CN104681438B - A kind of forming method of semiconductor devices - Google Patents

A kind of forming method of semiconductor devices Download PDF

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Publication number
CN104681438B
CN104681438B CN201310613731.9A CN201310613731A CN104681438B CN 104681438 B CN104681438 B CN 104681438B CN 201310613731 A CN201310613731 A CN 201310613731A CN 104681438 B CN104681438 B CN 104681438B
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silicon substrate
semiconductor devices
layer
forming method
bulk silicon
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CN104681438A (en
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刘继全
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Shanghai Huahong Grace Semiconductor Manufacturing Corp
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Shanghai Huahong Grace Semiconductor Manufacturing Corp
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/66674DMOS transistors, i.e. MISFETs with a channel accommodating body or base region adjoining a drain drift region
    • H01L29/66712Vertical DMOS transistors, i.e. VDMOS transistors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/26Bombardment with radiation
    • H01L21/263Bombardment with radiation with high-energy radiation
    • H01L21/265Bombardment with radiation with high-energy radiation producing ion implantation
    • H01L21/26506Bombardment with radiation with high-energy radiation producing ion implantation in group IV semiconductors

Abstract

The present invention discloses a kind of forming method of semiconductor devices, comprises the following steps:1)Deep trench is etched in bulk silicon substrate side;2)Channel bottom is injected and trap is pushed away;3)Silicon epitaxy layer is filled in trench interiors and is planarized;Then base, source region, grid, dielectric layer and front metal electrode are formed;4)Bulk silicon substrate opposite side is thinned, and opposite side progress ion implanting, laser annealing, back metal electrode are formed.The present invention makes the breakdown voltage of semiconductor devices, conducting resistance keep stable by the adjustment to silicon epitaxy doping concentration, gash depth and silicon wafer thickness.The inventive method can reduce the manufacturing cost of super-junction device, production efficiency be improved, while the conducting resistance of device can be reduced.

Description

A kind of forming method of semiconductor devices
Technical field
The invention belongs to semiconductor integrated circuit manufacture field, and in particular to semiconductor image sensor, more particularly to one Plant full isolation back side illumination image sensor and its manufacture method.
Background technology
VDMOSFET(VerticalDouble-diffusedMOSFET, vertical double-diffused MOS transistor)It can use and subtract The thickness of thin drain terminal drift region reduces conducting resistance, however, the thickness of drain terminal drift region, which is thinned, will reduce puncturing for device Voltage, therefore in VDMOS, the breakdown voltage for improving device is conflict with the conducting resistance for reducing device.Super junction MOSFET is using new structure of voltage-sustaining layer-using a series of p-type being alternately arranged and N-type semiconductor thin layer, in low voltage P-type N-type region is exhausted under lower backward voltage, realizes that electric charge is mutually compensated for, so that p-type N-type region can be real under high-dopant concentration Existing high breakdown voltage, so as to obtain low on-resistance and high-breakdown-voltage simultaneously, break traditions power MOSFET theoretical limits.
Super junction MOSFET difficult point is that device architecture forms difficulty, and the p-type and N-type semiconductor being mainly alternately arranged are thin The formation of Rotating fields.General forming method is:In N-type silicon epitaxy layer(That is the first semiconductor layer 22 in Fig. 1)It is upper to form deep Groove, then use P-type silicon epitaxial layer(That is the second semiconductor layer 23 in Fig. 1)Deep trench is filled, the structure of existing device is shown in Fig. 1. Due to involving thick epitaxial growth, deep plough groove etched, trench fill etc., cost is higher.How growth cost always industry is reduced The direction of boundary's research.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of forming method of semiconductor devices is proposed, production can be reduced Cost, improves production efficiency.
In order to solve the above technical problems, the present invention provides a kind of forming method of semiconductor devices, comprise the following steps:
1)Deep trench is etched in bulk silicon substrate side;
2)Channel bottom is injected and trap is pushed away;
3)Silicon epitaxy layer is filled in trench interiors and is planarized;Then base, source region, grid, dielectric layer and front are formed Metal electrode;
4)Bulk silicon substrate opposite side is thinned, and ion implanting, laser annealing, back-side gold are carried out to opposite side Category electrode is formed.
It is used as preferred technical scheme, step 1)In, the zanjon groove depth is 10-80 μm, and width is 1-10 μm, zanjon Separation is 2-15 μm, and the doping concentration for the bulk silicon substrate surveyed in advance so that the depth of deep trench is served as a contrast with semiconductor silicon The doping concentration at bottom is into positive corresponding relation.
It is used as preferred technical scheme, step 1)In, the bulk silicon substrate is N-type or p-type, and doping concentration is 1E13-1E17cm-3
It is used as preferred technical scheme, step 1)In, increase following steps before the etching deep trench:In semiconductor silicon Grown dielectric layer, the dielectric layer is at least one of silica, silicon nitride, silicon oxynitride, and thickness is 0.1 μm of -2 μ m。
It is used as preferred technical scheme, step 2)In, the doping class of the injection carrier type and bulk silicon substrate Type is identical, and implantation dosage is 1E11-1E14atom/cm2, Implantation Energy is 10-100Kev.
It is used as preferred technical scheme, step 2)In, increase following steps before injection:First at zanjon groove sidewall and bottom Portion grows a layer dielectric, and the deielectric-coating is at least one of silica, silicon nitride, silicon oxynitride, then is carved with anisotropic Etching method removes the deielectric-coating of zanjon trench bottom.
It is used as preferred technical scheme, step 2)In, the trap that pushes away is specially:The ion for being injected into channel bottom is carried out High temperature diffusion, makes it be diffused into below channel bottom 5-40 μm, and injection diffusion layer is between channel bottom formation one is continuous not Disconnected injection doped layer.
It is used as preferred technical scheme, step 3)In, it is described to be carried out in two steps in trench interiors filling silicon epitaxy layer:First Step, has the silicon epitaxy of identical doping type in deep trench underfill and bulk silicon substrate;Second step, continues in groove The filling silicon epitaxy opposite with bulk silicon substrate doping type, until groove is filled up completely with, also, the silicon substrate surveyed in advance Doping concentration so that second step inserts the doping concentration of the silicon epitaxy layer of groove and the doping concentration of bulk silicon substrate into just right It should be related to.
It is used as preferred technical scheme, step 4)In, the thickness after the bulk silicon substrate is thinned is 30-200 μm, and The doping concentration for the silicon substrate surveyed in advance, makes to be thinned the rear thickness of silicon chip and the doping concentration of silicon substrate into positive corresponding relation.
It is used as preferred technical scheme, step 4)In, the species of the ion implanting is at least one in B, P, As, Sb Kind, Implantation Energy is 10-1000Kev, and implantation dosage is 1E13-1E17atoms/cm2
It is used as preferred technical scheme, step 4)In, the energy of the laser annealing is 1.0-3.0J/cm2, spot length For 1-3mm, spot width is 0.3-1.5mm;Floor height doping implanted layer is formed after laser annealing at the bulk silicon substrate back side, With follow-up metal electrode formation Ohmic contact.
It is used as preferred technical scheme, step 4)In, the method that the back metal electrode is formed by evaporation or sputtering Metal level is formed at the bulk silicon substrate back side as first electrode, the species of metal is at least one in Ti, Ni, Ag, Au, Al Kind, thickness is 0.1-2 μm.
When so-called positive corresponding relation refers to variables A increase, variable B also increases;When negative corresponding relation refers to variables A increase, Variable B reduces.
The super-junction device of method is manufactured as described above, when the doping concentration Cn of silicon substrate is fluctuated within the specific limits, device Breakdown voltage BV and the conducting resistance Ron doping concentration Cp that pass through silicon epitaxy(Make the carrier amount phase of super junction P posts and N posts Deng), gash depth d and be thinned after silicon wafer thickness t adjustment and keep constant because:
BV∞d/Cn Ron∞t/Cn
Carrier is injected in channel bottom in addition and promoted, reduce the conducting resistance Ron of device.Inject and push away trap Depth 5-40 microns of depth below channel bottom.
Compared to the prior art, the invention has the advantages that:The present invention is by silicon epitaxy doping concentration, groove The adjustment of depth and silicon wafer thickness, makes the breakdown voltage of semiconductor devices, conducting resistance keep stable.The inventive method can drop The manufacturing cost of low super-junction device, improves production efficiency, while the conducting resistance Ron of device can be reduced.
Brief description of the drawings
Fig. 1 is the structural representation of existing device;
Fig. 2-Figure 12 is the manufacturing process flow schematic diagram of the embodiment of the present invention;Wherein, Fig. 2 is the step of the embodiment of the present invention Rapid 1)After the completion of section structure schematic diagram;Fig. 3 is the step 2 of the embodiment of the present invention)After the completion of section structure schematic diagram;Figure 4 be the step 3 of the embodiment of the present invention)After the completion of section structure schematic diagram;Fig. 5 is the step 4 of the embodiment of the present invention)After the completion of Section structure schematic diagram;Fig. 6 is the step 5 of the embodiment of the present invention)The silicon epitaxy first step filling after the completion of section structure Schematic diagram;Fig. 7 is the step 5 of the embodiment of the present invention)Section structure schematic diagram after the completion of the filling of silicon epitaxy second step;Fig. 8 is The step 6 of the embodiment of the present invention)After the completion of section structure schematic diagram;Fig. 9 is the step 7 of the embodiment of the present invention)After the completion of Section structure schematic diagram;Figure 10 is the step 8 of the embodiment of the present invention)After the completion of section structure schematic diagram;Figure 11 is the present invention The step 9 of embodiment)After the completion of section structure schematic diagram;Figure 12 is the step 10 of the embodiment of the present invention)After the completion of section Structural representation;
Description of reference numerals is as follows:
1 is bulk silicon substrate, and 2 be dielectric layer, and 3 be the second silicon epitaxy layer, and 4 be the first silicon epitaxy layer, and 5 be base region, 6 It is gate dielectric layer for source area, 7,8 be grid, and 9 be before-metal medium layer, and 10 be second electrode, and 11 be front injection diffusion Layer, 12 be that diffusion layer is injected at the back side, and 13 be first electrode.
21 be bulk silicon substrate, and 22 be the first semiconductor layer, and 23 be the second semiconductor layer, and 24 be base, and 25 be source region, 26 be gate dielectric layer, and 27 be grid, and 28 be before-metal medium layer, and 29 be second electrode, and 30 be first electrode.
Embodiment
The present invention is further detailed explanation with reference to the accompanying drawings and examples.
Embodiment:
As shown in Fig. 2-Figure 12, a kind of forming method of semiconductor devices of the invention specifically includes following steps:
1)The somatomedin layer 2 on bulk silicon substrate 1, bulk silicon substrate 1 can be N-type or p-type, and doping concentration is 1E13-1E17cm-3;Dielectric layer 2 is at least one of silica, silicon nitride, silicon oxynitride, and thickness is 0.1 μm -2 μm(See figure 2).
2)Deep trench is etched on bulk silicon substrate 1, zanjon well width is 1-10 μm, and depth is between 10-80 μm, groove Away from for 2-15 microns(See Fig. 3);And the doping concentration for the bulk silicon substrate 1 surveyed in advance so that the depth of deep trench is with partly leading The doping concentration of body silicon substrate 1 presets the breakdown voltage of device into positive corresponding relation, when mixing for bulk silicon substrate 1 When miscellaneous concentration is higher, the depth of appropriate increase groove, when the doping concentration of bulk silicon substrate 1 is relatively low, then appropriate reduction ditch The depth of groove so that when the doping concentration of bulk silicon substrate 1 is fluctuated within the specific limits(+/- the 50% of reservation value), device Breakdown voltage keeps constant.
3)Ion implanting is carried out in channel bottom, the type for injecting ion is identical with the doping type of bulk silicon substrate 1, If bulk silicon substrate 1 is doped to N-type, N-type is injected to;If bulk silicon substrate 1 is p-type, implanting p-type;Injection Dosage is 1E11-1E14atom/cm2, Implantation Energy is 10-100Kev;To prevent trenched side-wall to be injected into ion, it can use The method that trenched side-wall is protected with deielectric-coating, specific practice is:First in trenched side-wall and the layer dielectric of bottom grown one(Oxidation At least one of silicon, silicon nitride, silicon oxynitride), then with anisotropic etching method the deielectric-coating of channel bottom is removed, so After carry out ion implanting(See Fig. 4).
4)High temperature diffusion is carried out to the ion for being injected into channel bottom, it is diffused into below channel bottom 5-40 μm, and Diffusion layer is injected in channel bottom one continuous continual injection doped layer of formation, and diffusion layer 11 is injected as front(See figure 5).
5)Groove is filled with silicon epitaxy process.Silicon epitaxy filling is carried out in two steps:The first step, in channel bottom filling and half Conductor silicon substrate 1 has the silicon epitaxy of identical doping type, i.e. the first silicon epitaxy layer 4, if bulk silicon substrate 1 is doped to N Type, then the first silicon epitaxy layer 4 is N-type, sees Fig. 6;Second step, the second step filling of silicon epitaxy, its doping type and semiconductor silicon Substrate 1 is on the contrary, form the second silicon epitaxy layer 3, if bulk silicon substrate 1 is doped to N-type, the second silicon epitaxy layer 3 is P Type;If bulk silicon substrate 1 is p-type, the second silicon epitaxy layer 3 is N-type, sees Fig. 7.Outside first silicon epitaxy layer 4 and the second silicon The doping type for prolonging layer 3 is opposite.The doping concentration for the bulk silicon substrate 1 surveyed in advance so that second step inserts the second of groove The doping concentration of silicon epitaxy layer 3 and the doping concentration of bulk silicon substrate 1 mixing into positive corresponding relation, i.e. bulk silicon substrate 1 When miscellaneous concentration is high, the doping concentration of the second silicon epitaxy layer 3 is also high;When the doping concentration of bulk silicon substrate 1 is low, the second silicon epitaxy The doping concentration of layer 3 is also low, and final purpose is to make the semiconductor between the carrier total amount of silicon epitaxy in single groove and groove The carrier total amount of silicon substrate 1 is equal(See Fig. 7).
6)With chemical mechanical milling tech to being planarized at the top of groove(See Fig. 8);
7)Next with routine MOSFET techniques formation base region 5, before source area 6, gate dielectric layer 7, grid 9, metal Dielectric layer 9, second electrode 10 etc.(See Fig. 9).
8)Bulk silicon substrate 1 is thinned.Thickness after bulk silicon substrate 1 is thinned is 30-200 μm, and in advance The doping concentration of the silicon substrate of survey, makes to be thinned the rear thickness of silicon chip and the doping concentration of silicon substrate into positive corresponding relation.It is i.e. advance If the conducting resistance of low device, when the doping concentration of silicon substrate is high, the thickness of silicon substrate after appropriate increase is thinned;Work as silicon substrate Doping concentration it is low when, the thickness of silicon substrate after appropriate reduction is thinned so that the doping concentration of silicon substrate ripple within the specific limits When dynamic(+/- the 50% of reservation value), the conducting resistance of device keeps constant(See Figure 10).
9)Backside particulate injects and laser annealing.The species of ion implanting is at least one of B, P, As, Sb, injects energy Measure as 10-1000Kev, implantation dosage is 1E13-1E17atoms/cm2.The energy of laser annealing is 1.0-3.0J/cm2, hot spot Length is 1-3mm, and spot width is 0.3-1.5mm.After injection and laser annealing a floor height is formed at the back side of bulk silicon substrate 1 Adulterated implanted layer, and diffusion layer 12 is injected as the back side, can contact electricity with follow-up metal electrode formation Ohmic contact to reduce Resistance.The characteristics of laser annealing is that thermal range is controlled, i.e., only silicon substrate back temperature is high, and positive temperature is unaffected, no Influence whether the device at the back side(See Figure 11).
10)Back metal electrode is formed.Metal level is formed with the method for evaporation or sputtering at the back side of bulk silicon substrate 1 to make For first electrode 13.The species of metal is at least one of Ti, Ni, Ag, Au, Al, and thickness is 0.1-2 μm(See Figure 12).
The present invention makes hitting for semiconductor devices by the adjustment to silicon epitaxy doping concentration, gash depth and silicon wafer thickness Wear voltage, conducting resistance and keep stable.The inventive method can reduce the manufacturing cost of super-junction device, improve production efficiency, The conducting resistance of device can be reduced simultaneously.

Claims (10)

1. a kind of forming method of semiconductor devices, it is characterised in that:Comprise the following steps:
1)Deep trench is etched in bulk silicon substrate side;
2)Channel bottom is injected and trap is pushed away;
3)Silicon epitaxy layer is filled in trench interiors and is planarized;It is described to be carried out in two steps in trench interiors filling silicon epitaxy layer:The One step, has the silicon epitaxy of identical doping type in deep trench underfill and bulk silicon substrate;Second step, continues in groove The interior filling silicon epitaxy opposite with bulk silicon substrate doping type, until being filled up completely with groove, also, the silicon substrate surveyed in advance Doping concentration so that second step inserts the doping concentration of the silicon epitaxy layer of groove and the doping concentration of bulk silicon substrate into just Corresponding relation;Then base, source region, grid, dielectric layer and front metal electrode are formed;
4)Bulk silicon substrate opposite side is thinned, the thickness after the bulk silicon substrate is thinned is 30-200 μm, and The doping concentration for the silicon substrate surveyed in advance, makes to be thinned the rear thickness of silicon chip and the doping concentration of silicon substrate into positive corresponding relation;And Opposite side progress ion implanting, laser annealing, back metal electrode are formed.
2. a kind of forming method of semiconductor devices as claimed in claim 1, it is characterized in that, step 1)In, the deep trench Depth is 10-80 μm, and width is 1-10 μm, and zanjon separation is 2-15 μm, and the doping for the bulk silicon substrate surveyed in advance is dense Degree so that the depth of deep trench and the doping concentration of bulk silicon substrate are into positive corresponding relation.
3. a kind of forming method of semiconductor devices as claimed in claim 1, it is characterized in that, step 1)In, the semiconductor Silicon substrate is N-type or p-type, and doping concentration is 1E13-1E17cm-3
4. a kind of forming method of semiconductor devices as claimed in claim 1, it is characterized in that, step 1)In, the etching is deep Increase following steps before groove:The somatomedin layer on bulk silicon substrate, the dielectric layer is silica, silicon nitride, nitrogen oxygen At least one of SiClx, thickness is 0.1 μm -2 μm.
5. a kind of forming method of semiconductor devices as claimed in claim 1, it is characterized in that, step 2)In, the injection is carried Flow subtype identical with the doping type of bulk silicon substrate, implantation dosage is 1E11-1E14 atom/cm2, Implantation Energy is 10-100Kev。
6. a kind of forming method of semiconductor devices as claimed in claim 1, it is characterized in that, step 2)In, before injection Increase following steps:First in zanjon groove sidewall and the layer dielectric of bottom grown one, the deielectric-coating is silica, silicon nitride, nitrogen oxygen At least one of SiClx, then the deielectric-coating of zanjon trench bottom is removed with anisotropic etching method.
7. a kind of forming method of semiconductor devices as claimed in claim 1, it is characterized in that, step 2)In, it is described to push away trap tool Body is:High temperature diffusion is carried out to the ion for being injected into channel bottom, it is diffused into below channel bottom 5-40 μm, and injection is expanded Layer is dissipated in channel bottom one continuous continual injection doped layer of formation.
8. a kind of forming method of semiconductor devices as claimed in claim 1, it is characterized in that, step 4)In, the ion note The species entered is at least one of B, P, As, Sb, and Implantation Energy is 10-1000Kev, and implantation dosage is 1E13- 1E17atoms/cm2
9. a kind of forming method of semiconductor devices as claimed in claim 1, it is characterized in that, step 4)In, the laser is moved back The energy of fire is 1.0-3.0J/cm2, spot length is 1-3mm, and spot width is 0.3-1.5mm;Partly led after laser annealing The body silicon substrate back side forms floor height doping implanted layer, with follow-up metal electrode formation Ohmic contact.
10. a kind of forming method of semiconductor devices as claimed in claim 1, it is characterized in that, step 4)In, the back-side gold Category electrode is formed by evaporation or the method for sputtering forms metal level at the bulk silicon substrate back side as first electrode, metal Species is at least one of Ti, Ni, Ag, Au, Al, and thickness is 0.1-2 μm.
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CN105118824A (en) * 2015-07-21 2015-12-02 上海华虹宏力半导体制造有限公司 Manufacturing method of photoetching alignment mark applied to double-layer epitaxial process
CN108550529B (en) * 2018-04-28 2021-10-15 江苏新顺微电子股份有限公司 Manufacturing method of high-voltage VDMOS device
CN109659236B (en) * 2018-12-17 2022-08-09 吉林华微电子股份有限公司 Process method for reducing VDMOS recovery time and VDMOS semiconductor device thereof
CN109830434B (en) * 2019-01-30 2022-12-23 上海朕芯微电子科技有限公司 Wafer back thinning metallization method

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CN104377238B (en) * 2010-03-05 2017-04-12 万国半导体股份有限公司 Configurations and methods for manufacturing devices with trench-oxide-nano-tube super-junctions
CN102254796B (en) * 2010-05-20 2014-05-21 上海华虹宏力半导体制造有限公司 Method for forming alternative arrangement of P-type and N-type semiconductor thin layers
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