CN104710685A - Rich mineral paper tableware, and preparation method thereof - Google Patents

Rich mineral paper tableware, and preparation method thereof Download PDF

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Publication number
CN104710685A
CN104710685A CN201310677761.6A CN201310677761A CN104710685A CN 104710685 A CN104710685 A CN 104710685A CN 201310677761 A CN201310677761 A CN 201310677761A CN 104710685 A CN104710685 A CN 104710685A
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China
Prior art keywords
paper tableware
stone paper
carried out
calcium carbonate
production
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CN201310677761.6A
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Chinese (zh)
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杨金龙
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Individual
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Individual
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Priority to CN201310677761.6A priority Critical patent/CN104710685A/en
Publication of CN104710685A publication Critical patent/CN104710685A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/06Biodegradable
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses rich mineral paper tableware, and a production method thereof. The rich mineral paper tableware comprises calcium carbonate, polyethylene, polypropylene, an anti-oxidant, a resin, ACR adhesive, a composite stabilizing modifier, and wood fiber powder. The production method comprises following steps: (1) the raw materials are delivered into a mixer for high speed mixing at a certain ratio; (2) modification is carried out, wherein a mixture obtained via high speed mixing is subjected to full dispersing and kneading so as to obtain a strip material or a plate material; (3) pelleting is carried out, wherein a pelletizer is used for preparing material particles from the obtained strip material or the plate material, so that it is convenient for transporting, raw materials can be provided for a plurality of parallel production lines, and production efficiency is increased; and (4) production is carried out, wherein the material particles are subjected to extrusion and blow moulding so as to obtain needed products.

Description

Stone paper tableware and preparation method thereof
Technical field
The present invention relates to a kind of environment protecting tableware, be specially stone paper tableware and preparation method thereof.
Background technology
Ecotope is the primary condition of human survival and development, is the basis of socio-economic development.The protection and harnessing of ecotope, is not only the significant problem paid close attention in the world, and be related to 21st century China's economy and society Sustainable development.Forest is the skylight of ecotope, the Green Ark of the mankind, the cradle of civilization, research and practice shows, forest maintains future and the destiny of the mankind, as the theme of land ecology, forest is the key solving global ecological environment crisis, it can improve air quality, available protecting diversity of organism, prevent erosion, check desertification, prevent Soil degradation, alleviate the crisis of water resources, eliminate or alleviate noise pollution ... forest is the tie of relationship environment and sustainable economic development, it provides physical environment basis for Sustainable development, it is the main body of bioenergy.
United nations environment form claims: forest is as the most original maximum on the earth ecosystem, its area urgency of 30 years is in the past according to minimizing, only in the 90's of last century, Global Forests area just decreases 9,400 ten thousand hectares, account for 2.4% of the forest total area, indiscriminate felling of trees, overfarming makes the arable land serious degradation in the world 23%, the land area in the whole world more than 1/3 faces the prestige association of Desertification, and the water supply in the whole world has also lighted red light.
Data shows, the annual wood of China just total amount consumed reaches 1.7 billion cubic meters, and domestic 1.2 billion cubic meters that only can provide, imbalance between supply and demand is very outstanding, after it is predicted 3 years, China's timber supply and demand breach will reach 6000-7000 ten thousand stere, will reach 1.4-1.5 billion cubic meter to this numeral in 2015.
Statistics shows: the annual production and application of China reaches 60,000,000,000 pairs in the disposable wood sanitary chopsticks of catering trade, needs to blow to cut down 2,500 ten thousand large trees grown up 15 years, reduces area of woods 200 ten thousand stere.The disposable lunch-box that China uses every year is more than 12,000,000,000, the disposal plastic cup consumed and dixie cup reach more than 50,000,000,000, these Dining tool products are being provided convenience for people efficiently simultaneously, also many potential risks are brought, a large amount of consumption and the waste forest reserves, the green ecological environment that havoc people depend on for existence.They not easily reclaim, and be 200-400 at the degradation cycle of occurring in nature, if be buried in soil and the saturating acidity greatly affecting soil is hindered crop growth, eaten the lighter's Digestive tract by livestock by mistake and obtain seriously ill then dead, if burn, discharge a large amount of harmful poisonous gas.Owing to using these wastes that accumulate over a long period to cause the ecological environmental pollution be on the rise in a large number, having become global public hazards, to be named as white pollution be the invention suffering cake most, annoying China and the world.
How to control and eliminate this white pollution spread the Social Events that development has become the world today.For this reason many countries and regions start for a long time nontoxic can the development of degradable or renewable resource tableware material, successively have developed can be degradable the disposable dinner ware made by vegetable materials such as starch and grain shell, straw, bagasses or take starch as the polypropylene biological degradable tableware of main component, light, bio-degradable tableware and paper table ware are multiple, wherein simple, the large low price of output of the two degradative tableware indices good process of polystyrene, but it is undesirable to lack recovery value degradation effect.
Light, bio-degradable tableware in acrylic material, add the starch of more than 50% and the photo-thermal electricity of 10% urges depressant prescription, chemical reaction does not occur for starch in this degradable dinner set taking starch as major ingredient and auxiliary agent and poly-hydrocarbons changes, and therefore, the character of its plastics do not change.Only be to make its fragmentation by the effect of starch with the difference of common porous plastics mess-tin, fundamentally do not solve the character of plastic foam.Paper table ware can carry out renewable resources, easily degrade back to nature due to the value itself with recycling, and in degradation process without any hazardous and noxious substances remain in large spontaneous combustion be on our times generally acknowledge [Green Packaging] but its raw material is wood pulp and straw pulp, straw pulp is produced the problem of environmental pollution compatriots caused and is all known, wood pulp consumes the ecotope that above-mentioned forest resourceies destruction people Men Lai has survived in a large number, in addition the scarcity of resource is that it can not sustainable development, is faced with the double contradition of eco-environmental conditions.
Summary of the invention
Technical problem solved by the invention is to provide a kind of stone paper tableware and preparation method thereof, to solve the problem proposed in above-mentioned background technology.
For achieving the above object, the invention provides following technical scheme:
Stone paper tableware, comprises following parts by weight ingredient: calcium carbonate 60-80 part, polyethylene 18-43 part polypropylene 20-35 part, antioxidant 0.5-1 part, resin, ACR tackiness agent is 0.5-1.5 part, stable composition properties-correcting agent 1.5-2.5 part, wood fiber powder 25-35 part, fineness 80 order.
Described calcium carbonate particle diameter is 3-5 μm.
Described polyethylene two-way stretch need use high-density blown film level, d=0.95g/cm3, MI=0.05g/10min.
The preparation method of stone paper tableware, comprises the following steps:
(1) raw material is thrown in by a certain percentage carry out high-speed mixing into muller;
(2) modification: the raw material of working good is carried out fully dispersion and makes strip material or plate after rubbing by muller;
(3) granulation: use tablets press, by obtained strip or the finish mix grain of plate, material grain not only facilitates transport but also can supply raw materials to many parallel production lines, enhances productivity;
(4) produce: by material grain through extruding, blowing process makes desired product.
The present invention, compared with conventional art, has the following advantages:
The present invention does not adopt vegetable fibre, does not fall trees, and can save a large amount of timber, and conservation of nature is ecological; Do not need to add the chemical feedstockss such as strong acid, highly basic, SYNTHETIC OPTICAL WHITNER, not waste discharge, waste residue and toxic and harmful, belongs to Green Product.Product has good mechanical property, waterproof, protection against the tide, mothproof, folding, resistance toly to tear, oil resistant, nontoxic, tasteless, pollution-free, geometrical dimension stable, print distinctness is high, effective, can natural degradation be the features such as powder back to nature after abandoning.
Embodiment
Below in conjunction with the embodiment of the present invention, be clearly and completely described the technical scheme in the embodiment of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1
Stone paper tableware, comprises following parts by weight ingredient: calcium carbonate 60-80 part, polyethylene 18-43 part polypropylene 20-35 part, antioxidant 0.5-1 part, resin, ACR tackiness agent is 0.5-1.5 part, stable composition properties-correcting agent 1.5-2.5 part, wood fiber powder 25-35 part, fineness 80 order.
Described calcium carbonate particle diameter is 3-5 μm.
Described polyethylene two-way stretch need use high-density blown film level, d=0.95g/cm3, MI=0.05g/10min.
The preparation method of stone paper tableware, comprises the following steps:
(1) raw material is thrown in by a certain percentage carry out high-speed mixing into muller;
(2) modification: the raw material of working good is carried out fully dispersion and makes strip material or plate after rubbing by muller;
(3) granulation: use tablets press, by obtained strip or the finish mix grain of plate, material grain not only facilitates transport but also can supply raw materials to many parallel production lines, enhances productivity;
(4) produce: by material grain through extruding, blowing process makes desired product.
To those skilled in the art, obviously the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit of the present invention or essential characteristic, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.
In addition, be to be understood that, although this specification sheets is described according to embodiment, but not each embodiment only comprises an independently technical scheme, this narrating mode of specification sheets is only for clarity sake, those skilled in the art should by specification sheets integrally, and the technical scheme in each embodiment also through appropriately combined, can form other embodiments that it will be appreciated by those skilled in the art that.

Claims (4)

1. stone paper tableware, it is characterized in that, comprise following parts by weight ingredient: calcium carbonate 60-80 part, polyethylene 18-43 part, polypropylene 20-35 part, antioxidant 0.5-1 part, resin, ACR tackiness agent is 0.5-1.5 part, stable composition properties-correcting agent 1.5-2.5 part, wood fiber powder 25-35 part, fineness 80 order.
2. stone paper tableware according to claim 1, is characterized in that, described calcium carbonate particle diameter is 3-5 μm.
3. stone paper tableware according to claim 1, is characterized in that, described polyethylene two-way stretch need use high-density blown film level, d=0.95g/cm3, MI=0.05g/10min.
4. the preparation method of stone paper tableware, is characterized in that, comprises the following steps:
(1) raw material is thrown in by a certain percentage carry out high-speed mixing into muller;
(2) modification: the raw material of working good is carried out fully dispersion and makes strip material or plate after rubbing by muller;
(3) granulation: use tablets press, by obtained strip or the finish mix grain of plate;
(4) produce: by material grain through extruding, blowing process makes desired product.
CN201310677761.6A 2013-12-13 2013-12-13 Rich mineral paper tableware, and preparation method thereof Pending CN104710685A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310677761.6A CN104710685A (en) 2013-12-13 2013-12-13 Rich mineral paper tableware, and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201310677761.6A CN104710685A (en) 2013-12-13 2013-12-13 Rich mineral paper tableware, and preparation method thereof

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CN104710685A true CN104710685A (en) 2015-06-17

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106220961A (en) * 2016-08-12 2016-12-14 浙江山联新材料科技有限公司 The thin film being made up of calcium carbonate and manufacture method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1270969A (en) * 1999-04-16 2000-10-25 段锡黎 Plastic material with high-content inorganic filling and its production process and equipment
CN101659770A (en) * 2009-09-05 2010-03-03 常州金卡基材有限公司 Flame-retardant synthetic paper
CN102634117A (en) * 2012-04-26 2012-08-15 昆明钢铁控股有限公司 Masterbatch for stone paper and manufacturing method of masterbatch for stone paper
CN102775677A (en) * 2011-05-13 2012-11-14 陈昭田 Green and environmental protection paper and its manufacturing method
CN103333395A (en) * 2013-07-15 2013-10-02 合肥工业大学 High fill polyolefin composite film masterbatch and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1270969A (en) * 1999-04-16 2000-10-25 段锡黎 Plastic material with high-content inorganic filling and its production process and equipment
CN101659770A (en) * 2009-09-05 2010-03-03 常州金卡基材有限公司 Flame-retardant synthetic paper
CN102775677A (en) * 2011-05-13 2012-11-14 陈昭田 Green and environmental protection paper and its manufacturing method
CN102634117A (en) * 2012-04-26 2012-08-15 昆明钢铁控股有限公司 Masterbatch for stone paper and manufacturing method of masterbatch for stone paper
CN103333395A (en) * 2013-07-15 2013-10-02 合肥工业大学 High fill polyolefin composite film masterbatch and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106220961A (en) * 2016-08-12 2016-12-14 浙江山联新材料科技有限公司 The thin film being made up of calcium carbonate and manufacture method thereof

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Application publication date: 20150617