CN104644511B - The preparation method of cosmetic composition and its marine alga sun-prevention component - Google Patents
The preparation method of cosmetic composition and its marine alga sun-prevention component Download PDFInfo
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Abstract
The invention discloses the preparation method of a kind of cosmetic composition and its marine alga sun-prevention component.Said composition includes the component of following percentage by weight relative to the gross weight of the cosmetic composition：Navel shape seaweed extract 0.01 10%, preferably 5%；Dunaliella salina algae extract 0.01 10%, preferably 5%；Haematococcus pluvialis extract 0.0001 1%, preferably 0.001%；Sea water pearls powder 0.01 10%, preferably 1%；Codium Tomentosum extract 0.01 10%, preferably 10%.The present composition can not only effectively reduce the stimulation and allergic reaction that Orangic sunscreen is brought to human body, moreover it is possible to sun-proof while repair damage skin, be kept the skin wet for skin.The preparation method novelty of the present invention uses Moisturizing Agent Used in Cosmetic propane diols as Extraction solvent, and navel shape seaweed extract, Dunaliella salina algae extract and haematococcus pluvialis extract are obtained under specific preparation condition, avoid the harm of organic solvent used in traditional extraction.
Description
Technical field
The present invention relates to the preparation method of cosmetic composition and its marine alga sun-prevention component.The invention belongs to individual to protect
Reason field, the preparation method of algae component especially with notable anti-sunlight function and combinations thereof answering in sun care preparations
With.
Background technology
Ultraviolet is the main research focus of light aging at this stage.Ultraviolet is divided into three wave bands UVA, UVB, UVC.Wherein
UVC is almost fully absorbed by ozone layer, it is impossible to reaches earth surface.UVB be wavelength be 280-320nm ultraviolet, the big portions of UVB
Divide and absorbed by epiderm skin, horn cell DNA change will not be caused, but because its energy is higher, skin can be produced strong
Light injury, even result in cutaneum carcinoma.The size of generally use SPF SPF (Sun Protection Factor) value is commented
Defensive ability/resistance ability of the valency sun care preparations to UVB.UVA is the ultraviolet that wavelength is 320-400nm, has very strong penetration power, can
Dermal layer of the skin is reached, skin collagen and elastin laminin is destroyed, causes the generation of wrinkle, its damage is cumulative, is
Light aging main inducing, while stimulation melanin generates, and causes the colour of skin uneven.Generally use SPF PA (Protection
UVA) defensive ability/resistance ability of the sun care preparations to UVA is evaluated.
Skin is after by ultraviolet radiation damage, becomes to dry immediately coarse, follows the string and gloss.Therefore, sun-proof and
It is also vital to be kept the skin wet while reparation for skin.
Modern sun-proof technology makes every effort to find some gentle skin care ingredient Synergistics on the premise of sun-proof result is ensured
To improve sun-proof result, so as to reduce sun-screening agent dosage, excitant and security risks that sun-screening agent may be brought are reduced, is developed
Go out more gentle effective high-tech sun care preparations.Patent document CN102302417A is by oceanic shellfish active peptide, ocean glue
Former protein peptides, algal polysaccharides and sun-screening agent are combined, and while sun-screening agent dosage is reduced, improve its sun-proof ability and production
Product security.Patent document CN101161231A provide it is a kind of containing mangrove extract, oyster shell powder it is safe and efficient
Suncream.But prior art do not reported using the compounding use of algae component, sea water pearls powder and sun-screening agent it is anti-to improve
Index is shone, and increases haematococcus pluvialis extract and Codium Tomentosum extract, sun-proof while repair damage skin, deep moisturizing
Water lock, realize that the water of " outer (layer) is sun-proof, interior (layer) moisturizing " moistens sun-proof Creative Science and Technology Co. Ltd, also do not provide and be is prepared by marine algae extract
The improvement of technique.
The content of the invention
Problems to be solved by the invention
Present invention aims to improve sun-proof result with gentle marine alga skin care ingredient Synergistic, so as to reduce
Sun-screening agent dosage, excitant and security risks that sun-screening agent may be brought are reduced, develop more gentle effective high-tech
Sun care preparations.
Scientific research personnel of the present invention is by the discovery that studies for a long period of time, navel shape seaweed extract, Dunaliella salina algae extract and seawater
The compounding energy Synergistic of pearl powder improves sun-proof result, and common sunscreen agent is can obviously reduce when reaching identical SPF
Dosage, so as to effectively reduce sun-screening agent may to the stimulation and allergic reaction that part human body is brought, and further add rain life
The material such as haematococcus extract and Codium Tomentosum extract, sun-proof while repair damage skin, keep the skin wet, prevent for skin
Skin sunburn, skin is allowed to remain that water moistens.
The present invention innovatively uses Moisturizing Agent Used in Cosmetic propane diols as Extraction solvent, and in specific preparation condition
Lower acquisition navel shape seaweed extract, Dunaliella salina algae extract and haematococcus pluvialis extract, avoiding used in traditional extraction has
The harm that solvent may be brought, it is ensured that the security and validity of extract.
It is an object of the invention to provide a kind of cosmetic composition, can effectively reduce the dosage of sun-screening agent, reduce
The stimulation and allergic reaction brought to part human body, sun-proof while repair damage skin, kept the skin wet for skin.And by the group
Compound is applied to the purposes in sun care preparations.
Another object of the present invention is to provide three kinds of marine alga sun-prevention components, i.e. navel shape seaweed extract, Dunaliella salina
The preparation method of extract and haematococcus pluvialis extract, using Moisturizing Agent Used in Cosmetic propane diols as Extraction solvent, avoid
The harm that organic solvent used in traditional extraction may be brought, it is ensured that the security and validity of extract.
The solution used to solve the problem
The cosmetic composition of the present invention, relative to the gross weight of the cosmetic composition, including it is as follows
The component of percentage by weight：Navel shape seaweed extract 0.01-10%, most preferably 5%；Dunaliella salina algae extract 0.01-10%,
Most preferably 5%；Haematococcus pluvialis extract 0.0001-1%, most preferably 0.001%；Sea water pearls powder 0.01-10%, most preferably
1%；Codium Tomentosum extract 0.01-10%, most preferably 10%.
The composition also contains high stability organic uv absorbers, including diethylamino hydroxybenzoyl benzophenone first
One in the own ester of acid, Uvinul T 150, ethylhexyl methoxy cinnamate, BEMT
Kind is several.The percentage by weight of the high stability organic uv absorbers is relative to the cosmetic composition
Gross weight is：Diethylamino hydroxybenzoyl benzoylbenzoic acid own ester 0.1-10%, Uvinul T 150 0.1-5%, methoxyl group
2-Ethylhexyl cinnamate 0.1-10%, BEMT 0.1-10%.
The composition also contains inorganic UV barrier, and the inorganic UV barrier includes zinc oxide, dioxy
Change one or both of titanium, the percentage by weight of the inorganic UV barrier, combined relative to the sun care preparations
Thing gross weight is zinc oxide 0.05-20%, titanium dioxide 0.05-20%.
The composition also contains moisturizing ingredient, including marine algae extract, Sodium Hyaluronate, aloe extract, reed fragrant plant glue
One or more in oil, the dimethyl ether of polyethylene/polypropylene glycol -14/7, xylitol.
The composition also repairs composition, including vitamin E, ceramide, glucan, vitamin B5 containing damaged skin
In one or more.
The preparation method of navel shape seaweed extract, including by after the grinding of navel shape seaweed marine alga, take and be put into steeping tank simultaneously in right amount
Add a certain proportion of aqueous solution of propylene glycol, the solid-liquid ratio of the marine alga and aqueous solution of propylene glycol is 1:5-1:60, propane diols water
Solution reclaimed water is 2~1 with propane diols mass ratio:1~4, stirring immersion 8-24 hours, then treatment fluid is transferred in extractor
Row microwave abstracting, extraction time are 5-40 minutes, and Extracting temperature is 25-125 DEG C, microwave power 300-1500W, by extract
Filter and produce navel shape seaweed extract.
The preparation method of Dunaliella salina algae extract, broken wall treatment is carried out to Dunaliella salina using ultrasonic wave, broken
Supercritical carbon dioxide extracting is carried out after wall marine alga liquid is vacuum dried, extraction kettle supercritical carbon dioxide temperature is 20-50 DEG C,
Pressure is 10-40MPa, carbon dioxide flow 5-20kg/h, extraction time 2-8h, and resolution temperature is 20-35 DEG C, extraction knot
Dunaliella salina algae extract is produced after beam.
The preparation method of haematococcus pluvialis extract, including using aqueous solution of propylene glycol as solvent, to haematococcus pluvialis
Homogeneous broken wall treatment is carried out, treatment fluid is then subjected to ultrasonic extraction, the solid-liquid ratio 1 of the haematococcus pluvialis and solvent：5~
60, aqueous solution of propylene glycol reclaimed water is 2~1 with propane diols mass ratio:1~4,20-40 DEG C of ultrasonic temperature, time 3-15min, power
500-900W, supernatant being taken after crude extract refrigerated centrifuge, adding cosmetics-stage ethanol after room temperature is replied, stable to stand 2-10 small
When, centrifugation, supernatant vacuum drying removes ethanol and produces extract.
The purposes that the cosmetic composition of the present invention is used in sun care preparations, the sun care preparations include sun-proof
Breast, sunlight lotion, suncream, suntan lotion, sunscreen spray, sun-proof gel, sun screen, isolation breast, isolation dew, BB frosts, shampoo, shield
Hair element, toner.
Beneficial effects of the present invention
Compared with prior art, the present invention in the preparation process of marine alga sun-prevention component using cosmetics commonly use moisturizing into
It is allocated as Extraction solvent, making extract safe and effective, skin compatibility is more preferable.The present invention innovatively prevents natural seaweed simultaneously
Shine composition and be re-dubbed composition with sun-proof barrier factor sea water pearls powder, the sun care preparations prepared by said composition has multiple
Sun-proof result, while add marine alga moisturizing factor Codium Tomentosum extract and reach skin moisturizing, prevent skin water loss after shining,
Realize that the water of " outer sun-proof, interior moisturizing " moistens sun-proof science and technology.
Embodiment
The explanation present invention in further detail below.
The cosmetic composition of the present invention is mainly by mixing oil phase and aqueous phase, and add other compositions and obtain.
Oil phase can also contain as needed mainly by having emulsifying agent, coemulsifier, emollient, sun-screening agent to form
Other compositions.
As emulsifying agent, as long as Water-In-Oil (W/O) type, oil-in-water (O/W) type emulsification sun care preparations group can be formed
The emulsifying agent of compound, is just not particularly limited, such as usable cetostearyl alcohol, cetearyl glucoside, polysorbate-
60th, Phosphoric acid monohexadecyl ester potassium, the dimethyl silicone polymer of cetyl polyethylene/polypropylene glycol -10/1, lauryl polyethylene glycol/
Polypropylene glycol -18/18- dimethyl siloxanes, the dimethyl silicone polymer of polyethylene glycol -10, polyglyceryl-3 diisostearate etc..
As coemulsifier, such as stearine, PEG-60 rilanit specials, hydrolecithin etc. can be used.
As emollient, emollient usually used in cosmetic field is may be used at, is not particularly limited.It is specific and
Speech, C12-15 alcohol benzoic ethers, dimethyl silicone polymer, octyl group polymethyl siloxane, diisopropyl sebacate, different can be used
Dodecane, ring five dimethyl silicone polymer, C16-18 alkanols, phenyl trimethicone polysiloxanes etc..
As sun-screening agent, organic uv absorbers and inorganic UV usually used in cosmetic field are may be used at
Barrier, it is not particularly limited.Specifically, organic uv absorbers diethylamino hydroxybenzoyl benzophenone first can be used
The own ester of acid, ethylhexyl methoxy cinnamate, OXYBENZONE, Uvinul T 150, double-ethyl hexyl oxy phenol anisyl three
Piperazine, butylmethoxydibenzoylmethane, octyl salicylate, 4- methyl benzyl subunits camphor, Octocrilene etc..Nothing can be used
Machine ultraviolet isolating agent titanium dioxide and zinc oxide.
Aqueous phase includes NMF, thickener, pH adjusting agent, can also contain other compositions as needed.
As NMF, as long as the NMF that cosmetic field is commonly used just has no particular limits, such as can include
Glycerine, propane diols, marine algae extract, Sodium Hyaluronate, aloe extract, reed fragrant plant glue oil, polyethylene/polypropylene glycol -14/7
Dimethyl ether, xylitol, sorbierite etc..
As thickener, can include acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymer, carbomer,
Xanthans, distearyl dimethyl amine hectorite etc..
As pH adjusting agent, arginine, sodium hydroxide, potassium hydroxide, triethanolamine, aminomethyl propanol etc. can be included.
One or more in vitamin E, ceramide, glucan, vitamin B5 with damaged skin repair
It can also be added in cosmetic composition.
The present invention carries three kinds of marine alga sun-prevention component navel shape seaweed extracts, Dunaliella salina algae extract, haematococcus pluvialis
Thing and the combination of sea water pearls powder, Codium Tomentosum extract is taken to be used for cosmetic composition.Wherein described extract safety
Effectively, skin compatibility is more preferable.In addition, by the combinations thereof of the present invention, it is gentle that the present invention solves sun care preparations simultaneously
Property, wide spectrum is sun-proof and anti-light aging, after-sun, skin moisturizing, prevents a series of problems, such as skin water loss after shining, for sea
Application study of the algae in sun care preparations field opens a new method.The present invention uses the composition of the sun-prevention component containing marine alga
Afterwards, traditional sun-screening agent dosage can be significantly reduced, reaches gentle efficient sun-proof result, and takes into account after-sun and moisturizing effect, is begun
Skin health water profit is kept eventually.
As the navel shape Porphyra marine red alga of one of natural sun-prevention algae component, its extract, which contains, can absorb UVA
Active material-class mycetocyte element amino acid (MAAs) compound, and the energy absorbed is discharged with form of heat, and it is anti-not form oxidation
Product is answered, there is anti-oxidation function, is the biological sun-prevention component of natural safety.
Based on cosmetic composition, the addition of navel shape seaweed extract is 0.01-10%.As areola shape seaweed carries
Take the addition of thing to be less than 0.01%, UVA SPF PA is not obviously improved；Such as the addition of areola shape seaweed extract
Amount is more than 10%, and more preferably, but cost is too high, does not utilize implementation for the sun-proof result of composition.The addition of navel shape seaweed extract
Most preferably 5%, sun-proof result and cost performance are optimal.
Navel shape seaweed extract is prepared by the method comprised the following steps：After navel shape seaweed marine alga is ground, take suitable
The treated marine alga of amount is put into steeping tank and adds the feed liquid of a certain proportion of aqueous solution of propylene glycol, marine alga and aqueous solution of propylene glycol
Than for 1:5-1:60, aqueous solution of propylene glycol reclaimed water is 2 with propane diols mass ratio:1~1:4, stirring immersion 8-24 hours, then will
Treatment fluid, which is transferred in extractor, carries out microwave abstracting, and extraction process takes temperature programming, and extraction time is 5-40 minutes, extraction temperature
Spend for 25-125 DEG C, microwave power 300-1500W, extract is produced into navel shape seaweed extract by membrane filtration.It is described
It is dispersed in standby in cosmetics-stage glycerine, propane diols or butanediol after the concentration of extract rotated evaporimeter, can adds appropriate
Cosmetics Common Preservatives such as Phenoxyethanol, Sensiva SC50, pungent glycol etc..
Preferable preparation condition is after navel shape seaweed marine alga is ground 30 minutes, to take marine alga treated to be in right amount put into 100 liters
Steeping tank simultaneously adds aqueous solution of propylene glycol, and wherein the solid-liquid ratio of marine alga and aqueous solution of propylene glycol is 1:20, in aqueous solution of propylene glycol
Water is 1 with propane diols mass ratio:2, immersion 24 hours, extraction time 10min is mixed slowly, Extracting temperature is 100 DEG C, microwave
Power is 300W.The navel shape seaweed extract sun-proof result prepared by this optimum condition is optimal, and test formulations add 10% navel shape
PA values bring up to 10.5 from 5.6 after seaweed extract.
Dunaliella salina as one of natural sun-prevention algae component is a kind of green microalgae of thermophilic salt, and its extract contains
Phytofluene and phytoene there is unique absorption characteristic ultraviolet, have in UVB wave bands very strong ultraviolet
Absorb, can effectively reduce damage caused by UVB.
Based on cosmetic composition, the addition of Dunaliella salina algae extract is 0.01-10%.If Dunaliella salina
The addition of algae extract is less than 0.01%, and UVB SPF SPF is not obviously improved；If Dunaliella salina extracts
The addition of thing is more than 10%, and more preferably, but cost is too high, does not utilize implementation for the sun-proof result of composition.Dunaliella salina extracts
The addition of thing most preferably 5%, sun-proof result and cost performance are optimal.
Dunaliella salina algae extract is prepared by the preparation method comprised the following steps：Using ultrasonic wave to cleaning up
Dunaliella salina carry out broken wall treatment, will broken wall marine alga liquid vacuum drying after carry out supercritical carbon dioxide extracting, extraction kettle
Supercritical carbon dioxide temperature is 20-50 DEG C, pressure 10-40MPa, carbon dioxide flow 5-20kg/h, extraction time 2-8h, solution
Analyse pressure 0.8-2MPa, 20-35 DEG C of temperature.Extraction takes out extract after terminating from separator, and extract is dispersed in cosmetic
It is standby in the emollients such as grade jojoba oil, Nexbase 2004 or saualane.
Preferable preparation condition is broken wall Dunaliella salina algae solution, and overcritical titanium dioxide is carried out after being dried in vacuo 24h in 45 DEG C
Carbon extracts, and extraction kettle supercritical carbon dioxide temperature is 40 DEG C, pressure 20MPa, carbon dioxide flow 20kg/h, extraction time
6h, parse pressure 2MPa, 20 DEG C of temperature.The Dunaliella salina algae extract sun-proof result prepared by this optimum condition is optimal, test
Spf value brings up to 25.8 from 15.2 after formula 10% Dunaliella salina algae extract of addition, improves 69.74%.
The haematococcus pluvialis that composition is repaired as natural sun-prevention are a kind of green microalgaes, and its active component astaxanthin is to long wave
HaCaT cells (Human keratinocytes) oxidativestress damage radiation-induced ultraviolet (UV) A has protective effect, can effectively hinder
Only skin photoage, protect and stimulate skin self-regeneration, reduce injury of the ultraviolet to skin.
Based on cosmetic composition, the addition of haematococcus pluvialis extract is 0.0001-1%.If rain life is red
The addition of ball algae extract is less than 0.0001%, the repair unobvious to damaged skin；If haematococcus pluvialis extract
The addition of thing is more than 1%, causes to expect that body color is deeper, influences outward appearance.The addition of haematococcus pluvialis extract is most preferably
0.001%, the repairing effect and prepared cosmetic appearance to damaged skin are optimal.
Haematococcus pluvialis extract (astaxanthin) is prepared by the preparation method comprised the following steps：Using propane diols water
Solution carries out homogeneous broken wall treatment to haematococcus pluvialis as solvent, homogeneous speed 3000-12000rpm, time 1-20min,
Then treatment fluid is subjected to ultrasonic extraction, the solid-liquid ratio 1 of extraction：5~60, aqueous solution of propylene glycol reclaimed water is with propane diols mass ratio
2~1:1~4,20-40 DEG C of ultrasonic temperature, time 3-15min, power 500-900W, supernatant will be taken after crude extract refrigerated centrifuge
Liquid, cosmetics-stage ethanol is added after room temperature is replied, it is stable to stand 2-10 hours, centrifugation, supernatant is dried in vacuo and removes second
Alcohol produces extract.Extract is dispersed in the emollients such as sun flower seed oil, white pond flower seed oil or jojoba oil used for cosmetic
It is standby.
Preferable preparation condition is the solid-liquid ratio 1 of haematococcus pluvialis and solvent:10, aqueous solution of propylene glycol reclaimed water and propane diols
Mass ratio is 1:2,35 DEG C, time 15min, power 500W of ultrasonic temperature, after crude extract refrigerated centrifuge, supernatant is taken, waits to reply
Cosmetics-stage ethanol stable is added after room temperature and stands 4 hours, supernatant is dried in vacuo into removing ethanol after centrifugation produces extract.
Haematococcus pluvialis extract (astaxanthin) the content highest prepared by this optimum condition.
Sun-proof pearl powder as one of natural sun-prevention algae component can be effectively isolated by reflection and scatters ultraviolet
UVA and UVB.Pearl powder used in the present composition is derived from sea water pearls, digests to obtain through alkali protease, preparation method peace
Entirely, gained pearl powder has no side effect to skin.
Based on cosmetic composition, the addition of sea water pearls powder is 0.01-10%.If sea water pearls powder adds
Dosage is less than 0.01%, shielding ultraviolet rays DeGrain；If the addition of sea water pearls powder is more than 10%, pearl powder is difficult to
It is completely dissolved, influences the use feeling of prepared cosmetics.The addition of sea water pearls powder most preferably 1%, the shielding to ultraviolet
Act on and use feeling is influenceed optimal.
For Codium Tomentosum extract as natural moisture preserving composition as marine alga moisturizing factor, the sulfonation containing anion is miscellaneous more
Sugar can be combined with protein and mineral matter, adjusted osmotic pressure, reached the uniform moisturizing of deep layer.With reference to trehalose, Sodium Hyaluronate
With aloe elite, the efficient replenishing water and preserving moisture of deep layer, water loss after skin solarization is prevented.
Based on cosmetic composition, the addition of Codium Tomentosum extract is 0.01-10%.If fur pine algae carries
The addition of thing is taken to be less than 0.01%, to the moistening effect unobvious of skin；If the addition of Codium Tomentosum extract is more than
10%, more preferably, but cost is too high, does not utilize implementation for the moistening effect of composition.The addition of Codium Tomentosum extract is most preferably
10%, moistening effect and cost performance are optimal.
The solution of the present invention is triple sun-proof mechanism：
Navel shape seaweed extract can absorb UVA band ultraviolets, and Dunaliella salina algae extract can absorb UVB wave bands purple
Outside line, formation wide spectrum is sun-proof, and the anti-elite of shining of marine alga can inspire UV stress protective functions automatically, resist the first layer damage of ultraviolet
Wound, this is that the first weight is sun-proof.
Sea water pearls powder from ocean isolates UVA and UVB, triggers the second weight sun-proof by reflection and scatters ultraviolet；
The oxidation resistance of astaxanthin (haematococcus pluvialis extract) is more than 500 times of vitamin E, is effectively repaired remaining
Damage of the ultraviolet to skin, light aging is resisted, it is triple sun-proof so as to reach the；Marine alga guarantor is especially added with while triple sun-proof
The wet factor (Codium Tomentosum extract) deep moisturizing water lock composition, it is truly realized the water profit of " outer (layer) is sun-proof, interior (layer) moisturizing "
Sun-proof Creative Science and Technology Co. Ltd.
The own ester of the preferred diethylamino hydroxybenzoyl benzoylbenzoic acid of organic uv absorbers, the ethylhexyl three of the present invention
Piperazine ketone, ethylhexyl methoxy cinnamate and BEMT.Wherein methoxy cinnamic acid ethyl hexyl
Ester and Uvinul T 150 mainly absorb the ultraviolet of UVB wave bands, to prevent skin turn to red because of sun burn；Lignocaine oxybenzene formoxyl
Hexyl-benzoate mainly absorbs the ultraviolet of UVA wave bands, to prevent tanned and induced skin cancer；Double-ethyl hexyl oxy phenol first
Oxygen phenyl triazine is maximally effective broad spectrum UV absorbers, and very weak 330- is especially absorbed in other three kinds of ultra-violet absorbers
There is larger absorption in 350nm regions, to make up the deficiency of other three kinds of sun-screening agents.In four kinds of sun-screening agents, methoxyl group meat
Cinnamic acid ethylhexyl is the fine solvent of other three kinds of sun-screening agents, and they have the function that Synergistic each other, can obtain more
The sun-proof result of stability and high efficiency.
The dosage of currently preferred organic uv absorbers is preferably with respect to cosmetic composition gross weight
Diethylamino hydroxybenzoyl benzoylbenzoic acid own ester 0.1-10%, Uvinul T 150 0.1-5%, methoxy cinnamic acid ethyl
Own ester 0.1-10%, BEMT 0.1-10%.
The present invention further comprises inorganic UV barrier, preferably zinc oxide and titanium dioxide, and Method of ZnO will obstruct
UVA, titanium dioxide mainly obstruct UVB.
The dosage of inorganic UV barrier is zinc oxide 0.05- preferably with respect to cosmetic composition gross weight
20%, titanium dioxide 0.05-20%.
Embodiment
First, the selection of preparation condition
(1) preparation of Sunscreen Base Formula
The Sunscreen Base Formula of table 1.
Preparation technology：1) oil phase is mixed and heated to 75-85 DEG C, untill being completely dissolved；2) aqueous phase is mixed and heated to 75-
85 DEG C, untill being completely dissolved；3) oil phase is added into aqueous phase, 2000r/min homogeneous 10 minutes.Then cool down while stirring；4) it is cold
But to 40 DEG C, other raw materials are added, stirring is cooled to less than 30 DEG C, terminates.The SPF=15.2 of obtained sunscreen composition, PA
=5.6.
(2) preparation of navel shape seaweed extract and its sun-proof result
The navel shape seaweed extract obtained according to different preparation conditions shown in table 2, with 10% content and (one) part
Basic components in other raw materials add together, investigate and with the addition of the anti-of the navel shape seaweed extract that different preparation conditions obtain
Effect is shone, its result is as shown in table 2：
The sun-proof result for the navel shape seaweed extract that 2. different preparation conditions of table obtain
As shown in Table 2, the navel shape seaweed extract obtained according to the above-mentioned different preparation conditions of the present invention, with 10% addition
Amount is added in the Sunscreen Base Formula of table 1, and SPF, PA value have different degrees of raising, and the system wherein shown in embodiment 13
The sun-proof result for the product that standby condition obtains is optimal, i.e., spf value brings up to 17.6, PA values from 15.2 and brings up to 10.5 from 5.6, is
Currently preferred preparation condition.And the navel shape seaweed extract not obtained using preparation condition of the present invention, sun-proof result are poor.
(3) preparation of Dunaliella salina algae extract and its sun-proof result
The Dunaliella salina algae extract obtained according to different preparation conditions shown in table 3, with 10% content and (one) portion
Other raw materials in the basic components divided add together, investigate and with the addition of the Dunaliella salina algae extract that different preparation conditions obtain
Sun-proof result, its result is as shown in table 3：
The sun-proof result for the Dunaliella salina algae extract that 3. different preparation conditions of table obtain
As shown in Table 3, the Dunaliella salina algae extract that is obtained according to the above-mentioned different preparation conditions of the present invention, add with 10%
Dosage is added in the Sunscreen Base Formula of table 1, and SPF, PA value have different degrees of raising, and wherein shown in embodiment 35
The sun-proof result for the product that preparation condition obtains is optimal, i.e., spf value brings up to 25.8, PA values from 15.2 and brings up to 7.4 from 5.6,
For currently preferred preparation condition.And the Dunaliella salina algae extract not obtained using preparation condition of the present invention, sun-proof result
It is poor.
(4) haematococcus pluvialis extract (astaxanthin) prepares extraction effect
The content for the haematococcus pluvialis extract (astaxanthin) that 4. different preparation conditions of table obtain
As shown in Table 4, the haematococcus pluvialis extract (astaxanthin) prepared according to the different preparation conditions of the present invention can obtain
Obtain higher content astaxanthin.And haematococcus pluvialis extract (astaxanthin) prepared by the preparation condition wherein shown in embodiment 49
Content highest, it is 0.92mg/g, is currently preferred preparation condition.And the rain life not obtained using preparation condition of the present invention is red
Ball algae extract (astaxanthin) content is low.
(5) it with the addition of the sun-proof result after natural sun-prevention component
Navel shape seaweed extract is prepared according to above-mentioned preferred embodiment 13, salt is prepared according to above-mentioned preferred embodiment 35
Raw Du Shi algae extracts, haematococcus pluvialis extract (astaxanthin) is prepared according to above-mentioned preferred embodiment 49.And it will be prepared into
To marine alga sun-prevention component add according to the different ratio shown in table 6 together with other raw materials in the basic components of (one) part
Enter, investigate influence of the marine alga sun-prevention component to sun-proof result, its result is as shown in table 6：
The sun-proof result of 5. different sunscreen compositions of table compares
As shown in Table 5, meet the sunscreen composition of instant component proportioning, can obtain good sun-proof result, these
The proportioning of composition belongs to currently preferred scope.Wherein sun-proof result is optimal for composition 22.Given birth in view of rain red
Ball algae extract (astaxanthin) is natural pigment, has considerable influence to the outward appearance of prepared cosmetics, therefore, for tighter
The visual appearance of lattice, preferred composition 16, its proportioning is navel shape seaweed extract 5%, Dunaliella salina algae extract 5% and rain
Raw haematococcus extract (astaxanthin) 0.001%, Codium Tomentosum extract 10%, sea water pearls powder 1%, the composition is added
It is added to basic components SPF=15.2；In PA=5.6, formula SPF brings up to 26.2；PA brings up to 10.6.
Inventor also further compares research and found, on the basis of the formula in composition 16, further increase
Navel shape seaweed extract, (total dosage of natural sun-screening agents, is shown in the content of Dunaliella salina algae extract to 11% i.e. in composition 16
Comparative composition 1 and 2), as a result shows, although SPF is improved, relative to SPF more by a small margin
Ground increase, greatly improving for production cost is that the present invention is undesirable.Likewise, further increase the content of sea water pearls powder extremely
11% (comparative composition 3), although SPF is improved, pearl powder is difficult to be completely dissolved, and influences preparedization
The use feeling of cosmetic, therefore, and the present invention is undesirable.
(6) influence of the natural sun-prevention component to Orangic sunscreen dosage
The preferable addition of algae component that above-mentioned experiment is proved is added in Sunscreen Base Formula, investigates and is reaching phase
In the case of SPF, the dosage of Orangic sunscreen reduction.Its result is as shown in table 6：
Table 6. compares the dosage that Orangic sunscreen reduces when reaching identical SPF
| Sunscreen Base Formula | Inventive formulation | |
| Ethylhexyl methoxy cinnamate | 5% | 1.2% |
| Uvinul T 150 | 1% | 0.5% |
| BEMT | 1.5% | 0.4% |
| Uvinul A Plus | 1% | 0.05% |
| Navel shape seaweed extract | -- | 5% |
| Dunaliella salina algae extract | -- | 5% |
| Sea water pearls powder | -- | 1% |
| Experimental result | SPF=15.2, PA=5.6 | SPF=15.2, PA=5.6 |
As shown in Table 6, in the case where reaching identical SPF, the inventive formulation of marine alga sun-prevention component is added, can
The obvious dosage for reducing Orangic sunscreen, so as to reduce the stimulation and allergic reaction that Orangic sunscreen is brought to human body.
Utilization possibility in industry
The navel shape seaweed extract of the present invention, the system of Dunaliella salina algae extract and haematococcus pluvialis extract (astaxanthin)
Preparation Method is extracted using non-organic solvent, it is ensured that the security and validity of extract.By natural seaweed sun-prevention component and chemistry
Sun-screening agent is re-dubbed composition, and effectively reducing Orangic sunscreen may go forward side by side to the stimulation and allergic reaction that part human body is brought
One step adds the material such as haematococcus pluvialis extract and Codium Tomentosum extract, is skin sun-proof while repair damage skin
Keep the skin wet, prevent skin sunburn, allow skin to remain that water moistens, can be utilized extensively in cosmetic field.
Claims (15)
- A kind of 1. cosmetic composition, it is characterised in that relative to the gross weight of the cosmetic composition, including The component of following percentage by weight：Navel shape seaweed extract 0.01-10%；Dunaliella salina algae extract 0.01-10%；Rain life is red Ball algae extract 0.0001-1%；Sea water pearls powder 0.01-10%；Codium Tomentosum extract 0.01-10%.
- 2. composition according to claim 1, it is characterised in that the percentage by weight of the navel shape seaweed extract is 5%.
- 3. composition according to claim 1, it is characterised in that the percentage by weight of the Dunaliella salina algae extract is 5%.
- 4. composition according to claim 1, it is characterised in that the percentage by weight of the haematococcus pluvialis extract is 0.001%.
- 5. composition according to claim 1, it is characterised in that the percentage by weight of the sea water pearls powder is 1%.
- 6. composition according to claim 1, it is characterised in that the percentage by weight of the Codium Tomentosum extract is 10%.
- 7. according to the composition described in claim any one of 1-6, it is characterised in that the composition also has containing high stability Machine ultra-violet absorber, the high stability organic uv absorbers include diethylamino hydroxybenzoyl benzoylbenzoic acid oneself One kind in ester, Uvinul T 150, ethylhexyl methoxy cinnamate, BEMT or It is several.
- 8. composition according to claim 7, it is characterised in that relative to the gross weight of the cosmetic composition Amount, the high stability organic uv absorbers contain the material composition of following percentage by weight：Diethylamino hydroxybenzoyl benzene Carbamoyl benzoate own ester 0.1-10%, Uvinul T 150 0.1-5%, ethylhexyl methoxy cinnamate 0.1-10%, double- Ethyl hexyl oxy phenol anisyl triazine 0.1-10%.
- 9. according to the composition described in claim any one of 1-6, it is characterised in that the composition also contains inorganic UV Barrier, the inorganic UV barrier include one or both of zinc oxide, titanium dioxide, the inorganic UV resistance It is zinc oxide 0.05-20% relative to the cosmetic composition gross weight every the percentage by weight of agent, titanium dioxide 0.05-20%.
- 10. according to the composition described in claim any one of 1-6, it is characterised in that：The composition also contains moisturizing ingredient, The moisturizing ingredient include marine algae extract, Sodium Hyaluronate, aloe extract, reed fragrant plant glue oil, polyethylene/polypropylene glycol- One or more in 14/7 dimethyl ether, xylitol.
- 11. according to the composition described in claim any one of 1-6, it is characterised in that：The composition also contains damaged skin Composition is repaired, the damaged skin, which repairs composition, includes vitamin E, ceramide, glucan, one kind in vitamin B5 or several Kind.
- 12. the preparation method of a kind of composition according to claim any one of 1-11, it is characterised in that purple including navel shape The preparation method of dish extract, the preparation method of the navel shape seaweed extract include after navel shape seaweed marine alga is ground, taken suitable Amount is put into steeping tank and adds a certain proportion of aqueous solution of propylene glycol, and the solid-liquid ratio of the marine alga and aqueous solution of propylene glycol is 1:5- 1:60, aqueous solution of propylene glycol reclaimed water is 2~1 with propane diols mass ratio:1~4, stirring immersion 8-24 hours, then by treatment fluid It is transferred in extractor and carries out microwave abstracting, extraction time is 5-40 minutes, and Extracting temperature is 25-125 DEG C, microwave power 300- 1500W, extract is filtered and produces navel shape seaweed extract.
- 13. the preparation method of a kind of composition according to claim any one of 1-11, it is characterised in that give birth to and shut out including salt The preparation method of family name's algae extract, the preparation method of the Dunaliella salina algae extract is using ultrasonic wave to Dunaliella salina Broken wall treatment is carried out, supercritical carbon dioxide extracting, the overcritical titanium dioxide of extraction kettle are carried out after broken wall marine alga liquid is vacuum dried Carbon temperature is 20-50 DEG C, pressure 10-40MPa, carbon dioxide flow 5-20kg/h, extraction time 2-8h, resolution temperature For 20-35 DEG C, extraction produces Dunaliella salina algae extract after terminating.
- 14. the preparation method of a kind of composition according to claim any one of 1-11, it is characterised in that given birth to including rain red The preparation method of ball algae extract, the preparation method of the haematococcus pluvialis extract are included using aqueous solution of propylene glycol as molten Agent, homogeneous broken wall treatment is carried out to haematococcus pluvialis, treatment fluid is then subjected to ultrasonic extraction, the haematococcus pluvialis and the third two The solid-liquid ratio 1 of alcohol solution：5~60, aqueous solution of propylene glycol reclaimed water is 2~1 with propane diols mass ratio:1~4, ultrasonic temperature 20- 40 DEG C, time 3-15min, power 500-900W, supernatant is taken after crude extract refrigerated centrifuge, cosmetics are added after room temperature is replied Level ethanol, stable to stand 2-10 hours, centrifugation, supernatant vacuum drying remove ethanol and produce extract.
- 15. the purposes that a kind of composition according to any one of claim 1-11 is used in sun care preparations, it is special Sign is that the sun care preparations includes sunscreen, sunlight lotion, suncream, suntan lotion, sunscreen spray, sun-proof gel, isolation Frost, isolation breast, isolation dew, BB frosts, shampoo, hair conditioner, toner.
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| CN108524382A (en) * | 2018-07-25 | 2018-09-14 | 周恒� | A kind of sunscreen spray and preparation method thereof |
| CN109820811A (en) * | 2019-04-02 | 2019-05-31 | 陈晓艳 | A kind of anti-aging technology based on tcm therapy |
| CN110151619B (en) * | 2019-05-22 | 2022-02-11 | 广州盛世名妍健康科技有限公司 | Sunscreen composition containing multiple active substances |
| CN111991340B (en) * | 2020-10-10 | 2022-11-08 | 广州澳希亚实业有限公司 | Composition with effects of repairing, relieving and helping sleep, preparation method and application |
| CN113786350B (en) * | 2021-09-26 | 2024-01-26 | 湖北省麦诗特生物科技有限公司 | Essence emulsion composition with freckle-removing and brightening effects and preparation method thereof |
| CN116983231A (en) * | 2023-08-21 | 2023-11-03 | 广州君奕科技有限公司 | Biological sun protection and repair barrier additive composition, preparation method and application thereof, and sun protection value testing method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2472021A (en) * | 2009-07-21 | 2011-01-26 | Jurlique R & D Pty Ltd | Cosmetic sunscreen composition |
| CN103232375A (en) * | 2013-04-03 | 2013-08-07 | 大连医诺生物有限公司 | Novel high-efficiency extraction process for astaxanthin in Haematococcus pluvialis |
| CN104224650A (en) * | 2014-06-05 | 2014-12-24 | 温州医科大学 | Large seaweed extract sunscreen skin care emulsion and preparation method thereof |
-
2015
- 2015-03-10 CN CN201510104419.6A patent/CN104644511B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2472021A (en) * | 2009-07-21 | 2011-01-26 | Jurlique R & D Pty Ltd | Cosmetic sunscreen composition |
| CN103232375A (en) * | 2013-04-03 | 2013-08-07 | 大连医诺生物有限公司 | Novel high-efficiency extraction process for astaxanthin in Haematococcus pluvialis |
| CN104224650A (en) * | 2014-06-05 | 2014-12-24 | 温州医科大学 | Large seaweed extract sunscreen skin care emulsion and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| MiSSHA M Signature Radiance Foundation SPF20;misono;《CosDNA, http://www.cosdna.comchscosmetic_9dec92503.html》;20121021;第1-2页 * |
| TonyMoly My Sunny Kids & Mom Sun Cream SPF35_PA+++;佚名;《CosDNA, http://www.cosdna.com/chs/cosmetic_5a00179785.html》;20150306;第1-3页 * |
| 盐藻中β-胡萝卜素及多糖的研究;隋晓;《中国期刊网中国优秀博硕士学位论文全文数据库（硕士）医药卫生科技辑》;20060115(第01期);第11页、第17页 * |
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