CN106084386A - Moistureproof Honey comb like package carton and preparation method thereof - Google Patents
Moistureproof Honey comb like package carton and preparation method thereof Download PDFInfo
- Publication number
- CN106084386A CN106084386A CN201610438294.5A CN201610438294A CN106084386A CN 106084386 A CN106084386 A CN 106084386A CN 201610438294 A CN201610438294 A CN 201610438294A CN 106084386 A CN106084386 A CN 106084386A
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- Prior art keywords
- consumption
- honey comb
- preparation
- moistureproof
- weight portion
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Wrappers (AREA)
Abstract
The invention discloses a kind of moistureproof Honey comb like package carton and preparation method thereof, wherein, described preparation method includes: obtain mixture M after Low Density Polyethylene, butadiene, naphthenic oil, paraffin, ethyl acetate and dispersant are added hot mixing；By described mixture M through blow molding process, obtain waterproof membrane N；Waterproof membrane N is attached to Honey comb like package carton surface, obtain moistureproof Honey comb like package carton, solve traditional Packaging Box in it paper be kraft paper, boxboard or white board, the article that transport humidity is bigger, such as vegetable, aquatic products etc., the problem causing carton mechanical property drastically to decline of easily making moist.
Description
Technical field
The present invention relates to the preparation field of Packaging Box, in particular it relates to moistureproof Honey comb like package carton and preparation method thereof.
Background technology
In recent years, due to corrugated case have lightweight, resistance to compression, resistance to expose, anti tear and buffering, machine-shaping shockproof, easy
Etc. mechanical performance, it is possible to cycling and reutilization, the advantage such as environmentally safe is it is considered to be the preferred manner of food transport packaging.
But owing in it, paper is kraft paper, boxboard or white board, the transport bigger article of humidity, such as vegetable, aquatic products etc., easily
Make moist and cause carton mechanical property drastically to decline.
Therefore it provides one can be effectively moistureproof, the Honey comb like package carton that mechanical property drastically declines will not be caused because making moist
And preparation method thereof be the present invention problem of needing solution badly.
Summary of the invention
It is an object of the invention to provide a kind of moistureproof Honey comb like package carton and preparation method thereof, solve traditional wrapping paper
Case in it paper be kraft paper, boxboard or white board, the article that transport humidity is bigger, such as vegetable, aquatic products etc., easily make moist and lead
Cause the problem that carton mechanical property drastically declines.
To achieve these goals, the invention provides the preparation method of a kind of moistureproof Honey comb like package carton, wherein, described
Preparation method includes:
(1) mixed after Low Density Polyethylene, butadiene, naphthenic oil, paraffin, ethyl acetate and dispersant being added hot mixing
Compound M；
(2) by described mixture M through blow molding process, waterproof membrane N is obtained；
(3) waterproof membrane N is attached to Honey comb like package carton surface, obtains moistureproof Honey comb like package carton；Wherein, relative to
The Low Density Polyethylene of 100 weight portions, the consumption of described butadiene is 20-40 weight portion, and the consumption of described naphthenic oil is 5-15
Weight portion, the consumption of described paraffin is 1-10 weight portion, and the consumption of described ethyl acetate is 12-25 weight portion, described dispersant
Consumption be 1-5 weight portion.
Present invention also offers a kind of moistureproof Honey comb like package carton, described moistureproof Honey comb like package carton is by above-mentioned preparation side
Method prepares.
By technique scheme, the invention provides a kind of moistureproof Honey comb like package carton and preparation method thereof, wherein, institute
State preparation method to include: obtain after Low Density Polyethylene, butadiene, naphthenic oil, paraffin, ethyl acetate and dispersant add hot mixing
To mixture M；By described mixture M through blow molding process, obtain waterproof membrane N；Waterproof membrane N is attached to Honey comb like package carton table
Face, obtains moistureproof Honey comb like package carton, by the synergism between each raw material so that prepared Packaging Box not only possesses excellent
Good mechanical strength, and waterproof and dampproof ability is relatively strong, makes moist and is not result in that carton mechanical property drastically declines.
Other features and advantages of the present invention will be described in detail in detailed description of the invention part subsequently.
Detailed description of the invention
Hereinafter the detailed description of the invention of the present invention is described in detail.It should be appreciated that described herein specifically
Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
The invention provides the preparation method of a kind of moistureproof Honey comb like package carton, described preparation method includes: by low-density
Polyethylene, butadiene, naphthenic oil, paraffin, ethyl acetate and dispersant obtain mixture M after adding hot mixing；By described mixture M
Through blow molding process, obtain waterproof membrane N；Waterproof membrane N is attached to Honey comb like package carton surface, obtains moistureproof Honey comb like package carton；
Wherein, relative to the Low Density Polyethylene of 100 weight portions, the consumption of described butadiene is 20-40 weight portion, described naphthenic oil
Consumption is 5-15 weight portion, and the consumption of described paraffin is 1-10 weight portion, and the consumption of described ethyl acetate is 12-25 weight portion,
The consumption of described dispersant is 1-5 weight portion.
So that the Packaging Box prepared possesses the most excellent mechanical strength and waterproof ability, in the one of the present invention
In preferred embodiment, relative to the Low Density Polyethylene of 100 weight portions, the consumption of described butadiene is 25-35 weight portion,
The consumption of described naphthenic oil is 8-12 weight portion, and the consumption of described paraffin is 4-6 weight portion, and the consumption of described ethyl acetate is
15-20 weight portion, the consumption of described dispersant is 2-4 weight portion.
So that can preferably dissolve each other between raw material, the present invention one preferred embodiment in, described point
Powder is one or more in triethyl group hexyl phosphoric acid, sodium lauryl sulphate and methyl anyl alcohol.
Described Low Density Polyethylene can be the conventional use of type of those skilled in the art, such as, excellent in the one of the present invention
In the embodiment of choosing, in order to increase the waterproof ability of prepared Packaging Box further, the weight average of described Low Density Polyethylene
Molecular weight is 5000-8000.
So that the waterproof membrane N prepared can the most firmly stick to Honey comb like package carton surface, the present invention's
One preferred embodiment in, described preparation method also includes: described waterproof membrane N is heated to 45-50 DEG C, is attached to afterwards
Honey comb like package carton surface.
Present invention also offers a kind of moistureproof Honey comb like package carton, described moistureproof Honey comb like package carton is by above-mentioned preparation side
Method prepares.
Hereinafter will be described the present invention by embodiment.In following example, Low Density Polyethylene and fourth two
The commercially available product that alkene provides for Dongying City Hong Tai waterproof material company limited, naphthenic oil, paraffin and ethyl acetate are that Changzhou edifies
The commercially available product that Chemical Co., Ltd. provides.
Embodiment 1
100g Low Density Polyethylene, 25g butadiene, 8g naphthenic oil, 4g paraffin, 15g ethyl acetate and 2g triethyl group is own
Base phosphoric acid obtains mixture M after adding hot mixing；By described mixture M through blow molding process, obtain waterproof membrane N；Waterproof membrane N is heated
To 45 DEG C, and it is attached to Honey comb like package carton surface, obtains moistureproof Honey comb like package carton A1.
Embodiment 2
By 100g Low Density Polyethylene, 35g butadiene, 12g naphthenic oil, 6g paraffin, 20g ethyl acetate and 4g dodecyl
Sodium sulfate obtains mixture M after adding hot mixing；By described mixture M through blow molding process, obtain waterproof membrane N；Waterproof membrane N is heated
To 50 DEG C, and it is attached to Honey comb like package carton surface, obtains moistureproof Honey comb like package carton A2.
Embodiment 3
By 100g Low Density Polyethylene, 30g butadiene, 10g naphthenic oil, 5g paraffin, 18g ethyl acetate and 3g methyl anyl alcohol
Mixture M is obtained after adding hot mixing；By described mixture M through blow molding process, obtain waterproof membrane N；Waterproof membrane N is heated to 48
DEG C, and it is attached to Honey comb like package carton surface, obtain moistureproof Honey comb like package carton A3.
Embodiment 4
Being prepared according to the method for embodiment 1, except for the difference that, the consumption of Low Density Polyethylene is 100g, described fourth two
The consumption of alkene is 20g, and the consumption of described naphthenic oil is 5g, and the consumption of described paraffin is 1g, and the consumption of described ethyl acetate is
12g, the consumption of described triethyl group hexyl phosphoric acid is 1g, obtains moistureproof Honey comb like package carton A4.
Embodiment 5
Being prepared according to the method for embodiment 1, except for the difference that, the consumption of Low Density Polyethylene is 100g, described fourth two
The consumption of alkene is 40g, and the consumption of described naphthenic oil is 15g, and the consumption of described paraffin is 10g, and the consumption of described ethyl acetate is
25g, the consumption of described triethyl group hexyl phosphoric acid is 5g, obtains moistureproof Honey comb like package carton A5.
Comparative example 1
Being prepared according to the method for embodiment 1, except for the difference that, the consumption of Low Density Polyethylene is 100g, described fourth two
The consumption of alkene is 10g, and the consumption of described naphthenic oil is 3g, and the consumption of described paraffin is 0.5g, and the consumption of described ethyl acetate is
8g, the consumption of described triethyl group hexyl phosphoric acid is 0.5g, obtains moistureproof Honey comb like package carton D1.
Comparative example 2
Being prepared according to the method for embodiment 1, except for the difference that, the consumption of Low Density Polyethylene is 100g, described fourth two
The consumption of alkene is 45g, and the consumption of described naphthenic oil is 20g, and the consumption of described paraffin is 15g, and the consumption of described ethyl acetate is
30g, the consumption of described triethyl group hexyl phosphoric acid is 10g, obtains moistureproof Honey comb like package carton D2.
Test case 1
Prepared moistureproof Honey comb like package carton A1-A5, D1 and D2 are curved strength test, and to moistureproof Honey comb like package
The carrying out of carton A1-A5, D1 and D2 is persistently sprayed water after 20min, measures the bending strength of Packaging Box A1-A5, D1 and D2.
Table 1
By above table data it can be seen that the bending strength of the Packaging Box prepared within the scope of the present invention is higher than
Prepared Packaging Box D1 and D2 outside the scope of the invention, and the Packaging Box A1-A3 prepared in currently preferred scope
Bending strength is higher, and the bending strength of the carton after water spray the most substantially reduces, and illustrates that carton has stronger waterproof ability,
The mechanical strength of carton is not interfered with after humidity yet.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment
Detail, in the technology concept of the present invention, technical scheme can be carried out multiple simple variant, this
A little simple variant belong to protection scope of the present invention.
It is further to note that each the concrete technical characteristic described in above-mentioned detailed description of the invention, at not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to various can
The compound mode of energy illustrates the most separately.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as it is without prejudice to this
The thought of invention, it should be considered as content disclosed in this invention equally.
Claims (6)
1. the preparation method of a moistureproof Honey comb like package carton, it is characterised in that described preparation method includes:
(1) mixture is obtained after Low Density Polyethylene, butadiene, naphthenic oil, paraffin, ethyl acetate and dispersant being added hot mixing
M；
(2) by described mixture M through blow molding process, waterproof membrane N is obtained；
(3) waterproof membrane N is attached to Honey comb like package carton surface, obtains moistureproof Honey comb like package carton；Wherein, relative to 100 weights
The Low Density Polyethylene of amount part, the consumption of described butadiene is 20-40 weight portion, and the consumption of described naphthenic oil is 5-15 weight
Part, the consumption of described paraffin is 1-10 weight portion, and the consumption of described ethyl acetate is 12-25 weight portion, the use of described dispersant
Amount is 1-5 weight portion.
Preparation method the most according to claim 1, wherein, relative to the Low Density Polyethylene of 100 weight portions, described fourth two
The consumption of alkene is 25-35 weight portion, and the consumption of described naphthenic oil is 8-12 weight portion, and the consumption of described paraffin is 4-6 weight portion,
The consumption of described ethyl acetate is 15-20 weight portion, and the consumption of described dispersant is 2-4 weight portion.
Preparation method the most according to claim 1 and 2, wherein, described dispersant is triethyl group hexyl phosphoric acid, dodecyl
One or more in sodium sulfate and methyl anyl alcohol.
Preparation method the most according to claim 1, wherein, the weight average molecular weight of described Low Density Polyethylene is 5000-
8000。
Preparation method the most according to claim 1, wherein, described preparation method also includes: be heated to by described waterproof membrane N
45-50 DEG C, it is attached to Honey comb like package carton surface afterwards.
6. a moistureproof Honey comb like package carton, it is characterised in that described moistureproof Honey comb like package carton is by any in claim 1-5
One described preparation method prepares.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610438294.5A CN106084386A (en) | 2016-06-16 | 2016-06-16 | Moistureproof Honey comb like package carton and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610438294.5A CN106084386A (en) | 2016-06-16 | 2016-06-16 | Moistureproof Honey comb like package carton and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106084386A true CN106084386A (en) | 2016-11-09 |
Family
ID=57236352
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610438294.5A Pending CN106084386A (en) | 2016-06-16 | 2016-06-16 | Moistureproof Honey comb like package carton and preparation method thereof |
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| CN (1) | CN106084386A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111070773A (en) * | 2019-12-30 | 2020-04-28 | 宏观世纪（天津）科技股份有限公司 | Anti-crease treatment method for carton package |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102085943A (en) * | 2010-10-19 | 2011-06-08 | 曾广胜 | Waterproof moistureproof and shockproof honeycomb paperboard |
| CN102848686A (en) * | 2012-09-21 | 2013-01-02 | 浙江大学宁波理工学院 | Corrugated cardboard with one-side calcium-plastic paper and method for making corrugated cardboard |
| CN105419050A (en) * | 2015-12-19 | 2016-03-23 | 青岛宇星智能科技开发有限公司 | Environment-friendly degradable plastic thin film |
-
2016
- 2016-06-16 CN CN201610438294.5A patent/CN106084386A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102085943A (en) * | 2010-10-19 | 2011-06-08 | 曾广胜 | Waterproof moistureproof and shockproof honeycomb paperboard |
| CN102848686A (en) * | 2012-09-21 | 2013-01-02 | 浙江大学宁波理工学院 | Corrugated cardboard with one-side calcium-plastic paper and method for making corrugated cardboard |
| CN105419050A (en) * | 2015-12-19 | 2016-03-23 | 青岛宇星智能科技开发有限公司 | Environment-friendly degradable plastic thin film |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111070773A (en) * | 2019-12-30 | 2020-04-28 | 宏观世纪（天津）科技股份有限公司 | Anti-crease treatment method for carton package |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161109 |