CN102849983B - Stone paper for lamp decoration and its fabrication method - Google Patents
Stone paper for lamp decoration and its fabrication method Download PDFInfo
- Publication number
- CN102849983B CN102849983B CN201110179314.9A CN201110179314A CN102849983B CN 102849983 B CN102849983 B CN 102849983B CN 201110179314 A CN201110179314 A CN 201110179314A CN 102849983 B CN102849983 B CN 102849983B
- Authority
- CN
- China
- Prior art keywords
- stone paper
- decorative lamp
- coupling agent
- hollow glass
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Paper (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses stone paper for lamp decoration and its fabrication method. The stone paper comprises, calculated by weight percentage, hollow glass bead 15-20, metal deactivator 0.5-1.5, antistatic agent 0.5-1.5, lubricant 0.5-1.5, coupling agent 0.5-1.5, fire retardant 0.5-1.5, dispersing agent 0.5-1.5 and polyethylene in balance. The inventive stone paper adopts polyethylene as base material raw material, colorful hollow glass bead as filler, and other processing additives; the fluid obtained after material mixing has good fluidity and processing property, and can increase roller rotation speed, improve production efficiency and save cost while calendering with a calendering machine; and at the same time, the inventive stone paper satisfies material color variety requirement of lamp decoration.
Description
Technical field
The present invention relates to synthetic paper technical field, be specifically related to stone paper as decorative lamp material and preparation method thereof.
Background technology
Stone paper, is main raw material with inorganic mineral powder or other stopping composition exactly, adds what appropriate polyethylene and cementing agent were made.This paper waterproof is firm nonflammable, and papermaking, very environmental protection importantly need not chop at a tree.
Stone paper product applications is extremely extensive, and can be applicable to disposable life and consume articles for use, such as: refuse bag, shopping bag, food bag, cutlery box, the tablecloth, raincoat, dw etc.; Also can be applicable to cultural paper, such as: printing paper, writing paper, White Board etc.; Also can be applicable to building materials and ornaments, such as: decorative wall paper, decorative lamp paper etc.No matter be the stone paper of which kind, the filler adopting in its manufacture craft is CaCO
3, CaSO
4, polynite, talcum powder etc., use these fillers to make the poor fluidity of fluid, and processing characteristics is bad, and while calendering with rolling press, the rotating speed of roller is unhappy, and production efficiency is low.In addition, as the stone paper of decorative use, its outward appearance, color are had higher requirement.And the appearance luster of existing stone paper is single, cannot meet light fixture to the coloury requirement of finishing material.
Summary of the invention
The object of the invention is to overcome above-mentioned the deficiencies in the prior art, a kind of decorative lamp stone paper is provided, its appearance luster is abundant, meets the requirement of light fixture to finishing material.
For achieving the above object, the present invention adopts following technical scheme:
A kind of decorative lamp stone paper, is made up of following component by mass percentage:
Hollow glass micropearl: 15%～20%
Metal passivator: 0.5%～1.5%
Antistatic agent: 0.5%～1.5%
Lubricant: 0.5%～1.5%
Coupling agent: 0.5%～1.5%
Fire retardant: 0.5%～1.5%
Dispersion agent: 0.5%～1.5%
Polyethylene: surplus.
Hollow glass micropearl is different from the customary filler that general making stone paper adopts, as CaCO
3, CaSO
4, polynite, talcum powder etc., its main component is silicon-dioxide, is also a kind of inorganics.Hollow glass micropearl is the ball-type body of hollow, as spot contact bearing.Calcium carbonate is combined fluid flow with plastics have retardation, and hollow glass micropearl is spheroplast, just as spot contact bearing, can impel fluid mobile freely.With calcium carbonate comparison, the unit screw rod revolution throughput of hollow glass micropearl can increase by 10% left and right.Therefore, compare existing CaCO
3, CaSO
4, polynite, the fillers such as talcum powder, the good processability of hollow glass micropearl, adds man-hour, and the rotating speed of rolling mill roller can increase, and has correspondingly improved production efficiency, reduces production costs.
In addition, hollow glass micropearl is a kind of transparent material, and color is various, adopts the hollow glass micropearl of different colours can be made into the stone paper of various different colours.If blue hollow glass micropearl is under the irradiation of light, can present blue light, and the light of other color is just filtered.If the hollow glass micropearl of two or more color mixes, so under the irradiation of light, the color presenting or the same color of equal amts, for example, blue hollow glass micropearl mixes with yellow hollow glass micropearl, under the irradiation of light, present taking the yellow dichromatism of indigo plant as main multicolour effect so, can not become green.And the hollow glass micropearl of white is under the irradiation of light, can present colourful.Therefore, can, according to user demand, the hollow glass micropearl of a certain color or several different colours be mixed as filler, produce the stone paper of different colours, meet the requirement of light fixture to finishing material color.
Preferably, the proportion of described hollow glass micropearl is 1.5～2.0 g/ cm
3, diameter is 20um---40um.
Coupling agent can improve synthetic resins and inorganic filler or strongthener interface performance, in the course of processing, can reduce the viscosity of resin melt, improve the dispersity of weighting agent to improve processing characteristics, and then make goods obtain good surface quality and mechanical thermal and electric energy.As optimized choice, described coupling agent is one or more mixing in silicon ester coupling agent, titanate coupling agent, silane coupling agent.
As optimized choice, described metal passivator is N, N'-bis-salicylidene propylene diamine.
Lubricant can reduce the friction resistance of friction pair, slows down the wearing and tearing of product.Lubricant can also to friction pair play cooling, clean and prevent the effects such as pollution.In order to improve the lubricity of product, in product, add lubricant, described lubricant is preferably one or more mixing in Magnesium Stearate, micropowder silica gel, talcum powder, polyoxyethylene glycol, month extension alcohol magnesium sulfate.
Fire retardant can be given the function of polymkeric substance flame retardancy, postpones or prevents the especially burning of high score subclass plastics of plastics.Therefore, add fire retardant in product, described fire retardant is preferably magnesium hydroxide, aluminium hydroxide, ammonium polyphosphate, eight bromo ether, triphenylphosphate, hexabromocyclododecane, zinc borate, TDE, one or more mixing in encapsulated red phosphorus.
Anti-electric quiet dose can significantly be reduced surface of plastic products resistance, and anti-electrostatic high-efficient and lasting is suitable with resin compatible, and does not affect processing and the use properties of goods.In product, add anti-electric quiet dose, described antistatic agent is preferably one or more mixing in the stearic phthalein amine of ethoxylation, the cruel amine of oxyethyl group bay, glycerine-stearate, ethoxylated coco amine.
Dispersion agent can prevent sedimentation and the cohesion of immobilized particles, a stable pigment prose style free from parallelism of disperseing, the mobility of adjusting pigment particles, is embodied in: improve gloss, improve tinting strength and opacifying power, improve color development and toning property, prevent floating, prevent the aspects such as flocculation.The hollow glass micropearl that the employing of this product has multiple color is filler, adds and adds dispersion agent man-hour, is conducive to the tinting strength of hollow glass micropearl.Described dispersion agent is preferably one or more mixing in Zinic stearas, calcium stearate, microcrystalline wax, polyoxyethylene glycol, three stearic acid glycerine, oleic acid milling.
Another object of the present invention is to provide the preparation method of above-mentioned stone paper, and it comprises the steps:
A, each component vacuum-drying to material moisture is no more than to 3 ‰;
B, will after above-mentioned dry materials, deliver in tablets press, first at room temperature stir cold mixedly, be then heated to 100 DEG C of-110 DEG C of heat mixed, material fully mixes rear granulation;
C, the material after granulation is delivered on rolling press and rolled, being depressed into thickness is 0.2-0.5mm, obtains decorative lamp stone paper of the present invention.
It is base material raw material that decorative lamp stone paper of the present invention adopts polyethylene, the various hollow glass micropearl of color is filler, and add other processing aid, the good fluidity of fluid, good processability after mixing of materials, while calendering with rolling press, can increase the rotating speed of roller, enhance productivity, cost-saving.Meanwhile, product has also met decorative lamp to the abundant demand of material color.
Embodiment
Below in conjunction with specific embodiment, a kind of decorative lamp stone paper of the present invention and manufacturing process thereof are described in further detail, in embodiment, if no special instructions, component is mass percent.
Embodiment 1
Formula:
Proportion is 1.5g/ cm
3white hollow glass microballon 20%, metal passivator 0.5%, antistatic agent 0.5%, lubricant 1.5%, coupling agent 0.5%, fire retardant 0.5%, dispersion agent 0.5%, polyethylene: surplus.
Wherein, the diameter of white hollow glass microballon is 20um, and metal passivator is N, N'-bis-salicylidene propylene diamine; Antistatic agent is the stearic phthalein amine of ethoxylation; Lubricant is Magnesium Stearate; Coupling agent is silicon ester coupling agent; Fire retardant is magnesium hydroxide and aluminium hydroxide balanced mix; Dispersion agent is Zinic stearas.
Preparation method: be 2 ‰ by drying material in vacuum to the material moisture in formula; Dried material is delivered in tablets press, first at room temperature stirs cold mixedly, is then heated to 100 DEG C of heat mixed, and so cold mixed heat is mixed hockets, until material fully mixes, and then granulation; Material after granulation is delivered on rolling press and rolled, and being depressed into thickness is 0.5mm, obtains decorative lamp stone paper of the present invention.This stone paper will present colourful under the irradiation of light.
Embodiment 2
Formula:
Proportion is 2.0 g/ cm
3the transparent hollow glass micropearl 15% of blueness, metal passivator 1.5%, antistatic agent 0.5%, lubricant 0.5%, coupling agent 1.5%, fire retardant 0.5%, dispersion agent 1.5%, polyethylene: surplus.
Wherein, the diameter of blue transparent hollow glass micropearl is 40um, and metal passivator is N, N'-bis-salicylidene propylene diamine; Antistatic agent is the cruel amine of oxyethyl group bay; Lubricant is micropowder silica gel, talcum powder balanced mix; Coupling agent is titanate coupling agent; Fire retardant is ammonium polyphosphate; Dispersion agent is calcium stearate.
Preparation method: be 3 ‰ by drying material in vacuum to the material moisture in formula; Dried material is delivered in tablets press, first at room temperature stirs cold mixedly, is then heated to 110 DEG C of heat mixed, and so cold mixed heat is mixed hockets, until material fully mixes, and then granulation; Material after granulation is delivered on rolling press and rolled, and being depressed into thickness is 0.2mm, obtains the blue stone paper of decorative lamp of the present invention.This stone paper can present blueness under irradiate light.
Embodiment 3
Formula:
Proportion is 1.6 g/ cm
3red hollow glass micropearl 16%, metal passivator 0.6%, antistatic agent 0.7%, lubricant 1.2%, coupling agent 0.8%, fire retardant 0.6%, dispersion agent 1.0%, polyethylene: surplus.
Wherein, the diameter of red hollow glass micropearl is 30um, and metal passivator is N, N'-bis-salicylidene propylene diamine; Antistatic agent is glycerine-stearate; Lubricant is polyoxyethylene glycol; Coupling agent is silane coupling agent; Fire retardant is triphenylphosphate, and two kinds of hexabromocyclododecanes are by balanced mix; Dispersion agent is three stearic acid glycerine.
Preparation method: drying material in vacuum to the material moisture in formula is no more than to 2.5 ‰; Dried material is delivered in tablets press, first at room temperature stirs cold mixedly, is then heated to 105 DEG C of heat mixed, and so cold mixed heat is mixed hockets, until material fully mixes, and then granulation; Material after granulation is delivered on rolling press and rolled, and being depressed into thickness is 0.4mm, obtains the red stone paper of decorative lamp of the present invention.This stone paper can present redness under irradiate light.
Embodiment 4
Formula:
Proportion is 1.8 g/ cm
3blue hollow glass micropearl 8% and orange hollow glass micropearl 9%, metal passivator 0.7%, antistatic agent 0.5%, lubricant 1.0%, coupling agent 0.9%, fire retardant 0.7%, dispersion agent 1.1%, polyethylene: surplus.
Wherein, the diameter of blue hollow glass micropearl and orange hollow glass micropearl is 25um, and metal passivator is N, N'-bis-salicylidene propylene diamine; Antistatic agent is ethoxylated coco amine; Lubricant is to hang polyoxyethylene glycol and the moon alcohol magnesium sulfate by balanced mix; Coupling agent is that silicon ester coupling agent and titanate coupling agent are by balanced mix; Fire retardant is zinc borate, TDE, and three kinds of encapsulated red phosphorus are by balanced mix; Dispersion agent is that three stearic acid glycerine and oleic acid milling are by balanced mix.
Preparation method: drying material in vacuum to the material moisture in formula is no more than to 2.4 ‰; Dried material is delivered in tablets press, first at room temperature stirs cold mixedly, is then heated to 108 DEG C of heat mixed, and so cold mixed heat is mixed hockets, until material fully mixes, and then granulation; Material after granulation is delivered on rolling press and rolled, and being depressed into thickness is 0.3mm, obtains decorative lamp polychrome stone paper of the present invention.Mass-tone is blue and orange.
Embodiment 5
Formula:
Proportion is 2.0 g/ cm
3blue hollow glass micropearl 9% and yellow hollow glass micropearl 9%, metal passivator 0.5%, antistatic agent 1.5%, lubricant 0.5%, coupling agent 0.5%, fire retardant 1.5%, dispersion agent: 0.6%, polyethylene: surplus.
Wherein, the diameter of blue hollow glass micropearl and yellow hollow glass micropearl is 35um, and metal passivator is N, N'-bis-salicylidene propylene diamine; Antistatic agent is that three kinds of the cruel amine of oxyethyl group bay, glycerine-stearate, ethoxylation coconut are by balanced mix; Lubricant is month extension alcohol magnesium sulfate; Coupling agent is that silicon ester coupling agent and silane coupling agent are by balanced mix; Fire retardant is that TDE and encapsulated red phosphorus are by balanced mix; Dispersion agent be in polyoxyethylene glycol, three stearic acid glycerine, oleic acid milling three kinds by balanced mix.
Preparation method: drying material in vacuum to the material moisture in formula is no more than to 2.7 ‰; Dried material is delivered in tablets press, first at room temperature stirs cold mixedly, is then heated to 110 DEG C of heat mixed, and so cold mixed heat is mixed hockets, until material fully mixes, and then granulation; Material after granulation is delivered on rolling press and rolled, and being depressed into thickness is 0.3mm, obtains decorative lamp polychrome stone paper of the present invention.Taking blue and yellow as main.
Above-described embodiment is only the preferred embodiment of the present invention, can not limit protection scope of the present invention with this, and the variation of any unsubstantiality that those skilled in the art does on basis of the present invention and replacement all belong to protection scope of the present invention.
Claims (8)
1.
a kind of decorative lamp stone paper, is characterized in that: be made up of following component by mass percentage:
hollow glass micropearl: 15%～20%
metal passivator: 0.5%～1.5%
antistatic agent: 0.5%～1.5%
lubricant: 0.5%～1.5%
coupling agent: 0.5%～1.5%
fire retardant: 0.5%～1.5%
dispersion agent: 0.5%～1.5%
polyethylene: surplus;
described dispersion agent is one or more mixing in Zinic stearas, calcium stearate, microcrystalline wax, polyoxyethylene glycol, three stearic acid glycerine.
2.
decorative lamp stone paper as claimed in claim 1, is characterized in that: described coupling agent is one or more mixing in silicon ester coupling agent, titanate coupling agent, silane coupling agent.
3.
decorative lamp stone paper as claimed in claim 1, is characterized in that: described metal passivator is N, N'-bis-salicylidene propylene diamine.
4.
decorative lamp stone paper as claimed in claim 1, is characterized in that: described lubricant is one or more mixing in Magnesium Stearate, micropowder silica gel, talcum powder, polyoxyethylene glycol, magnesium laurylsulfate.
5.
decorative lamp stone paper as claimed in claim 1, is characterized in that: described fire retardant is magnesium hydroxide, aluminium hydroxide, ammonium polyphosphate, eight bromo ether, triphenylphosphate, hexabromocyclododecane, zinc borate, TDE, one or more mixing in encapsulated red phosphorus.
6.
decorative lamp stone paper as claimed in claim 1, is characterized in that: described antistatic agent is one or more mixing in the stearic phthalein amine of ethoxylation, the cruel amine of oxyethyl group bay, glycerine-stearate, ethoxylated coco amine.
7.
decorative lamp stone paper as claimed in claim 1, is characterized in that: the proportion of described hollow glass micropearl is 1.5～2.0 g/ cm 3 , diameter is 20 μ m-40 μ m.
8.
prepare a method for decorative lamp stone paper claimed in claim 1, it is characterized in that comprising the following steps:
a, each component vacuum-drying to material moisture is no more than to 3 ‰;
b, will after above-mentioned dry materials, deliver in tablets press, first at room temperature stir cold mixedly, be then heated to 100 DEG C of-110 DEG C of heat mixed, material fully mixes rear granulation;
c, the material after granulation is delivered on rolling press and rolled, being depressed into thickness is 0.2-0.5mm, obtains decorative lamp stone paper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110179314.9A CN102849983B (en) | 2011-06-29 | 2011-06-29 | Stone paper for lamp decoration and its fabrication method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110179314.9A CN102849983B (en) | 2011-06-29 | 2011-06-29 | Stone paper for lamp decoration and its fabrication method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102849983A CN102849983A (en) | 2013-01-02 |
| CN102849983B true CN102849983B (en) | 2014-11-19 |
Family
ID=47397026
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110179314.9A Expired - Fee Related CN102849983B (en) | 2011-06-29 | 2011-06-29 | Stone paper for lamp decoration and its fabrication method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102849983B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106835850A (en) * | 2016-12-30 | 2017-06-13 | 芜湖市哈贝纸业有限公司 | A kind of anti-mildew packing case paper of shock resistance |
| CN112521689A (en) * | 2020-12-04 | 2021-03-19 | 惠州莹光塑胶颜料有限公司 | Transparent flame-retardant plastic master batch and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1229719A (en) * | 1998-03-25 | 1999-09-29 | 香港商龙盟环保纸(集团)有限公司 | Mfg. method for environmental protective paper |
-
2011
- 2011-06-29 CN CN201110179314.9A patent/CN102849983B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1229719A (en) * | 1998-03-25 | 1999-09-29 | 香港商龙盟环保纸(集团)有限公司 | Mfg. method for environmental protective paper |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102849983A (en) | 2013-01-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103937279B (en) | A kind of magnetic wood plastic composite and preparation method thereof | |
| CN108026730B (en) | Light-weight environment-friendly type polypropylene composite materials floor and preparation method thereof | |
| CN102604211B (en) | Shock-resistant weather-resistant polypropylene material for light fixture and preparation method thereof | |
| CN102817460B (en) | Fly ash glass micro-ball filled PVC (Polyvinyl Chloride) micro-foamed floor and preparation method thereof | |
| CN102634116A (en) | Base paper of antiflaming environment-friendly rich mineral paper and manufacturing method of the base paper | |
| CN102286899A (en) | Polyethylene stone synthetic wallpaper and manufacturing process thereof | |
| CN101717554A (en) | Plastic profiled bar decorative layer combination material with metal-like natural texture, preparation method and application thereof | |
| CN102557518B (en) | Interior wall coating coil and preparation method thereof | |
| CN109608907A (en) | The method of modifying of stone paper modified calcium carbonate | |
| CN103233565B (en) | A kind of foaming embossment wall base cloth of bamboo charcoal nano diatom ooze and preparation technology thereof | |
| CN107312267A (en) | A kind of solid wood moulding fast assembling wall slab and its production technology | |
| CN106317855A (en) | Aging-resistant and high-hardness cable material and preparation method thereof | |
| CN102849983B (en) | Stone paper for lamp decoration and its fabrication method | |
| CN108086507A (en) | A kind of good acrylic board of flame retardant property | |
| CN106220941A (en) | A kind of waste paper/high density polyethylene (HDPE) luminescent composite and preparation method thereof | |
| CN106497117A (en) | A kind of environmental protection flame retardant Wood-plastic floor and preparation method thereof | |
| CN108530733A (en) | A kind of anti-aging type polyethylene color master batch and preparation method thereof | |
| CN107189221A (en) | A kind of environment friendly halogen-free fireproof polypropylene Masterbatch and preparation method thereof | |
| CN102729555B (en) | Environment-friendly composite stone plate and preparation method thereof | |
| CN102863718A (en) | Manufacturing method of calcium carbonate ceiling decorative plate | |
| CN111016355A (en) | Low-temperature-rise automobile interior material and preparation method thereof | |
| CN106995646B (en) | Pure polyester resin and preparation method thereof, sand grain powder coating containing pure polyester resin and preparation method thereof | |
| CN101935403A (en) | Formula and preparation method of transparent water-based rubber parting agent | |
| CN106592331B (en) | A kind of wallpaper PVC paste material | |
| CN102558919A (en) | Coated titanium white material and preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20141119 Termination date: 20160629 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |