterix Corp
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A Wengeya Bioenergy Technew SA
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/825—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with gallium, indium or thallium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/007—Mixed salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of gallium, indium or thallium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
    • C07C29/34—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups by condensation involving hydroxy groups or the mineral ester groups derived therefrom, e.g. Guerbet reaction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201380034827.8A 2012-06-29 2013-06-28 用于获得高级醇的催化剂 Active CN104736238B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12382262.9 2012-06-29
EP12382262.9A EP2679303B1 (en) 2012-06-29 2012-06-29 Catalyst and its preparation process for obtaining higher alcohols
PCT/ES2013/070442 WO2014001595A1 (es) 2012-06-29 2013-06-28 Catalizador para la obtención de alcoholes superiores

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CN104736238A CN104736238A (zh) 2015-06-24
CN104736238B true CN104736238B (zh) 2017-09-08

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US (1) US9266096B2 (enExample)
EP (1) EP2679303B1 (enExample)
KR (1) KR102113105B1 (enExample)
CN (1) CN104736238B (enExample)
BR (1) BR112014032469B1 (enExample)
CA (1) CA2877970C (enExample)
ES (1) ES2855323T3 (enExample)
HU (1) HUE053582T2 (enExample)
IN (1) IN2014MN02642A (enExample)
MX (1) MX357222B (enExample)
RU (1) RU2014152878A (enExample)
WO (1) WO2014001595A1 (enExample)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014130465A1 (en) * 2013-02-19 2014-08-28 Greenyug, Llc Production of higher alcohols
BR112016012629B1 (pt) 2013-12-04 2020-12-01 Rescurve, Llc método e sistema de destilação reativa
WO2015097285A1 (en) 2013-12-27 2015-07-02 Abengoa Bioenergia Nuevas Tecnologias, S.A. Process for the preparation of higher alcohols from lower alcohols by guerbet condensation
ES2570231B1 (es) * 2014-11-14 2017-04-19 Abengoa Bioenergia Nuevas Tecnologias, S.A. Proceso para la preparación de alcoholes superiores a partir de etanol y n-hexanol mediante condensación de guerbet
ES2570233B1 (es) 2014-11-14 2017-02-22 Abengoa Bioenergía Nuevas Tecnologías, S.A. Procedimiento de obtención de 1-octanol
ES2570227B1 (es) * 2014-11-14 2017-04-19 Abengoa Bioenergia Nuevas Tecnologias, S.A. Proceso para la preparación de alcoholes superiores a partir de etanol y n-hexanol mediante condensación de guerbet
WO2016075531A1 (en) 2014-11-14 2016-05-19 Abengoa Bioenergia Nuevas Tecnologias, S.A. Process for the preparation of higher alcohols from ethanol and n-hexanol by guerbet condensation
CA2994846C (en) 2015-08-19 2024-02-20 Rescurve, Llc Composition of catalysts for conversion of ethanol to n-butanol and higher alcohols
WO2017093473A1 (en) 2015-12-02 2017-06-08 Universiteit Gent Guerbet condensation reaction
ES2647963B1 (es) 2016-05-26 2018-10-03 Abengoa Bioenergía Nuevas Tecnologías, S.A. Procedimiento de obtención de 1-octanol
CN107983356B (zh) * 2017-12-07 2020-12-25 中国科学院山西煤炭化学研究所 一种合成高级支链醇的催化剂及制备方法和应用
CN111604056B (zh) * 2020-06-03 2023-05-12 中国科学院山西煤炭化学研究所 一种负载型金属氧化物催化剂及其制备方法和应用
CN112619654A (zh) * 2020-11-06 2021-04-09 上海簇睿低碳能源技术有限公司 一种甲烷二氧化碳重整制合成气的催化剂及其制备方法
CN112827483B (zh) * 2020-12-29 2022-10-25 宁波申江科技股份有限公司 一种制氢催化剂及其制备方法和应用
CN112916010B (zh) * 2021-01-26 2022-09-16 北京化工大学 一种炔烃选择性加氢用Cuy/MMgOx催化剂及其制备方法
CN117920221B (zh) * 2024-01-08 2024-12-03 东北农业大学 一种花球状镍钴铝层状氧化物催化剂及其制备方法和应用

Citations (4)

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US5219816A (en) * 1991-12-20 1993-06-15 Exxon Research & Engineering Company Dehydrogenation catalysts and process for preparing the catalysts
WO2000038832A1 (en) * 1998-12-23 2000-07-06 Den Norske Stats Oljeselskap A.S Catalysts consisting of metals on hydrotalcite-based carrier materials, and method for the preparation thereof
WO2009097312A1 (en) * 2008-01-28 2009-08-06 E.I. Du Pont De Nemours And Company Catalytic conversion of ethanol and hydrogen to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite/metal carbonate
EP2366664A1 (en) * 2010-03-09 2011-09-21 Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. Palladium-modified hydrotalcites and their use as catalyst precursors

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DE8600273U1 (de) * 1986-01-08 1986-03-06 Paul Hellermann Gmbh, 2080 Pinneberg Spannband, insbesondere zum Binden von langgestreckten Gegenständen
US5300695A (en) 1992-12-07 1994-04-05 Amoco Corporation Process for preparing alcohols
US5387570A (en) 1993-05-07 1995-02-07 Exxon Research & Engineering Co. Catalysts for iso-alcohol synthesis from CO + H2
KR20070085516A (ko) 2004-12-03 2007-08-27 가부시키가이샤 상기 고분자 알코올의 합성방법
WO2009026510A1 (en) 2007-08-22 2009-02-26 E. I. Du Pont De Nemours And Company Catalytic conversion of ethanol to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite catalyst
WO2009026523A1 (en) 2007-08-22 2009-02-26 E.I. Du Pont De Nemours And Company Catalytic conversion of ethanol to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite/metal carbonate
WO2009097310A1 (en) 2008-01-28 2009-08-06 E. I. Du Pont De Nemours And Company Catalytic conversion of ethanol and hydrogen to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite containing the anion of ethylenediaminetetraacetic acid
US8318989B2 (en) 2008-12-22 2012-11-27 E I Du Pont De Nemours And Company Process for producing guerbet alcohols using water tolerant basic catalysts

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
US5219816A (en) * 1991-12-20 1993-06-15 Exxon Research & Engineering Company Dehydrogenation catalysts and process for preparing the catalysts
WO2000038832A1 (en) * 1998-12-23 2000-07-06 Den Norske Stats Oljeselskap A.S Catalysts consisting of metals on hydrotalcite-based carrier materials, and method for the preparation thereof
WO2009097312A1 (en) * 2008-01-28 2009-08-06 E.I. Du Pont De Nemours And Company Catalytic conversion of ethanol and hydrogen to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite/metal carbonate
EP2366664A1 (en) * 2010-03-09 2011-09-21 Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. Palladium-modified hydrotalcites and their use as catalyst precursors

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Publication number Publication date
CN104736238A (zh) 2015-06-24
EP2679303A1 (en) 2014-01-01
KR20150090019A (ko) 2015-08-05
MX2015000225A (es) 2015-08-12
WO2014001595A1 (es) 2014-01-03
EP2679303B1 (en) 2020-11-11
KR102113105B1 (ko) 2020-05-21
US20150148569A1 (en) 2015-05-28
HUE053582T2 (hu) 2021-07-28
CA2877970C (en) 2020-11-17
MX357222B (es) 2018-06-28
BR112014032469A2 (pt) 2017-06-27
RU2014152878A (ru) 2016-08-20
BR112014032469B1 (pt) 2021-02-09
CA2877970A1 (en) 2014-01-03
US9266096B2 (en) 2016-02-23
IN2014MN02642A (enExample) 2015-10-16
ES2855323T3 (es) 2021-09-23

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