CN101659770A - Flame-retardant synthetic paper - Google Patents
Flame-retardant synthetic paper Download PDFInfo
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- CN101659770A CN101659770A CN200910182753A CN200910182753A CN101659770A CN 101659770 A CN101659770 A CN 101659770A CN 200910182753 A CN200910182753 A CN 200910182753A CN 200910182753 A CN200910182753 A CN 200910182753A CN 101659770 A CN101659770 A CN 101659770A
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Abstract
The invention relates to flame-retardant synthetic paper. The flame-retardant synthetic paper comprises polypropylene resin, polyethylene resin, an inorganic filler, a coupling agent, an antistatic agent, a lubricant and a coloring agent. The flame-retardant synthetic paper is characterized in that the flame-retardant synthetic paper further comprises a flame retardant. Raw materials and the partsby weight thereof are as follows: 100PHR of polypropylene resin, 20-90PHR of polyethylene resin, 50-300PHR of inorganic filler, 1-8PHR of coupling agent, 1-5PHR of antistatic agent, 0.5-5PHR of lubricant, 5-20PHR of coloring agent and 5-35PHR of flame retardant. Blending, mixing, rubberizing, molding by a calendar, leading out by a leading roller, embossing, cooling, corona treatment and windingare carried out on all the raw materials of the flame-retardant synthetic paper for preparing a product. The flame-retardant synthetic paper has the flame-retardant function and is difficult to burn.Even the flame-retardant synthetic paper is incinerated in a high-temperature incinerator, the flame-retardant synthetic paper can not produce harmful gas, not cause secondary pollution to society andhuman beings and be in line with the requirements of environmental protection.
Description
Technical field
The present invention relates to the synthetic paper technical field, specifically a kind of flame-retardant synthetic paper with fire retardation.
Background technology
At present, the synthetic paper of production relates to the macromolecular material synthesis technical field.Its development has had the history of decades abroad, because the production technology difficulty is big, production unit requires high, enterprise that in the world can mass production is few, has only several companies such as du pont company, Kimberly-Clark company, Japanese prince company and TaiWan, China Nan Ya Plastics company can mass-produce the synthetic paper of Gao Quality amount.Domestic also have the development and production of minority enterprise to make the inferior synthetic paper of high gear with macromolecular material.But macromolecular material such as acrylic resin, its oxygen index of polyvinyl resin be below 21, their easy firings and burn up very fiercely, and the thermal oxidative reaction that it is complicated has and emits the feature of sending out dense smoke and red-hot flame, does not also extinguish even leave flame.All there is inflammable problem in the synthetic paper of being made for main raw material by macromolecular material such as acrylic resin, polyvinyl resin etc. in the market.
Summary of the invention
The purpose of this invention is to provide a kind of that make of macromolecular material, have an anti-flaming function; nonflammable; even can not produce obnoxious flavour when in high-temperature incinerator, burning yet, can be to society and the human flame-retardant synthetic paper that causes the secondary public hazards and meet the national environmental protection requirement.
The objective of the invention is to adopt following scheme to realize: a kind of flame-retardant synthetic paper comprises acrylic resin, polyvinyl resin, inorganic fillings, coupling agent, static inhibitor, lubricant, tinting material.Be characterized in: also comprise fire retardant.Its each raw material and proportioning thereof are: acrylic resin 100PHR, polyvinyl resin 20-90PHR, inorganic fillings 50-300PHR, coupling agent 1-8PHR, static inhibitor 1-5PHR, lubricant 0.5-5PHR, tinting material 5-20PHR, fire retardant 5-35PHR.
The preparation method of this flame-retardant synthetic paper comprises following processing step: at first extract each raw material by the above-mentioned raw materials proportioning.Then confected materials is sent into high-speed mixer, mixed 12-18 minute, it is mixed.Compound is transported to planetary extruder carries out mixing gel, the planetary extruder temperature is set at 170-190 ℃.Be transported to the rolling press moulding after extruding, the rolling press temperature is set at 190-210 ℃, and velocity contrast is 1-2m/min between each roller.Draw through doff roll again and carry out embossed.Again through after online group cool off, corona treatment, the corona value of product is reached more than 40 dyne.Again after the center curl carry out rolling product, also can cut this product according to customer requirements.
Described inorganic fillings is selected the mixture of a kind of in lime carbonate, talcum powder, the clay or two kinds for use.
Described coupling agent is selected titanate coupling agent NDZ-201 for use.
Described static inhibitor is selected non-ionic composite static inhibitor HBS-302 for use.
Described lubricant is selected one or more the mixture in polyethylene wax in calcium stearate, Zinic stearas, barium stearate or the hydro carbons lubricant in the metallic soap class, paraffin, the whiteruss for use.
Described tinting material is selected Rutile type Titanium Dioxide or anatase thpe white powder for use, also can require other tinting material of choose reasonable according to the difference to color.
Described fire retardant is selected antimonous oxide, tetrabromo-bisphenol, zinc borate, hexabromobenzene, hexabromocyclododecane, tricresyl phosphate (2 for use, 3-two chloropropyls) ester, tricresyl phosphate (2, the 3-dibromopropyl) mixture of one or more in ester, two (2, the 3-dibromopropyl) fumarate.
This flame-retardant synthetic paper has the advantages that outward appearance, whiteness, deflection, printing that various paper should have are write, and has high strength that various high gear paper (containing various synthetic papers) should have, photostabilization, humidity simultaneously again, corrosion-resistant, anti-ly damages by worms, dimensional stabilizing, folding is folded, of many uses and the characteristics of renewable repeated use.And the more important thing is that this flame-retardant synthetic paper has the high flame retardant effect, be not easy burning, but but perfect combustion in the high temperature incinerator, and burning the time does not produce obnoxious flavour, can not cause the secondary public hazards, meets the requirement of national environmental protection.
The range of application of this flame-retardant synthetic paper is very extensive.Can be used for electron trade: as electronic product wiring board material, electronic chip dottle pin, thin film switch etc.Can be used for printing class: as senior chromaticity printing, book printing etc.Can be used for packaging group: as handbag, gift bag, food bag, garment bag, the packing bag of products such as medicine, makeup, food, Industrial products, tire.Can be used for being processed into various stationeries: as printing paper, copy paper, interleaving paper etc.Can be used for the material of construction class: as the body paper of coloured facing paper, home-use decorative paper, hanging raw stock, sliding door partition board paper etc.In addition, can also be used to make visiting ticket, greeting card, advertisement etc.Flame-retardant synthetic paper also has good development prospect except possessing widely range of application.Although the production of flame-retardant synthetic paper is subjected to the oil storage quantitative limitation, and price influences by oil price also, and the production of flame-retardant synthetic paper is already produced with conventional paper and compared, and incomparable environmental protection and printing advantage are arranged.
Advantage of the present invention provided a kind of that make of macromolecular material, have an anti-flaming function; nonflammable; even can not produce obnoxious flavour when in high temperature combustion furnace, burning yet, can be to society and the human flame-retardant synthetic paper that causes the secondary public hazards and meet the national environmental protection requirement.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described.
Embodiment 1
A kind of flame-retardant synthetic paper, each raw material and proportioning thereof are: acrylic resin 100PHR, polyvinyl resin 40PHR, lime carbonate 150PHR, titanate coupling agent NDZ-201 2.5PHR, non-ionic composite static inhibitor HBS-302 3PHR, calcium stearate 1.5PHR, Rutile type Titanium Dioxide 15PHR, fire retardant 30PHR.
Described fire retardant is grouped into by the one-tenth of following proportioning: zinc borate 4PHR, antimonous oxide 4PHR, hexabromocyclododecane 22PHR.
Its preparation method comprises following processing step: at first extract each raw material by the above-mentioned raw materials proportioning.Then confected materials is sent into the high speed kneader, mixed 12-18 minute, it is mixed.Compound is transported to planetary extruder carries out mixing gel, the planetary extruder temperature is set at 170-190 ℃.Be transported to the rolling press moulding after extruding, the rolling press temperature is set at 190-210 ℃, and velocity contrast is 1-2m/min between each roller.Draw through doff roll again and carry out embossed.Again through after online group cool off, corona treatment, the corona value of product is reached more than 40 dyne.Curl through the center again carry out rolling product.Also can cut this product according to customer requirements.
Embodiment 2
A kind of flame-retardant synthetic paper, each raw material and proportioning thereof are: acrylic resin 100PHR, polyvinyl resin 70PHR, lime carbonate 200PHR, titanate coupling agent NDZ-201 3PHR, non-ionic composite static inhibitor HBS-302 3PHR, polyethylene wax 1.5PHR, anatase thpe white powder 10PHR, fire retardant 18PHR.
Described fire retardant is grouped into by the one-tenth of following proportioning: antimonous oxide 7PHR, two (2, the 3-dibromopropyl) fumarate 11PHR.
Its preparation method is identical with embodiment 1.
Embodiment 3
A kind of flame-retardant synthetic paper, each raw material and proportioning thereof are: each raw material and proportioning thereof are: acrylic resin 100PHR, polyvinyl resin 30PHR, talcum powder 120PHR, titanate coupling agent NDZ-201 3PHR, non-ionic composite static inhibitor HBS-302 2PHR, polyethylene wax 1.5PHR, anatase thpe white powder 8PHR, fire retardant 15PHR.
Described fire retardant is grouped into by the one-tenth of following proportioning: antimonous oxide 5PHR, tetrabromo-bisphenol 1OPHR.
Its preparation method is identical with embodiment 1.
Claims (7)
1, a kind of flame-retardant synthetic paper comprises acrylic resin, polyvinyl resin, inorganic fillings, coupling agent, static inhibitor, lubricant, tinting material composition, it is characterized in that: also comprise fire retardant;
Each raw material and proportioning thereof are: acrylic resin 100PHR, polyvinyl resin 20-90PHR, inorganic fillings 50-300PHR, coupling agent 1-8PHR, static inhibitor 1-5PHR, lubricant 0.5-5PHR, tinting material 5-20PHR, fire retardant 5-35PHR;
Its preparation method comprises following processing step: at first extract each raw material by the above-mentioned raw materials proportioning, then confected materials is sent into high-speed mixer, mixed 12-18 minute, it is mixed, compound is transported to planetary extruder carries out mixing gel, the planetary extruder temperature is set at 170-190 ℃, be transported to the rolling press moulding after extruding, the rolling press temperature is set at 190-210 ℃, velocity contrast is 1-2m/min between each roller, draw through doff roll again and carry out embossed, again through after online group cool off, corona treatment, the corona value of product is reached more than 40 dyne, curl through the center again carry out rolling product, also can cut this product according to customer requirements;
Described inorganic fillings is selected the mixture of a kind of in lime carbonate, talcum powder, the clay or two kinds for use;
Described coupling agent is selected titanate coupling agent NDZ-201 for use;
Described static inhibitor is selected non-ionic composite static inhibitor HBS-302 for use;
Described lubricant is selected one or more the mixture in polyethylene wax in calcium stearate, Zinic stearas, barium stearate or the hydro carbons lubricant in the metallic soap class, paraffin, the whiteruss for use;
Described tinting material is selected Rutile type Titanium Dioxide or anatase thpe white powder for use, also can require other tinting material of choose reasonable according to the difference to color;
Described fire retardant is selected antimonous oxide, tetrabromo-bisphenol, zinc borate, hexabromobenzene, hexabromocyclododecane, tricresyl phosphate (2 for use, 3-two chloropropyls) ester, tricresyl phosphate (2, the 3-dibromopropyl) mixture of one or more in ester, two (2, the 3-dibromopropyl) fumarate.
2, a kind of flame-retardant synthetic paper according to claim 1, it is characterized in that: each raw material and proportioning thereof are: acrylic resin 100PHR, polyvinyl resin 40PHR, lime carbonate 150PHR, titanate coupling agent NDZ-2012.5PHR, non-ionic composite static inhibitor HBS-3023PHR, calcium stearate 1.5PHR, Rutile type Titanium Dioxide 15PHR, fire retardant 30PHR.
3, a kind of flame-retardant synthetic paper according to claim 2, it is characterized in that: described fire retardant is grouped into by the one-tenth of following proportioning: zinc borate 4PHR, antimonous oxide 4PHR, hexabromocyclododecane 22PHR.
4, a kind of flame-retardant synthetic paper according to claim 1, it is characterized in that: each raw material and proportioning thereof are: acrylic resin 100PHR, polyvinyl resin 70PHR, lime carbonate 200PHR, titanate coupling agent NDZ-2013PHR, non-ionic composite static inhibitor HBS-3023PHR, polyethylene wax 1.5PHR, anatase thpe white powder 10PHR, fire retardant 18PHR.
5, a kind of flame-retardant synthetic paper according to claim 4, it is characterized in that: described fire retardant is grouped into by the one-tenth of following proportioning: antimonous oxide 7PHR, two (2, the 3-dibromopropyl) fumarate 11PHR.
6, a kind of flame-retardant synthetic paper according to claim 1, it is characterized in that: each raw material and proportioning thereof are: acrylic resin 100PHR, polyvinyl resin 30PHR, talcum powder 120PHR, titanate coupling agent NDZ-2013PHR, non-ionic composite static inhibitor HBS-3022PHR, polyethylene wax 1.5PHR, anatase thpe white powder 8PHR, fire retardant 15PHR.
7, a kind of flame-retardant synthetic paper according to claim 6, it is characterized in that: described fire retardant is grouped into by the one-tenth of following proportioning: antimonous oxide 5PHR, tetrabromo-bisphenol 10PHR.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910182753A CN101659770A (en) | 2009-09-05 | 2009-09-05 | Flame-retardant synthetic paper |
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| CN200910182753A CN101659770A (en) | 2009-09-05 | 2009-09-05 | Flame-retardant synthetic paper |
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Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101831167A (en) * | 2010-05-28 | 2010-09-15 | 湖南科技大学 | Method for preparing polyurethane-based stone paper |
| CN102321293A (en) * | 2011-07-07 | 2012-01-18 | 山东华群新材料科技有限公司 | Method for making resin-based composite material replacing paper |
| CN102336536A (en) * | 2011-06-29 | 2012-02-01 | 夏丽蓉 | Polypropylene stone oil painting canvas and preparation method thereof |
| CN102417645A (en) * | 2011-08-17 | 2012-04-18 | 上海石美实业有限公司 | Production method of inflaming retarding stone paper |
| CN102501474A (en) * | 2011-10-20 | 2012-06-20 | 夏丽蓉 | Short glass fiber PP stone paper and preparation method thereof |
| CN102660061A (en) * | 2012-04-13 | 2012-09-12 | 苏州斯迪克新材料科技股份有限公司 | Film material for PE coated paper |
| CN102675721A (en) * | 2012-05-15 | 2012-09-19 | 山东华群新材料科技有限公司 | Manufacturing method of resin matrix composite wall paper |
| CN102775677A (en) * | 2011-05-13 | 2012-11-14 | 陈昭田 | Green and environmental protection paper and its manufacturing method |
| CN103012948A (en) * | 2012-12-28 | 2013-04-03 | 上海东升新材料有限公司 | Flame-retardant mineral paper and preparation method thereof |
| CN104277330A (en) * | 2014-10-16 | 2015-01-14 | 佛山市南海美之彩塑化有限公司 | Efficient low-cost flame-retardant PP masterbatch |
| CN104710685A (en) * | 2013-12-13 | 2015-06-17 | 杨金龙 | Rich mineral paper tableware, and preparation method thereof |
| CN104744821A (en) * | 2015-03-26 | 2015-07-01 | 马庆路 | Method for preparing multicolor sized environment-friendly synthetic paper |
| CN106009158A (en) * | 2016-06-16 | 2016-10-12 | 铜陵锋帆彩色印务有限公司 | Calcium plastic composite honeycomb packaging carton and preparation method thereof |
| CN107186996A (en) * | 2017-05-31 | 2017-09-22 | 江苏大海塑料股份有限公司 | A kind of preparation method of flame retardant type PVC wallpaper |
| CN107383540A (en) * | 2017-08-14 | 2017-11-24 | 桓仁广鑫科技有限责任公司 | A kind of environment protecting paper moulding process |
| CN107652519A (en) * | 2017-10-30 | 2018-02-02 | 桓仁广鑫科技有限责任公司 | A kind of manufacture method of environment-friendly type through long narrow flag |
| CN108912435A (en) * | 2017-04-24 | 2018-11-30 | 广州市寅源新材料科技有限公司 | A kind of environmental protection flame retardant polyolefin protective film and preparation method thereof |
| CN109206725A (en) * | 2018-11-26 | 2019-01-15 | 李美兰 | A kind of sealed polyethylene plastic formula |
| CN109402756A (en) * | 2018-10-24 | 2019-03-01 | 武汉纺织大学 | A kind of preparation method of fire-retardant Lyocell fibers |
| CN113185772A (en) * | 2021-04-16 | 2021-07-30 | 阜阳市尤美新材料科技有限公司 | Special synthetic paper for new crown detection box and manufacturing method thereof |
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2009
- 2009-09-05 CN CN200910182753A patent/CN101659770A/en active Pending
Cited By (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101831167A (en) * | 2010-05-28 | 2010-09-15 | 湖南科技大学 | Method for preparing polyurethane-based stone paper |
| CN101831167B (en) * | 2010-05-28 | 2011-12-21 | 湖南科技大学 | Method for preparing polyurethane-based stone paper |
| CN102775677A (en) * | 2011-05-13 | 2012-11-14 | 陈昭田 | Green and environmental protection paper and its manufacturing method |
| CN102336536A (en) * | 2011-06-29 | 2012-02-01 | 夏丽蓉 | Polypropylene stone oil painting canvas and preparation method thereof |
| CN102336536B (en) * | 2011-06-29 | 2013-07-24 | 夏丽蓉 | Polypropylene stone oil painting canvas and preparation method thereof |
| CN102321293A (en) * | 2011-07-07 | 2012-01-18 | 山东华群新材料科技有限公司 | Method for making resin-based composite material replacing paper |
| CN102417645A (en) * | 2011-08-17 | 2012-04-18 | 上海石美实业有限公司 | Production method of inflaming retarding stone paper |
| CN102501474A (en) * | 2011-10-20 | 2012-06-20 | 夏丽蓉 | Short glass fiber PP stone paper and preparation method thereof |
| CN102501474B (en) * | 2011-10-20 | 2014-11-19 | 夏丽蓉 | Short glass fiber PP stone paper and preparation method thereof |
| CN102660061A (en) * | 2012-04-13 | 2012-09-12 | 苏州斯迪克新材料科技股份有限公司 | Film material for PE coated paper |
| CN102675721A (en) * | 2012-05-15 | 2012-09-19 | 山东华群新材料科技有限公司 | Manufacturing method of resin matrix composite wall paper |
| CN102675721B (en) * | 2012-05-15 | 2014-06-25 | 山东华群新材料科技有限公司 | Manufacturing method of resin matrix composite wall paper |
| CN103012948B (en) * | 2012-12-28 | 2014-10-01 | 上海东升新材料有限公司 | Flame-retardant mineral paper and preparation method thereof |
| CN103012948A (en) * | 2012-12-28 | 2013-04-03 | 上海东升新材料有限公司 | Flame-retardant mineral paper and preparation method thereof |
| CN104710685A (en) * | 2013-12-13 | 2015-06-17 | 杨金龙 | Rich mineral paper tableware, and preparation method thereof |
| CN104277330A (en) * | 2014-10-16 | 2015-01-14 | 佛山市南海美之彩塑化有限公司 | Efficient low-cost flame-retardant PP masterbatch |
| CN104744821A (en) * | 2015-03-26 | 2015-07-01 | 马庆路 | Method for preparing multicolor sized environment-friendly synthetic paper |
| CN106009158A (en) * | 2016-06-16 | 2016-10-12 | 铜陵锋帆彩色印务有限公司 | Calcium plastic composite honeycomb packaging carton and preparation method thereof |
| CN108912435A (en) * | 2017-04-24 | 2018-11-30 | 广州市寅源新材料科技有限公司 | A kind of environmental protection flame retardant polyolefin protective film and preparation method thereof |
| CN107186996A (en) * | 2017-05-31 | 2017-09-22 | 江苏大海塑料股份有限公司 | A kind of preparation method of flame retardant type PVC wallpaper |
| CN107383540A (en) * | 2017-08-14 | 2017-11-24 | 桓仁广鑫科技有限责任公司 | A kind of environment protecting paper moulding process |
| CN107652519A (en) * | 2017-10-30 | 2018-02-02 | 桓仁广鑫科技有限责任公司 | A kind of manufacture method of environment-friendly type through long narrow flag |
| CN109402756A (en) * | 2018-10-24 | 2019-03-01 | 武汉纺织大学 | A kind of preparation method of fire-retardant Lyocell fibers |
| CN109206725A (en) * | 2018-11-26 | 2019-01-15 | 李美兰 | A kind of sealed polyethylene plastic formula |
| CN113185772A (en) * | 2021-04-16 | 2021-07-30 | 阜阳市尤美新材料科技有限公司 | Special synthetic paper for new crown detection box and manufacturing method thereof |
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