CN102417645A - Production method of inflaming retarding stone paper - Google Patents
Production method of inflaming retarding stone paper Download PDFInfo
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- CN102417645A CN102417645A CN2011102349831A CN201110234983A CN102417645A CN 102417645 A CN102417645 A CN 102417645A CN 2011102349831 A CN2011102349831 A CN 2011102349831A CN 201110234983 A CN201110234983 A CN 201110234983A CN 102417645 A CN102417645 A CN 102417645A
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Abstract
A production method of an inflaming retarding stone paper. The inflaming retarding stone paper comprises raw materials by weight of 55-65% of inorganic mineral, 15-30% of polyolefin, 8-18% of flame retardant and 1-5% of film-forming additive. The materials are sent to a high speed mixer to be uniformly mixed; and a mixed material is sent to an extruder and treated with milling and retrogradation to be prepared into particles; the particles are prepared into the inflaming retarding stone paper with a proper thickness by a paper film blowing machine. Because of addition of a special-purpose flame retardant, a defect of inflammability of existing stone paper is solved; the stone paper of the invention can be used for manufacture of a flame retardant wallpaper, is an ideal option for substituting an existing PVC wallpaper, and has wide market prospect.
Description
Technical field
The present invention relates to IC D21H slurry or pulp composition, other type paper not to be covered; Or C08K uses inorganics or non-polymer organic material as batching; Or the B32B sandwich-like product, promptly by flat or non-flat thin layer, the correlative technology fields such as product that for example foamed, cellular thin layer constitutes, particularly a kind of fire-retardant stone paper and its working method.
Background technology
At present, (Rich Mineral Paper RMP), also is Shi Kezhi to stone paper.With the limestone mineral resource is main raw material(s) (Paris white 70% ~ 80%); With the high molecular polymer is base material raw material (content is 20% ~ 30%); After utilizing the macromolecule interfacial principles of chemistry and macromolecule modified special process to handle, adopt polymer-extruded, blow molding technology to process.The stone paper product has like writing property of vegetable fibre paper and printing effect, the core capabilities that has more plastic packing article simultaneously and had.Its main raw material is the high molecular polymer with film forming properties---plastics (alleged base material); Used method of manufacture---polymer-extruded blow molding; It also is typical plastics processing film technology; The lime carbonate powder that its content is bigger is a kind of reduction plastics film transparency, and reduces the weighting agent of quantity of plastics.
Stone paper on market owing to generally use inflammable organic resin as membrane-forming agent, can be burnt in flame, does not have flame retardant resistance with its basement membrane as paper.As:
98,100,956 1 kinds of methods of making environmental protection paper of number of patent application comprise: (1) will comprise that the compsn of natural inorganic breeze, Vilaterm and auxiliary agent processes granulate material through the mixing polymerization of extrusion; (2) granulate material is dropped into the paper film and make machine, shape film forming pipe; (3) in the film pipe, fill the compression air, carry out the film pipe simultaneously and stretch, process environmental protection paper with two-way tissue intensity.The invention still further relates to a kind of compsn of making environmental protection paper, it comprises the natural inorganic breeze of 56 to 80 weight %, the Vilaterm of 43 to 18 weight % and the auxiliary agent of 1 to 2 weight %.
Number of patent application 200920011088; Stone, three layers of Composite Paper of moulding material; Form the inorganic matrix layer of second layer paper for being mixed and made into by water-ground limestone 80-90% and high density polyethylene(HDPE) 20-10% by the first layer paper, second layer paper and three-ply paper; The writing layer that the first layer paper is mixed and made into for the water-ground limestone by 40-30% ethylene-acrylic acid modified copolymer EAA and 60-70, the first layer paper laterally is compounded on the upper surface of second layer paper after stretching; Three-ply paper is a metallocene high density polyethylene(HDPE) mHDPE layer, and three-ply paper vertically is compounded on the second layer paper lower surface after stretching.Major ingredient is building stones, i.e. 1000-5000 purpose water-ground limestone, and raw material sources are abundant, and cost is low.Acidproof, alkaline resistance properties is high, can use at some special occasions.And the utility model selects for use the non-plant fibre material to process, and practices thrift timber, and water saving does not have harmful sewage when producing and obnoxious flavour enters, and helps environment protection.
201,010,216,146 1 kinds of stone paper of number of patent application and method of manufacture thereof, said stone paper comprises the component of following weight part: 6～12 parts of new LDPE (film grade)s, 6～12 parts of linear low density polyethylenes; 3～6 parts of hot melt adhesives, 5～10 parts of white titanium pigments, 65～75 parts of water-ground limestones; 3～5 parts of silane coupling agents; 0.5～1.5 part of Triple Pressed Stearic Acid, 0.5～1.5 part of epoxy plasticizer, 0.2～0.6 part of polyethylene wax.With the high molecular polymer is the base material raw material; Carry out composite modified to lime carbonate; And add other additives; Utilize the macromolecule interfacial principles of chemistry and macromolecule modified characteristics, after special process is handled, adopt mixed with polymers, filler is composite modified, polymkeric substance plastifies with filler, extrude curtain coating, calendering formation technology is processed.To save energy, protect national resource, improving environment has extraordinary meaning.
Just existing analysis of research achievements, improve and realize that paper and the fire-retardant technological approaches of paper product mainly comprise three kinds of methods:
Pickling process: this method is applicable to water-soluble flame retardant.The water-soluble flame retardant wiring solution-forming, be impregnated in the paper, behind heat drying, can make difficult combustion paper.The fire retardant papers poor water resistance that this method obtains, moisture absorption is strong, and the strength degradation of paper is remarkable, is prone to the jaundice hardening.Pickling process requires paper to have quite high water-absorbent and wet tenacity index, preferably floods goffered paper, coton paper, synthetic fibre paper and nonwoven fabric.Paper just can be accomplished dipping on the surface size press or on the Paper dyeing machine.
Coating method: this method is applicable to the fire retardant of insoluble or indissoluble.Be dispersed in the fire retardant powder in certain tackiness agent, process emulsus coating, the method with coating is coated in coating on the surface of paper then, can obtain the application type fire retardant papers through heat drying.The advantage of this method is the surface that the fire retardant major part concentrates on paper, and is also less to the physicals influence of paper, particularly as far as the converted paper of needs coating, only need be just passable at coating towel adding fire retardant, and this method can be accomplished on coating machine.For obtaining good flame-retardant effect, fire retardant is little and uniformly for well with grain.The shortcoming of this method is that flame retardant effect is undesirable.
Internal addition method: this method is suitable for and the water-insoluble fire retardant, fire retardant is added in the paper pulp with other filler go, and manufactures paper with pulp into paper then.It is more flexible to add the position, all can add from any position between hollander to head box or the cylinder vat, as long as can guarantee that its homodisperse in slurry is just passable.With other earthfill rockfill concrete riprap RCC seemingly, the pH value of slurry is between 4.5-5.0, its retention in paper is very high.The advantage of this method is the production that is applicable to various paper, and technological operation is simple, and the distribution of fire retardant in paper is more even, so the anti-flaming function of paper compares homogeneous.Shortcoming is that the fire retardant loss is more serious, and the retention of general fire retardant reaches 80% and just has been not easy very much.The best approach that solves losing issue is to use suitable glidant, better effects if when opening that this method is used for producing fire prevention cardboard or heavu weights.
Early stage research thinks, paper (cardboard) when burning, the paper pyrolysis before the flame and produce gas because the result of air and these gas motion effects, flame moves, spreads, spreads along paper, paper is heated to pyrolysis temperature simultaneously.But research in recent years proves, during burning, paper pyrolysis and the gas that produces are below flame.Because gaseous diffusion, make propagation of flame go out pyrolysis zone, simultaneously because the thermal conduction mutually and be heated to pyrolysis temperature to a contiguous paper, the combustion principle of Here it is paper (carton).Flame retardant resistance be meant material contact during burning things which may cause a fire disaster combustionvelocity very slow, can very fast cease combustion when leaving burning things which may cause a fire disaster and from horizontal blanking.
Do not contain special flame retardant in these technology in its moity, therefore existing stone paper is flammable, does not have flame retardant resistance, and disclosed to relate to the paper product flame-retarded technology less, such as:
The high polymeric solution of main phosphorous, the nitrogen as fire retardant for paper of 87,104,427 1 kinds of number of patent applications.After using various paper of this fire retardant proofing and oven dry, can make the flame retardant resistance of paper surpass JISZ-2150 standard, the flame place of arrival is charing, and oxygen index is up to 40, and tear index, fracture length equal strength parameter are basic suitable with former paper.Also have stronger moisture resistance through the fire retardant sheet processed, its whiteness is constant basically after pyroprocessing; Cotton, the timber handled with this fire retardant all have higher flame retardant resistance; This fire retardant can stamp out a fire and never resume combustion rapidly; Some midbody of this fire retardant can be condensed into solid, and some midbody can be prepared in use, is convenient to transportation and keeping.
200,910,182,753 1 kinds of flame-retardant synthetic papers of number of patent application.Comprise acrylic resin, polyvinyl resin, inorganic fillings, coupling agent, static inhibitor, lubricant, tinting material.Be characterized in also comprising fire retardant.Each raw material and parts by weight thereof are: acrylic resin 100PHR, polyvinyl resin 20-90PHR, inorganic fillings 50-300PHR, coupling agent 1-8PHR, static inhibitor 1-5PHR, lubricant 0.5-5PHR, tinting material 5-20PHR, fire retardant 5-35PHR.Each raw material of this flame-retardant synthetic paper through mixing, mixing gel, rolling press moulding, doff roll draw, embossed, again through cooling, corona treatment, rolling product.Have anti-flaming function, nonflammable.Even can not produce obnoxious flavour when in high-temperature incinerator, burning yet, can not cause the secondary public hazards to the society and the mankind, meet requirement on environmental protection.
200,710,089,563 1 kinds of flame-retardant tipping papers that are used for cigarette of number of patent application; Technical scheme comprises that the fire retardant of use comprises one or several in Antimony Trioxide: 99.5Min, zinc borate, white lake, the Marinco H; The ethanol of use 75% is made solvent, uses tensio-active agent StNa or sodium oleate to disperse, and dosage of surfactant is in 0.1%-1.2% (weight percentage of fire retardant relatively); Use flame-retardant tipping paper of the present invention; Can shorten the smouldering extinction time of residue cigarette end, improve security, reduce bad breath.
Number of patent application 201020538450 halogen-free flameproof label paper; Comprise range upon range of facestock layer, release lining paper; Between release lining paper and facestock layer, also has one deck adhesive layer; It is characterized in that simultaneously having a flame retardant coating at the non-adhesive layer of facestock layer, said adhesive layer is the fire retardant glue adhensive layer.The fire-retardant gluing layer that the said flame retardant coating and the back side apply can both improve the fire-retardant coefficient of trade mark, improves product and applies to the safety of electronic goods, and realized Halogen, realizes the safety non-toxic of label paper.
The making method of 200,610,046,901 1 kinds of fire-resistant writing papers of number of patent application relates to a kind of making method of writing paper, and this method is a raw material with paraffin, Z 150PH, and alcohol is solvent, and its making processes is: with CaHPO
4Be dissolved in alcohol, make saturated solution; Again body paper is soaked in CaHPO
4In the saturated solution 1～5 minute, take out and be fire-resistant writing paper after drying.Body paper is not carry out the paper that gluing is handled on the surface, CaHPO after paper pulp is processed into paper
4Refer to technical grade CaHPO
4The burning-point of fire retardant papers of the present invention can reach 420 ℃～500 ℃; This fire retardant papers is as common writing paper simultaneously, fluently writes above can using any pen, and the machine that also can print is printed.
Number of patent application 200410018793 contains the fire-retardant fireproof paper and the method for manufacture thereof of expansile graphite; The composition of this fireproofed paper; Comprise that weight percent is 20% to 80% and equally distributed expansile graphite, all the other are the equally distributed paper pulp that contains the paper grade (stock) fiber; Method of manufacture comprises: one, prepare raw material stage; Two, starch step fully; Three, mixing step; Four, the step of manufacturing paper with pulp; Five, processing treatment step; It is better that fireproofed paper of the present invention has fire-proof function, has wide range of applications, and method of manufacture is simple and easy, do not need to transform significantly original system paper equipment of making, and result of use is desirable.
As adopt the pros and cons of stone paper to be coated with fire retardant material simultaneously; Though possess certain positive flame retardant properties; But because sandwich stone paper can produce side infiltration burning when high temperature; Can not solve fire-retardant problem at all, thereby use the environment-friendly type stone paper to make wallpaper, must fundamentally solve the flame-retarded technology problem.
The disclosed new related art scheme that relates to stone flour system paper and fire-retardant type of paper product in this technical field is less.
Summary of the invention
The purpose of this invention is to provide the technology that a kind of effective raising improves the fire-retardant fireproof performance of ore system paper product, the technology of giving mainly realizes with additive process, promptly when raw material is mixed, adds fire retardant in process of production.
Goal of the invention of the present invention realizes through following technical measures: its raw material and weight ratio proportioning thereof are: the inorganic mineral of 55-65%; The 15-30% polyolefine; The fire retardant of 8-18%, the 1-5% film coalescence aid, above material is sent into high-speed mixer and is mixed, and mixture is transported to the mixing gel of forcing machine processes particle, through paper film inflation film manufacturing machine, processes the flame retardant type stone paper base material of suitable thickness.
The invention has the beneficial effects as follows: in the combination of raw materials of making stone paper, add an amount of fire retardant, make film forming stone paper have flame retardant resistance, make it to be used to make the basement membrane of flame retardant resistance wallpaper.Owing to add combustion inhibitor special, solve the inflammable defective of stone paper in the past, can be used for the manufacturing of flame retardant resistance wallpaper, be that the ideal that substitutes existing P VC wallpaper is selected, have wide market outlook.
Embodiment
Can find out by the sheet material flame mechanism, give it, must start with: isolate paper and flame, stop flame to burn, spread at paper from following three aspects with the fire prevention flame retardant resistance; Oxygen in reduction or the consumption burning situation, flame suffocates; Reduce combustion zone temperature or adopt refractory fibre, stop the paper pyrolysis.Above-mentioned purpose generally all is to realize through adding pharmaceutical chemicals.We call fire retardant to the pharmaceutical chemicals that this paper has anti-flaming function.Ignition-proof element relatively more commonly used has halogen, phosphorus, boron, nitrogen, aluminium etc.Fire retardant generally reaches fire-retardant purpose through following several kinds of approach.
Select fire retardant, must follow following principle:
Do not influence the physicals that at present sticks with glue agent, or with the tackiness agent that has added fire retardant, its physicals should satisfy production requirement.The physicals of tackiness agent comprises fluidised form property, adhesion strength etc.Selected fire retardant should be inexpensive, be easy to get.
Fire retardant work relates to the effect attributive classification and comprises: endothermic effect, blanketing effect, dilution effect, retarding effect
Fire retardant of the present invention is through its fire retardations of some mechanism performance, like heat-absorbing action, covering effect, suppress the smothering action of chain reaction, non-flammable gas etc.Most fire retardants are to reach fire-retardant purpose through some mechanism actings in conjunction.Fire retardant mainly contains organic and inorganic at present, halogen and non-halogen.Organic is to be some fire retardants of representative with bromine system, nitrogen system and red phosphorus and compound, and inorganic mainly is flame-retardant systems such as Antimony Trioxide: 99.5Min, Marinco H, white lake, silicon system.
Present technology has proposed in the combination of raw materials of making stone paper, to add an amount of fire retardant, makes film forming stone paper have flame retardant resistance, makes it to be used to make the basement membrane of flame retardant resistance wallpaper.The stone paper that adopts; Adopt the pros and cons of stone paper to be coated with fire retardant material simultaneously; Though possess certain positive flame retardant properties,, can not solve fire-retardant problem at all because sandwich stone paper can produce side infiltration burning when high temperature; Thereby use the environment-friendly type stone paper to make wallpaper, must fundamentally solve the flame-retarded technology problem.
The disclosed new related art scheme that relates to stone flour system paper and fire-retardant type of paper product in this technical field is less.
The present invention adds an amount of fire retardant to constitute mixture in the papermaking mixture of raw material; Thereby can be used for making the wallpaper of special flame retardant effect; This wallpaper has changed the inflammable defective of stone paper in the past; The metope that can be used for buildings is fitted, and has nonflammable, good smokeless flame retardant resistance, in water, soaks and does not influence the intensity of paper; Have nontoxic, odorlessness, low cost and other advantages, can produce the flame retardant resistance stone paper wallpaper that use properties is superior to existing PVC wallpaper fully.
A kind of fire-retardant stone paper of the present invention, its raw material and weight ratio proportioning thereof are: the inorganic mineral of 55-65%; The 15-30% polyolefine; The fire retardant of 8-18%, the 1-5% film coalescence aid, above material is sent into high-speed mixer and is mixed, and mixture is transported to the mixing gel of forcing machine processes particle, through paper film inflation film manufacturing machine, processes the flame retardant type stone paper base material of suitable thickness.
Starting material among the present invention are chosen comparatively extensive, such as, inorganic mineral can be flyash, slag etc.; Fire retardant can be nitrogenous and composite flame-retardant agent phosphoric.
To combine specific embodiment below, the present invention will be described further.
Embodiment 1:
A kind of fire-retardant stone paper, its raw material and proportioning thereof are: the inorganic mineral of 64% weight; 20% Vilaterm; 14% fire retardant, 2% film coalescence aid, above material is sent into high-speed mixer and is mixed, and mixture is transported to the mixing gel of forcing machine processes particle, through paper film inflation film manufacturing machine, processes the flame retardant type stone paper base material of suitable thickness.
The aforementioned inorganic mineral of mentioning is a natural whiting, and Vilaterm is low density or high density polyethylene(HDPE), or their mixture.
The aforementioned fire retardant of mentioning is a mixture, wherein: Antimony Trioxide: 99.5Min 4%, decabromodiphenyl oxide DBDPO:10%.
Antimony Trioxide: 99.5Min is the fire retardant of using the earliest; Be applicable to epoxy resin, urethane, X 050, PS, polyvinyl chloride, polyester etc.; Consumption wants big when using separately; Flame retardant effect poor (only if fire-retardant thing Halogen), when with halogen thing (R.HX) and time spent good synergistic being arranged then, flame retardant effect obviously improves.
The Antimony Trioxide: 99.5Min crystalline powder that is white in color.The heating flavescence bleaches after cold.Odorlessness.Being heated to 400 ℃ during high vacuum can distil.Be dissolved in sodium hydroxide solution, hot tartaric acid solution, hydrogen tartrate salts solution and sodium sulfide solution, be slightly soluble in water, rare nitric acid and dilute sulphuric acid.Specific density 5.67.655 ℃ of fusing points.1425 ℃ of boiling points.Medium lethal dose(LD&-{50}) (rat, per os)>20G/kG.Carcinogenic possibility is arranged.
Antimony Trioxide: 99.5Min is the fire retardant of using the earliest; Be applicable to epoxy resin, urethane, X 050, PS, polyvinyl chloride, polyester etc.; Consumption wants big when using separately; Flame retardant effect poor (only if fire-retardant thing Halogen), when with halogen thing (R.HX) and time spent good synergistic being arranged then, flame retardant effect obviously improves.
Embodiment 2
A kind of fire-retardant stone paper, its raw material and proportioning thereof are: the inorganic mineral of 58% weight; 25% polyolefine; 15% fire retardant, 2% film coalescence aid, above material is sent into high-speed mixer and is mixed, and mixture is transported to the mixing gel of forcing machine processes particle, through paper film inflation film manufacturing machine, processes the flame retardant type stone paper base material of suitable thickness.
The aforementioned inorganic mineral of mentioning is natural whiting and diatomaceous mixture, and polyolefine is low density or high density polyethylene(HDPE), Vestolen PP 7052, or their mixture.
The aforementioned fire retardant of mentioning is a flame retardant of magnesium hydroxide.
Calcining basic magnesium chloride fire retardant can pass through with certain density MgCl
2The aqueous solution and Natural manganese dioxide react 3h down at 80 ℃ and make basic magnesium chloride, and it is promptly got this fire retardant at 350 ℃ of calcination 3h, and its molecular formula is 2MgO1.93MgCl
25.4H
2O.Show that by TGA-DTA result the Heat stability is good of this fire retardant below 400 ℃, does not have thermolysis basically.During with 35Phr～50Phr filled nylon-6 6, PET and ethene-tetrafluoroethylene (E/TFE), the gained material has very good flame retardant property with it, and oxidation index is between 35～76.Drawing abillity is also comparatively good.
H is emitted in reaction
2O also generates the antimony halides that fusing point is lower, can gasify, and plays the dilution inflammable gas.Simultaneously his specific density is bigger, is covered in the polymer surface secluding air, can promote carbonization reaction, reduces the temperature of firing system, can catch in the combustion processes free HO. and H. in the gas phase, thereby suppress burning.In fact Antimony Trioxide: 99.5Min is the fire retardant synergist that generally uses, and is best with 3:1 with the ratio of halogen thing.
Embodiment 3
A kind of fire-retardant stone paper, its raw material and proportioning thereof are: the inorganic mineral of 63% weight; 25% polyolefine; 10% fire retardant, 2% film coalescence aid, above material is sent into high-speed mixer and is mixed, and mixture is transported to the mixing gel of forcing machine processes particle, through paper film inflation film manufacturing machine, processes the flame retardant type stone paper base material of suitable thickness.
The aforementioned inorganic mineral of mentioning is mica powder or ground silica, and polyolefine is low density or high density polyethylene(HDPE), Vestolen PP 7052, or their mixture.
The aforementioned fire retardant of mentioning is a phosphorus nitrogen fire-retardant master granule.
Claims (9)
1. fire-retardant stone paper working method is characterized in that: its raw material and weight ratio proportioning thereof are: the inorganic mineral of 55-65%; The 15-30% polyolefine; The fire retardant of 8-18%, the 1-5% film coalescence aid, above material is sent into high-speed mixer and is mixed, and mixture is transported to the mixing gel of forcing machine processes particle, through paper film inflation film manufacturing machine, processes the flame retardant type stone paper base material of suitable thickness.
2. fire-retardant stone paper working method as claimed in claim 1 is characterized in that its raw material and proportioning thereof are: the inorganic mineral of 64% weight; 20% Vilaterm; 14% fire retardant, 2% film coalescence aid, above material is sent into high-speed mixer and is mixed, and mixture is transported to the mixing gel of forcing machine processes particle, through paper film inflation film manufacturing machine, processes the flame retardant type stone paper base material of suitable thickness.
3. fire-retardant stone paper working method as claimed in claim 2 is characterized in that inorganic mineral is a natural whiting, and Vilaterm is low density or high density polyethylene(HDPE), or their mixture; Fire retardant is a mixture, wherein: Antimony Trioxide: 99.5Min 4%, decabromodiphenyl oxide DBDPO:10%.
4. fire-retardant stone paper working method as claimed in claim 1 is characterized in that its raw material and proportioning thereof are: the inorganic mineral of 58% weight; 25% polyolefine; 15% fire retardant, 2% film coalescence aid, above material is sent into high-speed mixer and is mixed, and mixture is transported to the mixing gel of forcing machine processes particle, through paper film inflation film manufacturing machine, processes the flame retardant type stone paper base material of suitable thickness.
5. fire-retardant stone paper working method as claimed in claim 4 is characterized in that, inorganic mineral is natural whiting and diatomaceous mixture, and polyolefine is low density or high density polyethylene(HDPE), Vestolen PP 7052, or their mixture; Fire retardant is a flame retardant of magnesium hydroxide.
6. fire-retardant stone paper working method as claimed in claim 1 is characterized in that its raw material and proportioning thereof are: the inorganic mineral of 63% weight; 25% polyolefine; 10% fire retardant, 2% film coalescence aid, above material is sent into high-speed mixer and is mixed, and mixture is transported to the mixing gel of forcing machine processes particle, through paper film inflation film manufacturing machine, processes the flame retardant type stone paper base material of suitable thickness.
7. fire-retardant stone paper working method as claimed in claim 6 is characterized in that inorganic mineral is mica powder or ground silica, and polyolefine is low density or high density polyethylene(HDPE), Vestolen PP 7052, or their mixture; Fire retardant is a phosphorus nitrogen fire-retardant master granule.
8. fire-retardant stone paper working method as claimed in claim 1 is characterized in that, inorganic mineral can be flyash, slag.
9. fire-retardant stone paper working method as claimed in claim 1 is characterized in that, fire retardant is nitrogenous and composite flame-retardant agent phosphoric.
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| CN102912671A (en) * | 2012-10-16 | 2013-02-06 | 四川海瑞尔重型包装有限公司 | Method for producing laminated flame-retardant paper |
| CN103012948A (en) * | 2012-12-28 | 2013-04-03 | 上海东升新材料有限公司 | Flame-retardant mineral paper and preparation method thereof |
| CN103276534A (en) * | 2013-06-06 | 2013-09-04 | 绍兴叶鹰纺化有限公司 | Method for processing non-woven wall fabrics |
| CN103319775A (en) * | 2013-07-09 | 2013-09-25 | 天象集团有限责任公司 | Environment-friendly inflaming retarding pasting material for veneering wall or sheet material as well as preparation method and application of environment-friendly inflaming retarding pasting material |
| CN105385029A (en) * | 2015-11-27 | 2016-03-09 | 江苏美达自粘材料有限公司 | Nonwoven wallpaper |
| CN105835555A (en) * | 2016-04-06 | 2016-08-10 | 王兆进 | Preparation method for digitally-printed wood-grained stone paper |
| CN108203895A (en) * | 2017-12-25 | 2018-06-26 | 福建省大投科技有限公司 | A kind of wet method prepares the production method of staple fibre paper |
| CN110511562A (en) * | 2018-05-22 | 2019-11-29 | 上海杰事杰新材料(集团)股份有限公司 | A kind of Antistatic flame-retardant nylon composite material and preparation method |
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| CN114057432A (en) * | 2021-11-01 | 2022-02-18 | 山东金泰恒盛新材料科技有限公司 | High-temperature-resistant stone paper and preparation method and application thereof |
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| CN103012948B (en) * | 2012-12-28 | 2014-10-01 | 上海东升新材料有限公司 | Flame-retardant mineral paper and preparation method thereof |
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| CN103319775B (en) * | 2013-07-09 | 2015-10-28 | 天象集团有限责任公司 | Environmental-protection flame-retardant for wall or panel overlay pastes material and method for making thereof and application |
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| CN105385029A (en) * | 2015-11-27 | 2016-03-09 | 江苏美达自粘材料有限公司 | Nonwoven wallpaper |
| CN105835555A (en) * | 2016-04-06 | 2016-08-10 | 王兆进 | Preparation method for digitally-printed wood-grained stone paper |
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| CN110511562B (en) * | 2018-05-22 | 2022-10-04 | 上海杰事杰新材料(集团)股份有限公司 | Antistatic flame-retardant nylon composite material and preparation method thereof |
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Application publication date: 20120418 |