CN106009158A - Calcium plastic composite honeycomb packaging carton and preparation method thereof - Google Patents
Calcium plastic composite honeycomb packaging carton and preparation method thereof Download PDFInfo
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- CN106009158A CN106009158A CN201610442888.3A CN201610442888A CN106009158A CN 106009158 A CN106009158 A CN 106009158A CN 201610442888 A CN201610442888 A CN 201610442888A CN 106009158 A CN106009158 A CN 106009158A
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- 238000004806 packaging method and process Methods 0.000 title claims abstract description 40
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 229910052791 calcium Inorganic materials 0.000 title claims abstract description 29
- 239000011575 calcium Substances 0.000 title claims abstract description 29
- 239000002131 composite material Substances 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 239000004033 plastic Substances 0.000 title abstract 3
- 229920003023 plastic Polymers 0.000 title abstract 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 34
- -1 polyethylene Polymers 0.000 claims abstract description 29
- 239000004698 Polyethylene Substances 0.000 claims abstract description 20
- 229920000573 polyethylene Polymers 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 19
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims abstract description 17
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 17
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims abstract description 17
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 12
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 12
- 239000004743 Polypropylene Substances 0.000 claims abstract description 9
- 229920001155 polypropylene Polymers 0.000 claims abstract description 9
- 238000001816 cooling Methods 0.000 claims abstract description 8
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 16
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 9
- 238000003490 calendering Methods 0.000 claims description 7
- 238000001125 extrusion Methods 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 238000005453 pelletization Methods 0.000 claims description 4
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims description 3
- 150000002118 epoxides Chemical class 0.000 claims description 3
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims 1
- 239000000123 paper Substances 0.000 abstract description 5
- 239000002655 kraft paper Substances 0.000 abstract description 3
- 235000013311 vegetables Nutrition 0.000 abstract description 3
- 238000005469 granulation Methods 0.000 abstract 1
- 230000003179 granulation Effects 0.000 abstract 1
- 238000005096 rolling process Methods 0.000 abstract 1
- ALVYUZIFSCKIFP-UHFFFAOYSA-N triethoxy(2-methylpropyl)silane Chemical compound CCO[Si](CC(C)C)(OCC)OCC ALVYUZIFSCKIFP-UHFFFAOYSA-N 0.000 abstract 1
- 238000005452 bending Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 230000007423 decrease Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 241000274582 Pycnanthus angolensis Species 0.000 description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000011087 paperboard Substances 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
- B32B3/12—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a layer of regularly- arranged cells, e.g. a honeycomb structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
- B32B2307/7265—Non-permeable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
- B32B2439/40—Closed containers
- B32B2439/62—Boxes, cartons, cases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Packages (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a calcium plastic composite honeycomb packaging carton and a preparation method thereof. The preparation method comprises the steps that polyethylene, polypropylene, calcium carbonate, zinc stearate, barium stearate, isobutyltriethoxysilane and an antioxidant are mixed, stirred and subjected to extruding granulation, and master batches M are obtained; the master batches M are subjected to rolling and cooling, and a base plate material N is obtained; the base plate material N is bound to the inner walls of the honeycomb carton, and the calcium plastic composite honeycomb packaging carton is obtained. The problems that due to the fact that inner paper of ordinary cartons adopts kraft paper or cardboard paper or whiteboard paper, when the ordinary cartons are used for transporting articles such as vegetables and aquatic products which are high in humidity, the cartons are prone to be affected with damp, and the mechanical property of the cartons is sharply reduced are solved.
Description
Technical field
The present invention relates to Packaging Box preparation field, in particular it relates to calcium mould composite honeycomb Packaging Box and
Its preparation method.
Background technology
In recent years, due to corrugated case have lightweight, resistance to compression, resistance to expose, anti tear and buffering, shockproof,
The easily mechanical performance such as machine-shaping, it is possible to cycling and reutilization, the advantage such as environmentally safe it is considered to be
The preferred manner of food transport packaging.But owing in it, paper is kraft paper, boxboard or white board, fortune
The article that defeated humidity is bigger, such as vegetable, aquatic products etc., easily make moist under causing carton mechanical property drastically
Fall.
Therefore it provides one can be the most waterproof, the calcium that mechanical property will be caused drastically to decline because making moist is moulded
Composite honeycomb Packaging Box and preparation method thereof is the problem that the present invention needs solution badly.
Summary of the invention
It is an object of the invention to provide a kind of calcium and mould composite honeycomb Packaging Box and preparation method thereof, solve
Common carton in it paper be kraft paper, boxboard or white board, the article that transport humidity is bigger, such as vegetables
Dish, aquatic products etc., the problem causing carton mechanical property drastically to decline of easily making moist.
To achieve these goals, the invention provides a kind of calcium and mould the preparation side of composite honeycomb Packaging Box
Method, wherein, described preparation method includes:
(1) by polyethylene, polypropylene, calcium carbonate, zinc stearate, barium stearate, isobutyl group three second
Epoxide silicon and antioxidant mix and blend, and extruding pelletization, obtain master batch M；
(2) described masterbatch M is obtained baseplate material N after calendering cooling；
(3) described baseplate material N is bonded in honeycomb carton inwall, obtains calcium and mould composite honeycomb packaging
Carton；Wherein, relative to the polyethylene of 100 weight portions, described polyacrylic consumption is 30-50 weight
Part, the consumption of described calcium carbonate is 10-20 weight portion, and the consumption of described zinc stearate is 1-5 weight portion,
The consumption of described barium stearate is 1-5 weight portion, and the consumption of described isobutyl group triethoxysilicane is 2-8 weight
Amount part, the consumption of described antioxidant is 1-4 weight portion.
Present invention also offers a kind of calcium and mould composite honeycomb Packaging Box, wherein, described calcium moulds composite honeycomb
Packaging Box is prepared by above-mentioned preparation method.
By technique scheme, the invention provides a kind of calcium and mould composite honeycomb Packaging Box and preparation thereof
Method, wherein, described preparation method includes: by polyethylene, polypropylene, calcium carbonate, zinc stearate,
Barium stearate, isobutyl group triethoxysilicane and antioxidant mix and blend, and extruding pelletization, obtain master batch
M；Described masterbatch M is obtained baseplate material N after calendering cooling；By bonding for described baseplate material N
At honeycomb carton inwall, obtaining calcium and mould composite honeycomb Packaging Box, Packaging Box is internal moulds composite wood for calcium
Material, has stronger waterproof ability, and being difficult to make moist causes carton mechanical property drastically to decline, and is simultaneously used for
The method preparing this Packaging Box is simple, raw material is easy to get.
Other features and advantages of the present invention will be described in detail in detailed description of the invention part subsequently.
Detailed description of the invention
Hereinafter the detailed description of the invention of the present invention is described in detail.It should be appreciated that this place is retouched
The detailed description of the invention stated is merely to illustrate and explains the present invention, is not limited to the present invention.
The invention provides a kind of calcium and mould the preparation method of composite honeycomb Packaging Box, wherein, described preparation
Method includes: by polyethylene, polypropylene, calcium carbonate, zinc stearate, barium stearate, isobutyl group three second
Epoxide silicon and antioxidant mix and blend, and extruding pelletization, obtain master batch M；By described masterbatch M warp
Baseplate material N is obtained after calendering cooling；Described baseplate material N is bonded in honeycomb carton inwall, obtains
Calcium moulds composite honeycomb Packaging Box；Wherein, relative to the polyethylene of 100 weight portions, described polyacrylic
Consumption is 30-50 weight portion, and the consumption of described calcium carbonate is 10-20 weight portion, described zinc stearate
Consumption is 1-5 weight portion, and the consumption of described barium stearate is 1-5 weight portion, described isobutyl group three ethoxy
The consumption of base silicon is 2-8 weight portion, and the consumption of described antioxidant is 1-4 weight portion.
So that the Packaging Box prepared possesses the most excellent waterproof ability and mechanical strength, at this
Bright one preferred embodiment in, relative to the polyethylene of 100 weight portions, described polyacrylic use
Amount is 35-45 weight portion, and the consumption of described calcium carbonate is 14-16 weight portion, the use of described zinc stearate
Amount is 2-4 weight portion, and the consumption of described barium stearate is 2-4 weight portion, described isobutyl group triethoxy
The consumption of silicon is 4-6 weight portion, and the consumption of described antioxidant is 2-3 weight portion.
In order to improve the stability of prepared baseplate material N, the present invention one preferred embodiment
In, described antioxidant is in antioxidant 1010, antioxidant 1076 or antioxidant 168
Plant or multiple.
So that the Packaging Box prepared possesses the most excellent mechanical strength, described extrusion temperature is
160-190℃。
Described polyethylene and polypropylene are the conventional use of types of those skilled in the art, such as, the present invention's
One preferred embodiment in, in order to improve mechanical strength and the water resistance of prepared Packaging Box,
The weight average molecular weight of described polyethylene is 6000-9000, and described polyacrylic weight average molecular weight is
7000-8000。
Present invention also offers a kind of calcium and mould composite honeycomb Packaging Box, wherein, described calcium moulds composite honeycomb
Packaging Box is prepared by above-mentioned preparation method.
Hereinafter will be described the present invention by embodiment.In following example, polyethylene is with poly-
The commercially available product that propylene provides for Dongying City Hong Tai waterproof material company limited.
Embodiment 1
By 100g polyethylene, 35g polypropylene, 14g calcium carbonate, 2g zinc stearate, 2g barium stearate,
4g isobutyl group triethoxysilicane and 2g antioxidant 1010 mix and blend, and extrude that (extrusion temperature is
160 DEG C) pelletize, obtain master batch M；Described masterbatch M is obtained baseplate material N after calendering cooling；
Described baseplate material N is bonded in honeycomb carton inwall, obtains calcium and mould composite honeycomb Packaging Box A1.
Embodiment 2
By 100g polyethylene, 45g polypropylene, 16g calcium carbonate, 4g zinc stearate, 4g barium stearate,
6g isobutyl group triethoxysilicane and 3g antioxidant 1076 mix and blend, and extrude that (extrusion temperature is
190 DEG C) pelletize, obtain master batch M；Described masterbatch M is obtained baseplate material N after calendering cooling；
Described baseplate material N is bonded in honeycomb carton inwall, obtains calcium and mould composite honeycomb Packaging Box A2.
Embodiment 3
By 100g polyethylene, 40g polypropylene, 15g calcium carbonate, 3g zinc stearate, 3g barium stearate,
5g isobutyl group triethoxysilicane and 2.5g antioxidant 168 mix and blend, and extrude that (extrusion temperature is
180 DEG C) pelletize, obtain master batch M；Described masterbatch M is obtained baseplate material N after calendering cooling；
Described baseplate material N is bonded in honeycomb carton inwall, obtains calcium and mould composite honeycomb Packaging Box A3.
Embodiment 4
Being prepared according to the method for embodiment 1, except for the difference that, the consumption of polyethylene is 100g, described
Polyacrylic consumption is 30g, and the consumption of described calcium carbonate is 10g, and the consumption of described zinc stearate is 1g,
The consumption of described barium stearate is 1g, and the consumption of described isobutyl group triethoxysilicane is 2g, described antioxygen
The consumption of agent 1010 is 1g, obtains calcium and moulds composite honeycomb Packaging Box A4.
Embodiment 5
Being prepared according to the method for embodiment 1, except for the difference that, the consumption of polyethylene is 100g, described
Polyacrylic consumption is 50g, and the consumption of described calcium carbonate is 20g, and the consumption of described zinc stearate is 5g,
The consumption of described barium stearate is 5g, and the consumption of described isobutyl group triethoxysilicane is 8g, described antioxygen
The consumption of agent 1010 is 4g, obtains calcium and moulds composite honeycomb Packaging Box A5.
Comparative example 1
Being prepared according to the method for embodiment 1, except for the difference that, the consumption of polyethylene is 100g, described
Polyacrylic consumption is 20g, and the consumption of described calcium carbonate is 5g, and the consumption of described zinc stearate is 0.5g,
The consumption of described barium stearate is 0.5g, and the consumption of described isobutyl group triethoxysilicane is 1g, described antioxygen
The consumption of agent 1010 is 0.5g, obtains calcium and moulds composite honeycomb Packaging Box D1.
Comparative example 2
Being prepared according to the method for embodiment 1, except for the difference that, the consumption of polyethylene is 100g, described
Polyacrylic consumption is 60g, and the consumption of described calcium carbonate is 30g, and the consumption of described zinc stearate is 10g,
The consumption of described barium stearate is 10g, and the consumption of described isobutyl group triethoxysilicane is 12g, described anti-
The consumption of oxidant 1010 is 7g, obtains calcium and moulds composite honeycomb Packaging Box D2.
Test case 1
Prepared Packaging Box A1-A5, D1 and D2 are curved strength test, and to A1-A5,
The inwall of D1 and D2 is persistently sprayed water after 20min, measures Packaging Box A1-A5, D1 and D2
Bending strength.
Table 1
By above table data it can be seen that the bending of the Packaging Box prepared within the scope of the present invention is strong
Degree is higher than outside the scope of the invention and prepares Packaging Box D1 and D2, and in currently preferred scope
The bending strength of the Packaging Box A1-A3 prepared is higher, and the bending strength of the carton after water spray is lower slightly
In the carton do not sprayed water, illustrate that carton has stronger waterproof ability, after humidity, also do not interfere with carton
Mechanical strength.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited to above-mentioned reality
Execute the detail in mode, in the technology concept of the present invention, can be to the technical side of the present invention
Case carries out multiple simple variant, and these simple variant belong to protection scope of the present invention.
It is further to note that each the concrete technology described in above-mentioned detailed description of the invention is special
Levy, in the case of reconcilable, can be combined by any suitable means, in order to avoid need not
The repetition wanted, various possible compound modes are illustrated by the present invention the most separately.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as its
Without prejudice to the thought of the present invention, it should be considered as content disclosed in this invention equally.
Claims (7)
1. a calcium moulds the preparation method of composite honeycomb Packaging Box, it is characterised in that described preparation side
Method includes:
(1) by polyethylene, polypropylene, calcium carbonate, zinc stearate, barium stearate, isobutyl group three second
Epoxide silicon and antioxidant mix and blend, and extruding pelletization, obtain master batch M；
(2) described masterbatch M is obtained baseplate material N after calendering cooling；
(3) described baseplate material N is bonded in honeycomb carton inwall, obtains calcium and mould composite honeycomb packaging
Carton；Wherein, relative to the polyethylene of 100 weight portions, described polyacrylic consumption is 30-50 weight
Part, the consumption of described calcium carbonate is 10-20 weight portion, and the consumption of described zinc stearate is 1-5 weight portion,
The consumption of described barium stearate is 1-5 weight portion, and the consumption of described isobutyl group triethoxysilicane is 2-8 weight
Amount part, the consumption of described antioxidant is 1-4 weight portion.
Preparation method the most according to claim 1, wherein, relative to the poly-second of 100 weight portions
Alkene, described polyacrylic consumption is 35-45 weight portion, and the consumption of described calcium carbonate is 14-16 weight portion,
The consumption of described zinc stearate is 2-4 weight portion, and the consumption of described barium stearate is 2-4 weight portion, institute
The consumption stating isobutyl group triethoxysilicane is 4-6 weight portion, and the consumption of described antioxidant is 2-3 weight
Part.
Preparation method the most according to claim 1 and 2, wherein, described antioxidant is antioxygen
One or more in agent 1010, antioxidant 1076 or antioxidant 168.
Preparation method the most according to claim 1, wherein, described extrusion temperature is 160-190
℃。
Preparation method the most according to claim 1, wherein, the weight average molecular weight of described polyethylene
For 6000-9000.
Preparation method the most according to claim 1, wherein, described polyacrylic weight average molecular weight
For 7000-8000.
7. a calcium moulds composite honeycomb Packaging Box, it is characterised in that described calcium moulds composite honeycomb packaging
Carton is prepared by the preparation method described in any one in claim 1-6.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610442888.3A CN106009158A (en) | 2016-06-16 | 2016-06-16 | Calcium plastic composite honeycomb packaging carton and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610442888.3A CN106009158A (en) | 2016-06-16 | 2016-06-16 | Calcium plastic composite honeycomb packaging carton and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106009158A true CN106009158A (en) | 2016-10-12 |
Family
ID=57088342
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| CN201610442888.3A Pending CN106009158A (en) | 2016-06-16 | 2016-06-16 | Calcium plastic composite honeycomb packaging carton and preparation method thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101451004A (en) * | 2008-12-26 | 2009-06-10 | 大连塑料研究所有限公司 | Film for producing composite paper-like film and paper-like film and method for producing the same |
| CN101659770A (en) * | 2009-09-05 | 2010-03-03 | 常州金卡基材有限公司 | Flame-retardant synthetic paper |
| CN102848686A (en) * | 2012-09-21 | 2013-01-02 | 浙江大学宁波理工学院 | Corrugated cardboard with one-side calcium-plastic paper and method for making corrugated cardboard |
-
2016
- 2016-06-16 CN CN201610442888.3A patent/CN106009158A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101451004A (en) * | 2008-12-26 | 2009-06-10 | 大连塑料研究所有限公司 | Film for producing composite paper-like film and paper-like film and method for producing the same |
| CN101659770A (en) * | 2009-09-05 | 2010-03-03 | 常州金卡基材有限公司 | Flame-retardant synthetic paper |
| CN102848686A (en) * | 2012-09-21 | 2013-01-02 | 浙江大学宁波理工学院 | Corrugated cardboard with one-side calcium-plastic paper and method for making corrugated cardboard |
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Application publication date: 20161012 |